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By Blattner P

The Late Miocene gold-silver bearing epithermal system at Waihi has some close similarities in its paleo-thermal and -geochemical structure with modern, volcanic-hosted geothermal systems such as Ohaaki-Broadlands. At Waihi an extensive braided quartz vein system is enveloped by hydrothermally altered andesites with minor tuff breccias and tuffs. A main stage of vein filling consists of multiple phases of chalcedonic quartz and fine to medium grained quartz, which are accompanied by pyrite, sphalerite, galena, chalcopyrite and acanthite below the base of oxidation. Platy calcite is present locally. Fluid inclusion studies indicate that the main stage quartz was deposited at temperatures of 189¦-273¦C from dilute (T¦ of -0.1 to -1.0¦C) fluids that were locally boiling. Homogenisation temperature Th versus T. data points lie within the field enveloped by dilution and boiling/gas loss paths determined for the Ohaaki geothermal field, and indicates that the parent hydrothermal fluid for the Waihi epithermal system had a similar composition to that at Ohaaki, ie 0.2 wt% equiv NaCI and 3.3 wt% equiv CO2. The hydrothermal alteration mineralogy and the isotopic composition of vein calcite indicate that the hydrothermal fluid contained relatively high concentrations of CO 2' as at Ohaaki. Oxygen isotope analyses of main stage quartz range from 6.1 to 11.6 %o and of vein calcite from 2.29 to 9.4% . Calculated d8Ow.½ values for the hydrothermal fluid that deposited the main stage quartz range from - 2.0 to -5.7%c , with a trend to less negative values with depth. They are similar to those in the deep chloride fluid in active geothermal systems with a substantial fluid throughput. A high fluid throughput at Waihi system is also evident from the extensive high intensity hydrothermal alteration and large volume of quartz deposited in the vein system.

Jan 1, 1995

Truly launched during the 1939-45 war, b¬,osted since by huge increases in demand for food, shelter and manufactures of ill kinds, petrochemicals have rocketed into prominence' all'oVer''th'e world and are accelerating to even greater heights.Manipulation of the hydrocarbons in petroleum or natural gas provides raw materials for a wid.e'variety of plastics, resins, detergents, rubbers, chemical intermediates, fibres and fertilisers. These in. turn.. go into a host of products essential to our way of life.A5 a source of chemicals, petroleum has achieved a high place. because of its abundance, relative.eheapness acid ease "f transport and because it can,be' economically processed.'If a nation's industrial' progress is measured by ' the ' modern yardstick of petrochemical production,'Australia has reasonto be proud, for it now has 1S petrochemical plants worth'156 million, either in operation or under construction.At several locations near Sydney and Melbourne, these plants produce petroleum ethylene, propylene, butadiene and benzene, or convert these building blocks into the three major thermoplastics (polyethylene; polyvinylchloride and polystyrene)-a.nd"S.B.R.synthetic" rubber. "A number bf other imr-ortant petrochemicals, including carbon black, and ammonia, also are made, or-planned...Most petrochemicals find application. in seven principal industries - rubber, fibres, detergents, surface coatings, automotive, agriculture and plastics. They play a .part in many other industries, including mining and metallurgy.In Australia, population growth,.an -incr.easing standard of living, greater industrial activity and the replacement of older materials all should considerably expand the markets for established petrochemical plants and lead to the introduction of new manufactures.Unless thwarted, these positive forces should propel petro-chemicals into a future glittering with promise;' ò 'However, some help for the infant industry seems needed if petrochemicals, while growing with the nation, are to contribute as they can to our national development.

