Search Documents

By Thomas L. Ochs

The stripping of iron-laden solvent with hydrochloric acid in the iron-removal step of the clay-hydrochloric acid process for the extraction of alumina from calcined kaolinitic clay results in a loaded ferric chloride stripping liquor. Treatment of this stripping liquor at boiling with calcined kaolin to form insoluble Fe203(s) and a dilute A1C13 solution was undertaken by the Bureau of Mines to characterize process problems and to aid in sizing of solids-liquid separation equipment. Variables identified as important in the chemical reaction were calcined kaolin particle size, ratio of calcined kaolin to FeC13, and reaction time. These parameters were tested for significance and their interactions investigated. Fine calcined kaolin (-65 mesh) at a greater than 1:1 mole ratio of contained acid-soluble A1203 to Fe203 equivalent of the FeC13 in the stripping liquor required less reaction time than coarser (-16 mesh) material. Solids-liquid separation of the reacted slurries by both settling and filtration requires flocculation.

Jan 1, 2011

By George A. Savanick

This paper reviews advances in the art of borehole (slurry) mining made by the Bureau of Mines from 1974 to 1980. The design of a proto-type borehole-mining tool (BMT) developed by the Bureau of Mines is pre-sented along with production data, reclamation data, and an application of the BMT to the mining of coal, uraniferous sandstone, oil sands, and phosphate ore. The BMT was first used near Wilkeson, WA, where steeply pitching metallurgical coal was mined at 8 st/h from a depth of 25 to 75 ft. Next, 940 st of uraniferous sandstone was mined at 8 st/h from a depth of 75 to 100 ft in Natrona County, WY. One thousand short tons of oil sands was mined in Kern County, CA, at the rate of 14 st/h from a depth of 110 to 150 ft in 1979. Most recently, 1,700 st of phosphate ore was produced at 25 st/h from deep (230-to 250-ft) deposits in St. Johns County, FL. Progressive improvements were made in the borehole mining technique. These include the use of the hydrostatic head of a water-filled borehole for roof support, and the development of methods to survey and backfill mined-out cavities.

Jan 1, 1987

By Alan A. Campoli

The U.S. Bureau of Mines evaluated two different conventionallongwall gate entry systems in the Southern Appalachian Basin, where mining and geologic conditions are conducive for coal pillar bumps. These gate entry systems were in a coal mine located in the Pocahontas No.3 Coalbed under approximately 2,000 ft of overburden and a massive quartzite sandstone member, and both employed a center abutment pillar flanked by yield pillars. The 8O-ft-square tailgate abutment pillars within the first study area began bumping 500 ft in advance of mining. This was accompanied by face bumps on the tailgate corner of the longwall face. The 120-by 180-ft tailgate abutment pillars within the second study area did not begin to bump until mining was approximately 100 ft past. Coalbed stress change and abutment pillar dilation data demonstrated that a 15-ft-wide perimeter of yielded coal surrounded a highly stressed core in both sizes of abutment pillars. The 62 pet more core area per foot of gate entry in the larger abutment pillars prevented excessive load transfer to the corner of the tailgate panel and eliminated the face bumps experienced with the original gate entry design.

Jan 1, 1990

By T. T. Campbell

This investigation was undertaken by the Bureau of Mines to determine if high-purity ductile molybdenum of uniform quality can be prepared by bomb reduction techniques. Molybdenum trioxide (Mo03) and mixtures of molybdenum dioxide (Mo02) and trioxide were reduced by magnesium in closed steel bomb reactors. Very high pressures in excess of 5,000 p.s.i. developed during magnesium reductions of Mo03. The addition of calcium oxide to the bomb charges caused a significant reduction in pressure. Reaction efficiencies higher than 95 percent were obtained during magnesium reductions of either Mo03 or mixtures of Mo02 and Mo03, but high pressures were encountered when the charges contained from 30 to 60 percent Mo02. Reaction efficiencies were usually low (less than 80 percent) when the bomb charges contained more than 40 percent Mo02. The charges with the best composition considering operating pressure, yield, and purity contained from 10 to 30 percent Mo02. The addition of small amounts of carbon to the reaction charges was helpful because some deoxidation occurred during the reduction and also during subsequent arc-melting of the regulus metal. The purity of the bomb-reduced, arc-cast molybdenum metal ranged from 99.2 to 99.8 percent and in some instances the metal contained as little as 5 parts per million oxygen.

