Search Documents

By H. Bouzahzah

The field of quantitative mineralogy has evolved significantly through the development of image analysis techniques and information technology. Quantitative mineralogical characterization can now be routinely conducted for determining ore compositions and understanding the behaviour of minerals within mineral separation processes. The characterization of mine tailings is another important application of quantitative mineralogy. The estimation of acid and neutralization potential as well as the interpretation of kinetic leaching test results are often based on quantitative mineralogical knowledge (mineral abundance, texture, metal distribution amongst minerals, etc.). The objective of this paper is to determine and compare the accuracy of four mineralogical characterization techniques that are often used for environmental sample analysis: (1) X-ray diffraction, (2) normal analysis from chemistry analyses, (3) normal analysis from specific gravity measurements and (4) SEM-EDS image analysis. For this purpose, three artificial samples were assembled by mixing pure minerals in proportions often observed in mineral processing plant tailings. BILMAT, a statistical data reconciliation software, was applied to reconcile the chemical analyses with the results of other mineralogical analysis techniques and to estimate the acid and neutralization potential of actual mine tailings samples. The acid mine drainage was qualified from the acid potential and neutralization potential equilibrium as determined through quantitative mineralogical analysis. The statistically reconciled data made it possible to predict the metal deportment as a function of their bearing minerals and therefore, in the case of neutral contaminated drainage, to assess metal leaching potential.

Jan 1, 2016

By M. J. Collins, B. Parekh, A. Hasenbank, B. Hewitt

Newcrest Mining Limited, originally as Lihir Gold, has operated a pressure oxidation plant for the recovery of gold from refractory ore since 1997. The mine and gold plant are located on Lihir Island in Papua New Guinea. Design of the original pressure oxidation circuit was based on the results of pilot plant tests conducted by Sherritt in Fort Saskatchewan. Following a decision to expand the plant in 2008, Lihir Gold contracted Sherritt to design a new autoclave. The design exercise utilized the original pilot plant test results, commercial process results at Lihir, and an understanding of advances in autoclave technology since the original plant was built. The new Lihir autoclave will be the largest horizontal, multiple-compartment autoclave in the world. The design process for the pressure oxidation expansion is described in this paper.

Jan 1, 2011

By John Drew Ridge

"Over the years, ore geologists have made innumerable observations as to the relationships of certain kinds of ore deposits to particular types of rocks and to the types of primary and secondary structures that these rocks contain. On the basis of these, the places in which to look for new are deposits are more clearly defined than they would be in an exploration program based largely or solely on concepts of ore genesis. This paper discusses the affinity of certain rock types and structures for such ore deposits as: (1) tin-tungsten associated with granitoid rocks; (2) lead-zinc of simple mineralogy in carbonate rocks; (3) massive base-metal sulphides in sedimentary or volcanic rocks; (4) massive base-metal sulphides and oxides at, or near, contacts with igneous rocks; (5) gold or gold-uranium in, or adjacent to, conglomerates; (6) shale- or sandstone-hosted copper; and (7) porphyry coppers. Additional varieties could be considered, but it appears that these examples are sufficient to demonstrate the validity of the suggestion that the use of observational characteristics is far more useful in mineral exploration than that of theories of ore genesis.As by-products of the theory of plate tectonics, many concepts have been put forward to explain how ore deposits of different kinds have been formed. Most, if not all, of these theories seem to be as valid as present-day information permits. However, do these ideas add to the ability of the ore geologist to find ore deposits? I doubt it, and offer reasons as to why I think so.To produce maximum results in any exploration program, the one that makes the greatest use of information produced about the geologic environment of the area being investigated is the one that will provide the greatest return in deposits found for the sponsors of the program. Such exploration is best designated as total exploration, and it certainly is the most effective way of uncovering such new deposits as may exist in the area being studied in particular and of adding to the sum total of nonfuel minerals deposits available to the industrial world in general."

