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By Erin Legault Seguin, Mike Rylatt, Curtis Mohns

"With energy costs increasing and ore grades diminishing, the role of pre-concentration in hard rock mining operations has been gaining greater interest. To maximize energy conservation, the pre-concentration process should be conducted at as coarse a crush size as possible while minimizing losses of pay metals. Dense medium separation (DMS) is a robust process that can be conducted at particle sizes as coarse as 300 mm and as fine as 500 µm with high separation efficiency, depending on liberation characteristics of the value minerals. The DMS process involves three steps: feed preparation, dense medium separation, and ferrous-based media recovery. This paper discusses each of these processing steps, but focus will be given to the dense medium separation stage. Various types of DMS equipment are reviewed. Pilot plant campaign case studies conducted at the SGS Lakefield site are presented, which have included a variety of mineral systems such as spodumene, sulphide-bearing gold ores, and complex sulphide ores. These case studies demonstrate that for amenable ores, mass rejection of 20-60% is possible while maintaining recoveries of greater than 90% in most cases.IntroductionPre-concentration is a process of rejecting mass of gangue while ensuring recovery of valuable minerals prior to more intensive, downstream processing. Pre-concentration has been practiced in industry for many years, and is gaining greater interest as the industry copes with processing lower grade, more difficult ores, typically requiring finer grind sizes and higher energy costs."

Jan 1, 2016

By C. H. Lee, K. Adham, D. Lemieux, J. P. Mai, A. M. S. Hussein, S. Francey

Copper concentrates contain an increasing amount of arsenic, as the older sources of cleaner ores are depleted. At the same time, the market-determined price penalties on arsenic rich concentrates are rising due to limited arsenic treatment capacity at smelters and increasingly stringent environmental emissions limits, necessitating arsenic removal from the copper concentrates. Heating the concentrate to about 700°C can remove significant amounts of arsenic (as elemental and/or sulfide); however, it is important to achieve that removal economically and with due consideration to post-roasting arsenic (toxic waste) treatment. A comparison is made among different roasting options (kilns, multi-hearths and fluid beds) to qualify their potential application to arsenic roasting of copper concentrates. Both direct and indirect methods of heating as well as inert, air and oxygen atmosphere options are considered. Technology comparisons are made with respect to the roaster’s operation, its off-gas treatment and arsenic stabilization. INTRODUCTION In the last twenty years, the arsenic content in globally produced copper concentrates have risen steadily due to the depletion of cleaner ores and the increase in complex concentrate production. Smelter contracts typically limit arsenic to less than 0.5wt%, with a penalty paid per unit of additional arsenic and other contaminants such as antimony. While penalties can vary, they can be on the order of $70/dry metric tonne of concentrate per 1% of arsenic. Strategies used by miners to avoid the price penalties have been to blend clean and complex concentrates, and to remove arsenic from complex concentrates to achieve smelter limits. Arsenic can be removed from copper concentrates by the heat-induced decomposition of the predominant enargite mineral (Cu3AsS4) at ~700°C. Roasting at such elevated temperature is a commercially proven option, but still suffers from process, cost and environmental challenges. After roasting, the released arsenic sulfide fumes can be separated from most of the entrained concentrate dust in cyclones. Then, the As2S3 laden off-gas can be oxidized to generate a still volatile oxide (As2O3), which can be further separated from the residual concentrate dust in a hot electrostatic separator. Next, the off-gas can be cooled with air or water, to either deposit the arsenic oxide in a dry or dissolved state. Dissolved arsenic acid can be oxidized to As(V) and reacted with iron to yield a stabilized ferrihydrite precipitate or scorodite that can be safely disposed. In the case of dry arsenic trioxide, it can be mixed with reactants (e.g. iron) and fluxes before thermal stabilization in a glass matrix, thus eliminating the need for costly oxidation.