Jan 1, 1962

By R O. Laidlaw, J L. Mauk

The Coeur d'Alene mining district in northern Idaho, USA is the second largest producer of silver in the world. Mesothermal silver-lead-zinc veins occur in the metasedimentary rocks of the Belt Supergroup with five main types of associated hydrothermal alteration: 1) feldspar destruction, 2) hydrothermal bleaching, 3) carbonatisation, 4) sulfidation, and 5) silicification. Hydrothermal bleaching is characterised by hematite destruction with associated siderite and quartz veins and veinlets, coarse euhedral pyrite and magnetite. Bleached zones envelop both mineralised and barren veins and extend for metres to tens of metres into the wall rocks. Carbonatisation consists of addition of siderite, which occurs as veins, veinlets, stockwork, irregular blebs or spots, and coarsely disseminated grains, depending on the relative distance from the main vein structure. Siderite envelops nearly all mineralised veins, relates to all other alteration types and extends from several metres to tens of metres into the wall rocks. Pyrite and galena alteration dominate sulfidation and are associated with some mineralised veins. Pyrite alteration strongly correlates with siderite alteration and exists in three main forms: a) very fine-grained pyrite flooding, which can extend for metres to tens of metres into wall rocks; b) coarse-grained, euhedral pyrite, which is sporadic and associated with the redox boundary in hydrothermally bleached zones; and c) small isolated zones (6 - 15 cm) of medium-grained, subhedral to euhedral pyrite associated with pervasive siderite alteration. Where present, disseminated galena extends for metres to tens of metres into the wall rocks. Silicification is characterised by veins, veinlets, stringers, irregular patches and variable hardness in siltites and commonly appears in association with hydrothermal bleaching and siderite alteration. Although related to mineralisation, silicification is sporadic and in most places a clear envelope around mineralised veins cannot be identified.

Jan 1, 2001

By C Zhang, I Canbulat, S Saydam, H Yu, H Chen

Natural rocks are frequently exposed to groundwater and complex geological conditions. Environments with water presence are more susceptible to chemical corrosion, which notably affects rock’s micro properties. Generally, the pH of acid mine drainage in hard rock mines can be low to 5, and the pH of quarrying waste deposits can be below 3. With the expanding scope of mining engineering in aquifers and salty areas, chemical corrosion can also caused by different types and concentrations of anions. The anions can significantly affect rock’s mechanical properties. Therefore, it is critical to emphasise the impact of anion and acid on the mechanical and micro characteristics of rock. This paper commences with an introduction to representative corrosive environments. Then the UCS tests are conducted on granite samples corroded by chloride ions and sulfate ions. Anion has negative effects on the strength of granite. The reason is that certain minerals can react and be dissolved by anions and hydrogen ions, such as Al2O3. Furthermore, the scanning electron microscope (SEM) shows that the roughness of the fracture surface increases with the anion concentration. The effect of acid is notably more pronounced than anion on the micro properties of granite. The initiated fissures and pores also increase with the concentration of SO42- and Cl- ions, which is the micro explanation for the impact of anion on rock strength and stability. Subsequently, the permeability of the granite specimens is tested. The reason that granite performs insensitivity to acid and anion is attributed to its low permeability and high content of inactive oxides, such as quartz. To summarise, anionic and acidic conditions can slightly deteriorate the mechanical and micro properties of granite. While SO42- demonstrates a higher level of corrosiveness on granite than Cl-.

Sep 1, 2024

By D M. Aranha, A R. Cabral

Theories on the origin of the Itabira iron formation (itabirite) in Quadrilßtero Ferrffero (QF), as elsewhere in the world, are restricted by the apparent lack of adjoining volcanic units, severe syndeformational metamorphism and deep weathering. Besides the three types of iron formations at QF (siliceous, dolomitic and amphibolitic; Dorr, 1969) we include a fourth type initially described as ocherous, goethitic, limonitic or even yellow iron formation. Considering its high magnetite content, it has been described as yellow magnetite itabirite (Pires, 1979). It was reported as formed by the alteration of the dolomitic itabirite (Dorr, 1969) although the anomalous Al2O3 contents are high for normal weathered itabirite. The yellowish magnetitic itabirite occurs at the bottom of the Itabira Iron formation, along the contact with the Batatal schists, and at the top units of the Itabira, within the Gandarela Formation. Within the magnetitic itabirite at the Tamanduß iron ore mine there are metric zones, concordant to the bedding of pillow-like structures, exhibiting a porous core, surrounded by an intermediate, more granular zone with numerous, minute rounded cavities grading to an external, fine-grained zone with much less minute cavities. In the external portions of some pillows a breadcrust type structure, derived by quenching with the water can be observed. In some other zones, such as the Barreiro hill, an outer, vesicular, whitish yellow, 5 - 10 mm thick, band grades to an aphanitic, isotropic band. The vesicles are slightly flattened against the band surfaces. The existence of fragmental layers showing flowage and fragment alignment, kaolinitic laminas and vesicles filled with kaolinite at Barreiro Hill and Capitpo do Mato Mine represent mesoscopic structures, indicators of a possible volcanic origin. Chemical compositions of the magnetitic itabirite from a wide area in QF revealed a relatively high Al2O3 content, consistent with a volcanic origin.