Jan 1, 1962

By L. Nahai

Iran's petroleum industry is nearly 50 years old and the oldest in the Near East. According to published figures, Iran ranks third in production and reserves in the Near East. These reserves (including probable reserves) are estimated at 35 billion barrels and constitute about 11 percent of the world's total. Iran is the sixth largest producer of crude petroleum in the world. The 1961 output of more than 430 million barrels was 5 percent of total world output for the year. In the same year, Iran ranked fourth among world petroleum exporters, providing 8.4 percent of total world exports.

Jan 1, 1963

By S. D. Cramer

Corrosion research is being conducted by the Federal Bureau of Mines to determine suitable construction materials for geothermal resource recovery plants. As part of this research, the corrosion resistance of 31 iron-nickel-, aluminum-, copper-, titanium-, and molybdenum-base alloys was characterized and evaluated in laboratory corrosion studies in low-and high-salinity geobrines representative of those found in the Imperial Valley, Calif. General, crevice, pitting, weld, and stress corrosion were measured at 105° and 232° C in deaerated brines and brines containing dissolved 02, C02, and CH4 General corrosion rates in deaerated brines at 105° and 232° C were usually below 5 mpy for the alloys tested except carbon steel, the low-alloy steels, Monel 400, 70-30 cupronickel, and the aluminum-base alloys. Dissolving carbon dioxide and methane in the brines at 2320 did not markedly alter these results. However, the introduction of oxygen, which can enter the brine during process operations, seriously degraded the corrosion resistance of many alloys by increasing the incidence of stress corrosion cracking, crevice corrosion and, except for the titanium-base alloys, pitting. In deaerated brine at 2320 C, the general corrosion rates for carbon steel and the low-alloy steels were relatively unaffected by pH in the range of 6.1 to 3.0. However, general corrosion rates increased sharply below pH 3.0. In deaerated brine at 232° C, welds in several iron-, nickel-, and titanium-base alloys corroded at rates comparable to the general corrosion rates of the alloys, but the addition of oxygen to the brine increased corrosion rates for welds in Inconel 625 and E-Brite 26-1. Alloys exhibiting good corrosion resistance in the deaerated Salton Sea KGRA-type brine at 232° C were E-Brite 26-1, Inconel 625, Hastelloy S, Hastelloy G, Hastelloy C-276, TiCode-12, Ti-0.2Pd, Ti-2Ni, Ti-1.7W, and TZM. The alloys most resistant to corrosion in oxygenated Salton Sea KGRA-type brine at 232° C were the titanium-base alloys. These alloys appear the most suitable for use in the construction of geothermal resource recovery plants. Carbon steel and the low-alloy steels are unsatisfactory for high-temperature, high-salinity brines and alternative low-cost materials with improved corrosion resistance should be sought.

Jan 1, 1980

Two coal seams were selected and the conceptual designs were based on the geological and physical conditions typical of these seams. As a result of the screening process presented below, the two coal seams selected were the Lower Kittanning Seam in central Cambria County, Pennsylvania and the Pittsburgh Seam in northwestern West Virginia and southwestern Pennsylvania. SELECTION PROCESS FIRST SCREENING OF LONGWALL OPERATIONS The list of longwall operations prepared in Phase I and included in the Phase I report, was used as the basis for a first screening. From this list it was determined which longwall operations were not in the Appalachian coal fields and not in a coal seam of the thickness range of 42 to 72 inches. The first screening eliminated 30 of the listed operations, leaving 48.

Jan 1, 1976

By Howard W. Wainwright

This bibliography was compiled by the Bureau of Mines as part of an investigation into the possible utilization of low-temperature coal-tar bases. The bibliography consists of literature and patent references from about 1945 to 1961 and is divided into the following headings: Analysis and Composition; Production, Synthesis, Reactions, and Utilization; and Separation, Purification, and Properties. Although over 1,000 references are included, no attempt was made to insure a comprehensive survey. The literature and patent references are arranged alphabetically by author or patentee. When several publications have the same author they are listed in reverse order of age, with the newest first. An author index is included because secondary authors are not cross-indexed. In almost every instance, the entry is accompanied by a Chemical Abstracts reference for those interested in locating an abstract of the original paper.

