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By A. Prokopiev

The biological stage of reclamation is the third final stage in remediation the damaged mining terrains, which is carried out following the completion of the mining technical stage. The biological stage of reclamation is carried out through restoration of the vegetation layer. The biological reclamation includes all activities related to the introduction into the terrain of vegetation, microorganisms, insects, and animals, with the acceleration of the succession and creating conditions for a sustainable ecosystem close to the natural one. It comprises of all anti erosion and other activities such as the preparation of the land for growing agricultural crops, sowing grass seeds, planting seedlings, amelioration of the soil and further care for the vegetation until its final place on the land. Mineral and organic-mineral ameliorants for biological reclamation were studied. The basic mineral ameliorant is Bulgarian natural zeolites. The zeolitic-rich tuff samples provided from Golobradovo deposit was characterized by their chemical and mineralogical composition and ion exchange properties and X ray analysis. The average content of clinoptilolite was found to be more than 80%. The materials had ion exchange capacity (NH4+) varying from 100 to 110 meq/100g. Chemical modifications of natural clinoptilolites were made in order to form active phases of nitrogen, phosphorus, potassium, and microelements. Slow-acting mineral ameliorant was developed. Organic-zeolite substrate for biological reclamation was developed. This new product is a mechanical mixture of organo-matter and modified zeolites. Agro-chemical parameters of new ameliorants were determined. The substrates including studied overburden dump soil and mineral or organo-mineral ameliorants are produced. The grass growth test was performed. Keywords: biological reclamation, ameliorants, damaged mining terrains

Sep 1, 2012

By P. V. Malyarov

"This paper examines the grinding and wear processes in drum mills. A summary of the industry’s long-term experience with the proposed linings is presented. A method is proposed for assessing the efficiency of the grinding energy distribution between the successive stages. A case study is presented of grinding energy redistribution at Talnakh Concentrator by replacing spiral classifiers with a drum-type hydraulic screen. The problems of the kinetics of grinding processes in ball mills and semi-autogenous (SAG) mills are examined. It is demonstrated that in ball mills the feed particles are disintegrated by triaxial compression in the mill zones where discrete slippage of the charge occurs at major force interactions between the layers. Mechanism underlying increases in the specific energy consumption in grinding circuits based on SAG mills is shown.The problem of improving the throughput and reducing the specific energy consumption in mineral feed grinding is highly relevant because of the significant energy intensity. Up to 80% of the consumed energy is used to disintegrate ore fed into the drum mill. At all development stages of the drum mill grinding theory, the researchers have paid a great deal of attention to studying the patterns of the charge motion and the kinetics of the feed particles disintegration processes. In [1], it was shown that, due to the slippage between the charge layers being lifted, drum mills at concentrator plants operate in a mixed cascade and waterfall mode. A feature of the mixed mode is the toe zone, where the charge contacts the lining and the transition to a circular path takes place. Studies of the charge motion in the toe zone made it possible to develop a method for designing cross-sectional profiles of lining plates [2] for ball mill drums. The method is based on the principle of interaction between the balls and the lining, where the non-working rear surfaces follow the relative motion path of the balls before impacting the lining, while the working surfaces are orthogonal to the rear ones. Lining with the proposed profile provides contact with the charge and slippage-free transition to a circular path. This ensures an longer service life of the lining, a reduction in specific energy consumption, and an increase in the mill’s feed rate. The proposed method is applicable when designing lining plates of various materials. Steel liners with the proposed profile have been successfully operated [3] for more than 40 years at a number of projects in the industry."

