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By A. Pankewitz

The well-established on-line particle size analyzer OPUS manufactured by Sympatec GmbH, has been successfully implemented in several mining and industrial minerals project. OPUS monitors the particle size distribution in 31 fractions as well as the solid concentration in opaque and highly concentrated ore and mineral slurries on-line in real time e.g. behind mills or cyclones applying 31 ultrasonic frequencies for highest resolution. Ultrasonic extinction overcomes all limitations known from optical and mechanical systems like contamination, blockage and wear. OPUS measures slurries in their original state without any dilution, hence no extensive sampling procedure or sample conditioning is required thus no dilution errors occur. Due to the OPUS design and suitable algorithms entrained air bubbles do not affect the quality of analysis at all. The sensor covers particle size distributions from 0,01 to 3.000,00 µm and solid concentrations up to 70 % by volume and can be easily adapted to a number of production lines simultaneously. Jiangxi Copper?s Dexing Mine is one of the biggest copper mines in Asia and among the first users for OPUS on-line particle size and concentration analysis in mining industry. OPUS is connected to 2 process lines. Jiangxi Copper has implemented OPUS for into their central control system for the grinding & classifying circuit of one SAG mill and one ball mill. Analysis data and process control as well as optimization based on OPUS particle size and concentration measurements will be discussed Keywords: particle size analysis, ultrasonic extinction, concentration analysis, grinding control

Sep 1, 2012

By T. Bhambhani, O. Yavuzkan, D. R. Nagaraj

"The recovery of oxide Cu minerals by flotation is a longstanding challenge in the minerals industry, especially for high acid-consuming ores which would not be economical for direct acid leaching. Sulfidization (often using controlled potential sulfidization or CPS) using NaSH (or Na2S) followed by flotation using traditional sulfide collectors is the widely used technique. CPS has certain limitations: a) inability to recover certain oxide Cu minerals because they are refractory to sulfidization, b) high consumption of NaSH (or Na2S), and c) potential health and safety hazards associated with NaSH (and Na2S). Flotation of oxide copper minerals using alkyl hydroxamate (AHX) collector has been studied extensively. Investigations using single minerals and laboratory ore flotation have been conducted in the past to demonstrate the efficacy of alkyl hydroxamates. The technology has been used intermittently in plants. One of the main challenges in plant use has been quantifying the true potential for alkyl hydroxamates for recovery of various oxide Cu species in complex and variable ore systems and identifying the most suitable conditions for optimal use. Quantitative mineralogical analysis using QEMSCAN was used in this study to characterize flotation products lab flotation samples. Analysis of concentrates and tails from hydroxamate flotation and CPS flotation stages demonstrated that certain oxide Cu minerals respond exclusively to alkyl hydroxamates and not to CPS. The hierarchy of interaction of AHX with the various oxide Cu minerals could be inferred from these studies. Finally, these studies also allowed quantification of a group of minerals species, which (erroneously) report as part of the Acid-Soluble Cu [ASCu] but cannot be recovered by flotation, thereby facilitating an estimation of the true recovery potential for alkyl hydroxamate.INTRODUCTIONCopper that is economically recoverable occurs in three major types of ores, which are defined by the modal mineralogy of Cu. For sulfide ores, Cu occurs as sulfide minerals and is satisfactorily recovered by flotation using sulfide collectors. Non-sulfide ores, which contain Cu in the form of oxides, phosphates, carbonates and silicates, described in the industry as “oxide” ores (or ores containing “acid-soluble” Cu or ASCu), are currently treated using hydrometallurgy, which involves leaching with dilute sulfuric acid followed by solvent extraction and electrowinning, unless the ores contain acid consuming gangue minerals such as dolomite. For mixed sulfide-oxide ores (i.e. containing both sulfide and oxide Cu minerals) that do not contain acid consuming gangue minerals, Cu values are easily recovered by flotation of sulfide Cu minerals followed by leaching of oxides (only when a leach plant is available). However, when the ore contains acid consuming gangue minerals flotation is required to recover both sulfide and oxide Cu minerals."