Jan 1, 1983

By M. H. Fathi

The aim of this work was to prepare the metallic coatings on 316L stainless steel dental implant and evaluate the corrosion characteristics and thus the biocompatibility of the uncoated and metallic coated dental implants and comparison of the effect of the type of coatings on biocompatibility. Three types of metallic coatings including Tantalum, Niobium, and Titanium coatings were made using physical vapor deposition process on 316L stainless steel dental implant. Structural characterization techniques including; X-ray Diffraction, Scanning Electron Microscopy and Energy Dispersive X-ray Analysis were utilized to investigate the microstructure and morphology of the coatings. Electrochemical potentiodynamic tests were performed in two types of physiological solutions at 37±1 °C in order to determine and compare the corrosion characteristics. All three types of metallic coatings had a positive effect on improvement of the corrosion behavior so that the coatings could increase the corrosion resistance of 316L stainless steel and this trend was independent to the type of physiological environment. Biocompatible metallic coatings could decrease the corrosion current density that is a distinct advantage for prevention of ion release. This can improve the biocompatibility of the implant and, consequently prevention of tissue damages, inflammation and irritation and obtained desirable histopathological response.

Jan 1, 2007

By M. Kunst

The creep behavior of three AJ62 alloys was investigated in a wide range of stresses and temperatures. Multi-level tensile creep tests revealed a distinct primary creep stage and a high stress exponent up to a value of 10. The threshold stress concept which is commonly used in combination with high stress exponents was utilized in the analysis of creep behaviour. This resulted in an effective stress exponent for the AJ alloys indi¬cating dislocation climb as the dominating creep mechanism. In addition, microstructural observations of the lamellar eutectic and of the a-Mg-matrix were carried out using opti¬cal microscopy, SEM and TEM. The creep properties of the alloys are discussed in the context of microstructural parameters such as phase volume-fraction, stability and solute supersaturation.

Jan 1, 2006

The major factors limiting the establishing of vegetation on the shale and sandstone wastes at Minto are high exchange acidity and low pH (shale pH 4-5, sandstone pH < 4). In the first revegetation program (1967-74), 3.8 million trees were planted without grading on 4,000 acres (red, jack and scots pine and black locust). White dutch and sweet clover, birds-foot trefoil and red top were established in selected areas, and ponds were stocked with brook trout. In the second phase of reclamation, beginning in 1979, a comprehensive plan will be initiated which will allow for forest production, wildlife development and recreational activities.

Jan 1, 1977

By Lloyd Buckingham

Barrick Gold Corporation (Barrick) has undertaken innovative methods of evaluating and improving the performance of grinding mills in several of its operations around the world. The results have been positive with some of the mines showing more than 20% net energy improvement leading to more than 43,000 tonnes per year reduction in CO2 emissions in four of the operations reviewed.

Jan 1, 2012

By G. F. Raymond, W. P. Armstrong

"At the time of this study, the Valley mine was producing 23 000 tonnes of ore per day from a large, low-grade porphyry copper orebody. Sulphide mineralization, principally bornite and chalcopyrite, occurs in a stock work of quartz veins in one phase of the Guichon Creek batholith. The property was explored from 1967 to 1982, and was placed in production in 1983.Using a three-parameter lognormal approximation developed by G.F. Raymond at Similkam een and Mount Isa Mines, a geo- statistical conditional probability ore reserve was estimated prior to mining. Comparisons with blasthole kriging and milled ore for the first 17 months of production showed close agreements at all cut-offs between conditional probability estimates and mineable ore. This was not true of either kriging or polygon estimates. An important part of this work was identifying and correcting for bias in both exploration and blasthole samples.IntroductionCominco&apos;s Valley lake deposit is a large, low-grade, porphyry copper orebody in the Highland Valley of British Columbia. Total indicated plus inferred ore reserves are 700 M tonnes at ore grade of 0.47070 Cu. At the time of writing, ore milling is at a rate of 23 000 tI d through the old Bethlehem mill. Mining is in 10m horizontal benches using 9.8 m3 shovels and 90 tonne trucks. Since this paper was written, Valley and nearby Lomex have been combined into Highland Valley Copper with a combined oreproduction of about 120 000 tI d.Copper mineralization, principally bornite and chalcopyrite, is regularly distributed throughout the deposit as disseminated low-grade within a granodiorite host rock, and as higher grade veinlets within a stock work of near-vertical quartz veins generally 10 cm or less in width. It is likely that problems with sample variability and sample bias are mainly related to mineralization within quartz veining. Valley geology has been described in detail by Allen and Richardson and by Osatenko and Jones (2). The exploration sampling program and identification of diamond-drill sample bias have been discussed by Armstrong and Newman&apos;»."