Jan 1, 2018

By Xiaoxu Sun, Jianchao Yao, Jiancheng He, Shijie Lu, Hongxi Zhou

"The ball mill performance relies on impact grinding, but it has disadvantage of the lower efficiency when the ore is finer; while tower mill relies on friction shear affection with high energy efficiency, which is considered to be one of the most potential fine grinding equipment all over the world. Generated by the agitator device, the internal media movement is complex because of comprehensive interaction of screw mechanism, cylinder structure and adjacent media, which is the key factor of grinding process. But the kinematics parameter ,such as speed, acceleration, stress and so on, of media motion cannot be obtained through traditional laboratory test method, which restricts deeply research on finer grinding mechanism seriously. In order to solve this problem, characteristics of media motion in tower mill is studied via the discrete element method. Coefficient of restitution, coefficient of static friction and coefficient of rolling friction are the key parameters affecting the media movement, which were calibrated by stacking angle test firstly. A 3kW tower mill is established as the model for simulation. At last one appropriate simulation strategy is selected to increase simulation accuracy. The characteristic of media motion is obtained based on the computer simulation analysis: macroscopically, the media in tower mill is a dynamic equilibrium state generally accompanied by spiral up and down movement all the time. And it has been found that the maximum lifting height is proportional to the rotation speed of agitator shaft. The velocity of media at the edge of screw stirrer is biggest, while the velocity of media near the cylinder wall is smaller, so the grinding performance between the two ring areas is the best. The rotational speed of agitator shaft and media filling ratio are the two most important operating parameters in tower mill. The impact curve of two main operating parameters on the grinding intensity and energy efficiency are obtained. All these can provide theoretical basis and technical support for operating parameters setting of industrial tower mill."

Jan 1, 2018

By V. A. Vorob'ev, A. N. Larionov, E. N. Ivanov, M. A. Ryazanov

The aim of the research is to increase the recoverable value of poor, difficult-to-digest complex mineral raw materials. In the Republic Belarus, universal centrifugal-shock devices have been created for crushing, grinding and classification of ore and non-metallic mineral raw materials in dry mode, which differ from foreign analogues by a higher level of resource saving (including electricity and materials). Dry-ore preparation technologies have been tested on a pilot scale: fine crushing (replacing grinding in rod mills), grinding (replacing wet grinding in ball mills) and pneumoclassification on different types of ores, - which made it possible to identify the criteria for the suitability and unsuitability of mineral raw materials for their use. The possibility of regulating the upper and lower limit of the size of the finished material is established, the possibility of reducing the yield of slimes (-0,020 mm) to 5 times is determined. A comparative analysis of the contrast degree of separation characteristics of ore a similar granulometric composition, crushed in wet and dry conditions, is performed. The achieved contrast degree of gravity properties after dry grinding - 104,3; after the wet - 60.2. When enriching on a centrifugal concentrator, gold recovery to the concentrate after dry grinding increased by 13.12% while improving the quality of the concentrate from 78.3 g/t gold to 90.75 g/t. When testing the gravity-flotation scheme for the enrichment of poor gold-quartz ore, the increment of gold extraction after dry grinding was 7.6% for gravity and 9.5% for flotation; the total increase in extraction is 17.1%. The possibility of flotation of a larger material after dry grinding has been proved, with an extraction gain of 1.5% compared to the flotation of thinner material after ball milling. The influence of dry technology on the efficiency of the leaching of gold and silver (an extraction gain of 5.5 to 10%) and heap leaching (extraction gain - up to 18.3%) was studied. The positive influence of dry ore preparation technologies on the efficiency of gold and silver heap leaching and heap leaching, thickening and filtration is proved. Lines of dry ore preparation technologies can be used in modular complexes for processing technogenic raw materials.

Jan 1, 2018

By Z. H. Li

In connection with the features of characteristic waste water (containing cyanogen, arsenic and heavy metal) pollutants discharged by gold industry as well as the environmental features at the location of gold production enterprises, this paper briefly described the traditional method of treatment, and focused on the argument for technologies of clean production, advanced treatment and process control technology. Moreover, it clarified the future policies and development trend for treatment on characteristic waste water from gold industry.