Jan 1, 2018

By Indresan Govender

A continuum based granular flow model of charge motion that combines the inherent frictional nature of particles with its distinctly fluid-like structure is presented. Starting with Newton?s 2nd Law on a volume element of charge, we derive the velocity field in the bed free-surface and the rising en-masse region. Invoking flux conservation within the two regimes of interest then yields a (simple) differential equation for the free-surface of the charge body. Combining the velocity field gradients with a suitable constitutive choice for the shear stress completes the picture with a description of the in-situ rate of shear power dissipation in a tumbling mill ? a mechanistically correct account of power draw in a tumbling mill. Positron Emission Particle Tracking (PEPT) was used to measure the in-situ flow fields of the charge within opaque systems like tumbling mills. The accurate velocity and mass distribution derived from PEPT form the basis for direct verification of the resulting granular flow models. In this regard a wide range of milling conditions is investigated and presented in this paper.

Sep 1, 2012

By E. Szelag

The adsorption and stabilization of mineral dispersed systems by using Pluronic copolymers with different molecular weights and EO content has been studied. The role of sequential adsorption of EO-PO copolymers and cationic surfactant (CTAB) on the carbonate particle properties and in determining the stability of their suspension was studied with particular attention to the conformation of the polymer at the solid-liquid interface. The purpose of this work was to investigate the flocculation phenomena, influence of polymer molecular size on stability of suspensions of magnesite and dolomite and the effect of addition mode of polymer and surfactant. The suspension stability measurements and the determination of sedimentation speed were carried out using an optical analyser (Turbiscan). In most of investigated cases, the biggest floccs and the fastest sedimentation were found for low concentrations of copolymers.

Jan 1, 2014

By Sun Chuanyao, Cao Fei, Sun Desi, Zhou Dezhi

"The research applies the density functional theory and molecule design technology to design and synthesize the novel flotation collectors for copper-sulphur separation. Density functional theory (DFT) was applied to investigate the electronic properties of O-isopropyl-N-benzyl thionocarbamate (IP-BIAN) and O-isopropyl-N-ethyl thionocarbamate (Z-200). The calculation results show that both the energy of highest occupied molecular orbital (EHOMO) and the lowest unoccupied molecular orbital (ELUMO) of IP-BIAN are smaller than that of Z-200, electronegativity of IP-BIAN is higher than that of Z-200. According to the Klopman’s generalized perturbation theory, the collecting power of the two compounds is predicted to be Z-200 > IP-BIAN, the selectivity of IP-BIAN is better than that of Z-200. Then the thionocarbamate molecular is synthesized, and the compounds are characterized by nuclear magnetic resonance (NMR). It turns out that the test result identifies the prediction after the flotation verified test of pure mineral and actual mineral. The results demonstrate that the EHOMO and ELUMO are smaller in the thionocarbamate after a nitrogen atom is bound to benzyl, the thionocarbamate has strong selectivity and low collecting power. The lower the LUMO energy of thionocarbamate is, the stronger the back donation covalent p-bond between collectors and chalcopyrite is, thus improving flotation power for chalcopyrite and selectivity against pyrite. The result proves the feasibility of design and synthesis of the novel thionocarbamate through the frontier orbital properties of the collectors.1. INTRODUCTION Thiocarbamate is a kind of nonionic polar collector and is now widely used as flotation collector for copper-sulphur separation. The flotation power of thiocarbamate to chalcopyrite is stronger than pyrite, so it has high selectivity against pyrite. The frontier orbital theory and density functional theory (DFT) has been widely applied to study the structure-activity relationship of flotation collectors [1-6]. The flotation test results can be interpreted by using the reaction energy criteria and quantum-chemical parameters, such as the energy of the highest occupied molecular orbital (EHOMO) and the energy of the lowest unoccupied molecular orbital (ELUMO) of collector [7-11]. In turn, there are rarely reports about screening the novel flotation collector, by the frontier orbital properties such as HOMO and LUMO of flotation collectors. In this thesis, we apply the density functional theory and molecule design technology to design and synthesize the novel flotation collectors for copper-sulphur separation. Based on the previous findings of the structure-activity relationship of xanthogen formats [12], it has stronger collecting ability to chalcopyrite while the xanthogen formats after a nitrogen atom is bound to benzyl. Thus, in this study, a novel thionocarbamate molecule O-isopropyl-N-benzyl thionocarbamate (IP-BIAN) will be constructed, when the group structure connected with N atom in the known collector O-isopropyl-N-ethyl thionocarbamate (Z-200) is replaced with ethyl by propyl. The collectors (IP-BIAN and Z-200) have been calculated by DFT methods in quantum chemistry. By analyzing the reaction energy criteria and the frontier orbital properties (HOMO and LUMO), this research predicts flotation performance of novel collectors (IP-BIAN), then the synthetic experiments and flotation verified tests are conducted. The research provides a new theory reference for screening out the high-effective flotation collectors of copper-sulphur separation. This technology adoption will contribute to the sustainable development of mineral resources as it shortens the research cycle of new collector molecules and reduces the investment."

