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By B. Chareyre, H. Pourpak, L. Scholtès, E. Papachristos

"Numerical methods used to study hydraulic fracturing in low permeability rock masses need to take into account the interaction between the progressive failure mechanism of the intact rock matrix and the pre-existing natural fractures. A fully coupled hydro-mechanical 3D discrete elements model dealing with such interaction is presented here. The ultimate objective is to grasp the role of the rock-matrix failure on the propagation of the main fluid driven fracture under different stress fields and pre-existing fracture orientations. The proposed method provides the spatiotemporal distribution of the induced crack events which can be tracked during the simulations, making possible the identification of the local mechanisms leading to macro-failure in the rock matrix or reactivation of the discontinuity planes. Fluid flow inside a fracture, pressurized crack and hydro-fracking experimental tests were simulated as part of the validation process of the model and, are presented in this paper.INTRODUCTIONWith the expansion of shale gas and geothermal reservoirs exploitation, the technique of Hydraulic Fracturing (HF) has been widely used over the past years (McClure, 2012; Britt, 2012). Despite recent advances in micro-seismicity analysis or numerical modeling (Nagel et al., 2013), the way progressive failure of rocks affects the fluid flow depending on the in situ stress conditions or the rock heterogeneities is not fully controlled yet (Zoback, 2010).In this work we focused on setting up a three-dimensional discrete elements model to study fluid driven fractures propagation. The intact rock is modeled by a discrete element method (DEM) able to reproduce fracture initiation and propagation (Scholtès and Donzé, 2013, Garcia et al., 2013). The pre-existing fractures are explicitly modeled and can be individually defined or be part of a discrete fracture network (DFN) (Harthong et al., 2012). Their mechanical response is fully coupled with the fluid within a HM-DEM framework. The fluid flow and it’s interaction with the intact matrix and the pre-existing discontinuities is modeled through a Pore-scale Finite Volume (PFV) scheme specially enhanced for fractured rock modeling (Chareyre et al., 2012, Catalano et al., 2014) ."

Jan 1, 2015

By Alan A. Barton

Introduction The Little Long Lac mine is situated in the Thunder Bay mining district, township of Errington, Ontario. The mine is located on the south side of the most westerly bay of Little Long Lac. The property consists of 36 claims, which comprise some 1,400 acres. This group of claims was staked in August, 1932, by Tony Oklend and Tom Johnson, and, after surface sampling, was optioned by the present controlling interests, who diamond-drilled it during the winter of 1932-33. In early spring, a small steam-driven plant was installed, and shaft sinking commenced on June 1st, 1933. During the summer, all supplies are transported to the mine from Hardrock station, at mileage 18 on the Canadian National Railway line from Longlac to Port Arthur. At Hardrock, which is seven miles from the mine, the railway skirts a bay of Little Long Lac, and supplies are loaded directly from railway cars to scows. Two scows are used, of 30-and 45-ton capacity, respectively. A 36-ft. pointer, powered by a 35 h.p. engine, is used as a tug. A good winter-road has been cut out from Geraldton to the mine, for winter transportation. Geraldton is about two miles north of the mine, and is also located on the Canadian National railway. A hard-surface road is now being constructed for summer as well as winter use. Geology The Little Long Lac gold area covers the northern limits of a large synclinal structure, the contact of the Keewatin flows and sediments, striking about twenty degrees north of west, with the dip of the sediments varying from eighty degrees north to seventy degrees south, the average being around eighty degrees south. The vein worked by Little Long Lac Gold Mines occurs in massive sedimentary rock of about the composition of arkosic or quartzitic greywacke, and consists of a shear-zone up to fifteen feet in width, striking N.75°E. and dipping steeply to the south, which has been filled by numerous narrow, parallel quartz veins and. veinlets. These are well mineralized. with arsenopyrite, pyrite, and some chalcopyrite and stibnite, and carry considerable quantities of visible gold. They show more than one age of quartz deposition, the quartz being fractured and re-cemented. The arkosic rocks separating the veins and veinlets are also slightly mineralized with pyrite. Work to date has indicated the probability that the vein-shear is controlled by local drag-folding.