Jan 1, 2014

By V. E. Vigdergauz

Possibilities of the analysis of potential energy of bubble-particle interaction on the basis of extended DLVO theory are discussed. Interaction energies of mineral silica, coal and pyrite particles with contact angles from 20 to 100 degrees and air bubbles in neutral and alkaline solutions are analyzed. It is shown that for hydrophilic silica, the formation of particle-bubble complexes (either in the area of primary or secondary potential minima) is impossible due to the high potential barriers (from 6000 to 140000 kT)and low values of the attraction force. There is shown that for coal and pyrite particles the energy of interaction vs. particle-bubble distance strongly depends on pH value. Improvement of floatability of minerals by the hydrophobization of their surface by collectors leads to the eliminating of potential barriers and the formation of the stable complexes of minerals and air bubbles in the area of primary potential minimum. In addition, due to hydrophobization of coal and pyrite changing pH has practically no influence on the energy of interaction. There are discussed results of the numerical calculations of normalized interaction forces in particle-bubble systems on the nanometer distances for pyrite, sphalerite, and chalcopyrite at contact angles up to 85° in comparison with the experimental data. The values of adhesion force for hydrophobized particles of coal and pyrite to air bubbles are about 10-5 N, that indicates stability of the formed flotation complexes. Examples of using the long-range and high-energy effect of hydrophobic interactions for improving minerals floatability are discussed. There are illustrated minerals wettability changes induced by the adsorption of thiol collector and hydrophobic polymer. Possibilities of flocculation and flotation of mineral slimes due the polymer-collector hydrophobic interactions are shown. Keywords: bubble-particle interaction, contact angle, extended DLVO theory, floatability

Sep 1, 2012

By C. Kleine

Coal sorting with an x-ray-transmission (XRT) sensor has experienced a lot of development since first described by Jekinson et.al. in 1974. Powerful computers and increasingly sensitive X-ray scintillation counters enabled the development of high-performance sensor-based sorting machines. The first industrial installation of a belt-type XRT-sorting for coal is in operation since 2004. It is upgrading high quality coal from 1% ash to 0.7% ash for cathode production. In comparison to the high quality coal which is treated with a belt-type sorter, the chute type sorter has been successfully optimized for high volume coal treatment of lower quality coals. This project was funded by the German Environmental Fund (Project Nr.244444). In cooperation with the RWTH Aachen University and Isambane Processing, CommodasUltrasort(now Tomra Sorting Solutions) conducted extensive pilot test work under production conditions in 2010 for the destoning of power station coal at Arnot Power Station in South Africa. The experience gained during this pilot test phase led to an optimized, redesigned PRO Secondary XRT Chute sorter which is now in operation at a South African coal mine. This flexible semi-mobile modular destoning plant is treating a size range of -120 mm +30 mm at a throughput of 150 tph. The implementation of this plant not only reduces the ash content, abrasiveness index and sulfur content significantly, but also reduces royalties, water treatment and transport costs.

Sep 1, 2012

By V. Hema

Granular materials are widely used in process industries, such as chemical, pharmaceutical, cement, food, detergents, and fertilizers. Mixing, blending, calcining, reduction, heating, and granulation of these materials are frequently carried out in rotating cylinders. In all of these processes, the mixing and segregation of these granular materials is important as this controls the secondary phenomena in the rotating kiln such as heat transfer to the material. A significant amount of work is available in the literature but to date these efforts have not been able to capture the important parameters affecting the mixing and segregation in rotating kilns. In addition, the range of parameter values studied so far is rather limited. Simulations of granular materials are based on either discrete elements or continuum models. The discrete element methods (DEM) combine semi-empirical models for the inter particle interactions with the equations of motion from classical mechanics to simulate the explicit paths of all granules in a rotary kiln, thus yielding realistic predictions of the mixing process. This approach is very demanding computationally, which strongly limits the number of granules and the number of revolutions in a simulation. Continuum models dispense with the discrete particles and can therefore be scaled up more easily. But the constitutive relations that serve as the foundation for continuum modeling are difficult to come by, and often only applicable to specific systems and conditions. Here we have chosen DEM simulation for investigating the mixing and segregation behavior of granular materials in a rotating cylinder. This work is directed towards demonstrating the capability of the prediction of the mixing and segregation behavior of granular materials in a horizontal rotating cylinder through discrete element simulation. Further the effect of particle size and rotational velocity on the mixing and segregation behavior is investigated. The simulation results are quantified in terms of mixing index, mixing rate, segregation index and percolation index. Keywords: DEM simulation, granular mixing

