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By Sarah K. DeBono, Alan J. Monaghan, Emmanuel V. Manlapig, Gregory J. Harbort

"The Jameson Cell is a type of flotation machine in which air and pulp are brought together in a vertical tube called a downcomer. Within the downcomer the air and pulp are dispersed into a dense foam of fine bubbles, which creates a favourable environment for bubble-particle collision and subsequent collection of hydrophobic particles. The intense collection zone within the downcomer can be considered similar to the zone between the rotor and stator in mechanical flotation cells.Research into the bubble-particle collision and fluid dynamics of mechanical cells rotor-stator zone has been limited by the difficulty of achieving accurate measurements in production sized machines. With the Jameson Cell the downcomer is largely external and separated from the flotation tank, allowing ready access to the primary contacting zone for measurement and analysis.An investigation has been undertaken into the operating characteristics of the downcomer relating to bubble-particle collision. An effective mapping of the downcomer has been made through measurements of void fraction and bubble size taken across cross sections of the downcomer. Analysis of these measurements has provided an interpretation of the variations in the air and fluid dynamics, bubble size and distribution throughout the downcomer chamber."

Jan 1, 2003

By Jim Petrie, Mary Stewart, Damien Giurco

This paper describes a generic approach to analysing the environmental and economic performance of a generic global mineral/metal value chain, with the express view of improving the quality of prospective decision-making within the industry in order to ensure more sustainable outcomes. As a point of departure we propose that it is not possible to place metals in the context of the sustainable development of society without paying due regard to the entire metals value chain. Thus, the starting point for this analysis is the development of a global stocks flows and transformations model, for the metal of interest. Any aspect of the value chain, e.g. “metals refining, “goods manufacture”, “use and disposal”, can be assessed, either relative to other stages in the value chain, or in more detail by focusing on the technologies used within that stage. The use of this model as a decision support tool is explored here for the case of copper. Both primary and secondary production routes are enumerated, covering a range of processes, for seven distinct geographic regions around the globe. The value of the modelling approach is explored for different energy mixes. In particular, the case study examines the impact of increased recycling on the (re) distribution of global and regional environmental impacts for technologies-in-place in these different regions. The aim of these case studies is to highlight to the minerals processing and metals refining industries their potential role in a more sustainable global society.

Jan 1, 2003

By D. Whittles, S. Kingman, K. Jackson, S. Bradshaw, N. Miles

The influence of microwave energy at high electric field strength on ore strength has been investigated. Two ores of varying mineralogy were treated in both multimode and single mode microwave cavities. After treatment, any change in strength relative to untreated ore was established. It was shown that in the multimode cavity reduction in strength was related to the applied power level. Results of tests carried out in the single mode cavities showed that, for both ores, reductions in ore strength > 50% could be achieved in very short periods (<1 second). Thermal stress analysis showed that the mechanism of microwave induced failure was the development of tangential stresses at the grain boundaries. It was concluded that operation at 915 MHz with high power and short residence times gives feasible scale-up possibilities.

Jan 1, 2003

By Matti Kongas, Kari Saloheimo, Antti Remes

"The paper studies the control performance of the flotation process as a function of the measurement accuracy and sampling frequency of an on-stream XRF analyzer, using a simple dynamic model. An additional aim is to assess how the economical result of a mineral flotation process depends on the quality of process control based on the on-line elemental assays.An on-stream XRF analyzer measures the concentrations of slurry lines in a continuous cycle from several process points. The control performance depends on the analytical accuracy and sampling frequency of the concentration measurement. With a long cycle time, the state of the process changes before a new measurement becomes available. With short measurement times the statistical variance of the counted Xray pulses increases, increasing the random error in the analysis. In addition, the measurement accuracy depends on the concentration of the component to be measured from the slurry.To quantify the effect of analysis error and frequency to process control, a simple dynamic process model is created in the Matlab environment. Data from a copper flotation circuit is used as a test case. The process model comprises a first order reaction equation and the grade-recovery -relationship estimated from process data. The control was modeled using the control strategies implemented into a rule based advanced control system. The economical performance of the control was studied by calculating the overall net smelter return at various analyzer parameter combinations."