Jan 1, 1988

By Brandt Porter, Lawrence K. Nordell, Alexander Potapor

"Improving comminution efficiencies with better machine geometries and motions, improved nip angles, rock movement control, and voids regulation among rocks are some of the next steps to better machine performance. Recent gains (~30%) using high pressure grinding rolls (HPGRS) and vertical roller mills, in theory and practice, are based on Prof. Klaus Schönert’s academic studies (1979–1996) on rock breakage physics. More recently, University of British Columbia Prof. Bern Klein’s studies (2006–present) via the Ph.D. thesis of Z. Davaanyam (2015) further validate theory with practice from laboratory measurements used in this paper.They demonstrated ideal rock compression breakage, within HPGR and vertical roller mill machines using a piston-die apparatus. Similar rock size range is used. The piston-die confine rock breakage behavior. However, these studies do not extend to larger rocks (> 75 mm), and do not demonstrate the influence of rock voids among bifurcation of rocks during comminution. Further, machines fed with larger rock sizes, such as gyratory, jaw, and cone crushers, are not designed or evaluated for geometry nip angle efficiency.Herein we illustrate a performance gain of a new comminution machine, the conjugate anvil-hammer mill (CAHM), first presented at SAG 2011 (Nordell, 2012). The CAHM machine digests rock sizes 400% larger than HPGR, improves rock grip/nip geometry, better improves rock voids, improves surface wear life > 500%, and improves rock containment and slippage during compression. In all, the CAHM machine shows 22 potential improvements over the HPGR. Most importantly, CAHM shows a 50% kWh/ton improvement compared to the HPGR. Our studies use an advanced Discrete Element Method (DEM) computer program called ROCKY. ROCKY simulates moving boundaries, surface wear mechanics, and incorporates rock breakage physics based on the fundamentals of JKMRC T10 protocol [×] with tuned A × b breakage parameters.We calibrate rock breakage in our DEM code to mimicking both UBC laboratory piston-die and HPGR comminution measurements. We then model CAHM with these known ore and machine properties. Differences are illustrated using DEM techniques on each machine, including key points of when each: use geometry; initiate bifurcation breakage; provide a map of particle size distribution by location; illustrate the importance of controlling voids to minimize agglomeration after breakage; machine performance limits; and kWh/ton benefit."

Jan 1, 2016

By H. Memarian

In the last few decades, many developing countries have tried to expand and improve upon higher education, which is acknowledged to be the leading factor for development. In this respect, develiping countries have significantly increased the number of tertiary institutions and their students. These rapid expansions, along with all the benefits, have drawbacks as well. An example is the status of mining engineering education in Iran. Presently, the number of active mining engineering departments in Iran (27) is more than the sum of similar departments in Canada, Australia, the United Kingdom, and South Africa (23 altogether). Also, the number of annual mining graduates in Iran (645) is more than the cumulative graduates of the United States, Canada, the United Kingdom, and Australia (613). The expansion of mining engineering education in Iran has coincided with the closing or merging of similar mining departments, as well as a decline in the number of interested students in the industrialized world. The present study shows that the need for development and the excessive number of high school graduates, resulting from high population growth in the early 1980s, are the two primary factors influencing the significant expansion of mining engineering education in Iran.