Jan 1, 1935

Operating CIP/CIL gold recovery plants in the arid regions of Western Australia face unique challenges due to water and ore quality issues. The presence of cations of Mg, Fe and Cu metals in water supplies and leached sulphide ores can have considerable effect on plant consumption of lime and cyanide, due to pH buffering and complexation effects. Reagent costs are critical to many of these operations. In this paper, computational modelling is used to analyse a number of process options to mitigate such issues. This requires careful consideration of the chemistry of the process system, and the ability to predict accurately the response of speciation and precipitation reactions to changing process conditions. The Mg-Fe-Cu-CN-H20 system is specifically modelled in this application. The Gibbs Free Energy Minimisation thermodynamic framework has been selected to model equilibrium phenomena. Furthermore, this approach has been extended to the process flowsheet level, incorporating multiple unit operations and recycle streams in a steady-state mass balance model. The Gibbs equilibrium composition module of HSC Chemistry software has been successfully integrated into the commercial flowsheeting package SysCAD. Consideration of the Gibbs Energy Minimisation capabilities of other flowsheeting packages has also been given. This approach has been successful in simulating the aqueous process chemistry typical of such plants. It has resulted in a predictive capability where equilibrium states respond appropriately to process changes. Potential cost savings may be identified by examining alternative process conditions to minimise overall reagent consumption.This methodology may be extended to other hydrometallurgical plants where issues of solution ideality, temperature and other equilibrium processes are sufficiently understood.

Jan 1, 2005

By Farzaneh Abedini, Narain Hariharan, Lucas C. McFarlane, Nikolas A. Romaniuk, Tiffany Thayne

The use of dewatered mine tailings as backfill material (commonly referred to as ‘paste’ backfill), is the most practiced form of backfill in Canada providing significant environmental benefits by reducing the size of external tailings facilities and improved economics through enhanced resource recovery. Paste backfill operations reuse filtered mine tailings with a cementitious binder and water to create a slurry that is hydraulically transported to refill underground stopes, later forming a structural network of cemented tailings in the mine stopes. Unlike typical structural applications that utilize General Use (GU) Portland cement; modern paste backfill operations maximize strength performance by blending Portland cement with ground granulated blast furnace slag (GGBFS) or other supplementary cementitious materials (SCMs). GGBFS and other SCMs offer key performance benefits and carbon reductions; however, the availability of these SCMs is rapidly dwindling in today’s carbon-constrained economy. This paper examines the development of an alternative binder system that provides similar performance and carbon reduction to that of GGBFS for mine backfill operations. The binder utilizes the chemical reaction between a reactive source of aluminosilicates and available calcium from calcium oxide or calcium hydroxide to replace between 50 to 100% of GGBFS. The performance of the binder is examined with insights into the hydration mechanisms that generate mechanical strength in the cemented paste network. Paste backfill slurries require precise engineering to create a material that maintains flowability during pipeline transport and generates enough strength to meet operational targets once placed in the stopes. Engineering of such slurries requires large amounts of water to be added to the binder-tailings matrix, far exceeding the typical water to binder ratios used in concrete mix designs. This characteristic of paste backfill warrants great emphasis on understanding the hydration mechanisms of the binder used in the paste backfill system. GU cement is typically composed of 50-70% tricalcium silicate and 15-30% dicalcium silicate.  The hydration mechanisms of these compounds consume 4 to 6 units of water to mineralize into calcium silicate hydrate cemented phases that result in compressive strength development. Cementitious aluminate and aluminosilicate phases make up 5-20% of GU cement and aid in secondary performance characteristics such as set time. Certain calcium aluminate hydrate phases such as monocarboaluminate and ettringite mineralize 10 to 32 units of water into their crystalline structure. Hydration products such as ettringite are traditionally avoided in construction applications due to their propensity for volumetric expansion after cement setting, leading to micro-fissures and subsequent strength degradation (known as ‘sulfate attack’). This paper proposes that such hydration products benefit the strength development in paste backfill slurries with the aforementioned characteristics due to their greater potential to mineralize free water. The newly developed calcium aluminosilicate binder is designed to replace 50-100% GGBFS or other SCMs used in paste backfill systems and meet operational strength requirements by providing exceptional hydration characteristics through cementitious reactions. Additionally, the aluminosilicates used have a minimal carbon footprint and a secure supply outlook, thereby allowing mine operators access to a low-carbon binder option throughout the mine’s lifespan.