Sep 1, 2012

By P. Matias

The study involved two projects that will produce copper concentrate and may have their operations integrated. Transport by trucks, conveyor belt, and the equipment called RopeCon were evaluated as options for the ore transport between the sites. A rainforest stretch, that Vale S.A. demands to preserve, is situated between the projects. It was suggested to further review RopeCon because it presents minimal interactions with the environment. To design the preliminary system layout, a research was done on the rainforest cover height data, but the information found was scarce and imprecise. For preserving the local forest, the use of this data would conduct to the oversizing of RopeCon towers and, consequently, overestimation of its costs. For the acquisition of reliable information, a method was developed using local data acquired through airborne laser survey. The volume between the digital surface and terrain models was calculated to generate a surface representing the forest cover height. It was revealed, by plotting the points obtained from this surface, that 85% of the vegetation is below 25 m. This height is suggested to review the preliminary project with a more accurate design of the equipment towers, thus reducing its costs estimates. The method permits the precise location of the large trees, making easier to find a pathway, for linear-shaped facilities, that would minimize the creation of vegetation-free zones as a measure to protect equipments against falling trees and forest fires. Keywords: forest cover, mining projects facilities, digital models, airborne laser survey

Sep 1, 2012

By P. Somasundaran

Treatment of mineral surfaces with appropriate surfactants plays an important role in mineral processing operations such as flotation, flocculation and dewatering. Recently biosurfactants, in particular, have received a considerable amount of attention because of their unique surface active properties and biodegradability. In this work we examined the performance of biosurfactants, sugar based alkyl glycosides and sophorolipid esters as reagents to control the hydrophobicity of minerals with selectivity of adsorption on mineral surfaces for flotation applications. It was discovered that n-dodecyl-ß-D-maltoside adsorbs on alumina, titania and hematite but, interestingly, not on silica. The hydrophobicity obtained is governed both by the surface coverage as well as the nanostructure of the adsorbed layer in terms of orientation of the adsorbed species. Surprisingly, even though the above surfactants are non-ionic, their adsorption was pH-dependent. We have correlated this pH dependence to the type of species on the mineral surface. Also it is shown that mixing of these surfactants with traditional ones can help reduce the carbon footprint due to synergy between the reagents and help selectivity due to antagonism. The experimental results were analyzed to get information on optimal pH and dosage conditions, for mineral surface modification. The study provides guidance for mineral treatments using biosurfactants and the potential use of these next generation reagents in mineral processing.

