Search Documents

By D. A. Rice

As part of its mission, the U.S. Bureau of Mines continues to develop technologies that will enable cost-effective compliance with environmental requirements. To this end, investigations to improve the kinetics of chalcopyrite dissolution by simultaneous grinding-leaching in ferric sulfate solution were conducted using the Bureau-designed turbo mill. The development of such a hydrometallurgical process would provide a nonpolluting alternative to conventional smelter technology. The effects of mill rotational speed and volume percent solids on the leaching time and energy required for copper extraction from chalcopyrite were evaluated. The results of this laboratory study have shown that the simultaneous grinding-leaching of chalcopyrite concentrate using the turbomill is technically feasible with essentially 100 pet extraction of copper being possible at 90° C. An optimal energy consumption of 1,153 kW?h/st of copper leached was found in batch testing with the mill operating at 400 rpm with a slurry containing 35 vol pet chalcopyrite. This energy consumption, while higher than other proposed leaching processes (about 600 kW?h/st), is of the same order of magnitude. Further refinement of the energy requirements would require additional testing using a continuous circuit. Leaching times of less than 1 h, for 80 pct copper extraction, are achievable using the turbomill grind-leach process.

Jan 1, 2010

By E. A. Sondreal

The Bureau of Mines investigated the use of lignite char for producing carbon disulfide; CS2 production rates were as high as when wood charcoal was used as raw material. The maximum space velocity for CS2 produced in the bench-scale study was 9,280 hour-1, reacting sulfur and lignite char at 792° C. The reaction temperature and the temperature at which the char was carbonized were the two most important factors in determining CS2 production rates. Increasing the carbonization temperature in nitrogen from 400° to 900° C advanced the temperature at which carbon disulfide was first produced from 550° to 850° C. The average activation energy for reacting chars with sulfur was 44,000 cal/g mole. The reaction was first order with respect to the partial pressure of sulfur. Increasing the rate of sulfur admission caused a decrease in rate of production at otherwise similar conditions. Rates were not affected by either char size or sodium carbonate catalysis. High space velocities at moderate temperatures using inexpensive lignite chars could offer an economic advantage in the manufacture of carbon disulfide provided that yields were attractive.

Jan 1, 1967

By C. J. Wilhelm

Brine produced from subsurface formations may be employed successfully instead of fresh water as a flooding, medium in the secondary recovery of oil. The feasibility of this substitution has been proved in the shallow "shoestring" area of eastern Kansas and northeastern Oklahoma, where the supply of fresh water often is limited. In this procedure all brine produced with the oil is returned to the formation and thus is prevented from contaminating streams and fresh-water supplies. This report includes a detailed description of a "flood project" in eastern Kansas studied by the Bureau of Mines. In an attempt to determine whether brine, when handled properly, can be used as effectively as fresh water in flooding oil from partly depleted, formations, an analysis was made of all .own conditions that influence flooding.

Jan 1, 1941

By C. J. Wilhelm

Brine produced from subsurface formations may be employed successfully instead of fresh water as a flooding, medium in the secondary recovery of oil. The feasibility of this substitution has been proved in the shallow "shoestring" area of eastern Kansas and northeastern Oklahoma, where the supply of fresh water often is limited. In this procedure all brine produced with the oil is returned to the formation and thus is prevented from contaminating streams and fresh-water supplies. This report includes a detailed description of a "flood project" in eastern Kansas studied by the Bureau of Mines. In an attempt to determine whether brine, when handled properly, can be used as effectively as fresh water in flooding oil from partly depleted formations, an analysis was made of all known conditions that influence flooding.

Jan 1, 1941

By F. G. Miller, H. C. Miller

Petroleum technologists and progressive operators constantly are striving to increase the percentage of oil that may to recovered from reservoir rocks through wells. The exhaustive studies that have been made of the function of natural as in the production of oil, for example, have aided operators greatly in increasing the quantity of oil recovered from reservoirs. Natural gas dissolved in and otherwise associated under pressure with oil in reservoir rocks, however, is not the only source of energy available for moving oil through sands to wells. In becoming "reservoir—energy conscious" engineers have learned that in many petroleum reservoirs the edgewater flanking the oil accumulation constitutes a potential source of energy capable, through proper control, of increasing oil—recovery efficiencies materially. No longer is the encroachment of water into the oil— and gas—filled tart of the reservoir considered as an evil to be combatted by devious methods but rather a natural consequence, incident to the withdrawal of nil and as from the wells, that may be used advantageously in lengthening the flowing life of wells and increasing the economic recovery of oil and gas.

