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By T. R. Madhavan

The development of contact angles on highly polished ?uraninite surfaces, using sodium oleate and dodecyl ammonium acetate as collectors, has been studied at different collector and hydrogen ion concentrations. It was found that sodium oleate in acidic media (up to a neutral: PH) and dodecyl ammonium acetate in neutral and alkaline media give good contact angles. It appears that the combined forms of these collectors, viz., oleic acid and free amine, are more important in effecting contact. W ITH the emergence of uranium as a strategic metal in the last fifteen years, considerable effort has been directed toward the commercial recovery of uranium from its ores. This has resulted in the development of a uranium technology. It is only in recent years, However, that fundamental data regarding the floatability and surface properties of uraninite and ?pitchblende have been elucidated by different methods. Contact-angle measurement is one of the important tools for tl1e evaluation of the conditions of floatability

Jan 1, 1964

By E. Ozberk, N. Gibson, W. G. Davenport

"In the 1950s, Canada produced more than ninety-five percent of the non-communist world's nickel and achieved dominance in terms of production, technology and pricing policies.Over the past thirty years there have been dramatic changes in the nickel industry to the extent that Canadian production is now less than thirty per cent of the total.In this document we have presented statistics relevant to this transformation and reviewed the technology, particularly with regards to energy and environmental considerations.Under the new market conditions nickel producers are likely to face more difficult competition than they have encountered in the past.The economic scene and measured nickel reserves dictate that for the purpose of increasing production, new nickel smelters will not be built in Canada in the foreseeable future. However, in order to reduce sulphur dioxide emissions, Canadian nickel smelters will possibly go through some modifications or rebuilding.IntroductionThis paper presents a review of the Canadian nickel industry in relation to the world nickel industry. Major changes are described which have occurred in the characteristics of the nickel market over the last thirty years. The pre sent status of the nickel market with respect to Forecasting future trends is reviewed and attempts are made to predict what further changes will take place in the next two decades. Comparisons are made of the economics of producing nickel from sulphide ores and oxide ores and the advantages and disadvantages the Canadian nickel producers face.A brief critique of the existing and emerging nickel production technologies in Canada and the world is carried out and attempts are mad e to predict the changes which may take place in the foreseeable future."

Jan 1, 1983

By T. A. Wheat

"The presently increasing world-wide interest in advanced ceramic materials is generally focussed on their exploitation in both structural and functional applications. With the opportunity to engineer microstructures and thereby closely control and tailor the final properties, there are many new applications being made for these materials in both areas.The scope and some of the applications for functional ceramics are reviewed and examples of the present Canadian activity in this field are discussed.BackgroundThere has been progressively increasing international interest in the development and exploitation of ceramic materials in the last five years. The stimulus for this interest arises from several quarters, each of which are independent of the other.• There is a growing awareness of the strategic nature and vulnerability of supply of the raw materials used to produce high performance metal alloys.• The metal alloys are reaching the upper temperature limit for their performance as structural components in engines.• The dramatic increase in oil prices during the late 1970s focussed attention on the need for reduced consumption in many sectors, i.e., there is a need for more efficient engines that operate at higher temperatures - above those tolerated by the present superalloys.• A number of ceramics, especially the structural materials such as SiC, A120 3, AI20rSi02, Si3N4 and the Sialons are produced using non-strategic raw materials and they can exhibit startling performance-auto turbo-rotors are in production mad e of Si3N4 that operate up to 190000 rpm at 600°C, 150000 rpm at 900°C.• Ceramic s are generally of lower density - significant in the weight-reduction of automobiles such as the replacement of a 20-kg five-segment steel leaf spring with a single segment carbon-fibre reinforced unit of 3 kg. • Ceramics also offer major ad vantages in generating, monitoring or controlling the electromagnetic spectrum whether in bulk or thin-film devices that exploit optical, magnetic, pyroelectric, piezoelectric, electronic and I or ionic conductivity characteristics.The opportunity to combine several of these char acteristics in a single material by composition, processing and microstructural design has resulted in an advanced ceramics industry that had world-wide sales in 1980of $4.2 billion (U.S.)(I) and is predicted to grow to sales in the range $7 to $10 billion by 1990 and $16 to $24 billion by the year 2000(2). However, at present, advanced ceramics account for less than 20010 of the total ceramic market."