Jan 1, 1962

By R. V. Higgins

"INTRODUCTION When nations throughout the world are pitted against each other in a war in which petroleum plays a major role, scientist and engineers of the petroleum industry must give serious thought to ways and means for recover¬ing greater percentages of oil from natural reservoirs than in the past. Petroleum and its products are vital to highly mechanized modern warfare, and the victorious nations will be those whose armies, navies, and air forces are supplied with adequate fuel oil, gasoline, and lubricants until the war is won.Efficient recovery of oil from underground reservoirs depends on many interrelated techniques; evaluation of the producing performance of wells upon the basis of their productivity indexes is one such tool. Oil wells usually yield oil at a maximum rate when first ""brought in"". The rate of production begins to decline soon after the first oil is delivered to the tanks, and although part of the decline usually can be attributed to natural reduction of reservoir pressure as oil and as are withdrawn from the reservoir, a larger proportion frequently is caused by greater saturation of water and as in the producing formation about wells and clogging of the pores of the sands by silt, organic salt, and insoluble hydrocarbons. If the maximum quantity of oil is to be recovered from reservoir sands and rocks by wells, it is then imperative that the ability of wells to produce oil be watched closely and all adverse influences that affect the case with which oil can flow to wells be corrected if possible."

Sep 1, 1942

By Walter Frank

The purpose of the work covered by this contract is to develop a ground and pilot conductor connector which will significantly improve mine trailing cable splice performance. This work compliments the work completed under Contract 00357100 on the development of crimp connectors for the phase conductors of trailing cables. A brief discussion on splice problems is presented as an introductory means and substantiates the need for the development and test programs outlined in this report. As with the phase development work, the ground and pilot connector work is essentially of an empirical nature. As a result time is devoted to explaining the derivations of the test procedures used. In order to familiarize the reader with connector terminology a section is devoted to a glossary of pertinent terms. The connector design effort includes connectors for splicing ground and pilot conductors. A distinction is made between connectors suitable for splicing round and flat ground configurations. The same also applies to the pilot conductors. During the course of this work, much time has been devoted to the question of suitability of round cable configurations for trailing cable applications. This is discussed in detail along with resulting conclusions and recommendations. A field test program was conducted in order to confirm ground and pilot connector laboratory data. This testing also determined the viability of the connector designs and recommended installation techniques in a mine environment.

Jan 1, 1979

By H. S. Auvil, L. D. Schmidt, H. G. Graham

"Several studies on the bulk density of coals prepared for byproduct-oven use were undertaken during the war by the Bureau of lanes in cooperation with the Office of the Solid Fuels Administrator and with the advice of the Coke Production Committee. The primary purpose of these studies was either to produce more uniform coke or to increase the throughput of existing facilities or both; the goal was increased Production of steel for war. As these studies were made, detailed reports were sent to the individual companies with whom the Bureau cooperated; also two reports,5/6/on the general subject of bulk-density control were published. In the course of the work, data were gathered that now prove of value in judging the merit of carious methods of testing bulk density and the limits of application of each method in byproduct-oven operations.Since the cessation of hostilities, the .Bureau section (Coke Production Survey Section) that conducted this work has been liquidated, but it was felt advisable to prepare a report on the accumulated experience so that it would be in a form available for the use of the industry and also as a base for any further research on the control of fluctuating bulk densities in coke ovens.It is hoped that the data and experiences recorded herein will be of material assistance to the many who have had difficulty in obtaining reproducible results in bulk-density testing. Since the data were gathered in the course of extending aid to individual plants in minimizing the deleterious effects of fluctuations in bulk density of oven charges on the quality and quantity of coke produced, certain desirable phases of an over-all investigation were not covered. However, on certain of these phases qualitative indications are available and the policy followed herein is that suggested by the American Society for Testing Materials Manual on Presentation of Data7/ that lacking quantitative information, relevant material should be included even though it ""may be qualitative in character, some may even be vague."""