Jan 1, 2019

By K. G. Thorne, L. J. Cabri, L. R. Fyffe, D. R. Lentz, D. Hoy

"Mineralization at the Main zone of the Clarence Stream gold deposit in southwestern New Brunswick occurs within a parallel series of quartz veins that occupy a NE-trending, steeply north-dipping, brittle-ductile shear zone related to the nearby terrane-bounding Sawyer Brook fault. This deformation zone cuts volcaniclastic sedimentary and volcanic rocks of the Silurian Waweig Formation, and is intruded by mantle-derived East Branch Brook gabbroic dikes and a number of felsic dikes. Intermittent shear-zone reactivation during local magmatic activity induced heterogeneous deformation and alteration of the country rocks and dikes. The terminal phase of shearing is associated with narrow pegmatite-aplite dikes that grade laterally into granophyric granite, and into an auriferous quartz vein. Gold, aurostibite, and gold-antimony intergrowths, predominantly with vein quartz, are associated with a low ƒO2 sulfide mineral assemblage (pyrrhotite, arsenopyrite, and berthierite) that has a sulfur isotopic signature consistent with a magmatic source. Gold saturation and deposition occurred episodically between 300° and 360°C at low activity of sulfur, predominantly in response to pressure reduction during brittle failure combined with the effects of decreasing temperature and sulfidation reactions during fluid-wall-rock interaction. Geochronological studies demonstrate that the timing of the emplacement of the pegmatite-aplite dikes and associated auriferous veins overlap with that of the Early Devonian Magaguadavic granite. Moreover, the composition of the dikes is consistent with their derivation from this granite as late fractionates. The Main zone of the Clarence Stream deposit is therefore interpreted to be intrusion-related, with the Magaguadavic granite being the ultimate source of the gold-bearing fluids. La minéralisation de la zone principale du gisement aurifère de Clarence Stream dans le sud-ouest du Nouveau Brunswick occupe une série de veines de quartz parallèles dans une zone de cisaillement fragile-ductile de direction NE et à pendage abrupt vers le nord apparentée à la faille de Sawyer Brook avoisinante qui délimite deux terranes. Cette zone de déformation recoupe les roches volcaniclastiques et volcaniques de la Formation de Waweig d’âge Silurien et est recoupée par les dykes de gabbro d’East Branch Brook, d’origine mantellique, ainsi que par divers dykes felsiques. La réactivation intermittente de la zone de cisaillement durant l’activité magmatique locale a entraîné la déformation et l’altération hétérogènes des dykes et de l’encaissant. La phase finale du cisaillement est associée à de minces dykes d’aplite-pegmatite qui passent latéralement à des granites granophyriques, puis à des veines de quartz aurifères. L’or, l’aurostibite et les intercroissances d’or et d’antimoine principalement associées aux veines de quartz sont associés à un assemblage minéral de sulfures à faible ƒO2 (pyrrhotite, arsénopyrite et berthierite) présentant une signature isotopique du souffre compatible avec une source magmatique. La saturation en or et la précipitation a eu lieu épisodiquement entre 300° et 350°C dans des conditions de faible activité de souffre, principalement en réponse à la baisse de pression durant la rupture fragile ainsi qu’aux effets de la baisse de température et aux réactions de sulfuration durant l’interaction entre le fluide et l’encaissant. Les études géochronologiques indiquent que l’âge de la mise en place des dykes de pegmatite-aplite et des veines aurifères qui leur sont associées coïncide avec le granite de Magaguadavic, d’âge Dévonien Précoce. De plus, la composition des dykes est compatible avec une origine provenant de ce granite sous la forme de phases fractionnées tardives. Le gisement principale (Main zone) de Clarence Stream est ainsi considéré comme étant associé aux intrusions, le granite de Magaguadavic étant la source ultime des fluides aurifères."

Jan 1, 2008

By F. A. McLean

At the Annual Western Meeting held at Blairmore, Alta., October 1924, the writer presented a paper drawing attention -to the advantages of portable gas-driven equipment for developing isolated mining properties. This type of equipment was at that time practically in its infancy and the details of results actually accomplished were somewhat meagre. During the last year or so a number of these plants have been installed so that it is now possible to offer more definite information regarding the actual mining progress accomplished with such plants and their cost of operation in various parts of the country. This paper has been written with the idea of reviewing the work done during the past year, and to supply data which may be of interest to those wh9 are confronted with the problem of selecting equipment for development or assessment work. Because drilling operations play such an important part in mining, one of the first problems that usually confront the prospective? mine owner is the selection of the proper com-pressed-air plant. The size and type of equipment and the method of driving it require careful consideration. The size and type of equipment is determined largely by the funds available, transportation facilities, and the speed with which the programme of development is to be carried out. The selection of the proper method of drive usually depends on local conditions, such as the relative cost of various fuels, and has an important bearing on operating costs.