Jan 1, 1987

By John A. Allan

The subject chosen for this paper is not a new one, but the subject matter is so extensive that something new can always be said .about it. We are just beginning to realize how little is actually known about the character of Alberta coal, except for a few general facts. The object of this paper is not to explain that our previous information, in whole or in part, on the coal resources of Alberta, has been incorrect, but rather to present some new facts obtained as a result of recent study in the field and in the laboratory. As field investigation continues the problem of determining the character of a coal seam for any great distance laterally becomes more and more complex. Our present knowledge of Alberta coal deposits should not be discussed before due reference is made to those great pioneers who blazed the trails for later geologists, by recording their observations on the general geology of Alberta. Geologists, to-day, particularly those of us who are striving, year after year, to unravel the mysteries of stratigraphy, palaeontology, and structure, in so far as these are related to the coal resources of Alberta, fully realize our indebtedness to those three trail-makers, Dawson, McConnell, and Tyrrell. Had these geologists not recorded their observations correctly, nor interpreted the broad geological facts contained in Nature's book, with still uncut pages, how much slower would have been the progress of our coal knowledge in the succeeding years. It is true that many of the interpretations given to observations by these pioneers have had to be changed as a result of closer studies, but we must also expect that the geological interpretation from present day observations will be changed by future workers, as Nature's book is read and re-read.

Jan 1, 1925

By J. Manchisi

This study has investigated the use of blast furnace slag as functional adsorbent for metal ions in acid mine drainage treatment. This opportunity has not yet been developed into a practical process partly because of limited understanding of rates and mechanisms of adsorption process and inconsistency in interpretations of adsorption data. The overall objectives were to determine the efficiency and mechanisms of sorption process of metal ions in a multiadsorbate system. We employed standard materials characterisation techniques to analyse composition, structure and surface morphology of the slag. Batch adsorption experiments were then conducted to study the mechanisms, kinetics and efficiency of metal sorption as a function of pH, phase ratio, mixing time, mass and particle sizes of slag. Both XRF and adsorption data suggested the slag to possess acid neutralising capacity. This slag is non-crystalline based on XRD pattern, has adequate porosity and pore volume comparable to similar commercial adsorbents but it has inferior pore structure, pore size distribution and BET surface area to be effective under wide applications. Metal sorption increased with decrease in slag particle diameter, decrease in initial metal concentration and increase in the mass of slag. Although slags have demonstrated to efficiently treat low concentrations of single and multiadsorbate effluents using fine particle sizes, they have limited capacity to treat multiadsorbate systems for some metal ions. This is probably due to low affinity, competitive adsorption or limitation in material?s adsorptive properties. Sorption mechanisms probably involve precipitation and ion exchange on the basis of alkaline pH and exchangeable slag surface ions. Sorption preference is proposed as Fe2+>Cu2+>>Cd2+>Co2+>Mn2+. Despite these limitations, deeper understanding of sorption behaviour of metal ions by slags for application in dilute and large volumes of effluents is necessary where precipitation and other standard techniques are either inefficient or uneconomic. Thus, this study has established that sorption capacity of slag to remove metal ions from acidic effluents is selective, limited to certain metal ions and for other ions only at low concentrations. Further adsorption studies in multiple solutes under various experimental conditions or those that can propose an economic slag activation process are needed that improves or widens adsorption window.