Mar 1, 1938

By A. L. Engel

The Stayton Mining District in San Benito County, Calif., near Hollister, includes several square miles with many occurrences of antimony ore. The sample submitted for the test described in this paper came from a vein said to have been traced and sampled for 5,000 feet on the surface, 1,500 feet carrying 2-1/2 to 3 percent antimony and the remainder 1/2 to 2 percent. Thirty thousand tons 'With a content of 3 percent antimony are said to be blocked out. A drift of 200 feet on the vein has shown ore containing 4.2 percent antimony. The present sample assayed 3.8 percent. Previous flotation investigation of this are resulted in a recovery of only 71.6 percent in concentrates containing 56.8 percent Sb. It was desired to develop a method of treatment that would give better results. The antimony in the sample occurred as the mineral stibnite, Sb2S3, antimony sulfide.

Jan 1, 1949

By G. W. Jones, F. E. Scott, R. E. Kennedy

Methylene chloride , dichloromethane CH2C12 , a low - boiling and highly volatile organic chlorinated compound, is used extensively as a refrigerant in air conditioning installations , as an intermediate in organic synthesis , and as a solvent for cellulose acetate and other materials . As its vapors are not inflammable in air at ordinary temperatures , it can be used to advantage where it would be highly dangerous to use ordinarily inflammable solvents . The question has been raised as to its inflammable range in pure oxygen and in air enriched with oxygen . To find the answer to this question, tests were carried out with various mixtures of methylene chloride , oxygen, and nitrogen mixtures . It was found that methylene chloride has wide limits of inflammability in pure oxygen . Additional tests were then made to establish the complete range of inflammability of these gases . The methylene chloride employed in the tests was cbtained from the Eastman Kodak Co. It had a reported boiling range of 40.5 ° to 42.0 ° C. and a density of 1.322 at 20 ° C.

Oct 1, 1943

By J. F. Papp

The microstructures of a CF2Br2-inhibited methane flame and its uninhibited analog have been determined using molecular beam-mass spectrometry. The slightly lean flames were stabilized on a cooled porous plug burner at reduced pressure. Composition profiles of stable, intermediate, and radical species and temperature profiles were obtained. Comparisons of the uninhibited and inhibited flame profiles revealed the following inhibition effects; a shift of the primary reaction zone to higher temperatures, a higher maximum flame temperature, an increase in the CH3 concentration, and a reduction in the H2CO, H, 0, and OH concentrations. Kinetic analyses of the data yielded rate coefficients at flame temperatures for the reactions H + CH4 ? CH3 + H2, H + O2 ? OH + O, CO + OH ? CO2 + H, and CH3 + O ? H2CO + H. CF2Br2 is judged to decay by thermal decomposition and abstraction reactions.

Jan 1, 1981

This manual provides instructions for installling, operating, and maintaining protective canopies on the Joy Mfg. Co. cutter. These instructions are based upon two actual installations: one made in a mine and one in the factory. The parts list and engineering drawings for the protective canopies are included at the end of the manual. And a discussion of some alternative design concepts is also included. The manual can also be used for retrofitting other cutters with similar protective canopies. Skilled mechanics can determine if the instructions herein would be applicable to the other cutters and can determine any necessary modifications if they are not.

Jan 1, 1973

By James S. Browning

The Bureau of Mines conducted laboratory and small--scale continuous tests of weathered mica pegmatite ores from Hart County, Ga., to determine the technical feasibility of recovering commercial-grade mica concentrates by flotation. Two modifications of the Bureau-developed anionic-cationic method were used. In one method, sodium carbonate and calcium lignin sulfonate were used for pH control and quartz depression; this method yielded mica concentrates containing 98.5 percent mica with a recovery of 91.4 percent. In the other modification, lime and sodium silicate were used with the calcium lignin sulfonate; concentrates containing 98.9 percent mica with a recovery of 86 percent were obtained.