Jan 1, 2007

By D. C. Carter

"The Nova Scotia Department of Mines and Energy located a drillhole at Riverside Corner, Hants County, Nova Scotia, to examine the stratigraphy, structure and potash potential of the Kennetcook River gravity low. This evaporite-related gravity anomaly is one of the largest virtually unexplored gravity anomalies in Nova Scotia. The drillhole intersected a structurally complex sequence o flower Windsor Group (&apos;B&apos; Subzone) evaporites. Downhole geophysical wireline logs were used, in conjunction with detailed lithological descriptions, to interpret the structure and stratigraphy of the sequence. Similar application of total gamma ray, density, caliper and neutron-neutron log responses allows stratigraphic correlation of Windsor Group carbonate marker units separated by up to 35 km in Cape Breton. This work confirms the value of downhole geophysical logs as a tool in the exploration of evaporite deposits regardless of the presence or absence of high quality core. INTRODUCTIONThe exploration methodology for evaporite (specifically salt/potash) deposits in eastern Canada (and worldwide) is relatively simple: identify a negative gravity anomaly within a favourable geological setting, Windsor/Cordroy Group sediments in eastern Canada, and drill it (Anderle, 1980). Although this is an obvious oversimplification of the necessary expertise in the planning and complet ion of an exploration program, those familiar with potash exploration drilling can attest to the risks and expense, in terms of time and problems , associated with the location and drilling of diamond-drill wildcat holes. Potash exploration programs in eastern Canada, their results and inherent difficulties, have been documented by Anderle et al. (1979), Cooper (1981), Dekker (1982), Carter and Boehner (1986), Carter (1988) and Carter and Anderle (in prep .).Downhole geophysical wireline logs have become an important tool in the stratigraphic and structural interpretation of evaporite sequences in eastern Canada and, in many cases, represent the only information recovered or the only information available due to the drilling method (rotary) and/or the long term instability of evaporite cores. This paper documents examples of downhole geophysical log responses which, combined with detailed lithological examination of drill core, or in the absence of core, are used in the interpretation of the complex lithology and structure of a deformed evaporite deposit. Geological and geophysical data from the Nova Scotia Department of Mines and Energy (NSDME) Riverside Corner 85-1 drillhole are presented here as a partial case history and prime example of the use of this method to interpret the complex structure of an evaporite deposit. Drilling of NSDME Riverside Comer 85-1 was conducted in late 1985and early 1986by the Department (Carter and Boehner, 1986) under a program to assess the potash potential of selected areas of the province as part of the Canada-Nova Scotia Mineral Development Agreement 1985-89. A reinterpretation of a portion of the available data from two exploration drilling projects on Cape Breton Island in the Canso-Bras d&apos;Or area is also presented (see inset, Fig. I). Several drillholes have intersected the Windsor Group evaporite sequence in these areas and the available geophysical logs are a valuable tool in the interpretation of the structure of the deposits. However, no attempt has been made to present or discuss the detailed geological investigation and comparison of these two deposits. They are presented here as an example of the reinterpretation of existing data and their application to stratigraphic correlation and structural interpretation of complex evaporite deposits. Further work is necessary to document the stratigraphic and structural correlation of these two areas."

Jan 1, 1989

By D. W. Bacon

Plant process optimization programs are often costly, both in technical effort and loss of production. Evolutionary Operation or "EVOP" is a mode of plant operation consisting of controlled cyclical changes in process conditions by which information is provided concerning potential process improvements while both volume and quality uniformity in production are maintained. Its conceptual simplicity and low cost of utilization have led to successful adoption in a variety of industrial manufacturing operations. This paper is an expository account of basic EVOP theory, the problems encountered and the organization required in applying it to a processing plant. Illustrations are provided which indicate the payoff that can result.