Aug 1, 2013

By A. Ockewitz, A. Trondl, D. -Z. Sun

"Numerical simulation of extrusion processes offers an efficient method for tool design and optimization of geometries and properties of extruded parts. However, until now there are few systematic investigations about influences of material model and different parameters e.g. for friction and thermal processes on calculated local and global responses. Since extrusion processes are essentially influenced by friction between billet and extrusion tools, new friction tests were performed in this work to develop a reliable friction model. Compression and torsion tests were performed at different temperatures and velocities to calibrate the material model for extrusion simulations. Extrusion processes for circular rods and U-profiles were conducted at TU Berlin with backward and forward extrusion for different extrusion ratios, billet temperatures, product velocities and cooling conditions. This work focuses on numerical simulations of the extrusion tests with the FE code HyperXtrude. Based on the calculated distributions of local strain, strain rate and temperature the recrystallized volume fraction and grain sizes were calculated with empirical models and compared with the experimental results from optical micrographs and EBSD scans. The calculated total and friction forces and temperatures were compared with the experimental results and the deviations between experiment and simulation were analyzed.INTRODUCTION Extruded aluminum components are widely used in vehicle constructions due to light weight and manufacturing consideration. Local mechanical properties in the components are inhomogeneous as a consequence of the spatial distribution of microstructure which is influenced by numerous factors like material composition, temperature, tool design, friction, extrusion ratio and speed during the extrusion process. For the optimization of the extrusion process with regard to all these factors numerical simulation can be an essential tool. Based on results of finite element simulations of the extrusion process the microstructure in the extruded components can be predicted and then the resulting mechanical properties can be numerically determined instead of by costly trial and error methods. The aim of the work presented in this paper is the development of a numerical method for the simulation of extrusion processes with modeling of microstructure."

Jan 1, 2018

By Ruan Chi, Zhenyue Zhang, Zhengyan He

In order to understand what governs the leaching of exchangeable rare earth (RE) and impurities and enhance the RE leaching process, the effects of the concentration of ammonium sulfate, pH and leaching temperature on the migration of RE and aluminum (Al) during the leaching of weathered crust elution-deposited rare earth ore was studied. The elution curves for ammonium ion (NH4 +) were also studied to reduce the consumption of the leaching agent. It was found that a high concentration of leaching agent can enhance the leaching process of RE and Al, reduce the breakthrough volume of NH4 + and more rapidly obtain the equilibrium of NH4 +. However, excessive leaching agent can both increase the cost and the burden on the environment. There is almost no variation on the elution curves of RE and Al in the pH range of 4-8 and control of the pH of the leaching agent can be omitted. It is better for the leaching work to be done in summer since higher temperatures can enhance the RE leaching process and improve the use ratio of ammonium. Using 0.1 mol/L ammonium sulfate for leaching 250 g RE ore, 95.42% RE extraction can be obtained when the volume of leachate is 102.6 mL. At this moment, only 18.17% of NH4 + is used to exchange RE and 49.22% of NH4 + is left in the leachate that can be reused as leaching agent by replenishing ammonium sulfate. The results of our studies can provide theoretical guidance for high efficiency and low consumption exploitation of RE ores.

Jan 1, 2016

By R. B. Roberts, A. L. Mular

A simple way to determine the IEP of oxide minerals is described. The method is shown to apply for fine powders of Fe203 and ZnO. The IEP lies at pH 6.95 for Fe203 and at pH 9.08 for ZnO.