Jan 1, 1926

By Fabien Miller

Automation technologies are increasingly envisaged to improve underground mining productivity. However, the technologies need to be used and adopted gradually in order to get the best benefits. This paper presents the technical and operational aspects of autoguided production vehicles at Brunswick Mine. During 2001 Noranda?s Brunswick Mine has successfully commissioned an automated haulage zone where two optically guided trucks transport ore from a remotely operated chute to two orepasses. Operational advantages include increased system capacity and enhanced safety and comfort for the operator. The data obtained up to now indicate that the system can operate reliably in mine production

May 1, 2002

By M. Kane, B. Bissonnette, D. Hodouin

"A laboratory cell has been designed for a careful investigation of gold ore cyanidation using mathematical modelling of the process kinetics. The cell is a stirred vessel with continuous monitoring and control of pH, oxygen and free cyanide contents. Samples are automatically extracted for gold analysis. The instruments are connected to a microcomputer which records all the measured variables and calculates the reagent consumption (air or oxygen, cyanide, lime). For cyanide control a sample is automatically extracted and filtered and the solution analyzed, using a specific electrode, by a flow injection technique. The rate of gold dissolution is modelled using a kinetic model the parameters of which are calculated by a non linear least-squares technique. The parameters of an empirical model of reagent consumption are also estimated. The resulting model is used in a simulator for gold cyanidation plant design, tuning and control.INTRODUCTIONThe leaching of gold ores in a cyanide solution is the usual method for gold extraction from raw ores. This process requires long reaction times and leads to very significant consumption of cyanide. The optimization of the cyanidation plant operation is a very important aspect of gold ore processing for increasing gold recovery and decreasing operating costs. The key parameters to the improvement of gold extraction are the selection of an efficient solution chemistry, the design of the size and the arrangement of the equipment and the correct tuning of the operating variables. Automatic control strategies can then be applied to maintain industrial operations at their optimum setpoints.Two approaches can be used for optimizing design and control of cyanidation circuits, either empirical trials for improving process performances or mathematical modelling of the process kinetics for subsequent analysis, simulation and optimization. The advantages of the second approach, which is used in this study, is that it gives a systematic pattern to interpret data and reliable tools, in as much as the models are good, to improve operation performances. In order to determine the structure and the coefficients of cyanidation models, well controlled measurement and calibration procedures must be used. The purpose of the paper is to present an equipment and a test procedure for modelling the kinetics of gold ore cyanidation."

Jan 1, 1990

By Willem P. C. Duyvesteyn

"Scandium International Mining Corp (SCY) has been involved in the commercial development of its Nyngan Scandium Project for about ten years. Various studies at a variety of global R&D organizations have been carried out in an attempt to define the deportment of scandium in both the limonite as well as the saprolite phases of Nyngan ore to assist with process development. Technologies such as sulfuric acid baking, high pressure acid leaching, sulfuric and hydrochloric acid atmospheric leaching and heap leaching have been extensively investigated both at the bench and pilot scale level to arrive at the most economic process flow sheet that will be discussed in some detail in this paper. Solvent extraction, ion exchange and other refining technologies have been tested and an optimum configuration has been established for the Nyngan project which is expected to be the first primary scandium mine and metallurgical plant in the world.Because of a lack of product availability the current scandium market is limited to less than 20 tons per year. Technologies have been identified to produce product with different specifications for aluminum alloys and solid oxide fuel cell applications. Preliminary economics have identified that Nyngan will be a robust and low capital cost project that can readily be expanded as the size of the scandium market increases."