Jan 1, 2018

By J. Faitli

The Lake Balaton is the biggest and for many reasons the most important lake in Hungary. To preserve its healthy nature it is necessary to remove the accumulated mud time to time, similarly to the many living waters, lakes and rivers everywhere. Typical existing technologies (mechanical, hydraulic) require large depositional areas, where the removed slurry and mud is dewatered through very long time. One problem is the non existence of an economical mud thickening technology. Another major problem is that current methods remove the sand fraction with the mud as well. Many times sand has to be complemented from outer sources to endanger the natural balance of the living water. By the financial support of the NKFP 3A/068/2004 Hungarian Research Project our consortium has been looking for the solution to the above mentioned problems. The original ideas of the project were: 1. Sand should be separated and returned to the water by hydrocyclon; 2. New mud thickener should be developed based on the principle that vibrating rods can force settling and packing of mud particles. The work was started by fundamental research with different samples from Lake Balaton and River Bodrog. An automated settling column (45L) has been built for the investigation of the effect of vibrating rods on the settling behavior of suspensions. An optical sensor has been developed by with the settling curve (height of settling slurry as function of time) can be automatically measured. Different vibrating methods and parameters have been tested by the application of a linear motor and mechanical eccentric drive. On the basis of the fundamental research a new thickener, called the rod ? lamella thickener has been developed and an industrial size (50m3/h) mud removing technology has been built. Main parts of the technology are the traditional dredging barge and the thickening technology. The thickening and sand separation technology is tugged by the dredging ship. Its main elements are the homogenization tank, slurry pump, hydrocyclon and the rod ? lamella thickener. In this unit lamellas carry out pre-thickening, then vibrating rods further increase the concentration. The thickened mud is transported out by a screw - of which revolution number is precisely controlled - against a spring supported valve. Paper reports about the design, building, water probe and on-site tests of this mud removing technology. Two new patents had been presented, one is about the rod ? lamella thickener and the other is about the mud removing technology with sand separation.

Jan 1, 2014

By G. Rajesh

Mathematical modeling of bioremediation has gained importance as it is used as an optimization tool for the remediation process involved in contaminated sites. The bioremediation of Cr(VI) has been studied taking into consideration the initial Cr(VI) concentration Cr(VI)ini, bacterial growth substrate concentration (S), maximum growth rate (µmax), yield coefficient (Y), half saturation constant (Ks), and inhibition constant (KI). As the enzymatic reaction is also affected by initial substrate concentration (Sini) and Ks, different ratios of (Ks/Sini) are analyzed. As the inhibition constant (KI) is not constant for all the enzyme reactions and it varies with Cr(VI)ini, the correlation between (KI) and Cr(VI)ini is developed. A set of differential equations pertaining to bioremediation of Cr(VI) has been solved using FORTRAN 90 program adopting the model developed. The results are verified with the experimental data from the literature and a good correlation has been obtained between the experimental data and the model predictions. Keywords: bioremediation, hexavalent chromium, mathematical model, inhibition kinetics