Jan 1, 2003

By Xie Jiyuan, Hu Yuehua, Yang Songrong, Zhu Zhansheng, Qiu Guanzhou

"By the end of 2000, the first bio-oxidation plant in China that designed by ENFI come successfully into commercial operation in Yantai Gold Smeltery. Its capacity is 50t/d of refractory gold ore concentrate. After the extension, the capacity of bio-oxidation plant reached 80t/d of refractory gold ore concentrate at end of 2001.The refractory gold ore concentrate treated is from different gold mines. After proportionate feeding, the feed typically consists of Au (52.7g/t), S (24.42%), As (3.58%).The bacterial culture used in the bio-oxidation circuit is taken from a mine in south of China, and has been grown over 20 years on a variety of sulfide concentrates in a laboratory of mineral processing, and has shown to be adaptive to growth in a high concentrations of arsenic. It is a mixture of mesophilic microorganisms. The nutrients used in the bio-oxidation process are (NH4)2SO4, KH2PO4, KOH.Before feeding to bio-oxidation circuit, the concentrate would be milled to minus 43µm. The biooxidation product is fed to solid/liquid separation system that consists of a thickener and two press filters, solid from the system is fed to CCD circuit, liquid from the system is fed to neutralization area. The neutralized product is fed to another solid/liquid separation system, and the solid from the system is disposed of on a wasted quarry pit, the liquid from the system is returned to bio-oxidation circuit for reusing."

Jan 1, 2003

"The Merensky Reef is a platinum group minerals (PGM) bearing reef in the Bushveld Igneous Complex in South Africa. The reef has been treated by bulk PGM and sulphide flotation with the aim of maximisingthe valuable minerals recovery and gangue minerals rejection.Synthetic water with a calcium concentration of 80 ppm and 500 ppm was prepared and the flotation results obtained were compared to a simple electrolyte in order to determine the effect water quality has on pentlandite and pyroxene surface alteration and, ultimately, floatability. During the study, the possible effect of interactions between the minerals investigated and Ca2+ ions in the presence of sodium isobutyl xanthate was studied at pH 6 and pH 9 by means of zeta potential determinations, microflotation tests and ToF-SIMS analysis.The results obtained on 1:1 pentlandite-pyroxene mixtures showed that the quality of process water plays an important role in flotation. The flotation recoveries of pentlandite and pyroxene were lower in synthetic process water compared to those obtained in a simple electrolyte solution."

Jan 1, 2003

By Kauko T. Ingerttilä, Jouko O. Kallioinen, Jaakko O. Leppinen, Alexander V. Lashkul, Vladimir E. Nenno

"Separation in Froth (SIF) is a process for the separation of mineral particles during their descent downwards through a moving froth layer, generated on the surface of water or some other liquid media by means of a bubble generator and frother. Due to the special operation principles of SIF it is possible to separate mineral particles that are about 10 times coarser than the optimal particle size for conventional flotation. In this paper the performance of the SIF technique is presented in the separation of apatite, calcite and silicate minerals from various industrial sources, based on tests with laboratory and pilot plant-scale SIF machines. Basic laboratory test results of the flotation of pure diamonds are also presented.It was shown that calcite, apatite and diamonds with particle size up to about 3 mm can be successfully floated with SIF at high recovery and grade, provided that the degree of liberation is sufficiently high. Coarse calcite (+0.25-2.8 mm) was concentrated with reverse SIF in one flotation step at 87% recovery with better than 99% grade. Apatite particles coarser than 0.2 mm are not well floated in the conventional flotation circuit leading to high P2O5 content in the coarse size fractions of flotation tailings. On the contrary, SIF is capable of recovering such coarse particles at high recovery. However, P2O5 content of the SIF tailings starts to increase at about 0.7 mm due to insufficient liberation of apatite. At higher particle size the lack of hydrophobicity of apatite particles is also likely to lower the recovery.The pilot plant testwork showed that SIF can be successfully used at operating plants not only for preliminary upgrading of the feed of conventional flotation, but also for producing final grade calcite concentrate (>99.5%) from the screen overflow or from the cyclone underflow in a particle size range up to 1 mm. It was particularly promising that the separation took place in one SIF flotation step, instead of several stages of the conventional flotation circuit, with over 90% calcite recovery. The specific capacity determined with the 1 m2 pilot plant unit was approximately 30 t/m2h. Simultaneously the consumption of chemicals was significantly lower than for conventional flotation."