Jan 1, 1966

By R. A. Gannicott

Trend surface analysis was used to investigate the geochemical dispersion patterns of Si, Ai, Fe, Mg, Ca, Na, K, Ti and Rb in the footwall of the Seneca massive sulphide prospect in southwestern British Columbia. Surfaces for various element ratios were also produced to see if the distributions of the elements are related to each other. Trends developed by the elements redistributed during hydrothermal alteration may be difficult to detect for various reasons, such as too few and widely separated sample points, random analytical errors or local variations in rock chemical composition that are not related to regional trends. Trend surface analysis is useful to distinguish regional trends from local fluctuations. The computer program used in this study is capable of calculating surfaces up to the 6th degree polynomial, but provides for automatic termination when the variables in the equation for successive surfaces become effectively collinear. With the relatively small number of data points used (21 samples) in this study, such termination occurred after the quadratic surface. Results show that, at the Seneca prospect, Mg and K increase, and Na and Ca decrease, toward a common centre which corresponds closely with the best drill-core intersections of ore. The centre is interpreted as a volcanic vent and as the source of mineralization . Quadratic surfaces for element ratios show that K/Ca decreases and Fe/Mg increases away from this vent. Thin-section and X-ray diffraction analyses indicate that these variations reflect sericitization of plagioclase and an increase in the Mg content of chlorite near the vent. The mineralization , rock types and element dispersion patterns at the Seneca prospect are similar to those reported for volcanogenic massive sulphide deposits at Bathurst, New Brunswick, and in the Hokuroko district of Japan.

Jan 1, 1979

By B. R. Schneiders

"Atikokan is 200 km west of Thunder Bay and earned its mining fame from the discovery of the Steep Rock Iron Range in the late 1930s. Gold, however, was discovered in the Atikokan and Mine Centre areas in the late 1800s and eventually led to one of Ontario's first gold camps, and a total production of approximately 52,000 oz of gold and 174,000 oz of silver from 218,000 tons milled.The general geology of the area consists of Early Precambrian rocks of the Wabigoon and Quetico subprovinces, separated by the east-trending Quetico Fault. The Wabigoon Subprovince, to the north, consists of metavolcanics, minor metasediments and granitic batholiths. The Quetico Subprovince consists of metasediments and granitoids. Small ultramafic plutons occur throughout the metasediments.Within a 50-km radius of Atikokan, more than 50 gold occurrences, prospects and past producers have been discovered since the 18oos. The Atikokan Gold Study performed by the Ontario Geological Sur vey (Wilkinson, 1980, 1982) defined three types of gold mineralization in which gold is concentrated in quartz and quartz-carbonate veins:I) Metavolcanic-Hosted, Stratabound Type-associated with altered felsic fragmental units and chemical sedimentary rocks; possible gold mineralization source rocks. The mineralization is due to metamorphogenic (epigenetic) enrichment. Associated with dynamic metamorphism events and/or felsic intrusive events.2) Marmion Lake Batholith Type-occurs within the gneissic core of the batholith associated with north east-trending lineaments, representing faults or shear zones. Mineralized veins are related to several periods of deformation and shearing, suggesting that metamorphogenic veins were produced during dynamic metamorphism.3) Contact Zone Type -occurs in the contact zone rocks between gneissic batholiths and meta volcanic belts. Hydrothermal solutions produced during several deformational periods acted to leach and concentrate gold mineralization. Localized, discontinuous shear zones host the epigenetic (metamorphogenic) veins.Twenty-one properties in the area were mapped and sampled, and researched petrographically and geochemically. Geological data from the Atikokan Economic Geologist Program of the Ontario Geological Survey are used in discussing the types of mineralization, genetic models, and exploration targets and techiques."

Jan 1, 1983

By A. R. MacPherson

"This paper considers four aspects of autogenous grinding. Part 1 discusses statements on power efficiency of autogenous grinding compared to conventional crushing and grinding systems. It also demonstrates how high-power efficiency can be obtained from autogenous grinding systems. Part 2 considers a simple method of testing ores to determine the type of autogenous plant which can treat these ores on a commercial basis. A comparison of testing for simple small plants vs large plants or complex ores is included. Part 3 considers important aspects which have to be considered in proper design of an autogenous grinding system. Part 4 discusses problem ores and how they can be treated in an autogenous system. INTRODUCTIONAfter about 35 years of using autogenous grinding plants in the mining industry, it is perhaps time to review where we are with this, by now, relatively old development. Autogenous grinding in this paper means grinding run-of-mine ore by fully autogenous means or by using a ball charge to assist the grinding (semi-autogenous). Also, autogenous grinding can be eitherby dry or wet.The use of autogenous grinding in the fifties was making its slow start, and it was not until the sixties that more of the mining industry would consider its use . By the seventies, most builders of new plants would have considered autogenous grinding, whether they used it or not, in the final design.In the eighties, most large plants use autogenous mills and to reduce over-all operating costs, many older conventional plants are now looking and actually retrofitting these old plants with autogenous grinding mills.It is evident that many misconceptions concerning autogenous grinding are still current. Some come from improperly designed plants which result from poor test work. There are many considerations in the proper design of autogenous plants. Some ores have been found to give problems even in a well designed plant. These ore types are beginning to be classified and recognition in the test stage allows steps to be taken in the design so that these ores can be efficiently handled in autogenous grinding plants.Therefore, this paper will address the following aspects of autogenous grinding:1. Misconceptions regarding autogenous grinding.2. Testing of ores to ensure a well designed commercial plant.3. Important considerations in mill design.4. Difficult ores, their recognition and types of design to handle such ores."