Jan 1, 2016

By Michael Young, Josh Rubenstein, Michael Cooper, Tom Shouldice, Dan Curry

"Xstrata Nickel Australasia’s Cosmos plant in Western Australia is currently implementing a debottlenecking project to increase nickel output while maintaining metallurgical performance and a low unit cost for production. Mineralogical analyses indicated that the processing bottlenecks could be removed by simply reconfiguring portions of the circuit as well as adding capacity with technical advancements – notably an IsaMill™, Jameson Cell, Wemco® SmartCell™ and Larox Filter.The Wemco® SmartCell™, which is particularly suited for coarse mineral flotation, and Jameson Cell, which is particularly well suited for fast floating and fine minerals, combine as rougher scalpers to complete the main stream portion of the flotation circuit. Addition of the two new cells meet the required flotation capacity to handle the forecast increase in nickel feed grade and tonnage.The addition of an IsaMill™ for regrinding allows the SAG mill to produce a coarser primary product, thus enabling increased throughput. The advantages offered by the IsaMill™ include operation in open circuit (internal classification), an inert grinding environment (ceramic media) for better downstream flotation (“clean” new surfaces), compact footprint (easy to retrofit into existing plant) and energy efficiency. With the new rougher capacity addition, the remaining original plant cells were reconfigured to suit the new regrind mill and cleaning requirements. The existing 24 m2 Larox pressure filter was replaced with a larger 32 m2 unit to dewater the increased concentrate output.The paper describes the upgrade at the Cosmos concentrator with particular emphasis on the mineralogical data and metallurgical benefits associated with the changes.INTRODUCTIONThe Cosmos concentrator is located 680 km northeast of Perth in Western Australia. The deposit’s development and operations were started in 1999 by Jubilee Mines NL, Cosmos’ previous owner, with the first production of nickel concentrate in April 2000. The Cosmos concentrator treats a komatiite hosted high grade nickel sulphide ore, with sulphides being predominantly pentlandite and pyrrhotite with lesser amounts of pyrite and chalcopyrite."

Jan 1, 2010

By O. P. Garg

"The Iron Ore Company of Canada (IOC) operations in Labrador and Quebec, in Canada, is among the largest openpit mining complexes on a world wide basis. Since the 1981-82 recession, IOC has embarked on a comprehensive cost reduction and productivity improvement program in order to survive in the world iron ore market.This paper will outline the approach used in prioritizing the cost reduction items.IntroductionMuch of the mining industry in North America is in a crisis state. Most producers are operating at production levels well below capacity, some have been merged or sold, while others have been mothballed or closed permanently. For many of us still operating, the future is uncertain. Despite the many cutbacks and closures, there is still an abundant supply of minerals in the world market and there is almost no hope for any relief on price pressures on most mineral commodities in the near future. The Iron Ore Company of Canada (IOC) operates an iron ore mine, a concentrator and a pellet plant known as the Carol Project located in Labrador City, Newfoundland. This concentrator and the pellet plant have the annual capacity to produce 20 million and 10 million tons respectively. A company owned and operated railway links this operation with the dock terminal facilities in Sept-Iles, Quebec.In the past decade the Iron Ore Company of Canada has been one of the largest producers of iron ore products in the world. Its pellets and concentrates as well as natural ores were sold in North America, Europe and the Far East. In 1981-82, sales, particularly in North America, went into a serious decline. For almost 30 years, the gospel IOC preached to employees was ""production, production!"" There were many innovations, and millions of dollars were spent on the biggest and best equipment, on research and development, on training and developing employees."

Jan 1, 1987

By François Robichaud

"The Laronde mill has been in operation since 1988. Actual milling rate ranges from 7,000 to 8,500 mtpd. Laronde uses SAG/ball mill grinding followed by copper and zinc flotation circuits. A cyanidation/Merrill-Crowe process recovers the remaining gold and silver in the flotation tails.In 1999, the carbon in pulp circuit was replaced by a Merrill-Crowe circuit in order to cope with a much higher ratio of silver/gold associated with the discovery of the Penna shaft. Marine type diatomaceous earth was used as filter aid in both clarifier pressure leaf filters and recessed pressure filter presses from 1999 to 2005. In 2005, this filter aid was gradually replaced by alpha-cellulose after several laboratory and plant filtration trials. The selected cellulose is considered to be much less sensitive to parameters such as pH and reagent concentration and have increased clarifier and filter press filtration performance. Also, since cellulose is exothermic, replacing diatomaceous earth with cellulose as filter aid in the filter presses has increased calcining and oxidation rates in the calcining ovens since cellulose is exothermic. Finally, better calcining conditions have resulted in energy and reagent savings at the arc furnaces.This paper describes how the filter aid replacement has contributed to increasing productivity and Net Smelter Return of the refinery while reducing worker’s hazards and operating cost.INTRODUCTIONAll Merrill-Crowe circuits in the world are operated with filter aids. For years, the market for precoat filter aid has been dominated by mineral filter aids such as diatomite and perlite. Flowsheet and equipment selection at the Laronde refinery were performed in the late nineties. At that time, some key parameters of the design criteria had clearly identified marine type diatomaceous earth (DE) as the most successful filter aid. Parameters such as reagent cost and availability, clarity of the filtrate solution and good historical filtration performance in other concentrators had designated DE as the best suited filter aid. Pregnant solution processed in the refinery from its start-up through 2001 was fairly stable in flow rate and reasonable in terms of impurity content (cationic and anionic compounds)."