Jan 1, 1967

By H. E. Pawson

Giant Yellowknife is located 600 air miles north of Edmonton on the north shore of Great Slave Lake in the Northwest Territories. In its 24 years of operation some 7,730,000 tons of ore have been treated to yield $175,000,000 worth of gold.The gold ore occurs at irregular intervals throughout a fold-like sericite schist zone cutting Precambrian rocks. The ore is characterized by 40 to 80% quartz - carbonate and about 10% pyrite and arsenopyrite. Considerable amounts of stibnite and antimony sulpho-salts are also present. Gold is finely divided in the native state existing in complex association with the sulphides. In most instances stibnite is barren but minor values are evident on occasion. Visible native Fold, quite prevalent in the early operating years, is, practically non-existent today. It was readily apparent from mineral dressing investigations conducted in .1944 that Giant ore would be difficult to treat. By 1948 a flow sheet had been established and operations began. In the ensuing years, changing ore characteristics necessitated modifications to some process steps and complete abandonment of others. By 1962 the major metallurgical problems were solved and all that remained was the refining of operating performance to its highest level.With one or two exceptions today's operation follows the practice established by 1962 (Fig. 1 - Flowsheet).

Jan 1, 1973

By A. Aaltonen, S. Paloranta, H. Myllykangas

A property based dynamic model of flotation was built and validated for training purposes. The model is based on the work of the AMIRA P9 project. The recovery of each particle with composition and size is calculated in a given simulation step. The model takes into account machine and operational parameters such as air flowrate and froth height. The model was created using fullscale test data on Pyhlisalmi Cu-Zn-pyrite ore with flotation kinetics of multiphase particles determined. Simulation and validation shows that model can predict the dynamic behavior of the process accurately enough for training purposes.

Jan 1, 2009

By François Robert

"The Eastern Abitibi Sub province (Quebec segment), contains two main types of gold deposits: the common quartz-vein type and the rare pyritic type. Both occur in areas dominated by volcanic rocks and are spatially associated with major fault zones.Quartz-vein gold deposits consist of simple to complex networks of quartz-carbonate-pyrite veins in reverse shear zones and extensional fractures. They occur in areas dominated by mafic volcanic rocks and are commonly associated with small syn- to late-tectonic porphyritic felsic intrusions. Associated alteration, which postdates peak metamorphism, is dominated by carbonatization, sericitization and pyritization of the wallrocks. These deposits formed late in the geologicalevolution of the Abitibi.Pyritic gold deposits range from deformed massive sulphide lenses to zones of syntectonic pyrite-rich veinlets and associated pyrite disseminations. These deposits occur in environments dominated by felsic volcanic rocks that are typically converted to sericite schists near the deposits. The associated pre-metamorphic aluminous alteration is now characterized by metamorphic sericite, andalusite, kyanite and chloritoid, overprinted by a late retrogression of alumino- silicates. These deposits probably represent deformed volcanogenic massive sulphide deposits, but the timing of gold introduction in these is not fully understood.The differences in geological attributes reflect significant differences in the genesis these deposits: the pyritic deposits probably have a multistage genesis, including a pre-tectonic stage, in contrast to a single stage late-tectonic genesis for the quartz-vein deposits.RESUMELa partie Est de la Sous-Province de l’Abitibi( segment québécois) renferme deux types de gites d' or: ceux de type ""veine de quartz"" et ceux, plus rares, de type ""pyriteux"". Ces deux types se trouvent dans des secteurs particulièrement riches en roches volcaniques et mantrent une association spatiale avec des zones de failles majeures.Les gites de type ""veine de quartz"" correspondent à des réseaux de complexité variable de veines de quartz-carbonate-pyrite se développant dans des zones de cisaillement inverse et des fractures de tension. Ils se concentrent dans les régions dominées par des roches volcaniques mafiques et s’associent fréquemment à de petites intrusions porphyriques felsiques syn- a tardi-tectoniques. L’altération associée ace type de glte est postérieure à la phase majeure du métamorphisme et consiste en une carbonatisation, une sericitisation et une pyritisation des épontes. La mise en place de ces gites est tardive par rapport à l'évolution géologique de l'Abitibi.Les gites d' or de type pyriteux consistent en des lentilles de sulfures massifs déformes, des zones d' abondantes veinules pyrite uses syntectoniques, et des zones de pyrite disséminée. Ces gites se retrouvent dans des empilements contenant surtout des roches volcaniques felsiques qui sont transformées en schiste à séricine pres des gisements. L’altération a l’umineuse pre-metamorphique associée a ce type de glte a donné naissance, lors du metamorphisme regional, a la sericite, a 'andal ousite, a Ia lcyanite et au chloritoi""de; par la suite, les alumino-silicates ont été affectes par une alteration retrograde tardive. Ces gites representent probablement des depOts de sulfures massifs volcan gènes déformes, mais la chronologie de la mise en place de l'or dans ceux-ci est encore mal comprise.Les caractéristiques géologiques propres à chacun de ces types de gites reflètent des conditions de formation différentes: le type ""pyriteux"" montre une histoire génétique polyphasée, incluant une étape pre-tectonique alors que le type ""veine de quartz"" s’est développe au cours d’une seule phase tardi-tectonique."