Jan 1, 2005

The subject of steel wire ropes covers such a wide range of points that it would be impossible to deal with it fully in one paper, and in view of the apparent scarcity of published information on the subject it is proposed in this paper to deal with those items which should give the mining engineer a better understanding of the basic factors which affect the design.selection, and use of ropes. The matter will be considered under the following headings:-1. Brief history of steel wire rope-making.2. Rope-making terms.3. Wire rope materials.4. Characteristics affecting economy, operating life, and serviceability of a rope.5. Properties of construction of rope, and stresses met with in wire ropes.6. Drum and sheave sizes and sheave bearing pressures.7. Storage, handling, and maintenance of ropes in service.8. Common factors affecting rope life, particularly winding and haulage ropes.9. Inspection of ropes.GENERALWire rope, which was invented for, and first applied to mine winding, has become an indispensable aUXiliary throughout the whole field of mining, be it for underground, open cut, or dredge work, as well as the requirements of transport and treatment of ores.Though wire ropes appear simple collections of wire and fibre, the demands made upon them are many, and the stresses and abuses to which they are exposed in service are varying, and often of serious dimensions.The exposition of these stresses and abuses, particularly dynamic stressing, corrosion, etc., all of which seriously affect the safety and economical life of the ropes, is often enough to frighten most practising mine staffs, who are aware that before the requirements of economic operation stands the still more important question of safety in mining.

Jan 1, 1947

By J B. Holman, P A. Weber, P Lindsay

Underground and opencast coal mining has occurred since 1896 on the Stockton Plateau, West Coast, New Zealand. Acid Rock Drainage (ARD) from historic and current mine workings has had an adverse environmental impact on the surrounding aquatic environment. The two main catchments affected by ARD from historic and current mine workings are the Mangatini and St Patrick Stream catchments. Solid Energy New Zealand Ltd (SENZ) is using active (e.g. alkali dosing) and passive (e.g. engineered cover) technologies to mitigate the adverse environmental effects associated with ARD contaminated waterways. This paper discusses the passive technologies. Principal strategies include the capping of high capacity potentially acid-forming volumes of overburden. The mudstones were found to generally have the highest sulphur levels compared to other overburden lithologies. Areas with high mudstone volumes are prioritised to be encapsulated and 390 Ha is planned to be capped in the Mangatini catchment in the near future.   Monitoring beneath granite, cement kiln dust and coal combustion product covers show oxygen can be reduced to less than 10% of atmospheric levels. Laboratory column leach tests that were subjected to oxygen flux rates of 10 % showed reducing oxygen ingress into acid-forming material can result in significant acid load reductions.   The oxygen content below the cement kiln dust cover was generally lower than 5% and water quality measured in lysimeters beneath this cover improved after 50 weeks of emplacement. Column leach tests containing saturated samples were undertaken to determine the most appropriate water medium in preventing pyrite oxidation. The sample saturated with ARD (pH ~ 3) had a negligible acid production rate and leached very minor Al concentrations although Al is soluble at low pH. This indicated saturating waste rock dumps with ARD can be an effective method in mitigating ARD formation.