Sep 1, 2012

By M. Bergerman

Sossego was the first Vale SAG mill operation to process copper-gold ore. It is located in Para state, south east of Amazon region in Brazil. The comminution circuit was designed to treat 41 000 metric tons per day comprising primary crushing, one 11.6 m SAG mill operating in closed configuration with cone crushers, followed by two 6.7 ball mills. In the first three years of continuous operation Vale investigated alternatives for obtained improved performance of the circuit by investigating operating conditions, mainly focusing on SAG mill. A number of actions were then implemented, which resulted in significant increase in overall production. Vale then decided to further assess the performance of the comminution circuit as a function of ore characteristics. A comprehensive ore characterization program was then conducted, together with the calibration of mathematical models on the basis of surveys carried out at the industrial circuit. The simulator was then used to predict the production level associated to each ore type, as well as to establish the optimized circuit configuration and tailored operating conditions. The ongoing validation program is planned to consolidate the selected strategy, as well as showing the benefits in adopting such indices in mine planning, as opposed to rather simplistic approaches. This paper describes in detail the main aspects of optimizing the industrial circuit performance, as well as the successful method for predicting the production as a function of ore characteristics.

Jan 1, 2014

By V. Panayotov, M. Panayotova

"Wastewater from ores processing is often polluted by molybdate and sulfate (SO42-) ions. Sorption is one of suitable methods for removing those pollutants when presenting in low concentrations. This work reports results on adsorption of sulfate and molybdate ions on metal modified (with barium - Ba and lead - Pb) and organic reagent modified (with Hexadecyl-trimethyl-ammonium bromide - HDTMA) clinoptilolite. Zeolite’s modification with Pb, Ba and HDTMA increases its uptake capacity with respect to Mo(VI) at pH 3, with the uptake capacity decreasing in the order CL-Pb > CL-HDTMA > CL-Ba. Lead-modified clinoptilolite shows high uptake with respect to Mo(VI) in acidic, neutral and slightly alkaline conditions. The presence of SO42- in concentrations twice higher than the amount of Mo(VI) do not interfere with the Mo(VI) removal by CL-Pb. Zeolite’s modification with Ba and Pb renders it able to immobilize SO42- from water in the pH range 3-9. Kinetics of the uptake process is best described by the pseudo-first order kinetic equation. Increasing the initial concentrations of Mo(VI) and SO42- increases the removed amount of pollutants. INTRODUCTION Wastewater from copper-molybdenum ores processing is often polluted by molybdate and sulfate ions. Molybdenum (Mo) migrates easily in water and consequently the Mo polluted areas could extend for hundreds and thousands of meters (Ryzhenko, 2010). Molybdate anion is the only Mo(VI) species in natural water, i.e. at pH > 6.0. Its median freshwater hazardous concentration affecting 5% of the species (HC 5.50%) is 38.2 mg Mo/L (De-Schamphelaere et al., 2010). The marine water chronic toxicity (HC 5.50%) is assessed at 5.74 mg Mo/L (Heijerick et al., 2012). The predicted no-effect concentrations (PNEC) are 12.7 mg Mo/L and 1.92 mg Mo/L correspondingly for freshwater and marine water (Heijerick et al., 2012a). When sulfates present in drinking water in excess of 250 mg/L they cause a cathartic action (especially in children) in the presence of sodium and magnesium, and when the concentration exceeds 600 mg/L, diarrhea. When sulfate-rich effluents are discharged into the environment, they may increase the acidity of water bodies and soils (Guimarães and Leão, 2014). Because of the adverse effects to human health and the environment, limits are set for SO42- concentrations in waters and wastewaters in the range of 250 / 500 mg/L."