Jan 1, 2003

By Tamara F. Kondrateva, Evgenia E. Savari, Galina V. Sedelnikova, Rauf Y. Aslanukov, RAS (INMI), Grigori I. Karavaiko

"The investigation is dedicated to study of biohydrometallurgical processing of refractory gold-arsenic concentrate with the large content of pyrrhotite. Sulfide concentrate of chemical constituents: 75g/t Au, 4,7g/t Ag, 6,3% As, 29,3% S, 2,3% Sb, 0,5% ? (organic) and of mineral composition, %: 11,8 arsenopyrite, 39 pyrrhotite, 12 pyrite, 2,9 antimonite and the rest – aluminosilicates, carbonates and quartz, was studied. The recovery of gold from concentrate by cyanidation is 51,2%. The rest of gold is embedded as finegraded segregation in sulfides.Sulfide oxidation process study is described. Bacterial oxidation was executed on a pilot laboratory unit using combined autotrophic bacterium: A. thiooxidans , A. ferrooxidans, Leptospirillum ferrooxidans and sulfobacillus thermosulfidooxidation, pH=1,5-2,2, t=28-32?C, oxidation time 120 hours. Pyrrhotite is the least stable sulfide mineral with electrode potential 0,45V versus arsenopyrite (0,55 V) and pyrite (0,55-0,6 V) and is oxidated primarily. Pyrrhotite oxidation is followed by large amount of elemental sulphur, which has a bad influence on cyanidation.It’s established that the rate of arsenopyrite (for the first 48 hours) from concentrate containing 39% pyrrhotite is 2-3 times as less as the rate of arsenopyrite bio-oxidation from concentrate without pyrrhotite. The arsenopyrite bio-oxidation is accelerated only after the elemental sulfur was oxidized by bacterium A. thiooxidans and elemental sulfur percentage was reduced from 6,8 to 3,9%. The bacterium concentration is increased from 2,5x107 to 2,5x109 cells/ml. Almost full oxidation of arsenopyrite (98%) and pyrrhotite (98- 99%) is finished in 120 hours. We have studied two pretreatment methods for elimination sulfur content influence on cyanidation: aeration in lime and electrochemical treatment. Such an operation enables to have supplemental oxidation of elemental sulfur and other oxygen and cyanide absorbants before cyanidation. After treatment the content of elemental sulfur was decreased from 3,9 to 2,2%, gold recovery from 90 to 96% and cyanide consumption from 16,2 to 7,2 kg/t decreases. The content of toxical rhodonite-ions in liquid phase of pulp and disinfection reagents consumption were decreased as result of elemental sulfur content in bio-oxidated product reduction."

Jan 1, 2003

By Rhulani F. Maluleke, Francis W. Petersen, John H. Marsh, Johann de T. Steyl, Allan Nesbitt

"Pressure leaching of chalcopyrite and nickeliferrous pyrrotite at temperatures between 105 and 200 ºC has been proposed as a potentially viable route for the extraction of mineral elements from sulphide concentrates. In general, these concentrates contain iron, and the economic success of the processes is partially dependent on the choice of the environmentally acceptable iron-removal technique. One of the most widely used methods for the removal of iron from sulphate liquors is precipitation as hematite, goethite, or jarosite. The nature of the iron precipitate formed, dictates downstream dewatering and residue treatment and disposal options. However, a better understanding of iron precipitation under the defined process conditions would consequently be of benefit in process design and optimization.This study investigated the precipitation of iron in the autoclave at temperatures between 105 and 200 ºC. The effects of temperature, acid concentration, iron concentration, and the presence of other metal cations on the nature and composition of the precipitates were determined."