Jan 1, 2007

By K Hskansson

In earlier studies along a mining region recipient (the river VormbScken, northern Sweden), the fraction of certain trace metals recovered in the particulate phase has been found to increase with increasing concentrations of particulate iron. This study was conducted to see if the pattern could be reproduced by adding minor amounts of ferrous iron, simulating groundwater inputs. When the iron is oxidised in the near neutral river water, it will form iron oxyhydroxides and precipitate. Trace metals may be either co-precipitated along with the iron, or adsorbed onto the freshly formed precipitates. If this is the case, such a mechanism may be incorporated as a part of a final polishing step in a mine drainage treatment system based on natural attenuation processes. The experiments were performed at 0¦C and 22¦C, on authentic river waters collected during the winter and summer of 2002, respectively. In order to investigate the influence of particles and bacteria initially present, filtered river waters (4 solution were added to the experimental beakers, increasing the iron content of the waters by 0 - 1.5 mg/L. The oxidation and precipitation processes were followed by means of filtration (0.2 ¦m) for up to seven days. In order to be able to compare the experimental results with the actual field situation, on both experimental occasions, surface water samples were collected also from three stations situated along the river. The samples collected were analysed for iron, calcium, and trace metals by AAS and ICP-MS. The iron oxyhydroxides formed in the experiment did not influence the partitioning of As, Cu, and Pb to the same extent as the particulate iron encountered along the river appeared to do. Cd and Zn were recovered mainly in the dissolved (

Jan 1, 2003

The Mungana group of mines, in the Chillagoe district, yielded 334,000 tons of ore giving 31,831 tons of lead, 7,907 tons of copper and 3,228,600 ounces of silver. The Girofla mine produced approximately 220,000 tons of ore, and with the Lady J ane mine supplied most of the ore from this centre. The deposit was discovered in 1888, but active development did not commence from the main shaft until 1898. A subsidiary of the New Chillagoe Railway and Mining Co. Ltd., the Mungana (Chillagoe) Mining Co. Ltd., worked the mine from 1902 until 1914, selling copper, copper-lead, lead ores and fluxes to the smelters at Chillagoe. The smelters stopped operations in 1914 when the richer ores of the Girofla had been worked out and production from the Lady Jane had ceased due to heavyground and fire. The Girofla shaft was 823ft. deep with a cross-cut at 810ft. At the 710ft. level contour drives had delineated the orebody, which had been stoped about 10ft. above the level. Except for flux ores which had been stoped only for favourable smelter tariffs, the orebody was practically exhausted above the 610ft. leveL Under company ownership the mine yielded 139,265 tons of an average grade of 4.QlYr copper, 16.2% lead and 12.5 oz. per ton silver.In 1921 the Queensland Government re-opened the mine and worked it until 1927. The North Lode (Fig. 2) was discovered almost immediately at the 100ft. level and was worked down to the 410ft. leveL The ore from this branch and the completion of the stope at the 710ft. level yielded about 80,000 tons of ore averaging 0.4 copper, 9.8 lead and 7.8 oz. per ton silver during this period.

Jan 1, 1953

IT is most remarkable and valuable property of mediurn and high carbon steels that they should be so susceptible to heat treatment, the wide range of variability in tenacity, ductility, etc, due to the normal influence of the carbon in the untreated material being enormously inereased thereby.The physical properties of steel and other metals are much more closely related to their structure than to their ultimate analysis.For instance, we may by chemical analysis determine the carbon content of a steel to be 0.5% ; but this information alone is insufficient to enable us to say what are the physical properties of the metal.Such a steel may possess 11 tensile strength of anything from 35 tons per sq. in., with much ductility, up to 80 tons per sq. in., with practically no ductility, according to its heat treatment. A microscopie examination, on the other hand, would show the structural composition of the steel, from which its physical properties could be approximately deduced. From this it will readily be understood that the microscope has played an important part in the development of modern rnetallurgy, and to-day it is in daily use for the examination of metals and alloys in the laboratories of most works dealing with the rnanufaeture and working of metals.THE IRON-IRON CARBIDE EQUILIBRIUMTo understand fully the mode of occurrcnce of the different constituents of a knowledge of the Iron-Iron Carbide equilibrium diagram (Fig. I) is essential to heat-treat steel successfully and to interpret microstructures correctly such a knowledge isabsolutely indispensable.A portion of the Iron-Iron Carbide Diagram, dealing with steels below 1000 and containing up to 1 carbon is given below.It should be noted that the diagram deals entirely with pure carbon steels, and does not indicate the influence of the usual so-ealled "impurities" present in all commereial carbon steels...