Jan 1, 1966

By Richard L. Sayrs

The Eve Mills deposit is in Monroe County, Tenn., near the southeastern corner of the State. The deposit was examined in February 1943 by a Bureau of Mines engineer, and drilling the property was recommended to increase the on: reserves enough to justify mining should war needs require it. The deposits were explored, by 32 diamond-drill holes totaling 11,649 feet during the periods from July 1943 to November 7, 1945, and from April 1944 to August 17, 1944. The drilling campaign disclosed a large area of mineralization. The ore, however, is apparently confined to long, narrow sheets. The indicated grade of the ore bodies blocked cut by the Bureau of Mines is 4.o8 percent zinc and 2.10 percent iron.

Jan 1, 1949

By H. B. Salisbury

As a part of a research program designed to help minimize national requirements for new mineral commodities by maximizing recovery of metals from domestic secondary resources, the Bureau of Mines investigated the development of economic methods for recovering copper and associated metals from complex electronic scrap. Three types were selected for research: (1) multiple-pin plugs and connectors, (2) obsolete aircraft radio assemblies, and (3) the magnetic fraction of shredded electronic scrap furnished by the Bureau's Avondale Research Center. The plugs and connectors, after incineration to remove plastic components and melting, yielded a brittle ingot, as did the internal portion of the radio assemblies. The brittle ingots were ground to minus 35-mesh for processing, and the magnetic material was used in the as-received condition. A process using pretreated or raw scrap as a copper precipitant in various concentrations of acidulated copper sulfate solution was developed as a means of effecting an initial separation and upgrading in the form of high-grade cement copper containing all or most of the precious metals.

Jan 1, 1981

By Ed Mchugh

NIOSH researchers collected basic data from two blast rounds at the SSX-Steer Mine as a component of a larger study on controlled blasting, the goal of which is to reduce injuries from falling rocks in underground mines. Drilling and blasting procedures at the mine were observed. Rock mass property data were collected, a program of seismic monitoring and analysis was conducted, and 3-D laser survey scans of the workings before and after each blast were performed. The geologic data showed that the rock mass quality was characterized as poor to very poor. It was essentially uniform within the panels examined. The recorded seismic data indicated that fill material acted as an effective damper to seismic energy. The pre- and post-blast laser scans showed both over-break and under-break conditions, highlighting the problems associated with blasting a weak rock mass. By comparing the achieved results to the intended design, potential improvements in the drilling and blasting practices can be identified. Comparison of these data with similar data from other mines will help define how various combinations of rock and fill behave during blasting. Through studies such as these, data collection procedures and analysis techniques can be refined. An ultimate goal is to develop blast procedures tied to rock mass characteristics that can minimize damage to rock in the perimeter of the opening, limiting the amount of loose rock and improving the safety of miners.

Jan 1, 2007

By James A. Wasson

This report analyzes the petroleum-production potential of the basal Greenbrier dolomite zone, Sycamore-Millstone field, Sherman District, Calhoun County, W. Va., through the application of certain secondary-recovery methods. The well logs obtained and the core recovered from a well in this formation permitted an evaluation of the productive capability of the reservoir, Approximately 120,000 stb of oil may be produced from a 20-acre five-spot unit at breakthrough if the property is waterflooded. At an assumed limiting producing gas-oil ratio of 20)000 sef/stb, approximately 69,000 stb of oil should be recovered by low-pressure gas drive.

Jan 1, 1967

By J. B. Zadra

During the investigations of the occurrence of manganese in the western United States, the Bureau of Mines received a 100-pound sample of manganese ore from the Doyle-Smith property, Yuma County, Ariz. Laboratory tests were made to determine the amenability of this ore to standard ore-dressing methods of concentration to produce a marketable-grade product. The Doyle-Smith claims are in northern Yuma County, within 15 miles of the Artillery Peak deposit. The lot of ore used in the test work was taken from the outcrop of a large, massive, irregular bed of oxide manganese ore found on the claims.