May 4, 2025

By H. R. Huffman

"This paper reviews the history of iron powder production, and outlines the varions production methods. The uses of iron powder and the reasons for its use are also covered. The paper concludes with a look at future trends in powder metallurgy.INTRODUCTION TO POWDERSTHE IRON POWDER INDUSTRY is enjoying a very rapid growth. The annual consumption of iron powder is now at the 100,000-ton level, twenty times higher than it was at the end of World War II, and the yearly in-crease bas been almost consistent at 20 per cent. This is expected to increase, bringing the tonnage to 200,-000, or even (according to some experts) to 270,000, in 1970. In any event, powder metallurgy is expanding at high speed and making an important impact on the production of iron and steel products. Some indication of the faith in the future market may be indicated by the commencement of three new powder production plants in Canada with a total capacity of 136,000 tons annually."

Jan 1, 1969

By Narasimha Mangadoddy, Balraju Vadlakonda

"Bubble size distribution, bubble rise velocity and gas and solids hold-up are the key major hydrodynamic parameters that are extensively used for column flotation design and performance evaluation. The distribution characteristics of mean gas hold-up is studied using electrical resistance tomography (ERT) coupled with pressure transducers (PT) in column flotation. The ERT technique facilitates non-invasive and nonintrusive visualization of different flow regimes even in the presence of particles in a column flotation. The effect of superficial gas velocity, feed flow rate and slurry height in the column on mean gas hold-up and its radial distribution has been analysed for both two-phase and three phase flows. Experimental results show ERT coupled with PT is suitable as an online monitoring tool to provide useful information on the three-phase flow hydrodynamic parameters of the column flotation. The tomography images, which were generated using a modified sensitivity back projection algorithm, are employed to explore the influence of parameters in two phase flow in column flotation. Mean gas and solids hold-up values extracted from ERT have been critically analysed for the column operating in various flow regimes. Gas hold-ups and solid hold-ups results using ERT are in very good agreement with conventional estimation and correlations obtained using pressure transmitter methods. Meanwhile, the results show that the gas hold-ups in the centre region increase constantly with an increase in the superficial gas velocity, whereas solid hold-ups distribution is very heterogeneous for high gas velocity. Furthermore, the results also indicate that ERT is a very powerful tool for diagnosing the 'inside' flow behaviour of gas –liquid–solid three phase flow in columns operating for a wide range of flow regimes.INTRODUCTIONColumn flotation is perhaps the most significant technological innovation in flotation machinery and its successful introduction in mineral processing plants. There has been a lot of attention in understanding the various mechanisms that take place during operation. Due to many reasons column flotation has been found to yield better performance than conventional flotation cells, particularly with fine particles (Honaker & Mohanty, 1996). Due to complex flow behavior in nature, the performance of column flotation influenced by on flow characteristics of the process, (Jena, Biswal, Das, & Reddy, 2008). Previously basic research is carried out to evaluate the effect of the hydrodynamic parameters on performance of column flotation (Finch, J.A.;Dobby, 1991). Many techniques have been developed that could be used to experimentally analyse the hydrodynamics of column flotation. Tomography techniques are well sound to investigate the hydrodynamics for process equipment. Among that, Electrical resistance tomography (ERT) has been used in various industrial investigations for visualization of the concentration profiles and characteristics of the fluid dynamics in gas–liquid two-phase systems (Wang, Dickin, & Mann, 1999; Williams, R.A; Wang, 2000). ERT is an imaging technique to analyse the internal flow behavior non-intrusively. ERT provide very useful tools for measuring and monitoring of column flotation process on line. Due to its high speed capability, low cost measurement, robust sensors, ERT is considered to be the most powerful tool among other tomography techniques such as positron emission tomography (PET), magnetic resonance imaging (MRI), optical and infrared tomography. Application of ERT has extended in process systems due to its improved speed of data acquisition, sensitivity, flexibility and noise immunity. In multiphase flow of bubble columns, gas hold-up and solid hold-up are explored by using the coupling of ERT and difference pressure method (Jin, Han, Yang, & He, 2010)."