Jan 1, 2007

By Carl Bertrand, Patrice Nadeau, Claude Bazin

"Rio Tinto Fer et Titane processes the ore extracted from the Lac Tio orebody to concentrate the hemo-ilmenite (FeO.TiO2-Fe2O3) mineral that is subsequently smelted to produce pig iron and titanium oxide slag. The ore is crushed, heat treated (roasted) and concentrated using dry magnetic separators. This paper describes a model to predict the magnetic susceptibility of the roasted ore and its behaviour in the magnetic separation plant. The model uses a classification of the ore as a function of the size and magnetic susceptibility of the particles. A subsequent division into mineral species allows the simulation of the magnetic separation process. The model is used to assess various operating options when process disturbances occur.INTRODUCTIONOre processing operations consist of ore size reduction followed by the recovery of valuable species in a concentrate that is subsequently sold for its minerals or metal content. The concentration processes are based on the physical and/or chemical properties of the minerals contained in the ore. Flotation is typically used to recover minerals of base metals such as copper, zinc, lead or nickel. Iron ore and other dense minerals are typically concentrated by gravity separation processes. Magnetic separation uses the magnetic properties of the minerals to concentrate magnetite and other minerals, to clean coal concentrate and to recycle ferrosilicon for dense separation processes (Brophy, 1985).Magnetic separators can be divided into low and high intensity separators and high gradient magnetic separators (Gillet, 2008). Most of the low gradient magnetic separators are built as rotary drums that are operated in wet or dry conditions. Dry magnetic drum separators are used by Rio Tinto Fer et Titane in Sorel-Tracy, Canada to concentrate hemo-ilmenite from the ore extracted at the Lac Tio Lake mine near Havre St-Pierre, Canada. The analysis of production data suggests that process improvement could be achieved by identifying key variables for the control of the magnetic separation circuit and/or by modification to the circuit flowsheet. The use of a process model was considered to be an effective approach to conduct a preliminary analysis of the circuit with a view toward process optimization. However, the literature contains few detailed studies dealing with the modelling of magnetic separation processes."

Jan 1, 2011

By R. Nendick

"IntroductionThe Ancient Egyptians recovered gold from the mud in the bottom of ponds by having teams of maidens sit around the pond dipping goose feathers dipped in grease into the mud. The gold would preferentially stick to the oily surface and was periodically washed off to give a gold concentrate. This was a forerunner of today's flotation processes.In Greek mythology Jason and the Argonauts pursued the Golden Fleece, which was a primitive form of gravity concentrate produced when gold ore slurry was passed over a sheeps fleece. The heavy gold settled and was caught in the fleece, producing a rich concentrate that allowed Jason & Company to perform the first recorded case of highgrading. The process was a forerunner of todays shuiceboxes used in placer mining.From these simple beginnings, gold metallurgy has progressed to a state where very complex flowsheets are proposed, sometimes to perform a simple metallurgical task. Figure (i) shows a hypothetical flowsheet to identify the range of unit processes that might be brought to bear on a refractory ore. The flowsheet identifies the three primary areas of gold metallurgical operations:Ore PreparationExtractionRecovery."