Jan 1, 1926

By R Huntley, D Sims

Pajingo gold mine produces over 240 000 oz Au per year from underground mining using longitudinal bench stoping methods with a 15 m sublevel interval. Average mine head grade is around 12 g/t Au, contained within quartz veins between 0.5 to 16 m wide. The veins dip steeply (>60¦) and exhibit strike variations which lead to many curved and meandering drive/stope geometries. Unplanned dilution at Pajingo is predominantly controlled by fault planes that subparallel the vein and commonly lead to slabbing failure from the stope walls. Initial efforts at determining maximum spans were based on using the Stability Graph method of stope stability. However the method had a number of shortcomings that did not address mine site observations, including previous mining, interaction of different joint sets and the presence of discrete shears which resulted in poor prediction of stability. A method was developed to rate the risk of dilution for a stope based on observations made in the ore drives. The method utilises profile mapping of the ore drive, structural features observed and the orebody itself, on 10 m spaced sections along the ore drive. A matrix of factors determines the dilution risk for stoping at the time of mapping and the rating is transferred to longsection plots in the office. The dilution risk rating is used to determine the position and density of cable bolt support aimed at lessening the risk, and can be used to review blasthole designs prior to finalisation. The method has been used for more than two years and has proven to be a good indicator of potential unplanned dilution (ie waste outside of ring design). A recent review of the dilution risk mapping process has indicated it is assisting in reducing the impact of dilution at the operation and has the scope to be utilised further in the design process.

Jan 1, 2002

Vatukoula, the Fijian equivalent of gold rock, is the name of the community embracing the gold mines owned and operated by Emperor Gold Mining Company Ltd., Loloma (Fiji) Gold Mines, N.L., and' Dolphin Mines Ltd. It is situated in the Tavua Goldfields approximately five miles from the northern coast of Viti Levu, the largest island of the Colony of Fiji.The climate is sub-tropical, there being a definite wet and dry season. The wet season is somewhat variable in length but usually extends from December to March, during which time most of the rainfall for the year is recorded.Although the average annual rainfall is 71 in., more than twice this amount has been recorded. Precipitation at the rate of 5 in. per hour is not uncommon and 15 in. of rain has been registered in 24 hours. The mining methods adopted, therefore, had to suit these wet conditions.The occurrence of gold in the Tavua area has been known since 1872, but it was not until 1932 that discoveries were made which led to the formation of the present operating companies. In 1934 the Emperor Gold Mining Company Ltd. commenced operations, followed in 1935 by the Loloma (Fiji) Gold Mines, N.L., and later by the Fiji Mines Development Ltd., now known as the Dolphin Mines Ltd. Up to the end of 1951 these three mines had produced 2,501,688 tons of ore from which 1,277,881 oz. of fine gold and 347,429oz. of silver were obtained, realizing in Fijian currency £13,025,153.The three mines are situated close togeth.er on contiguous mining leases, and, although under common management, are operated as separate en,tities. Since 1944 all the...