Jan 1, 2016

By Xiaoguang Zhao

The coal mining area in Northern Shaanxi, China, has been taken as the study area, and the damage mechanism of the ecological environment is discussed on the basis of analyzing the characteristics of natural eco-environment and resource development in this area. Mining subsidence is taken as an example, and by using the Gray Correlation Analysis method, the key impact factors have been selected. An assessment model with fuzzy comprehensive evaluation has been constructed, and 12 coal mines have been quantitatively assessed. This paper also constructs an ecosystem health assessment method and index system in the coal mine area on the basis of ecosystem health theory, and assesses the ecosystem health status in the Shenfu coal mining area from 2000?2006. The research results are expected to help the eco-environment protection process in the designated coal mining area.

Aug 1, 2013

By M. J. Nicol, T. Moyo

Ammoniacal solutions are an effective lixiviant for the oxidative dissolution of some mineral sulphides. A detailed study of the anodic dissolution of chalcopyrite in ammonium sulphate-ammonium hydroxide solutions has been carried out using cyclic voltammetry, chrono-amperometry and rest potential measurements. The role of the copper(II)/copper(I) redox couple in the oxidation process has been evaluated. Rest potentials have been found not to be affected by oxygen but to increase with an increase in initial copper(II) concentration. Pseudo-steady-state anodic current densities measured in the absence of copper(II) ions at the rest potentials obtained in the presence of copper(II) ions increase with increasing concentration of copper(II) ions, confirming the positive effect of copper(II) ions on the rate of dissolution of the mineral. Cyclic voltametric and chrono-amperometric data show that in the absence of initial copper(II) ions, the rate of dissolution in the presence of dissolved oxygen is significantly lower. These results confirm that the effective oxidant for the mineral under the conditions of the study is copper(II) and not dissolved oxygen. Coulometric measurements have been used to establish the stoichiometry of the anodic reaction at different potentials.

Jan 1, 2014

"A growing public awareness of work-related diseases such as pneumoconiosis and the impact of this awareness on legislative bodies and on the skilled labour market are reasons why the Canadian mining industry must consider dust control of top-drawer importance. Measurements and standards related to the hazard are necessary to control a dust situation and to avoid excessive risk. The author discusses some of the methods of measurement, standards proposed and terminology used in this developing technology. The purpose primarily is to give a better understanding of the basic advances achieved by those who have applied current knowledge with a measure of success."