Jan 1, 1952

By Graham W. Marks, Clyde A. Bridger

"INTRODUCTION An electrolytic process for the preparation of metallic cobalt has been developed recently in the Bureau of Mines Experimental Station at Boulder City, Nev. Chemical analysis shows this cobalt to contain impurities in small percentages, chief of which is nickel. It is desirable to be able to determine these impurities spectrographically. This report is concerned with a procedure for the spectrochemical determination of nickel in cobalt.Previous spectrographic work on cobalt was done by Breckpot and Mevis,/ who used the method of homologous pairs of lines. However, it was felt that a more detailed investigation was needed, employing the method of internal standards.ACKNOWLEDGMENTWe are indebted to B. G. Knickerbockor and his staff at the Boulder City, Nev., station of the Federal Bureau of Mines for their cooperation, and particularly to Richard W. Lewis and Robert G. Sanderson, who prepared nickel-free electrolytic cobalt for us."

Feb 1, 1948

By R. D. Berkenkotter

This report describes a weighted method for evaluating the mean and variance of assay data from samples of different length . The method , which produces unbiased estimates from which valid confidence limits can be computed , is appropriate for bedded deposits of variable bed thickness and for vein deposits of variable vein width . Assay data from the bedded Florida phosphate deposit is used to illustrate the procedure .

Jan 1, 1964

By E. C. Lane

"In a previous paper the Bureau of Mines. 3/ presented in condensed tabular form all analyses of Texas crude oils made by the Bureau up to March 193K. This previous report states;The first Al well in Texas was drilled near Oil Springs, Nacogdoches County, in 1863-67. However, the first oil field of major importance in the State was discovered at Corsicana,Navarro County, in 1895. Since that time the petroleum industry try in the State has spread and grown until today petroleum from Texas is an important commodity in world petroleum markets.Since March 1939 samples of Texas crude oils from many new fields, and some older fields not covered in the previous report, nave been analyzed. Those analyses arc reported in the present paper. The annual production by years from 1896 to 1940, inclusive, taken from the figures in the Bureau of Mines Minerals Yearbook, are given in table 1. Production for 1896-1940, inclusive, totals 6,579,715,000 barrels.Various authors reported upon developments and production in the Texas fields in the Transactions of the American Institute of Mining and Metallurgical Engineers, Petroleum Division, for 1941. 4/"

Apr 1, 1943

By P. M. Ambrose

This report describes an accident, which took place in the Chemical Corrosion Laboratory at the College Park, Md., Station of the Federal Bureau of Mines. The accident occurred while Walter L. Acherman, chemist, was performing a routine manipulation during a corrosion experiment involving commercially pure titanium and red-fuming nitric acid. There was a sudden and very violent reaction, and a large quantity of acid was thrown in the face and over the body of Acherman, causing serious injury. L. B. Golden, chief of the Chemical Corrosion Section, was exposed to nitric acid fumes during the ensuing rescue and first-aid operations and died on January 25, 1954. According to the medical report, the direct cause of Mr. Golden's death was pulmonary edema and confluent bronchopneumonia; the contributary cause, was inhalation of fumes from red fuming nitric acid. The following employees of the College Park Station contributed to this report by supplying information on the accident and assisted in the rescue operation: L. B. Golden, chief, Chemical Corrosion Section; T. E. Green, chemist; Robert Warf field, chemist; L. A. DeVivo, laboratory mechanic; D. W. Chalkley, laboratory mechanic; E. H. Neagle, laboratory welder; and R. L. Heath, laboratory general mechanic.

Jan 1, 1955

By H. W. Brandt

A field test was designed to inject a specially formulated two compound epoxy resin into the roof rock ahead of a working face to cement fractures and formation interfaces at the Westmoreland Coal Co., Winding Gulf Div., Eccles No. 5 Mine, Eccles, West Virginia. Five 30 foot long X 2 inch diameter, hold were drilled at an angle of 15° above the plane of roof line front the face of a working entry. The epoxy resin compounds were pumped through a proportioning unit and mixed in-line before being discharged into the drill hole under treatment it injection pressures up to a maximum of 450 psig. When the coal face was advanced an anomalous failure of the roof rock occurred in the treated section. Further testing was suspended until the cause of the failure could he determined. The polymers were tested, under confined conditions, in 2 inch pipe columns. Extreme temperature and pressure (up to 2400 psig) rises were recorded as they cured, It was concluded that this pressure source fractured the rock and caused the roof failure. The entire program was terminated after it was determined that the heat rise and resultant high pressures could not he controlled chemically or mechanically.

Jan 1, 1978