Jan 1, 2003

By M. Barsky, E. Barsky

A study was conducted to elucidate the relationship between the hovering velocity and the particle settling velocity. The experiments were carried out in a water medium on five materials ranging in density from 1.070 to 4.000 kg/m3. Analysis of the results with allowance for the distribution of stream velocities over the cross section of the pipe revealed that the final settling velocity of the particles was equal to their local hovering velocity (on the stream axis), and not to the average velocity of vertical flow as is generally believed. It therefore follows that the kinetic structure of the stream must be taken into account when constructing theoretical models of the process for purposes of computation. In addition, the optimal stream velocity is not always equal to the hovering velocity and in fact is governed by other factors as well. Illustration is provided by the results of a study conducted in a vertical cascade classifier comprising eleven identical stages. The feed material was introduced at each stage successively beginning with the topmost (i* = 1 ) and ending with the lowermost (i* = 11). First, the stream velocity that yields optimum separation conditions at each stage of the cascade (i.e. k=50%, k being the yield of a given size class in the fines for a single stage) was sought. Subsequently the conditions of optimal separation for the instrument as a whole were determined (i.e. F(x) = 50%, F(x) being the yield of a given size class for the entire instrument). The results of the study are presented in the table.

Jan 1, 2003

By A. C. Maffei, M. V. Lins Gonçalves

Ore concentration processes are a function of the respective particle size distribution; however, most of them do not use an efficient operational method to determine it. From a practical point of view, the surface area can be calculated for any size analysis. The physical principles for determining the size distribution in each method are different, for the results will not be compared directly. During the development of the research project of the sulfide ore flotation method using inert gas, different methods for calculating the specific surface area have been used, such as sieving, sedimentation/X-ray, laser diffraction and BET, i.e. specific techniques to determine the specific surface area of copper and gold ore concentrates. The statistical method of minimum squares was used to achieve practical correlation equations among them. Regarding these two ores, if one knows a specific surface area value using one of the methods above, one can predict the result of the others. Diminution of the reagent consumption was so controlled and it could be even decreased by using inert gas.

Jan 1, 2003

By Frank Cappuccitti, Stephen Chryssoulis, Stamen Dimov

Surface organic microanalysis of platinum (Pt) and palladium (Pd) minerals by TOF MS1 is an attractive complement and potential alternative to conventional collector screening methods. Its attractiveness lies on its ability to focus on individual Pt and Pd mineral particulates, therefore providing a more targeted approach. The only requirement is knowledge of the occurrence (mineral composition, grain size and association) of Pt/Pd in the feed sample. This newly developed technique can detect, and identify collectors and quantitate loadings on individual Pt/Pd mineral particulates at plant concentration levels. Using this technology, collector loadings were measured on Pt and Pd metal plates and on PtS2 and PdS particulates which had been exposed together to aqueous solutions of different collectors. Thus, data were obtained on collector selectivity, the effect of sulphur; and of depressants, the latter in combination with TOF-LIMS2 results. Staged rougher tests on North American and UG-2 ores linked Pt/Pd flotation kinetics with collector loadings and ultimately grade/recovery.

Jan 1, 2003

By Francesco Vegliò, Luigi Toro, Francesca Beolchini, Francesca Pagnanelli, Stefano Ubaldini

"Biosorption is an innovative technology used to remove heavy metals from aqueous solutions from mining waters and other industrial wastes. A wider application of this alternative process is strictly dependent on the understanding of the chemico-physical aspects involved, in order to optimize the operating conditions. Mechanistic models are the most useful tools used for understanding purposes, even if the empirical models are still widely applied for their simplicity.In this paper especially propagated biomasses of Sphaerotilus natans, calcium alginate and some waste materials were tested as adsorbents for single and binary solutions containing heavy metals at different pH. The equilibrium experimental results were fitted according to empirical and physical models with growing complexity outlining the inadequacy of the predictive models; in fact, the non-ideal interactions among metals require the insertion of additional correction parameters."