Jan 1, 2014

By E. Guerrini, M. Maccagni, J. Nielsen

"The solution for the treatment of the EAFD has not yet been fully achieved. Some of this dust has still not found an appropriate final destination. Large consortium treatment plants are quite expensive both in terms of investment and operating cost. Meanwhile, the tolling expenses for steel production companies are becoming very important, causing them to look for alternatives. Some steel plants are looking to close their production loop by internal treatment of their dust. Some years ago, Engitec began studying the coupling of the EZINEX® Process, an ammonium chloride electrolysis to recover the zinc contained in the EAFD, with the INDUTEC® Process, a pyro process based on an induction furnace that can convert EAFD into a C.Z.O. similar to the Waelz oxide. The combination of these two processes provides an alternative to the existing treatment options and is particularly interesting for relatively small capacities. In this paper, we would like to give the latest update about these two processes and their possible integration INTRODUCTION Zinc is contained in numerous wastes and secondary raw materials that can be thought of as high zinc concentrate mines. This is a very interesting source of Zn that is typically easily exploitable. Unfortunately, only a portion of these materials are currently processed to recover the metal value, while stabilized or unstabilized landfilling is often the final destination. Pyrometallurgical processes are mainly used to convert the zinc into crude zinc oxide (CZO). The various processes are very similar and characterized by the fact that the zinc bearing materials are usually submitted to a thermal treatment [1] in which the zinc is reduced, vaporized and re-oxidized producing CZO. This material not only contains zinc oxide, but also relatively high concentrations of heavy metals. Many potential CZO sources, such as electric arc furnace dust (EAF), galvanizing ashes, brass foundry and converters fumes also contain chlorides, fluorides and alkali metals that will transfer to the CZO. The classic example is the Waelz oxide [2]. This CZO is an intermediate product that must be transformed into zinc salts or zinc metal. Until now, the conversion to zinc metal is done through two main processes: the sulphate leaching and electrowinning system and the Imperial Smelting Process (ISP). ISP is facing a crisis for technical and economic reasons that has led to the closing of most of the existing plants. In any case, before being fed to one of these two processes, the CZO must be treated to eliminate or reduce some of the contained impurities. In particular, the halides are most harmful to these processes."

Jan 1, 2018

By E. Guerrini, M. Maccagni, J. Nielsen

"The solution for the treatment of the EAFD has not yet been fully achieved. Some of this dust has still not found an appropriate final destination. Large consortium treatment plants are quite expensive both in terms of investment and operating cost. Meanwhile, the tolling expenses for steel production companies are becoming very important, causing them to look for alternatives. Some steel plants are looking to close their production loop by internal treatment of their dust. Some years ago, Engitec began studying the coupling of the EZINEX® Process, an ammonium chloride electrolysis to recover the zinc contained in the EAFD, with the INDUTEC® Process, a pyro process based on an induction furnace that can convert EAFD into a C.Z.O. similar to the Waelz oxide. The combination of these two processes provides an alternative to the existing treatment options and is particularly interesting for relatively small capacities. In this paper, we would like to give the latest update about these two processes and their possible integration INTRODUCTION Zinc is contained in numerous wastes and secondary raw materials that can be thought of as high zinc concentrate mines. This is a very interesting source of Zn that is typically easily exploitable. Unfortunately, only a portion of these materials are currently processed to recover the metal value, while stabilized or unstabilized landfilling is often the final destination. Pyrometallurgical processes are mainly used to convert the zinc into crude zinc oxide (CZO). The various processes are very similar and characterized by the fact that the zinc bearing materials are usually submitted to a thermal treatment [1] in which the zinc is reduced, vaporized and re-oxidized producing CZO. This material not only contains zinc oxide, but also relatively high concentrations of heavy metals. Many potential CZO sources, such as electric arc furnace dust (EAF), galvanizing ashes, brass foundry and converters fumes also contain chlorides, fluorides and alkali metals that will transfer to the CZO. The classic example is the Waelz oxide [2]. This CZO is an intermediate product that must be transformed into zinc salts or zinc metal. Until now, the conversion to zinc metal is done through two main processes: the sulphate leaching and electrowinning system and the Imperial Smelting Process (ISP). ISP is facing a crisis for technical and economic reasons that has led to the closing of most of the existing plants. In any case, before being fed to one of these two processes, the CZO must be treated to eliminate or reduce some of the contained impurities. In particular, the halides are most harmful to these processes."

Jan 1, 2018

By Skinner. W.