Jan 1, 1986

By Franciszek Letowski

"Recovery of precious metals associated with a sulphidic matrix has an important economic effect on complex sulphide ore treatment. Because a significant portion of the silver and gold associated with pyrite are rejected to tailings during the selective flotation of pyritic Zn-Pb-Cu ore, other ore processing routes have been investigated.Direct leaching of the ore with ferric sulphate solution followed by separation of different components of the solid suspension by flotation was applied. Such a process allows for: production of zinc sulphate solution; transformation of galena PbS to insoluble lead sulphate PbS04 and its accumulation in a non-floatable fraction together with precipitated geothite FeOOH and other insoluble gangue minerals; separation of sulphur and non-decomposed sulphides in the floatable fraction.Laboratory research carried out on the ore samples from an Alaskan pyritic deposit from the Delta region indicates that gold and silver are mostly concentrated in the floatable fraction.Total recovery of zinc from the ore attains 96.5% to 98.5% after ferric sulphate leaching. About 85% of copper was extracted from the ore during the ferric sulphate and subsequent ferric chloride leaching, and about 6% of the copper remained in the non-floatable fraction and mixed fraction during the leaching-flotation step. Extraction of lead from the nonfloatable fraction during leaching with calcium chloride solution attained 98% to 99%. Extraction of silver from the floatable fraction during leaching with ferric chloride solution reached 98%. Extraction of gold from the floatable fraction during cyanide or thiourea leaching reached 71% to 89%. The results of the laboratory research are presented."

Jan 1, 1987

By J. A. Finch, A. R. Laplante, R. Espinosa-Gomez

"The Niobec concentrator rejects up to /5% of the Nb as slimes (-10u.m). The recovery of Nb from these slimes by column flotation is being studied. An essential condition for selective flotation is slimes dispersion. A particle size analyzer, the Sedigraph 5000D, was used to monitor dispersion in plant waters with combinations of organic and inorganic dispersants and flotation reagents. Flotation reagents were particularly detrimental to dispersion with sodium silicate. The best dispersion conditions were selected for column flotation tests. These tests revealed that reagent combination had a pronounced effect on froth stability. Careful frother selection achieved good froth stability under conditions of good dispersion. Plant water increased the required dispersant concentration causing mineral depression.IntroductionSlimes (-10 u.m) rejected at Niobec contain up to 15070 of the over-all Nb content . Recovery of Nb from these slimes would significantly increase over-all recovery. A suggested recovery route involves two phases: (1) carbonate flotation (to remove most of the carbonates) depressing silicates and pyrochlore (as currently done at Niobec); and (2) selective (direct) pyrochlore flotation from the silicates. Phase 2 has been addressed and several routes to achieve selective flotation are available. Phase I was attempted with the selective reagent scheme used at Niobec but a considerable amount of pyrochlore floated with the carbonates due to poor slimes dispersion."

Jan 1, 1987

By K B. Bowley

This paper covers the application of a systematic maintenance plan by the Plant Engineering Department of Rio Algom Mines Limited, Milliken Division. The plan established the function of work study, developed and installed formal work planning and labour cost control procedures, and extended the existing preventive maintenance routines. In June, 1961, assisted by management consultants, a more scientific approach to maintenance was instituted. The emphasis was placed on the control of labour. The development and application of the primary control system was established with-in six months. Since then, the Department has operated for a year, consolidating the system. The procedure of the installation, the results achieved and the results to be expected will be discussed. JNTRODUCTION THE Milliken Division of Rio Algom Mines Limited operates a 3,000-ton-per-day uranium mine, in the Elliot Lake district of Ontario, which went into production in April of 1958. The lowest operating level is 3,000 feet below surface. Mining is carried out by open stopping, with planned pillar support and footwall haulage on rail.