Jan 1, 1990

By J. Visman

"SummaryThis paper is presented as part of a programme to show the steps taken by industry and others interested in supplying a solid fuel of constant quality to 'satisfy a consuming market. The paper deals with the general principles underlying quality control in coal preparation plants, namely, constant quality and close adherance to acceptance limits. It also describes how control of ash content is ""generally hampered by the problem of coal sampling .and the long duration of the ash analysis and how these difficulties may be overcome.Quality control can be effected in several ways. Thorough blending wll reduce variations appreciably, except those of long trend. The latter can be detected by automatic sampling and quick ash analysis. At present, under favourable conditions, a system of half-hourly ash determinations with an accuracy of 0.5 to 1.0 per cent can be realized, to the effect that trends with a 'wave length' of more than two hours cu be eliminated within the limits of accuracy of the ash figures. The general solution of the problem is a combination of blending, accurate sampling, quick ash determination, and statistical analysis of the pattern of ash distribution.The use of statistical methods of analysis, such as the t test and F test, is •discussed at some length in order to emphasize the importance of the correct evaluation of observational data if there is to be confidence in the validity of test results.General ConsiderationsCOAL, as a fuel, is too cheap for a long haul across the country. The limiting distance depends on the price of the local competitive fuels, and, as the price depends to a great extent on quality, so does quality, to the same extent, command the market."

Jan 1, 1952

By Joseph U. Messenger

A method of applying ammonium hydroxide to a drill stem containing hydrogen sulphide gas and hydro-gen-sulphide-bearing oil and water so as to remove the hydrogen sulphide as ammonium sulphide is de-scribed. It was concluded that the method allowed trips with drill pipe filled with sour fluids to be made more safely, more rapidly, and more economically. INTRODUCTION THE DANGER of poisoning rig crews during drill stem tests of sour wells by exposing them to hydrogen sulphide gas is well known in Canada. Concentrations of hydro-gen sulphide in sour gases range from 0 to 40 volume percent. There have been numerous casualties from hydrogen sulphide exposure during drill stem testing. Some have resulted in permanent injuries; in some cases the injuries have been fatal. For example, in Alberta in 1957 there were four deaths and 100 exposures which required medical treatment. These fatalities and injuries indicate the need for a more effective way of handling hydrogen sulphide in oilfield operations.