Jan 1, 1972

By D. Mas Ivars, K. Suzuki, J. A. Vallejos

"A comprehensive geotechnical characterization has been undertaken at the El Teniente mine to describe and determine the rock mass behaviour strength properties of the primary copper ore. The Synthetic Rock Mass (SRM) modelling approach is used to simulate the mechanical behaviour of this heavily and unfractured rock mass. The micro-parameters of the model have been calibrated against mechanical properties and scaling laws for intact rock and veins, in order to represent virtual samples of four different geotechnical units. Results can be used to predict the rock mass scale effects, anisotropy, and brittleness properties that cannot be obtained using empirical methods.INTRODUCTIONThe primary copper ore at the El Teniente mine is described as very competent and massive, given that it exhibits a brittle behaviour (Rojas, Cavieres, Dunlop, & Gaete, 2000). This description is coherent with the geological description of the rock mass, which does not have discontinuities match as the definition provided by International Society of Rock Mechanics (ISRM, 1981). Only faults can be classified as discontinuities, but they are widely spaced. The primary copper ore has a high frequency of veins, where the cooper mineralization is hosted, these vein network structures are known as stockwork. Soft veins containing weak minerals as infill (chalcopyrite and anhydrite) control the disassembling of the rock mass during caving (Brzovic & Villaescusa, 2007).Presently, there are mainly two traditional methods used to estimate the strength of the rock mass: 1) determination of the strength envelope of the rock mass using scaling parameters from laboratory tests and 2) using numerical modelling based on back analysis of previous experiences of failure observed and measured in mining or civil excavations. The primary copper ore of El Teniente mine has no fractures; therefore, it is difficult to determine a rating that would enable to scale laboratory data, such as, RMR (Laubscher, 1977) or GSI (Hoek, 1994). This is the reason why the first option is not valid unless the entry data is manipulated or adjusted in order to obtain reasonable results. The second option requires, in general, a good characterization of a previous failure event in the rock mass, which is not always available. In recent years, new techniques of numerical modeling have been developed (PFC3D, ELFEN, Abaqus). Those methodologies are the third way to estimate the strength of the rock mass, but they are still in development. Particularly, the concept of SRM developed by Itasca is implemented in this study (Pierce, Mas Ivars, Cundall, & Potyondy, 2007; Mas Ivars et al., 2011), aiming to capture the real behaviour of the rock mass."

Jan 1, 2015

By H. Blaha, H. Wagner

"Room and pillar workings in salt mines are preferred sites for underground waste disposal. A critical issue in selecting waste disposal sites is long-term behaviour of such workings. The long-term behaviour of salt pillars is controlled by the pillar geometry, i.e. the height, width and length of pillars and the level of pillar stress. The latter has a strong influence on creep characteristics of salt pillars whereas the width to height ratio of salt pillars determines the strength of pillars and the deformation characteristics of salt pillars.Three different regimes of pillar creep behaviour of salt pillars can be distinguished, namely a stress level below which the rate of creep approaches a value of zero, a stress range where the rate of creep is constant and finally a stress level above which the rate of creep accelerates. Long-term stability of room and pillar workings can be assured only when the pillar stress level falls within the first stress regime. Strength and creep tests on model salt pillars have shown that at stress levels below 40% of pillar strength the rate of creep approaches a value of zero, between stress levels of 40% and 65% the rate of creep is constant but increases with stress level. Above pillar stress levels of 65% the rate of creep accelerates.Long-term measurements of pillar deformation and surface subsidence above relatively shallow room and pillar workings in salt mines have confirmed these observations. Long-term strength of salt was found that be between 60% and 65% of short term strength. The evaluation of salt pillar behaviour on the basis of critical pillar stress levels was found to be superior to the traditional factor of safety concept because it allows relating pillar deformation measurements to actual pillar conditions. The approach described in the paper was used successfully to evaluate the stability of room and pillar workings in a salt mine and to design strategies to stabilise critical pillar workings."

Jan 1, 2015

By M. Mbonimpa

Field experimental cells were constructed in 2007 to assess the performance of different cover scenarios for the reclamation of the Parc 1 tailings disposal facility at the Westwood-Doyon Mine site (Abitibi, Quebec). Three configurations of cover with capillary barrier effects (CCBEs) with different thicknesses and material types for the moisture retention layer (MRL) were studied. MRL with 80 cm till, 40 cm till, and 40 cm clayey silt were used for cell nos. 2, 3, and 5, respectively. The capillary barrier layer (CBL) and drainage and protection layer (DPL) of the CCBE consisted of 30 cm gravel. A reference cell without cover was also constructed to compare the geochemical performance of the CCBEs. Due to an unexpected flooding in the leachate exit area of the cells in spring 2008, the cell instrumentation for hydrogeotechnical monitoring was postponed to spring 2009. Changes with time in volumetric water content, suction, soil oxygen concentration, and temperature were measured at different depths. This paper presents and discusses preliminary results obtained from spring 2009 to autumn 2010. In all cases, the degree of saturation Sr is lower in the CBL than in the MRL, indicating the presence of capillary barrier effects at the interface of these layers. Cell nos. 2 and 5 showed hydrogeotechnical behavior typical of an effective CCBE, with Sr maintained above 85% in the MRL and lower than 30?50% in the DPL and CBL. Based on the obtained results, and as expected, MRL thickness and the type of construction material used appear to affect the hydrogeotechnical behavior of the CCBE. Oxygen concentration profiles through the CCBEs were used to estimate the oxygen flux, and results indicate that cell nos. 2 and 3 performed better than cell no. 3. CCBE performance is currently being investigated using the geochemical monitoring data.