Jan 1, 1953

About 74% of global seismic energy release occurs in the Circum-Pacific zone. Worldwide, about 71% of seismic energy release is in the form of shallow earthquakes, 27% as intermediate, and 2% as deep earthquakes. Seismic energy release is variable in time and has been shown to correlate with the amplitude of the Chandler wobble. It was high during the period 1949 to 1967, and is now at a rather low level, with the latest earthquake over M = 8.0 having taken place in Indonesia in 1971. The average worldwide recurrence rate for the expected largest magnitude earthquake (M "9.5) has been estimated as several tens of years, in marked contrast to the several tens of thousands to hundreds of thousands of years separating the largest volcanic eruptions. Geological studies are needed to establish reliable mean intervals between large earthquakes, and to detect the e;:istence of long-term fluctuations in the ste of occurrence. Seismic gaps have proved seful in static forecasting of large earthquakes, by identifying places where closer study of the variation with time of seismicity, deformation, and other parameters, may lead to the dynamic p_ediction of time, place and magnitude of earthquakes. The model of stress concentration at asperities explains the main features of seismicity in the Circum-Pacific. Slow earthquakes have been detected instrumentally, notably an event immediately preceding the 22 May 1960 Chile earthquake, the largest this century. It seems likely that this type of deformation may explain both instrumentally detected and macroscopically observed pre-seismic deformation, as well as unusual animal behaviour reported before some earthquakes. Seismic and volcanic events are interdependent, with large earthquakes commonly triggering eruptions. Melting of rock and intrusion of magma is likely to accompany many earthquakes.

Jan 1, 1987

The current quantity of rejects from coal beneficiation in Australia represents 20 to 25% of raw black coal production. Approximately 80% of the rejects are derived from coarse processing for particles in the 200mm to 0.5mm size range. The safe and enviornmentally acceptable storage of coarse coal rejects is of interest to coal mining companies. Additional public benefit would be derived from the utilisation of a waste product as a source of fill material for civil and mining engineering applications. BHP Engineering has taken a leading role in the design for storage and utilisation of coarse rejects from two mines associated with the Broken Hill Proprietary Conipany Ltd. The tailings dam at Stockton Borehole Colliery (N.S.W.) is to be raised and a study by BHP Engineering has shown that coarse rejects are suitable for the formation of the supporting embankment surrounding a compacted clay core. Transportation and storage of coarse rejects at the Thiess Dampier Mitsui Riverside Mine (Moranbah, Qld) is achieved by a conveyor leading directly from the coal preparation plant to a discharge stacker on the crest of the rejects stockpile. Production of coarse rejects was higher than anticipated for the initial dump design. BHP Engineering has completed a review of dump design with emphasis on safe operating conditions for the conveyors and stacker system. Data on the geotechnical properties of coarse rejects from Australian coal mines are presented. Coarse coal rejects are a material which should not be considered as waste, but as a potentially valuable resource for many future applications. Appropriate engineering design for the storage and utilisation of coarse rejects would result in an improved environment and economic benefits for the Community.

Jan 1, 1987

By L Huang

"Successful rehabilitation of tailings landforms of tens to thousands of hectares in size at base metal mines is critical to mining companies’ ‘social licence to operate’. Rehabilitation technology used is closely related to both the economic sustainability of the mining company and the ecological sustainability of the mined environment. Conventional technology to rehabilitate mine waste landforms is costly and constrained by the availability of soil (to reconstruct root zones) and clay materials (to reconstruct compressed layer). Depending on mine waste properties and site-specific resource availability, it is not uncommon to cost A$0.1–0.5 M/ha for the establishment of conventional cover systems over mine waste domains, which often accounts for large proportion of the total closure costs. This can lead to costs approaching several hundred millions dollars for rehabilitating larger tailings and acidic waste rock using conventional cover systems.The present extended abstract proposes a suite of new technologies to tackle the problems outlined above and discusses critical factors in successful rehabilitation from substrate levels to the whole landform performance, in two key aspects:in situ engineering of tailings soil to offset/reduce materials requiredin situ chemical engineering of massive hardpan layer through alkali-activation and mineral gel cross-linking network mechanisms to encapsulate reactive tailings and achieving sustainable hydro-geochemical stability in root zones.This aims at functionally replacing the roles of the compressed clay layer and capillary breaks in conventional covers. These technologies would improve both the economic and ecological sustainability of mine waste rehabilitation, thus addressing the triple-bottom line of mining and mineral processing industries not only in Australia but other countries.CITATION:Huang, L, 2016. Emerging technology for economic and ecological sustainability in the rehabilitation of metal mine tailings, in Proceedings Life-of-Mine 2016 Conference, pp 128–131 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Jun 28, 2016