Jan 1, 1963

By V. Prostakova, M. Shevchenko

The copper smelting gas / slag / matte / metal / solids system with the Cu-Fe-Ca-Si-O-S major elements has been a long-term focus of the present overall research program using integrated experimental and modelling approach for the phase equilibria characterisation and development of a thermodynamic database. A systematic investigation of phase equilibria of slag systems in equilibrium with Cu metal is providing information for systems where copper coexists in slag with lead, zinc, and aluminium oxides as major components. Experimental studies involve high-temperature equilibration of synthetic samples; rapid quenching; and measurement of the compositions of equilibrium phases using electron probe X-ray microanalysis (EPMA). Particularly important feature of the present study a wide range of temperatures (660-1670°C) being characterised that reveals major inconsistencies in the existing thermodynamic description of the multicomponent system, and allows to establish the thermodynamic properties from phase equilibria in a reliable way. FactSage-based thermodynamic modelling is integrated with experimental research. Initial thermodynamic assessments are used to identify priorities for experiments, planned to provide specific data for thermodynamic optimisation. Significant improvement in the accuracy of the phase equilibria description is achieved, in particular in the PbO-Cu2O-SiO2, ZnO-Cu2O-SiO2, and Cu2O-CaO- Al2O3 systems in equilibrium with metallic Cu. INTRODUCTION Slags high in lead and copper are generated in primary metal production in the smelting of lead sulfide concentrates and in pyrometallurgical metal recycling systems. The compositions of these slags are varied due to increased fraction of recycled materials in the feed as well as introduction of previously unused chemical elements to modern technology. Therefore, their processing becomes chemically more complex; in that way they contain a large number of different metals. These slags form complex non-ideal solutions (with possible formation of several immiscible slags) that can coexist with stoichiometric solids, solid solutions, mattes and molten metal depending on the bulk composition and process conditions. Predicting the outcomes of smelting and refining processes is becoming increasingly difficult. To assist in the optimisation of these metallurgical processing operations, a comprehensive research program is underway to develop accurate thermodynamic databases for these non-ferrous process systems.

Jan 1, 2019

By A. Pratt

Portland cement is primarily used to solidify backfill in underground mine workings and it represents a major cost in mining operations. CANMET-MMSL has invented an alternative binder technology that does not contain any amount of Portland cement and is made using waste materials, such as development rock and smelter slag. The technology has been successfully tested with many types of base metal and ferrous slag. Research conducted in collaboration with several mining operations in Canada has shown that the CANMET-MMSL binder has considerable potential as a replacement for Portland cement in mine backfill. An integral part of the overall mining operation, backfill is used for two main purposes: safety and environmental remediation. Depending on the mining method used, backfill provides a working surface, stabilizes stope and pillar walls, as well as the surrounding rock mass, and controls caving of stope backs. There are several benefits associated with the replacement of Portland cement in backfill, including reductions in (i) the footprint by placement of slag waste underground, (ii) the environmental effects and long term liability resulting from disposal and containment of slag waste on surface such as acid rock drainage, (iii) GHG as a result of reduced Portland cement usage (the production of 1 ton of Portland cement produces 1 ton of GHG), and (iv) the significant costs associated with reduced Portland cement usage.

May 1, 2010

By F. R. Jones, B. W. Taylor, A. R. MacPherson, L. J. Lamb

"The Lake St. Joseph Iron Deposit is in Northwestern Ontario. Exploration to date by Steep Rock Iron Mines Limited has indicated an ore reserve of 683 million long tons. Metallurgical investigations have proved that suitable oxide pellets and/or superconcentrates can be economically produced from this ore. Studies of the Lake St. Joseph iron ore deposits have covered the period 1956-71, and have embodied applications of the improvement in mining and processing technology over this period. Market demand in the early 1960's for high-grade oxide pellets as a replacement for natural iron ores for the blast furnace first drew attention to the potential of the Lake St. Joseph deposit. The current market trend toward utilization of sponge iron to replace steel scrap as feed to electric furnaces and cupolas now suggests that the deposit can better be exploited as a prime source of superconcentrates."