Jan 1, 2018

By L. Tong

Stirred milling of laterites offers possibilities for improving liberation and selective size reduction of soft nickel-bearing minerals in laterites. Batch grinding tests were performed in a Netzsch LME4 stirred mill on a siliceous goethitic (SG) nickel laterite sample (-2000 µm particle size) to evaluate the effect of operating conditions such as stirrer speed, grinding time, pH, solid content, water salinity and charge volume. The target was to produce a -38 µm fraction in the milling product with high nickel recovery and grade. Addition of dispersant (sodium hexametaphosphate) was also optimized with respect to the rheology of the slurry. In terms of stress intensity, the optimum grinding conditions for selective size reduction were: 1000 rpm, 50 per cent charge volume. At higher stress intensity (2000 rpm), Ni recovery in the -38 µm product was higher, but Ni grade was low, due to the breakage of the harder siliceous particles. Decreasing the yield stress by modifying slurry pH or adding dispersant improved the rheological properties of the pulp, but had no great influence on Ni upgrade in the fine product. Modifying water salinity by adding 2 M NaCl had also little effect. The breakage of the +38 µm particles in the feed determined Ni upgrade greatly. Ni grade in the -38 µm product decreased with grinding time, suggesting that the Ni-bearing minerals break first, while the harder siliceous minerals have a lower breakage rate. The breakage rates with respect to sample mass for Ni, Mg and Si indicate that: Mg > Ni > Mass > Si. The optimum grinding time for the highest Ni upgrade was 0.25 min. The Ni grade increased from 0.88 per cent to 1.35 per cent (upgrade 54 per cent), with 24 per cent Ni recovery. Keywords: fine grinding, stirred media mill, nickel laterite, slurry rheology

Sep 1, 2012

By O. Jerez, A. Novoselov, L. Gutiérrez, J. Morales, U. Kelm

"In Chile, the evaluation to reprocess tailings for elements other than the traditional Cu, Mo, Au, and Ag, as well as projects to implement long-term monitoring of mining residue sites are key elements of the government’s roadmap laid out for the mining industry for the next two decades. Characterization routines for tailings and mining residues in general have to be adapted from traditional ore and gangue mineral and micro-chemical studies. This contribution summarizes key aspects for the regional mining industry for a basic characterization of tailings with emphasis on small- to medium-size operations with limited in-house facilities and funds to carry out extensive characterization programs. The oldest tailings in Chile were deposited almost a century ago; this fact gives importance to the recovery of past ore /gangue feed information, process circuits and changes (e.g. acid to alkaline flotation), process water provenance and recovery, meteorological registers, and routines of filling a tailings impoundment. Basic characterization should include X-ray fluorescence spectrometry combined with laser diffraction (LD) granulometry followed by X-ray diffraction (XRD), optical microscopy (OM) and automated mineral analysis (AMA) on a reduced set of samples identified by hierarchical cluster analysis. For this detailed stage, only coarse tailings are recommended for direct a study by microscopy and automated mineralogy (P80 >100 µm); for fine tailings (P80 ~30 µm) a combination of XRD and deposit type adapted sequential extraction are more informative options. In particular, for XRD of clay phases, losses of crystallinity may result in deviation of spectra from standard reference phases due to prolonged storage. To monitor surface alteration, scanning electron microscopy can be complemented by Raman spectroscopy to detect residual reagents on mineral surfaces. For reactivity modeling BET measurements are essential."

Jan 1, 2018

By Ari Kokko

Metso has a long history supplying boilers for high ash coal firing. These boilers are based on circulating fluidized bed (CFB) technology. CFB?s biggest benefit is fuel flexibility ? it can burn fuels from high moisture content to high ash content. Metso has delivered tens of CFB boilers burning waste or high ash coal starting on 80?s. Some of the boilers have been in operation twenty years meaning that there is a long term experience from these plants available. This feedback includes boiler performance and maintenance issues of the boiler. Metso is also delivering coal washing plants to improve coal quality, i.e. reducing ash content of the coal. The idea to combine coal washing plant and CFB boiler was made up two years ago in Metso. Up-coming legislation of coal washing and restrictions for washery reject land-filling in India are good drivers for this kind of concept. Pre-study of this kind of concept led to the conclusion that coal washing process can be fine-tuned so that reject?s calorific value is only 1100 kcal/kg and that was set as a target for boiler design. Metso shipped 200 tons of washery reject to its own research center located in Tampere Finland. First a wide range of fuel characterization tests were done in lab-scale and after that one week test run in 4 MW CFB pilot boiler was done. Test run proved that 1100 kcal/kg can be fired without any support fuel with special boiler design. Test run results gave a good set of data regarding combustion efficiency, emission performance and boiler dynamic behaviour when burning this kind of fuel. These results are introduced in this paper. This paper introduces also the CFB boiler concept for washery reject firing including boiler plant, fuel and ash handling systems and flue gas cleaning system. Power plant can be integrated with coal washing plant so that boiler size matches with washing plants c