Jan 1, 1989

By H. D. S. Miller

"Artificial stope support has become an essential component of many underground mining operations. Because the use of cable bolts in open stopes is a relatively new concept, most support is still designed by trial and error or by rules of thumb. This often results in costly overdesigned support or inadequate support which leads to stope failure.This paper proposes guidelines to determine support requirements using the stability graph method. The stability graph method is an empirical open stope design technique that takes into account the key factors that influence stope stability. The factors for the design of a cable bolt support system include bolt length, bolt intensity and the original rock mass competency and can be estimated using empirically calibrated charts. The empirical charts were developed based on more than 60 case histories of cable bolting success and failure in Canadian open Slope mines.The concept of pre reinforcement and supp ort stiffness will also be discussed.INTRODUCTIONArtificial support, in the form of rock anchors, has become an important component of all underground mining operations because its stabilizing effect contributes to make underground workings safer. There are several types of rock anchors featuring different properties and having a variety of functions. This paper focusses on grouted cable bolt applications in large open stope mining. Such a support system may improve the competency of the disturbed rock mass to a point approaching the undisturbed rock quality by limiting joint movement and dilation. This results in more stable, possibly larger and, thus, more efficient production stopes."

Jan 1, 1989

By A. Glover

As the demand for natural gas as a prime global energy source continues to grow, the search for new sources of the fuel spreads into geographical areas that are more remote from the marketplace. Along with this comes the need for longer and ever more efficient pipelines. This requirement for higher value in natural gas transportation is satisfied to a large extent through the application of high strength technology and innovative design approaches that support increased design and operating pressures. This paper reviews the latest accomplishments and successes in these technologies for use in gas transmission. It also explores some of the technologies which are targeted for the future to allow the industry to achieve even higher benchmarks in reliability and cost-effectiveness. The central element in the theme of high strength technology for gas pipelines is that of high strength steel. From tensile strengths of Grade 359 a few decades ago, more and more operators are now specifying Grade 550 linepipe for their large diameter projects. As well, Grade 690 steel is operating successfully in limited transmission applications and Grade 825 has recently been installed. With the introduction of the latest high strength pipe comes the need for high strength fittings. The industry's first Grade 550 fittings were recently specified and installed on a project with Grade 825 line pipe. High strength materials can only be implemented successfully if compatible design and construction processes are in place. The latest developments in strain- and reliability based design will be described as well as the corresponding advancements in welding and inspection technology.