Jan 1, 2003

By Francesco Vegliò, Luigi Toro, Francesca Pagnanelli

"Different hydrometallurgical processes have been studied in order to recover manganese(II) from oxidised minerals such as MnO2 (Vegliò and Toro, 1994). An innovative acid reductive leaching carried out in soft experimental conditions was here considered using agro-industrial wastes containing carbohydrates as reducing agents (Vegliò et al., 1998).The leaching process was investigated from a kinetic and equilibrium point of view in order to optimize the experimental conditions and obtain high purity and concentrated MnSO4 solutions.The overall leaching process (not considering the complex network of intermediate oxidation reactions of the carbohydrates in hot sulphuric acid medium (Vegliò and Toro, 1994)) can be described by the following reaction:24 MnO2 + C12H22O11 + 48 H 24 Mn2+ + 12 CO2 + 35 H2O (1)A Shrinking Core Model (SCM) was modified by a variable activation energy term to take into account both the variable reagent concentrations and the reaction rate change with respect to the manganese dioxide conversion. The influence of the particle size in the kinetic model is discussed with the support of SEM analysis and BET surface measurements before and after leaching.Manganese extraction yield was maximised (170-190 g/L) using appropriate carbohydrates and acid excesses, while impurity concentrations were kept low (Fe<10ppm and Ca<300ppm) pre-treating the ores, using hydroalcoholic leaching medium and different combinations of down-stream processes. In particular precipitation, solvent extraction and adsorption onto active carbon were tested to eliminate Fe and Ca from MnSO4 solutions."

Jan 1, 2003

By K. A. Natarajan

Interaction with microorganisms results in significant surface chemical changes on minerals. For example, chemolithotrophs such as Thiobacillus ferrooxidans and Thiobacillus thiooxidans significantly alter the surface chemistry of several sulfide minerals such as pyrite, chalcopyrite, sphalerite and galena. Heterotrophic bacteria such as Bacillus sp. could alter the electrokinetic properties of oxide minerals such as hematite, alumina, silica, kaolinite and calcite. Microbe-mineral interactions could thus be beneficially utilised in mineral beneficiation as different from bioleaching. Microbially induced mineral beneficiation unlike bioleaching deals with interfacial phenomena at mineral-solution-bacteria interfaces and surface chemical changes are brought about at very rapid rates amounting to a few minutes resulting in mineral separations in an aqueous medium.

Jan 1, 2003

By Elzbieta Mielczarski, Jerzy Mielczarski, Jan Drzymala, Yann Duval

"The monoalkyl ethers of polyethylene glycols are universal flotation reagents because they can be used as collectors, frothers, surfactants, and depressants. Their collecting power was demonstrated for different minerals including coal and quartz.It was confirmed in this work that monoalkyl ethers of polyethylene glycols could be used as collector in flotation of quartz in a monobubble Hallimond cell. Since feldspar does not float in the same cell, it was also shown that selective separation of quartz and feldspar in the Hallimond tube is possible. However, a trail to use the monoalkyl ethers of polyethylene glycols compounds for separation of quartz and feldspar by flotation of mixture of these minerals in a Mechanobr laboratory flotation machine was futile, indicating that these reagents required special environment for flotation.Most probable parameter responsible for a decrease in quartz flotation in the flotation machine is the hydrodynamics of process, and different adsorption/desorption conditions. To prove this, another series of experiments was carried out to separate quartz and feldspar, in which a laboratory flotation column was utilized. The performance of the flotation column was in between that of in the Hallimond tube and flotation machine. These experiments confirmed that the hydrodynamics of flotation plays a vital role in flotation of quartz with monoalkyl ethers of polyethylene glycol compounds."