Sep 1, 2012

By A. Vidyadhar

Using pure quartz and hematite minerals, the adsorption mechanism of mixed cationic/anionic reagent schemes was investigated through Hallimond flotation studies. The flotation response of quartz and hematite independently with cationic and anionic collectors as well as with mixed cationic/anionic collector systems is assessed. The flotation response as a function of pH and collector concentration was investigated. The single mineral flotation tests in the presence of anionic collectors, quartz does not respond to flotation, but the C12 amine flotation of quartz was observed to be pH and concentration dependent. It was observed that hematite flotation recovery is maximum at acidic pH with sodium dodecyl sulphate (SDS), neutral pH with oleate, and at basic pH about 9.5 with C12 amine. Flotation results with both quartz and hematite indicate an increased adsorption of cationic collector in the presence of anionic collector apart from its own co-adsorption. The incorporation of oleate in between C12 amine molecules decreases the electrostatic head-head repulsion and thereby increasing the adsorption of C12 amine due to attractive tail-tail hydrophobic bonds, besides forming a closely packed adsorbed layer enhancing the hydrophobicity. The increase in oleate concentration beyond C12 amine concentration leads to the formation of soluble C12 amine-oleate complex / precipitate and the adsorption of these species decreased the flotation since the alkyl chains are in chaotical orientation with a conceivable number of head groups directing towards the solution phase. Keywords: quartz, hematite, adsorption, mixed collector system, flotation, zeta-potential

Sep 1, 2012

By E. V. Koporulina, E. L. Chanturiya, M. V. Ryazantseva, E. S. Zhuravleva

"The morphology of the surface of sphalerite, galena and chalcopyrite and the adsorption of butyl xanthate under conditions of preliminary treatment of minerals by the products of water electrolysis were studied using atomic force microscopy (AFM) and Diffuse Reflection Infrared Fourier Transform Infrared Spectroscopy (FTIR). It was determined that practically all types of treatment by electrochemically modified water (a product of non-diaphragmatic treatment, anolyte and catholyte) lead to an increase of surface roughness of the studied minerals due to formation of small rounded shape particles. In contrast to that, after treatment of chalcopyrite by anolyte, its surface becomes smoother. Various effects of treatment by the water electrolysis products on the adsorption of chemical and physical forms of butyl xanthate on the studied sulfides were established. As a result, the efficiency of the complex of AFM and FTIR methods, as one of the ex-situ approaches for monitoring the surface state of sulfide minerals and direct investigation of BKx adsorption products was demonstrated.INTRODUCTION In mineral processing, copper-zinc sulfide ores are one of the most complex products in view of their mineral composition, fine dissemination, complex inter-growth and the proximity of the technological characteristics of copper, zinc and iron sulfides. For the most complete disintegration, fine grinding of ores to a size of 0.074-0.044 mm is necessary. Consequently, the main method for processing of such ores is flotation, which bases on the difference in physical and chemical properties of the mineral surfaces, in particular, degree of wettability. The separation of copper and zinc minerals and their separation from ferrous and other sulfides, sulfosalts and rock mineral is a very difficult task (Chanturiya, 2000). For the successful separation of copper and zinc minerals in the appropriate selective concentrates, it is necessary to find conditions for the most complete liberation of ore and rock-forming minerals and for increase the contrast in physical and chemical properties of their surfaces. Despite significant progress in the processing of copper-zinc sulfide ores, the problem of the selectivity of the separation of the main ore minerals has not yet been fully solved and requires innovative approaches (Chanturiya, 2015). To date, various methods of preliminary energy processing of complex ores are used: magnetic pulse treatment, impact by high-voltage nanosecond pulses, electrochemical effects (including products of water electrolysis (Chanturiya et al., 2014; Bunin et al., 2015; Chanturiya et al., 2014a; Chanturiya et al., 2016), processing with flotation reagents, etc. Electrochemical treatment of water in various modes allows to obtain products of electrolysis with different oxidation-reduction properties: acid anolyte with a high oxidation potential and dissolved oxygen content, an alkaline catholyte with high reducing properties and a product of non-diaphragmatic treatment with enhanced reduction properties."