Jan 1, 2005

Adaptive processing is often related to the mineral composition of the mining block currently processed. The portions of waste, ore and secondary product minerals considered are always positive and typically sum to 100% (i.e. a composition). A typical solution to predict block averages of spatially dependent quantities would be block kriging. However, kriging is based on spatial correlations and it has been repeatedly shown that correlations of compositional data are spurious and blurred by the constant sum constraint. Aitchison (1982) proposed a general solution for compositional problems, based on transforming the compositional data to a set of logarithms of ratios of components, and analysing the transformed scores. The transform is chosen to be invertible to ensure that no information is lost in the process. This methodology avoids spurious correlation problems and ensures coherence between results obtained with different subcompositions. Pawlowsky-Glahn and Olea (2004) adapted the approach for point-support geostatistics, allowing the prediction of point compositions from spatially neighbouring data, without the artefacts induced by standard multivariate cokriging. Unfortunately upscaling the results of this approach with block cokriging is not straightforward, because of the nonlinearity of logratio transforms. Furthermore, we have to consider those nonlinearities created by the dependence on the block composition of extraction efficiency and processing costs of the possible processing choices. This paper proposes a solution for predicting the conditional expectations of the benefit of processing the block with each processing choice using geostatistical simulations of the local values of the composition and the resulting block integrals. The computation for a large number of blocks can be done efficiently using Cholesky decomposition. The approach also allows the calculation of prediction errors for expected compositions and expected benefit at almost no additional computational cost. Such compositional approach is necessary, for example when processing choices depend on proportions of certain minerals after other components have been removed; or if processing alters the composition in a multiplicative way, by partially removing a portion of some components.

Aug 1, 2013

By B. D. H. Knights, M. A. W. Bryson

Flotation of PGM ores, specifically UG-2, presents a number of technical challenges. These centre on the prevalence of chromite. Subject to over-grinding, chromite is primarily recovered to the flotation product through entrainment. This is of unique concern as it must be kept below a threshold for downstream smelting, with significant operational and monetary penalties being imposed should it exceed this concentration. A number of strategies have been developed to maximise PGM recovery in the presence of this unwanted contaminant. Specialised flowsheets form a vital basis and advanced control algorithms further enhance PGM recovery while minimising the recovery of chromite. Advances in Mineral Processing Science and Technology Proceedings of the 48th Annual Conference of Metallurgists of CIM Sudbury, Ontario, Canada Edited by

Jan 1, 2009

By Dirk Claessens

The term ?cost? is too small when describing the destructive power of safety incidents for mining companies. Breaches in employee or environmental safety are felt way beyond the bottom-line: human life can be taken; ecosystems tarnished; the ire of peoples, media and government inflamed; significant halting of production; and high levels of legal and financial challenges. According to a recent survey of Mining executivesi, ?ensuring workforce safety? was the most important issues identified above any other, with a plurality of 31 percent, reigning above capital projects, product efficiency, and equipment reliability. We accept that safety is a most paramount issue, yet for many reasons we keep approaching the problem the same way we have in the past. We need to stop doing the same things decade over decade and try something new. New innovations are significantly changing the fundamentals of how mining companies explore, excavate, produce, refine and distribute their valuable commodities. Technologies such as visualization, analytics, location awareness, and gaming simulation are making these enterprises smarter. Now, attention turns to an area we?ve long held as integral to our business: safety. By using the same breakthrough technologies that are changing our business, we can now boldly imagine ? and credibly strive for ? a world of zero incidents.