By F Baars, M Zu, C A. RosiFre, L Lobato

A genetic model for the genesis of high-grade (>65 wt per cent Fe) Proterozoic, banded iron formation (BIF)-related iron deposits such as the Tom Price, Mount Whaleback deposits in the Hamersley Province (Australia), the N4E, N4W, N5 deposits at Carajßs (Brazil), the Aguas Claras, Conceitpo, and Casa de Pedra deposits in the Iron Quadrangle (Brazil), the Donkerpoort West, Kwagas East deposit in the Thabazimbi iron ore district (South Africa), or the Saksagan ore field at Krivoy Rog (Ukraine), needs to take into account the: timing of regional metamorphism with respect to the upgrade of BIF to high-grade iron ore; significance and relationship of the proto-ore to the hydrothermal alteration minerals and zonation and the process of iron enrichment; source and oxidation state of the hydrothermal fluids that caused the iron enrichment; types of geochemical processes that caused the hydrothermal alteration and iron enrichment; and significance of the widespread carbonatisation of the host rocks as a prerequisite for high-grade BIF-related iron mineralisation.We argue that a unifying model for high-grade BIF-related iron deposits cannot, presently, adequately explain the geological and geochemical characteristics observed in these deposits and, therefore, provide two end-member models that take into account the diversity of geological and geochemical ore deposit features. Our discrete model for the genesis of high-grade, BIF-related iron deposits is based on the interpreted tectonic setting, distinct hydrothermal fluid source of, and processes observed in, major BIF-related iron deposits. We divide two end-members: Proterozoic deep fault-magmatic (Carajßs) type, and Proterozoic rift-basin (Hamersley) type.Both end-members experienced varying degrees of deep weathering episodes that effected the hypogene enrichment and, ultimately, yielded the high-grade iron ore mined in many places today.

Jan 1, 2005

THE slag from the blast furnaces having been granulated, a representative sample is taken to the sample mill. It is then dried, crushed through a 100-mesh screen, intimately mixed, and packeted for assay purposes.METHOD OF ANALYSISINSOLUBLEWeigh 1 grm. of the finely-pulverized slag into a 3t-in. casserole, moisten with a little water to prevent sticking, cover with a clock glass, and add 20 cc. of hot acid (1 HNOs, 3 HCI, 4 H2 0). Evaporate slowly to dryness on a hot plate and bake (without overheating) until all the gelatinous silica is dehydrated. Cool, add 20 cc. HCI (1-1), and boil gently for several minutes; filter into a 300-cc. beaker, cleaning out the casserole thoroughly with a rubber-tipped glass rod. Wash residue with hot distilled water and transfer it to a No. 1 porcelain crucible. Dry, ignite, cool in a desiccator and weigh as total insoluble matter. Dilute filtrate to 200 cc. and neutralize some of the excess HCI with NHa.OH. Warm, and pass H2S for 15 min. Filter and wash withhot water. Boil off H2 S, oxidize with 5 cc. HNOll , reduce bulk of the solution by evaporation. to about 100 cc., and transfer to a 250 cc. flask.SILICAFuse insoluble residue over a blast lamp in a platinum crucible with three or four times its weight of anhydrous carbonate of soda, for 10 to 15 minutes, or until decomposition is complete. Cool, and extract fusion in an 8-in. evaporating dish with HCI (1-1); rinse crucible and cover with distilled water, and evaporate to dryness over a water bath. Take up dry mass with 10 cc. strong HCI, and then.