Jan 1, 2018

In this paper, the recovery of copper minerals and molybdenite in the rougher/scavenger banks of two separate mineral processing plants is compared with recovery in laboratory (batch) cells. A number of metallurgical surveys were conducted in two plants treating porphyry copper and molyb-denum ore. Batch flotation tests were performed on plant conditioned flotation feed slurry, in parallel with the plant metallurgical surveys. The effect of flotation feed density on recovery of copper minerals and molybdenite in the plant and batch laboratory cells was investigated. Changes in flotation pulp density had little effect on copper mineral recovery, in both plant and laboratory cells. The ultimate recovery for molybdenite, on the contrary, increased considerably when the pulp density was reduced, both at plant and laboratory scale. Recovery of copper minerals in the plant and laboratory cells was comparable, while molybdenite recovery in laboratory flotation cells was 3%~13% higher than in plant. It is hypothesised that the flotation rate of molybdenite is sensitive to cell hydrodynamic conditions (i.e. local turbulent energy dissipation) more than the flotation rate of copper. The flotation behaviour of molybdenite particles is likely to be predominantly controlled by bubble-particle collision frequency, which is enhanced in high local turbulent energy dissipation environment. For chalcopyrite, the flotation recovery is mostly determined by attachment and stability efficiencies. An increase in local turbulent energy dissipation, while increasing collision efficiency, may negatively impact on attachment and stability efficiencies. The outcomes may have a considerable impact on increasing molybdenite recovery from porphyry ores.

Jan 1, 2014

With rapid development of Chinese iron & steel industry, it is of significance to intensify the utilization of domestic complex iron ore resources. The tin, zinc-bearing complex iron ores are typical polymetallic and intractable ones because of the complicated intergrowth relations among the multi-elements, and they have not been efficiently utilized, presently. Based on the thermodynamic analysis of iron, tin and zinc oxides reduction by CO, the technological conditions of tin and zinc recovery and pellets preparation from tin, zinc-containing iron concentrates by selective reduction roasting are studied and a new comprehensive utilization process is developed in this investigation. Under the optimum conditions, the tin and zinc volatilization is respectively in excess of 80% and 70%, and the compression strength of roasted pellet is more than 2500 N/P. Moreover, the residual tin and zinc in the finished pellets is below 0.06%. The finished pellets can be used as high quality iron-making burdens for large-scale blast furnace.

Jan 1, 2014

By R. S. Wang

The flotation of pyrite which be pretreated by electrochemical ways under external controlled voltages in different pH is explored. The floatability of pyrite is increased indistinctively after being pretreated in acidic and xanthate environment; Whereas, it is increased obviously between 400~800 millivolt in alkaline and xanthate condition. The reason for higher recovery of pyrite is that oxida-tion reaction, which results in S0 and S02, takes place on its surface, and that ethyl xanthate is oxi-dized into dixanthogen. In the meantime, the kinetics and mechanism is also studied.