Jan 1, 1972

By Chen Xia, G. Deschenes, Wan-Tai Yen

"Ammonium thiosulphate is a potential replacement for the cyanide in gold leaching. However, the high reagent consumption hinders its practical applications. In order to reduce the thiosulphate consumption, chemical additives were used. The gold leaching tests were conducted on a sulphide copper-bearing gold ore with 0.3M thiosulphate, 0.03M copper sulphate and 3M ammonium hydroxide solution at 44% solids and pH 10.2. Sulphate, sulphite, amino acid and chelating agents were initially used as additives. It was found that chelating agents (EDTA and NTA) could reduce the thiosulphate consumption from 30 kg/t to 17.8 kg/t with some increase of gold extraction. The improvement from other additives was not significant. Other approaches were also attempted to reduce thiosulphate consumption with some success. The thiosulphate consumption could be reduced to about 17 kg/t by reducing copper sulphate concentration fiom 0.03M to 0.0015M; adding 0.04M of EDTA; replacing copper sulphate with 0.001M of nickel sulphate. The increase of pulp density fkom 44% to 60% solids could reduce the thiosulphate consumption to 17 kg/t as well. Limiting the dissolved oxygen content by sparging nitrogen reduced the thiosulphate consumption further to 10 kg/t. It could be concluded that the regulations of copper and oxygen supply in the lixiviant were the keys to reduce the reagent consumption.INTRODUCTIONCyanidation, as the predominant gold leaching method, has been used in mining industry for more than a century. The low reagent requirement and the high performance are the reasons for its great success. However, cyanidation cannot deal with ores containing large amount of copper, nickel, arsenic and zinc minerals. This type of ore may consume more reagents and result in a poor gold extraction. On the other hand, the carbonaceous materials may preg-rob the gold from pregnant solution and make cyanidation a problem leaching method. Further more, the high toxicity of cyanide represents another challenge to modern gold mines. In the beginning of the year 2000, an environmental disaster caused by an accidental spill in Yugoslavia was broadcasted world-widely (Gurevitch 2000). Gold mine operators are facing higher social pressures and increasing costs on environmental protections. The usage of cyanide in mining industry has been banned in some countries and locations such as Czech Republic, Japan, Turkey, California, Colorado, Wisconsin and Montana States. Thus, a non-cyanide lixiviant is required."

Jan 1, 2002

By J. D. T. Steyl, C. A. Biley

"The chemistry of electrolyte systems containing iron remains generally poorly understood despite their prevalence in many natural and industrial processes, particularly in hydrometallurgy. These systems are typically challenging to study and model due to their affinity for complex formation and precipitation even at low pH. Recent developments in the hydrometallurgical processing of nickel laterites at Anglo American have called for a deeper understanding of the fundamental chemistry of the Fe2(SO4)3–FeSO4–H2SO4–H2O system. This paper details the development of an internally consistent, Pitzer ion-interaction model of this system, with explicit recognition of important contact ion pairs (CIPs). The primary application of this model is a thermodynamic framework for the interpretation of kinetic processes occurring during iron(III) reduction with SO2. Adopting a rigorous thermodynamic basis for the system chemistry facilitates the formulation of simple rate expressions that are capable of inherently capturing complex effects. While the iron(III) reduction case study remains the focus of this work, the developments have more universal applications and the thermodynamic speciation model can be extended into other systems containing acidic ferric sulfate.INTRODUCTIONIron is present in nearly all hydrometallurgical refining circuits typically as both a necessary and unwanted impurity and needs to be removed and disposed in a safe and efficient manner. This is generally performed by precipitation to form a range of solids such as hematite, goethite or jarosite. Numerous studies in the open literature have focussed on the removal of iron from refractory gold sulfide ore (Berezowsky & Weir, 1989; Berezowsky et al., 1991) and zinc pressure leaching (Buban, 1999; Ismael, 2003), and PGM matte sulfide circuits (Dutrizac & Monhemius, 1986). Moreover, since ferric iron is a strong oxidizing agent, it has been used extensively as a leaching agent for sulfide minerals (Dreisinger, 2006). Given the outlook of challenging economic conditions, declining ore grades and increasing levels of impurities, effective iron management is going to become increasingly critical to all hydrometallurgical processes.Against this background, and considering the widespread importance of acidic iron sulfate systems throughout natural and industrial processes, it is unexpected that the knowledge of the fundamental solution chemistry of these systems contains such significant gaps, particularly at the conditions typically found in hydrometallurgical applications. Existing literature describing the measurement and modelling of solution speciation in these systems have highlighted their significant chemical complexity (Magini & Caminiti, 1977; Magini, 1979; Lee & Tavlarides, 1985; Stipp, 1990; Papangelakis et al., 1994; Gil et al., 1995; Majzlan & Myneni, 2005; Kormanyos et al., 2008; Yue et al., 2014). Partially responsible for the lack of quantitative speciation measurements is the strong tendency of ferric to hydrolyse at even low pH (Flynn, 1984), complicating the laboratory study of such systems. Moreover, the large number of aqueous species that may co-exist simultaneously makes the study of individual species and the modelling of the numerous interactions between these species extremely difficult (Dry & Bryson, 1988; Stipp, 1990; Majzlan & Myeni, 2005; Kobylin et al., 2007)."

Jan 1, 2016