Jan 1, 1922

Neutralisation, normally using lime, is the most widely used method for treating high flows of acid mine drainage (AMD). Lime costs can be very high however. If carbonate sources could be used to achieve pH values above six, costs could be greatly reduced. For example, use of locally quarried limestone at Mt Lyell could potentially reduce alkali costs from about $A 3.5 to $A 1 million/year. Methods for enhancing the effectiveness of limestone and magnesite for neutralising Mt Lyell and Savage River AMD respectively have been examined through a series of investigations. Small-scale testwork found that the maximum pH economically achievable with ground limestone was about five, due to slow dissolution rates and surface armouring. The problems of surface armouring were greatly reduced by the use of crushed limestone or magnesite at high pulp densities (75 per cent solids w/w), enabling pH values >6 to be achieved in a practical time frame. The use of particle sizes in the range 6 mm and finer also reduces costs by avoiding the need for grinding, and reduces the problems of solid-liquid separation and solid recycling that arise if large additions of ground carbonate are used. Pilot scale tests were carried out using tumbling drum reactors with limestone and Mt Lyell AMD and a pulsed-bed static reactor with magnesite and Savage River AMD. pH values averaging 6.2 and 6.4 were achieved with Mt Lyell and Savage River AMD respectively. Approximately 80 per cent of feed acidity was neutralised. A preliminary engineering design and cost estimate has been completed on the pulsed-bed reactor and shows that the concept is technically feasible and, if results are confirmed, economically attractive. Further pilot testing is planned.

Jan 1, 2002

Airblast overpressure legislative limits can be extremely difficult to meet throughout Australia, which has by far the most stringent limits of any nation in the world. As the difficulty in meeting the limits is strongly dependent on the scale of mining, it is not surprising that the Australian coal mining industry is experiencing particular difficulties in meeting these limits. Eight full scale overburden blasts have been modelled with respect to overpressure impact for a strip coal mine, involving both dragline (cast) blasting and pre-strip (non-cast) blasting. Overpressure levels in the range 100 to 125 dBL have been measured at distances varying from 2.4 to 5.7 km, and modelling has successfully estimated both the amplitude and shape of overpressure waveforms to within an average of 1.2 dBL. Typical errors of prediction are around 0.6 dBL. This accuracy of prediction has been achieved by considering the impact of only the face holes, and the accuracy of prediction of both shape and amplitude suggests that it is these holes which dominate the environmental overpressure impact at distances in the range two to six kilometres, for cast and pre-strip blasting operations. Modelling has been based upon the Elemental Overpressure Wavelet proposed by Richards and Moore (2002), incorporating actual hole coordinates, actual delay timing, and assumed delay scatter statistics. The incorporation of delay scatter statistics has been particularly significant, and allows the determination of the range over which the peak overpressure levels are expected to vary. To date, modelling has considered only the use of conventional pyrotechnic delays, though simple adjustment to the scatter definition would allow estimation of overpressure levels, and their variability, with electronic delays.

Jan 1, 2004

By D E. Ralph, D-J Kim, G-J Ahn, Y-H Rhee

The amount of discarded dry batteries are presently found to be increasing globally and waste cathode active materials of the lithium ion battery industry are among them. Hydrometallurgical operations are being applied to recover the valuable metals from these waste batteries. To find an economic and environmentally friendly process, the bioleaching process was applied in the present investigation for recovery of valuable metals. Its principle is the microbial production of sulfuric acid and simultaneous leaching of metals. Bioleaching of spent lithium ion secondary batteries, containing LiCoO2, has been studied in this investigation. A new method for recovery of cobalt, potentially the basis of an economic and environmentally friendly process was examined. The present study has been carried out using chemolithotrophic and acidophilic bacteria Acidithiobacillus ferrooxidans, which utilises elemental sulfur and ferrous ion as the energy source to dissolve metals from spent batteries. Bio-dissolution of cobalt was found to be faster than lithium. The effect of initial Fe(II) concentration, initial pH and solid/liquid (w/v) ratio were studied in detail. Higher Fe(II) concentration showed a decrease in dissolution due to co-precipitation of Fe(III) with the metals in the residues. Similarly, at higher initial pH values and higher solid/liquid ratio (w/v) metal dissolution was found to be inhibited. The optimised conditions for bio-dissolution were solid/liquid (w/v) ratio û 10 g/L, initial Fe(II) concentration û 3 g/L, elemental sulfur û one per cent (w/v) and initial pH û 2.5. In the optimised conditions, cobalt dissolution was observed to be about 60 per cent, whereas that of lithium was ten per cent after 20 days. A first order kinetic model was derived to study the rate of dissolution of both the metals.

Jan 1, 2006