Aug 1, 2013

By M. Pötsch, A. Kluckner, P. Söllner, W. Schubert

"The in situ block size is a key parameter in the geomechanical characterization of rock masses. It describes the fracturing of the rock mass and thus is a measure for the degradation of the rock mass strength. Several classification systems use the in situ block size. For instance, the Geological Strength Index (GSI) requires the “blockiness” and joint surface condition factor as key input parameters. The “blockiness” has recently been related to the in situ block volume (Cai et al., 2004). Due to the limited information about the internals of a rock mass, it is not possible to determine the in situ block size directly. Currently, the in situ block size is determined by calculations using oversimplified models, vague estimations or, due to the lack of relevant information, it is neglected. As remote measurement systems have become available for rock mass characterization, a more comprehensive record of discontinuities can take place. Measurements can be performed on exposed rock outcrops and in particular on tunnel faces and walls, delivering the location, orientation, spacing and persistence of discontinuities at an arbitrary number and locations. An estimation of the in situ block size at the same level of sophistication is still not available. This paper aims at examining the relationship between visible and measureable information at the rock surface, and the in situ block size. Three-dimensional block model simulations were performed using the block model engine of the distinct element code 3DEC. Initial investigations focussed on the minimally required observation area in order to obtain reliable block size distributions. Based on a representative volume element, a reference distribution of the block area at the observation area for a specific discontinuity system was determined. Subsequently, the size of the observation area was decreased stepwise and each new distribution was compared to the reference distribution. For all analyzed systems, it turned out that the mean block area must be smaller than 1% of the observation area to achieve a reliable block size distribution. Further simulations focussed on discontinuity systems with three non-persistent sets. The results were compared to the formula proposed by Cai et al. (2004). A transformation factor T was introduced which replaces the persistence terms in Cai et al.’s proposed formula. The factor describes the correlation between block volumes generated by persistent and corresponding non-persistent discontinuity sets. The simulations included the variation of the discontinuity set spacing, persistence, and orientation. The mean and additionally the 25%-, 50%- and 75%-quantiles of the block size distribution were analyzed. Examining all values for the transformation factor the distribution can be described by a power function with a negative exponent. The function depends on the persistence only. Finally, the results of random simulations were compared to the analytical formula using the transformation factor. The predicted mean and selected quantiles show a good agreement with the simulation results. It gives a comprehensive picture about the block size distribution in discontinuity systems with three non-persistent sets."

Jan 1, 2015

By H. Higuchi

The Sumitomo Metal Mining Company Ltd. (SMM) started to produce electrolytic nickel at the Niihama Nickel Refinery in 1939. In 1992, the conventional matte electrorefining process was converted to the matte chlorine leach electrowinning (MCLE) process, which is currently in practice. SMM has mainly used two kinds of nickel matte as the raw material for the MCLE process. Treatment of new raw materials, which have different impurity contents from the original nickel matte, has become mandatory because of changes in the market. Therefore, the MCLE process has been required to increase its flexibility to treat the different impurity contents in the new raw materials. An increase in the capacity for iron removal is included in such requirements. A new iron removal circuit in the MCLE process, based on a process development study, was recently installed. The iron removal circuit is in operation, and efforts are currently underway to optimize the performance of the circuit by changing the present operating parameters. In addition to the removal of the iron, the application is also expected to improve the nickel recovery. The outline of the new circuit and the current iron balance in the MCLE process are described in this paper, together with the effect of the circuit on iron treatment capacity.

Jan 1, 2006

By R. Baker

A novel electrochemical half-cell and corresponding working electrode were designed to evaluate the electro-catalytic activities of catalysts in an environment close to that of an operating proton exchange or polymer electrolyte fuel cell (PEMFC). Cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) techniques were employed using the novel cell to characterize various methanol electro-oxidation parameters that contribute to the overall reaction on a fuel cell anode. The effect of temperature on methanol oxidation kinetics was examined in the potential range of 0.31 to 0.65V (vs. NHE). The data was collected in the temperature range of 20 to 80°C. Based on the experimental analysis and literature data, an equivalent circuit model (ECM) for methanol oxidation was proposed and was used to fit the EIS experimental data. The experimental data and ECM electrochemical data was used to extract electrochemical kinetic parameters for methanol oxidation such as the exchange current density, Tafel slope, and energy of activation for the reaction. Kinetic data, especially at different temperatures, is very limited in the literature.

Jan 1, 2005

By Q. Han

Irradiation of high energy ultrasonic vibration in metals and alloys generates oscillating strain and stress fields in solids, and introduces nonlinear effects such as cavitation, acoustic streaming, and radiation pressure in molten materials. These nonlinear effects can be utilized to assist conventional material processing processes. This article describes recent research at Oak Ridge National Labs (ORNL) and Purdue University on using high intensity ultrasonic vibrations for degassing molten aluminum, processing particulate reinforced metal matrix composites, refining metals and alloys during solidification process, welding, and producing bulk nanostructures in solid metals and alloys.

Jan 1, 2014