Aug 1, 2013

By Hongpu Kang

The fully mechanized top coal caving mining method has been the main mining approach for thick coal seams with high output and efficiency in Chinese coal mines. The gateroads for the top coal caving mining faces should be driven along the floor of the thick coal seam with a part of the seam as roof. The support of the gateroads is commonly difficult because of the low strength and broken structures of the coal seams, and the increasingly large section of gateroads meeting the need of greater and greater face coal output. Based on the analyses on the geomechanics properties and production conditions of the top coal caving mining, the influences of the top coal caving mining parameters on the stability of gateroads, including mining thickness and face length, are studied. The deformation and damage features of the rock mass surrounding the gateroads with the top coal seam as roof are investigated, the interaction of the support with the surrounding rock mass, the support theory are studied. The bolting design method and criteria, bolting forms and parameters for the gateroads with the top coal as roof are put forward. The rock bolting components, including bolt bars, face plates, cable tendons, meshes, and steel straps, are introduced. Finally, the gateroad bolting effects are evaluated through a typical case study on the basis of field monitoring data, such as the displacement of surrounding rock mass and the forces along bolts and cables.

Aug 1, 2013

By N. W. Xu, M. D. Wei, F. Dai, B. Li

"Chevron notched samples achieve general acceptance for measuring the Mode-I (opening mode) fracture toughness of rocks. The cracked chevron notched semi-circular bending (CCNSCB) sample, which is developed from the International Society of Rock Mechanics suggested the cracked chevron notched Brazilian disc method, has recently received much attention. However, these chevron notched methods have not been fully mastered, some ideal assumptions based by their theories and formulas, such as the straight-through crack assumption (STCA), have not been verified detailedly. Fractures of CCNSCB specimens were numerically simulated considering different heterogeneities, geometrical and mechanical parameters. The results show that, the real fractures of CCNSCB specimens are never satisfied with the STCA. In fact, micro fractures not only occur in the notch tip but also the two chevron edges. Consequently, the crack front features prominently in a shape of parabolic curve, far from being straightthrough. Moreover, curvature of the crack front is only affected by shape of the chevron ligament. Cracks usually start from two sides of the notch tips rather than center of the notch width, and propagate deviating from the postulated fracture routes. These fracture mechanisms induce errors with the measurements, and thus more attentions should be paid to the real fractures of the chevron notched samples for measuring fracture toughness more accurately. INTRODUCTIONWith the increasing requirement of people for resources and energies, frequent rock engineering activities have been conducting, such as underground excavation, oil exploration and deep burial of nuclear waste. Many problems appear in rock fracture. Consequently, there are more and more attentions paid in rock fracture mechanics due to its broad application prospects for solving these engineering problems. Since Mode-I (opening mode) fracture is the most common failure mode in rocks, Mode-I fracture toughness is a primary parameter to predict rock mechanical properties in actual engineering, and thus its accurate values are necessary to the researches of rockburst, rock mass slope stability, rock cutting, hydraulic fracturing, tunneling, et al. Therefore, it is thus significant to evaluate and study relevant methods to obtain the reliable value."