May 1, 1946

By William L. Rice

This Bureau of Mines Open File Report on nickel is one of a series of minerals availability commodity deposit abstracts. Nonconfidential information from the Minerals Availability Program data base covering domestic and foreign nickel properties and deposits has been abstracted for use in this report. Abstracts include applicable data on location, published reserves and resources, geology, mine and beneficiation systems, and operation information.

Jan 1, 1984

By P. L. Swanson, F. M. Boler

The U.S. Bureau of Mimes conducts research at the Galena Mine, Wallace, ID, with the aim of mitigating the effects of rock bursting. Destress blasting is commonly used as a stress control technique at the mine. A digital seismic array and an array of borehole pressure cells (BPC's) had been installed near the site of a stope undergoing mining and periodic destressing. The instrumentation was being monitored at the time of a destress blast of the 46-99 stope. No significant seismic events occurred coincident with the destress. However, the destress was followed by a 21/2-week period of increased seismic activity, including two damaging events on February 7, 1990, at 034500 (hour, minute, and second) and 122020 Pacific standard time. BPC measurements indicated coseismic ground pressure changes on the order of 200 to 300 kPa associated with the damaging events. Fault plane solutions and dislocation models established that stress changes induced by the event at 034500 may have been significant in promoting the occurrence of the event at 122020. Theoretical investigations suggest that applying knowledge of the existing stress field, an understanding of rock burst mechanics, and fracture mechanics principles can improve destress effectiveness.

Jan 1, 1993

By James R. Dunn

Samples were taken of industrial mineral waste materials which are potentially capable of being used for filling underground coal mines for subsidence control in the Pittsburgh and the Scranton-Wilkes Barre areas of Pennsylvania. The samples were subjected to potentially relevant standard tests which are commonly used 1n the evaluation of soil materials and mineral "aggregate materials. Measurements of plasticity, liquid limit, and gradations, particularly in the -200 mesh size range, indicated a comparative lack of clay minerals. Cementitious reactions between sources of alkali, such as calcium hydroxide or portland cement stack dust, and of silica, such as clay or fly ash, were found to occur in various mixes of high-bulk materials. Strengths of up to about 400 psi at 84 days were observed. The possibility of emplacement of high-bulk material by both turbid flow (or density currents) below water and by mud flows above water were considered and both appear to be reasonable and possibly simpler than the current mechanisms of emplacement.

Jan 1, 1977

By R. H. Sprute

This report describes Bureau of Mines laboratory test results in electrokinetic dewatering and consolidation of metal-mine tailings. Tailings were placed in 0.3-cubic-foot Plexiglass models, and dc potential was applied until dewatering ceased. Time-oriented measurements of water removal, changes in resistivity, and power consumption were recorded during the dewatering process. Dewatered material was tested for moisture content and density. Equipment and procedures were developed to optimize the method for unclassified mill tailings from a particular mine in the Coeur d'Alene, Idaho, district. Results indicate the method to be highly effective in dewatering and consolidating this material.

Jan 1, 1974

By Arthur C. McFarlan

There are two distinct coal fields in Kentucky-the Eastern field constituting a part of the Appalachian coal region and the Western field constituting the southern part of the Eastern Interior region. The outcrop pattern of the State is dominated by the Cincinnati arch. Coal-bearing Pennsylvanian strata occupy a low structural position on either flank, preserved thereby from erosion, which in the past has removed these same beds, though a much thinner succession, from the crest of the arch. General geological relationships are shown in figures 1 and 2. On April 13, 1750, Dr. Thomas Walker discovered the first coal recorded in Kentucky. He entered the State through Cumberland Gap (Cave Gap) and found coal a few miles north.

Jan 1, 1944

By L. G. Marshall

This report describes dredging and processing of sand and gravel from a glacial-fluvial deposit in the Raccoon River valley near West Des Moines, Iowa. Preliminary cleaning and separation of the sand and gravel at the dredge site with subsequent transportation to separate plants and the production and disposal of the various grades of aggregate material are also described. The geology of the deposit is summarized. A tabulated summary of costs in units of labor, power, and supplies is included.