"Introducing cutting-edge development work, which aims to simplify mineral processing flow-sheets, reduce costs and address environmental issues. Over the past four years Innovative Mineral Processing Technologies Pty. Ltd (IMPTEC) Australia have developed a Super-fine Crusher and a Planar Magnetic Separator which offer low cost, wet or dry alternatives to conventional grinding and conventional magnetic separation. Each of these machines has been successfully trialed at pilot scale and are now in the process of transitioning to commercial scale. This paper reports on the progress made in each of these fields. The potential scope for application of super-fine crushing technology as an alternative to grinding is potentially expansive and could include beneficiation of metalliferous ores, precious metal ore processing, hydrometallurgical processing, industrial minerals and coal processing, plastic fillers and ceramics processing as well as processing of cementitious slags and fly-ash. IMPTEC have recently achieved outstanding results at pilot scale with a dry combination of super-fine crushing and planar magnetic separation, which offers an alternative to the wet processing of magnetic iron ores. The dry combination has set new laboratory performance benchmarks when compared with the industry standard wet Davis Tube Tester. The test results have also established a strong evidence base showing that super-fine crushing achieves liberation of value minerals at coarser sizes when compared with grinding. The dry combination of super-fine crushing and planar magnetic separation also addresses environmental issues and completely eliminates grinding. An IMPTEC super-fine crusher is currently undergoing commercial trials, generating ultra-fine products from granulated lead blast furnace slag for use as cement substitutes. The performance of the super-fine crusher on this extreme duty highlights the potential benefits of super-fine crushing over the wide range of industries and applications where conventional grinding is employed.INTRODUCTION Present day mineral processing practices can become anchored in convention, where, inefficient methodologies are recognized and accepted as “best practice” or “industry standard”. Motivated by this challenge, IMPTEC has undertaken the development of radically different and improved methodologies in the fields of fine comminution and magnetic separation. Whilst, crushing is much less energy intensive and generally less capital and maintenance intensive than grinding, the technology has stalled due to the lack of crushing devices, which have the capacity to adapt to fine and ultra-fine duties. Grinding practice advances have been achieved through major increases in machine size and power. However, these advances are also accompanied by major escalations in capital, operating and maintenance costs. The economics of this strategy has become increasingly questionable. A typical example is the viability of low-grade magnetite beneficiation, which can hinge largely on the cost of grinding to fine and ultra-fine liberation sizes."

Jan 1, 2018

By Q. W. Jiang

This paper presents a new process for producing industrial magnesium sulphate using waste water from titanium white plant and magnesium oxide from calcinations of magnesite ore as raw materials. With the laboratory experimental equipment, the waste liquid and magnesium dioxide react effectively at ambient temperature and under atmosphere pressure. Via the press filter, a clear liquid predominately containing magnesium sulphate is obtained. It is further evaporated and crystallized by cooling, separated by centrifuge and dried. Consequently a high quality of industrial magnesium sulphate is achieved as the final product. In the course of process, as the majority of valuable component (SO42-) is recovered in the final product, most of impurities from waste acid is being removed into the by- product. With the simple operational process, it is possible for titanium dioxide plant to resolve the environmental problem completely and benefit from the industrial magnesium sulphate product as well. The filter cakes containing valuable elements such as Mg, S, Fe, Mn, V, Ti are by-product proposed to be used for manufacture of agriculture fertilizer particularly for peanut planting.

Jan 1, 2014

By A. P. Das

Biomining technology focuses on achieving effective recovery of precious metals from their ores and concentrates using microbial techniques. Biomineral extraction of manganese from low-grade manganese ores using bioleaching was investigated in this paper. Five fungal strains were selected for screening of bioleaching of low-grade Mn ore collected from Sanindpur iron and manganese mines, Koira Sector, Keonjhar, Odisha, India. A fungal strain, Aspergillus niger was selected as it showed high efficiency of manganese leaching. Growth of the fungus was determined in terms of sbiomass dry weight and the final pH was monitored. The selected fungal strain was used for bioleaching of low-grade manganese ore of -150µm size particle size at 2 % pulp density with 2g/100ml sucrose concentration for duration of 20 days. About 60 % of Mn bioleaching was obtained with A. niger. The fungal species proved to be useful for manganese biomining.