Jan 1, 2015

By S. Caron

From the early 70?s, ?Centre de Recherche Minérale? (CRM) has conducted and co-ordinated Research and Development activities for the mineralurgical and metallurgical industries. Since 1999, CRM has continued its mandate through COREM which is a consortium of 13 members that uses the benefits and advantages of collaborative pre-competitive industry / university research. In particular, COREM?s ?In-Situ Optimization Group? is involved in the implementation of modern optimization and control tools. The POP Project was launched in order to increase and consolidate the use of modern optimization and control tools and methods for mineralurgical and metallurgical processes. To ensure a successful transfer in the industry, there are a number of essential activities that have to be undertaken. These activities have been identified by COREM?s members and are grouped into three main modules: - R&D Module: Research and Development in universities, research centres and other partners; - Technology Transfer Module: integration of new tools and methods into the POP Software, industrial applications and technical support; - Training Module: education of new engineers in universities, continuing education of plant personnel through on-site workshops and resource networking by specific information exchange tools. This paper outlines the opportunities that led to the definition of the POP Project and describes its main modules. The main features of the POP Software are presented, the first application is described and finally, future developments are discussed.

May 1, 2001

By E. P. Wiechrnann, C. M. Castro, G. A. Vidal

In copper Eta plants the optimal current density setpoint depends on the electrolyte composition and temperature. However, conventional plants operate with large standard deviations. A value of 14% with current densities offsets up to ±50% is typical. For worst, during opencircuit or shortcircuit events this variation can be from -100% to +200%. Naturally, energy consumption and copper quality are compromised. Several devices have been successfully employed to reduce set point deviations. Last developments include; Optibar Segmented Intercell Bars, Outotec Electrodes Arranging Method and NTC Selective Electrodeposition Enhancers. This paper researches and compares these technologies. It is shown that short circuits can be effectively reduced in occurrence and magnitude. Moreover, 95% of the electrodes can be forced to operate within ±10% of the set point. The specific energy consumption is reduced from 2,000 KW per Ton to values close to 1,900 KW per Ton.

Jan 1, 2011

By Jason Mewis

Jason Mewis is the founder and president of ENGCOMP, a consulting engineering firm in Saskatoon Saskatchewan focusing on the mining sector. He has over 17 years of experience working on projects for the heavy industrial market in Saskatchewan, as both a Senior Structural Engineer and Project Manager. Jason is an entrepreneur with experience in many areas including estimating, planning, facilitation, and Risk Analysis. He has presented at many seminars and conferences across North America on the subject of Project Risk and and has become recognized for his expertise in this area of project management.

May 1, 2013

By John Wightman

LOCATION OF PROPERTY THE property of Caribou Gold Mines, Limited, is situated in the north-eastern part of Halifax county, seven miles south of the Canadian National railway line at Upper Musquodoboit. Approach to the village is by a secondary road, improved recently by waste rock from the mine dump. A two-wire telephone line, seven miles long, built and owned by the present operators, provides communication to the nearest telephone exchange, Parker's Corner. HISTORY In 1870, the Caribou area was recognized as a proclaimed gold district. From then on, operations were intermittent, with periods of considerable activity by small companies until there were no fewer than seven mines in a district two miles long by three-quarters of a mile wide. These were the Holman, Truro, Caffrey, MacDonald or Elk, Lake, Dixon, and Hilchey properties, all of which have had separate stamp-mills, and have produced gold for varying periods. Depths of the workings range from 100 feet to 1,000 feet. Power was generated at each property by means of steam boilers. At the present time, the Consolidated Mining and Smelting Company of Canada, Limited, controls all the leased areas, approximately 800 acres, and is operating by means of one central vertical shaft. GEOLOGY The district in and about Caribou Mines has an elevation of approximately five hundred feet above sea level. The area is fairly well wooded, with rock outcrops here and there. These outcrops, along with information from test-pits and shafts, have been the basis for the very excellent geological map of the district prepared by E. R. Faribault some years ago. The rock structure, which is one of the best examples in Nova Scotia of an elliptical dome, has its anticlinal axis in a northeast-southwest direction, and flat plunges in the same directions.