Jan 1, 1958

By I. L. Sills

Introduction So many minerals and mineral products are used in the glass industry that it would require an unduly long paper to deal adequately with all of them. Only those that go to make up the batch for the more common types of glass will be discussed here, and even with these only, the list is a lengthy one. It is true that for the body of the glass comparatively few materials are required-as silica sand, soda-ash, lime, and feldspar. The others are used mainly to colour or decolorize the glass, or to give it some other desired characteristic, such as high lustre, greater physical strength, or opalescence; but, although they may be present in very small quantities, they are just as in-dispensable to the glass industry as are the main constituents of the batch. Sand Sand is essentially quartz, the dioxide of silicon, Si02. Most glass contains from 71J to 75 per cent silica. Sand for use in the glass industry, or &apos;glass sand&apos;, is obtained both from deposits of unconsolidated material, commonly referred to as &apos;sand&apos;, and from solid rock-sandstone, quartz, or quartzite. For the manufacture of glass, the material must possess a high degree of purity, as noted below, so that, although sand is widespread in most parts of the world, and sandstone, quartz, and quartzite are not at all uncommon, it is only in certain places that suitable deposits are found. At the present time, most of the glass sand used in Canada is imported from France, Belgium, and the United States. The French material, from Fontainebleau, near Paris, is known the world over as a very high quality glass sand. That from Belgium is nearly as good and is lower is price.

Jan 1, 1934

By D. J. Hains

IN this paper we shall examine the Why, Where and How concerning the agglomeration of iron ores and concentrates. Fig. l answers the questions @f why there is so much interest at the present time in the art of agglomeration. The use of sinter or pellets in the blast furnace has materially increased their rated •capacity. ':'President Hains Company Ltd. Engineering J. S. McMahon ( 1) reports an increase from 653 tons of .pig iron per day to 1140 tons of pig iron per day with the use of a 100 per cent sinter burden on one of his blast furnaces. In the United States the use of 100 per cent pellets has increased pig iron production from approximately 1800 tons per day to over 3000 tons pig iron per day (2). In our economic system the general objective is to produce more and better commodities cheaper. Fig. 2 shows the decrease in coke consumption with increased tonnages from the furnaces when using -

Jan 1, 1961

By J. -C. Parisien-La Salle, D. Blais, G. P. Demopoulos

"In this work the dissolution, precipitation and adsorption behaviour of gold in acidic iron sulphate media containing small amounts of chloride ions is investigated via batch laboratory tests and OLI thermodynamic calculations over the temperature range 25-250°C. Chloride ions may be present in industrial pressure oxidation/pressure leaching (POX/PL) operations due to elevated water salinity levels or due to intentional addition as is the case of the CESL Copper Pressure Leaching Process. Thermodynamic calculations show that AuCl4 - may form depending on the free Cl-/Au ratio and temperature, its stability increasing with increasing Cl- concentration and decreasing with increasing temperature. On the other hand during POX/PL, we know that massive precipitation of iron in various hydrolysis products and compounds occurs. Hence of interest is the question how AuCl4 - that may form during leaching interacts with the iron precipitation products. Gold(III) chloride was found to co-precipitate with iron(III) (oxy) hydroxides and arsenates forming in the autoclave but not with natrojarosite. Upon further investigation it was discovered that activated carbon added in the autoclave (as done in CIL) acts as preferential sink for the mobilized gold, hence opening the potential for the development of a direct cyanide-free gold recovery process in acidic sulphate leach reactors.INTRODUCTIONThe recovery of gold from ores and concentrates has evolved over the years with processing routes becoming increasingly complex. Given the high value of gold, any reduction in losses during recovery operations constitutes an important economic benefit. One such loss that needs to be addressed is the potential solubilisation of gold during pressure oxidation (POX) of refractory sulphidic gold feedstocks. For example, Agnico Eagle Mines reported a loss in gold recovery due to the formation of a gold chloride complex (Garofalo, 2009). Gold is known to form complexes in solution, such as gold(III) chloride, if an excess of chloride ions are present. The fate of such soluble gold chloride during pressure oxidation and the subsequent neutralization of the acidic discharge slurry will determine if gold is lost or recovered in the downstream cyanidation operation. Thus it is of interest to know under what conditions gold chloride may stay soluble or co-precipitate along primary (formed in the autoclave) or secondary (formed during neutralization) precipitates. Furthermore, the mode of co-precipitated gold, such as adsorption on iron compounds, like goethite and hematite (Machesky et al., 1990; Nachayev, 1984); substitution in one of the precipitated phases; or finally chemical reduction to metallic state would have consequences in terms of gold recovery."

Jan 1, 2012