Sep 1, 2012

By B. Vasanthakumar

In this study, the effect of adaptation of B.subtilis to sphalerite and galena with respect to the selective flotation of sphalerite from the sphalerite-galena synthetic mixture has been examined. The changes in the surface charge of the mineral and the bacterium, cell wall components and the profiles of secreted proteins are discussed. The flotation recovery of galena increases with the increase in the adaptation cycle of B.subtilis to sphalerite and galena, while the flotation recovery of sphalerite is independent of the adaptation cycle with either mineral. From the gel electrophoresis analysis, the protein profile for the unadapted and adapted cells is found to differ distinctly and this may be attributed to varying molecular weight fractions arising from different growth conditions. Electrokinetic measurements showed shifts in the iso-electric points of not only B.subtilis but also of the chosen minerals after adaptation. Additionally, the zeta potential of B.subtilis is found to become less negative after bacterial adaptation to the chosen sulfide minerals, while it showed an increase in the magnitude of surface negative charge after various enzymatic treatments. The change in the surface morphology and cell wall components such as phosphate, uronic acid and acetylated sugars of the bacterial species during adaptation to sphalerite and galena has been assessed. Selective flotation tests on a synthetic mixture of galena and sphalerite confirm that sphalerite can be preferentially floated from galena in the presence of the insoluble fraction of lysed B.subtilis cells initially adapted to sphalerite, with a high selectivity index. Keywords: bioflotation, b.subtilis, mineral adaptation, sphalerite, galena

Sep 1, 2012

By Yuliy Rubinstein

"The paper presents a analysis of the history and the trends of development of flotation apparatus. The laws of their evolution are stated and the place and role of column flotation are indicated. It is demonstrate development and different design of column apparatus. The major parameters of column cell such as diameter and height are discussed. Options are proposed on optimization of hydrodynamic characteristics of columns with large-capacity cells. High efficiency of columns with cell height of 4-6 m is shown on examples of coal preparation. A new generation of multi sectional column cells has been developed. In the cells are zones with different aerohydrodynamic parameters: combined in the machine are co-and counter- counter flows of phases. The transition from single-chamber column to multi-sectional apparatus makes it possible to create favourable hydrodynamic and aeration regimes in each section of the column dependent on the pattern of material distribution by floatability. Efficiency of application different designs column apparatus uses shown on the example of enrichment of various non-ferrous metals ores and coal. The principles of mathematical simulation of the flotation process are developed. A scaling-up procedure for column cells was based on flotation macro- and micro- dynamics simulation.INTRODUCTIONColumn flotation is considered to be one of the most significant achievement in the field of mineral processing in the end of last century. We cannot but agree with this statement but would like to understand what underlies this success. History of the flotation column can not be considered in isolation from the development of flotation apparatus on the whole. It can be argued that the first attempt to switch from oil flotation to the use of bubbles during flotation was performed Bessel brothers in 1877 (Berlin patent 42 class 22, July 2) and in 1886 (Berlin patent 39,369 May 12). According to these patents, the crushed ore was mixed with oils , hydrocarbons and water. Then the pulp received in this way was heated up to boiling . Air bubbles and steam formed during boiling facilitate the flotation of ore particles coated with oil (first patent) or bubbles been generated by the reaction of lime with acid (second patent). The evolution in the design of the flotation apparatus incorporates the following key stages. Further development is connected with the Francis Elmore’s idea to use gas bubbles received at water electrolysis (UK, 13578; 1904). This method was not introduced then, but much later, in our time and on the essentially new technical basis it found a use for sewage treatment (electroflotation). Gas bubbling under vacuum patented also by Elmore (UK, 17816; 1904) obtained a practical use. It should be noted that the method did not lose its importance till now. The design of the camera has been surely optimized (Glembotskii etal, 1963). A year later A. Macquisten (UK, 26712) developed pressure (compression) flotation. Thus, the H.Sulman, H.Picard, D. Bell’s (US, 853120, May 29, 1905) basic patent and the adjoining T. Goover’s patent 1910 (US, 953746) formed the basis of the first and most important element of modern flotation: flotation with air bubbles sucked in from the environment. In 1914, J.Callow received a patent for on an apparatus where air was sparged through the porous false bottom of the cell ( US, 1104755). Woolen fabric folded four times was fixed on a perforated metal frame to be used for air sparging (Gaudin, 1932). The following year Durrel created the prototype of the injection (ejector) apparatus. The jet aerator made it possible to significantly reduce the size of the bubbles, in comparison with the filter cloth. An apparatus with slurry pre-aeration in an airlift prior to feeding into separation cell was developed Wagner in 1917 (US, 1235083). And finally, the first column apparatus with a counter-current of slurry and air was developed by M. Towne and S. Flynn in 1919(US, 1,295,817). ("