Jan 1, 1938

By Chuan-Jian Zhong

Gold-based nanoparticles in the size range of a few nm have attracted increasing interests in catalysis, sensors and biomedical applications. The study of the unique catalytic properties of nanosized gold was inspired by the pioneering work of Haruta on the nanogold-catalyzed CO oxidation (1-4). There have been a number of excellent reports discussing both fundamental and application aspects of gold nanoparticles in catalysis (3-8). Our work reported herein is aimed at investigating the preparation and application of gold and its alloy nanoparticles for potential applications in fuel cell catalysis. Fuel cells operating by electrochemical oxidation of hydrogen or methanol fuels at the anode and reduction of oxygen at the cathode are attractive power sources due to their high conversion efficiencies, low pollution, lightweight and high power density. While methanol offers the advantage of easy storage and transportation in comparison with hydrogen fuel cell, its energy density (~2000 Wh/kg) and operating cell voltage (0.4 V) are much lower than the theoretical energy density (~6000 Wh/kg) and the thermodynamic potential (~1.2 V). The poor activity of the anode catalysts and inefficient activity or issue related to "methanol cross-over" at the cathode electrode are associated with the loss of about one-third of the available energy at the cathode and the other one-third at the anode. Extensive studies have been focused on Pt-group metals (Pt+Pd+Rh+Ru+Ir (PGM)) for both anode and cathode catalysts. A major problem is the poisoning of Pt by COlike intermediate species (9,10). Recently, oxide-supported gold nanoparticles in the <10 nm size range have emerged as one of the best catalysts for CO oxidation (1-3,11), and for water gas shift reaction in reforming stage using 5 nm Au on Fe2O3 (6). Gold and its alloy with other metals in the nanosize range present new alternatives (2,12). Whether the unique properties of gold nanoparticles can be exploited for addressing these problems is a focus area of our work. The ability to harness the large surface area-to-volume ratios and the unique surface sites of nanoparticles in <10 nm size range, especially in heterogeneous catalysis, constitutes a major driving force in fundamental research and practical applications of nanoparticle catalysts. It is this size range over which the metal particles undergo a transition from atomic to metallic properties. The understanding of factors controlling the morphological and surface reconstitution associated with such a size range is of fundamental importance to the ultimate exploration of nanostructured catalysts. We have been investigating the interfacial structures and properties of core-shell types of nanoparticles consisting of gold or alloy nanocrystal cores and organic monolayer shells that were prepared by twophase synthesis (13) and processing (14) protocols. Important attributes of such nanoparticles include controllable size monodispersity, processibility, and stability towards size- and composition-tunable catalysis (15-21). Some of these attributes were studied for understanding their electrocatalytic properties in the oxidation of methanol and reduction of oxygen, which are of fundamental interest to fuel cell technology.

Oct 1, 2003

By B. J. McKay, K. Schneider, H. B. Nadendla

"A series of experiments were conducted to assess the impact of zinc additions on the morphology and soundness of the interface of Al-Mg compound castings. It was found that high amounts of zinc (>15wt%) are necessary to affect the morphology and microstructure of the interface. At these zinc concentration levels, the formation of the zinc-rich phases t1 and ? were observed along with the Al-Mg intermetallic phases ß and ?. The micro hardness of all phases across the interface was found to be similar, ~200 Hv. This even hardness gradient is thought to avoid mechanical failure in the interface under load. In samples containing large concentrations of zinc (>15wt%), the formation of bubble shaped voids as well as the complete transformation of the aluminium alloy was observed. While the exact mechanism causing the voids has not been identified it thought to be connected to the Kirkendall effect. INTRODUCTION Conventional single material components are increasingly failing to meet the demands, in terms of cost and performance, of the transport industry. Compound castings have been identified as a promising alternative as they possess a number of benefits (Bührig-Polaczek, Röth, Baumeister, Nowack, & Sussmann, 2006). Compound casting is described as a process in which a metallic melt is cast around a solid metal shape. Preliminary research has concluded that for the stability of such a resultant hybrid structure it is imperative that both metals form a sound connection via form closure, force closure, or material bonding. A continuous material bond between the two metals is also highly desirable as the formation of a crevice between the metals could lead to galvanic corrosion, particular in a humid environment (Lao, 2013; Rübner, Günzl, Körner, & Singer, 2011). Even though Al-Mg compound castings could offer the biggest potential in terms of weight savings to date only a limited amount of research concerning such structures exists."

Jan 1, 2018