Jan 1, 1963

By D. W. Blaylock

1. The Lower Freeport and Lower Kittanning beds are the most important beds in Clearfield County, Pa., from the standpoint of production. The Lower Kittanning bed has the largest remaining recoverable reserves of any of the beds in the county. 2. Known measured and indicated reserves in all beds, based on a minimum thickness of 14 inches and 1,800 short tons per acre-foot of coal in place, are estimated at 1,909 million short tons as of January 1, 1953. Of this total, 1,177 million short tons is in beds 28 inches and more thick. Areas in some beds were omitted from the estimate because available data relative to the bed characteristics are too meager to make an estimate that conforms with the definitions of measured and indicated coal adopted for this study. Should future drilling or development prove reserves in these areas, such reserves should be added to the total estimated reserves.

Jan 1, 1955

By Peter de Bakker

The objective of this contract was to develop a simple, reliable, economical, remote-control roof bolting module for installation of mechanical and resin bolts. It was to be capable of placing longer than seam height bolts, up to 10 ft lengths, from a seam height of 36 to 72 in., while keeping the operator under supported roof. The resulting machine, called REM-Bolter, is a low profile unit that utilizes Foster-Miller Flexible Shaft Roof Drill, a Bendix Roof Bolt Inserter and a newly designed. Roof Bolt Lifter/Torquer. Every effort was made to strike a compromise between complete automation and complete manual control. In a controlled laboratory environment the REM-Bolter remotely installed 1000 bolts. Subsequently the machine was tested in an operating coal mine where 500 holes were drilled (and an equal number of bolts were installed) remotely, over a 4 month period. The results of all tests Live shown that the operator of a machine of this kind can quickly, and repeatedly, install rootbolts remotely from his operator compartment some 8 ft away from the drilling/bolting action. The report includes recommendations for improvements to the present REM-Bolter design that would translate the present test bed into a second generation test bed and a potential first generation production unit.

Jan 1, 1983

By E. P. Dowding, J. Schlocker, C. H. Fuchsman, R. R. Lloyd, Mahan. W. M., O. C. Garst, W. T. Rawles

"INTRODUCTION The United States, although the leading consumer of chromite, depends almost entirely on imports for its supply. For instance, the consumption during. 1941 amounted to 714,645 long tons, whereas the domestic chromite production, although the highest since 1918, was 12,731 long tons or only 1.78 percent of the domestic consumption. 9/ Domestic production was tremendously, accelerated,after 1941 by war demands; however, only a small proportion of this domestic product was of sufficient quality to be substituted for the high-grade imported chromite demanded for metallurgical purpose. Chromite is used largely for making ferrochromium, an alloy containing 60 to 70 percent chromium which is used in making alloy steels. Peacetime specification for ferrochromium required that it should contain 68 to 69 percent chromium. These specification were lowered to between 60 and 63 percent, chromium in 1941 to permit the use of lower-grade ores. The specifications for metallurgical chromite, used for making ferrochromium, were established first by the Metals Reserve Company at 48 percent Cr203 and a Cr. Fe. ratio of 3 : 1 but later were lowered to 45 percent Cr203 and a Cr : Fe ratio of 2.5 : 1. The ratio of chromium to iron in chromite is important, because the contained iron enters the alloy in making ferrochromium and, although an ore may contain the required 45 percent Cr203, it may contain too much to be suitable for ferrochromium production. The principal sources of domestic chromite are California, Oregon, Montana, and Alaska minor, small, and widely scattered deposits in another dozen States. Without exception, these deposits are low-grade, require beneficiation to produce a commercial product, and are not competitive with imported high-grade ore in normal times. Nevertheless, these deposits form strategic reserve, which must be utilized in periods of national emergency. Recognizing this fact; the Bureau of Mines for many years has undertaken investigations to develop methods of utilizing domestic chromite ores. The problem has been approached from three angles: (1) Mechanical methods of concentration; (2) beneficiation by chemical or metal¬lurgical methods; and (3) production of metallic chromium by electrolysis of solutions prepared from ore or concentrate."

Feb 1, 1946