Jan 1, 2003

By S. K. Kawatra, S. J. Ripke, T. C. Eisele

"An estimated 600,000 tons of bentonite clay are used annually in the U. S. as binder for production of iron ore concentrate pellets. Since this is a significant cost item for the plants, and the addition of bentonite to the pellets contributes undesirable silica into the finished pellets, there is considerable incentive for finding methods to reduce bentonite use. One way to reduce bentonite levels is to selectively use those bentonites that are most effective in this application, so that a lower dosage will still produce a sufficiently strong pellet. Unfortunately, there are no satisfactory methods available for accurately predicting which bentonites are actually most effective, short of using them to actually make pellets. One of the popular methods for attempting to evaluate bentonites is the “Plate Water Absorption” (PWA) test. While some plant operators accept the PWA results as indicating the relative quality of bentonites, others disagree and claim that, over a fairly broad range of values, PWA does not correlate with bentonite performance.Since both Ca+2 and Mg+2 ions are known to reduce the swelling and water absorption capacity of bentonite, it was believed that the presence of these ions in plant recycle water could be changing the bentonite performance. Since the standard PWA test uses only distilled water for its measurements, it could not detect these effects. Experiments were therefore carried out on a number of different bentonites using a modified PWA tests, with plant recycle water replacing the distilled water. These experiments showed little effect of the plant water on the PWA value, and chemical analysis of the water showed that the levels of dissolved salts were quite low.Water and accompanying salts were then extracted from a magnetite concentrate filter cake by rinsing with distilled water. Analysis of this water showed an extremely high level of dissolved salts, particularly salts of calcium and magnesium. When concentrations were compared with the recycle water from the plant filters, it was determined that levels of Ca+2 and Mg+2 retained in the filter cake were over 500 times higher than levels in the recycle water. This extreme elevation of soluble salts in the filter cake is believed to be due to adsorption of these ions into the electrical double layer of the magnetite particles."

Jan 1, 2003

By Hong Nguen Vu, Pavla Ovcarí, Peter Fecko, Barbara Tora

"The goal of the work was verification of bacterial leaching on the samples of black coal. From the results obtained it was clear that the coal is very well leached by Thiobacillus ferrooxidans and this technology can be used for coal desulphurization. A leaching time of one month is required, to remove 65% of total sulphur and 85% of pyritic sulphur.Microscopic evaluation of samples from Jaworzno showed, that it should be classed as a coal with low coalification, probably from black coal hemiphase. Macerals of the liptinite group were well distinguishable; they were of a dark brown colour. Evidence of coal mass oxidation was apparent on the fresh sample; in the test samples (during bacterial leaching) small grains were oxidised."

Jan 1, 2003

By Rebecca Hope, Derick Moolman, Frikkie Malan

"Despite the lip service that has been paid to pro-active plant maintenance processes over recent years, a significant portion of maintenance in industry is still reactive. The business driving force to prevent expensive production opportunity costs arising from “break-down maintenance” is obvious. Various benefits can be derived from successfully deploying remote equipment diagnosis technology and associated business processes.From an end-client’s viewpoint these include the ability to predict and take actions to prevent equipment breakdowns, increasing the lifetime of equipment by responding to appropriate operating instructions and therefore improving the return on capital expenditure. Better planning and scheduling of maintenance priorities and resources with performance measures like an Equipment Health Index are also possible. The knowledge that a qualified supplier engineer is constantly in touch with the operating conditions of their equipment, albeit remotely, is more than a comfort, and can be translated into quantifiable cost savings and improved supplier service levels."

Jan 1, 2003

By Jian Zhang, Yongfu Yu, Fuguang Zhang, Liping Che

There is one large-scaled iron ore deposit in Inner Mongolia of China, but it is very complex which includes about 170 types of minerals and 71 elements. The hematite, magnetite are mainly iron ores. It is difficult that the iron mineral can be separated efficiently by common dressing methods due to the complexity, and the iron concentrates in the mineral processing factory contains many foreign substance such as K, Na and Si so that the process in iron mill is influenced because of the foreign substance, so it is vital reducing the foreign substance.

Jan 1, 2003