Jan 1, 2018

By Elisabeth Schmidt

The conventional Canadian oil sand processing, the Clark Rowe process, is associated with many risks for the environment and high energy costs. To recover the bitumen from the oil sand (tar sand), large quantities of water have to be heated up and mixed with caustic soda and the oil sand. During this process, tailings with stabilized clay colloids are formed and dumped in tailings ponds. To avoid these disadvantages, a new, non-aqueous extraction process is to be established. Organic solvents are used instead of water and caustic soda to mobilize the bitumen from the sand-clay mixture. Pressure filtration, washing and steam pressure filtration are part of the new concept. A mixture of organic solvents and the oil sand is first pressure filtrated in a nutsch filter until a saturation level of one is obtained. After the cake has been formed, the filter cake is washed with organic solvent to flush the bitumen loaded solvent out of the cake. The following steam pressure filtration mechanically and thermally removes the remaining volatile components of the solvents from the filter cake. The filtrates from the pressure filtration, the washing phase and partly from steam pressure filtration are subsequently thermally treated to recover the organic solvents and obtain a higher bitumen concentration in the mixture. This mixture is then lead to an upgrader to win synthetic crude oil (SCO). The recovery of bitumen in the conventional hot water extraction process based on the Clark Rowe process can, in highly optimized plants, achieve between 88 and 92 %. Variation of oil sand properties leads to an actual range of between 80 and 90 % of bitumen recovery. With the alternative process based on organic solvents, the bitumen recovery exceeds the recovery of the conventional process by up to 16 percentage points. The composition of the two organic solvents in the first step of forming a suspension with the oil sand is important. The aromatic component is crucial for liberating and solving the asphaltenes, which tend to flocculate. The order of the two components of organic solvents is also important in the washing step. The paraffinic component is essential to achieve successful steam pressure filtration with respect to fast steam breakthrough and a filter cake free from organic compounds, as a result of its lower boiling point. Keywords: oil sand, filtration, organic solvents, pressure filtration, steam pressure filtration, filter cake washing

Sep 1, 2012

By N. Vorob?ev-Desyatovskii

The process of gold(I) adsorption on activated carbon (AC) from aqueous Na[Au(CN)2] and the state of the adsorbed gold cyanide complex on the adsorbent surface was investigated by photometry, XPS, XANES methods. By DFT method, quantum-chemical calculations were performed of the gold cyanide species on activated carbon surface. It was established that the binding of gold(I) with the surface of carbon involved several simultaneous processes governing the selective adsorption of gold(I) from the cyanide solutions.

Sep 1, 2012

By P. K. Fedotov

Centrifugal separation opens its new application fields in the Mining Industry. The up-to-date equipment for ultra-fine ore and concentrates grinding allows an efficient use of centrifugal concentration for micronic gold grains recovery. Moreover, advanced centrifugal concentrators are presented on the market: concentrators with continuous concentrate discharge designed both for ore and non-metallic minerals concentration process. The conducted tests proved the centrifugal concentration to be efficient process for gold recovery from finely ground concentrates and ores (less than 20 µm). Knelson concentrator application for such a fine material in different process circuits makes possible to raise the total gold recovery level of plants. In the circuits of coal plants and in course of coal slimes treatment the centrifugal concentration may be used before flotation in order to improve process performances. A centrifugal concentrator KC-CVD with continuous concentrate discharge working on 0.3 (0.5)mm fraction before flotation is

Jan 1, 2014