Jan 1, 2014

By V. F. Petrov, O. D. Khmelnitskaya, V. M. Lodeischikov

"The processing of copper gold ores is one of the major issues of gold-mining industry in the beginning of 21st century. In this case, application of ammoniacal cyanidation process for this type of mineral raw materials deserves special attention. Irgiredmet Institute has carried out a wide range of studies on ammoniacal cyanidation process and evaluated the possible commercial use of this process for Russian operating plants. Copper gold-bearing ore from a current Russian deposit was studied. The content of gold and copper in the ore is 9.4 g/t and 0.4%, respectively. Based on the results of preliminary test work, a flow sheet was developed. It included gravity concentration followed by cyanidation of the gravity tailings using CIP. The flow sheet provides sufficient total gold recovery (91.5%). However, this technology has disadvantages, such as high specific consumption of reagents: 4.5 kg/t NaCN and 13.5 kg/t Ca(OCl)2 the ore and the increased gold grade in the liquid phase of the tails slurry (0.2 g/t). In order to improve cyanidation process parameters, test work on gravity tails processing using ammoniacal cyanidation was carried out. After the test work was completed, ammoniacal cyanidation flow sheet for copper gold-bearing ores was developed. Leaching conditions were optimized using recycled process solutions. Recommendations on gold recovery from the solutions and tails detoxification are given. The proposed flow sheet provides 91.5% gold recovery. In this case, compared to the conventional option, the consumption of cyanide decreases by 3-4 times.INTRODUCTION The technology of precious metals recovery from gold-bearing ores is based on cyanidation. This accounts for up to 90% gold recovery and the significant portion of silver (Lodeischikov, 1999). However, there exists the category of so called refractory ores. They are not amenable to direct cyanidation (without using additional expensive processes), or they are characterized by low indices of metals recovery and high consumption of reagents. The latter also include copper gold ores. Their deposits can be found extensively both worldwide and in Russian Federation. A feature of these ores is that they contain not only gold but also copper. It is considered not only as a valuable component but also as a harmful mineral impurity that hinders gold cyanidation, gold precipitation from the solutions by cementation onto zinc dust and adsorption onto activated carbon (CIL, CIP-processes), detoxification of cyanide bearing effluents."

Jan 1, 2018

By S. Castro, L. Gutierrez

"Mining operations are often located in remote arid environments with limited access to fresh water. Shortage of fresh water in such cases makes it necessary to use seawater in mineral processing plants. Such plants treating Cu- Mo sulfide ores in seawater have been fully operational in Chile (e.g. Las Luces, Centinela). In many cases process waters used in commercial flotation plants (e.g. Mt Keith in Western Australia) are even more concentrated electrolyte solutions than seawater. This paper is an attempt at classification of the flotation operations carried out in process waters that are concentrated electrolyte solutions.INTRODUCTIONAccording to Gleick (1966), of the total Earth’ water resources 97.5% is in the oceans and ice caps, and thus only about 2.5% is fresh water. Shortage of fresh water in many parts of the world makes it necessary to use seawater in mineral processing operations. The existing commercial operations using seawater as well as recent research projects that deal not only with sulfide ores but also with apatite ores provide a lot of information that can now be generalized. The progress that has been made in this area is reviewed and based on this information an attempt is being made at classifying the flotation operations carried out in highly concentrated electrolyte process waters.SALT FLOTATIONFlotation in highly concentrated electrolyte solutions was studied by Klassen (Klassen, 1963). He reported that hydrophobic, bituminous coals, could float in salt solutions without addition of any other flotation agents. The process is referred to as salt flotation. Other inherently hyhrophobic minerals (e.g. talc, graphite, sulfur, etc.) were shown to behave similarly (Klassen and Mokrousov, 1963)As Figure 1 shows, some coals float quite well in solutions of Na2SO4, NaCl and NaNO3 (Klassen, 1963). While there are differences between the tested salts (explained by different foamabilities of these solutions) all the tests indicate that only bituminous coals float well in concentrated electrolyte solutions. 0.3 M solutions are quite sufficient to initiate a good and very fast flotation. If wettability of various coals is compared it becomes obvious that these well floating coals are very hydrophobic bituminous coals (Figure 2)."

Jan 1, 2018

By C. A. Acuña

Extensive literature exists on the motion of single bubbles and the behaviour of swarms of bubbles. This contribution describes work to track and reveal the motion of individual bubbles in a swarm. The technique is based on high speed cinematography and tracking of multiple moving objects. Image processing algorithms were implemented in Matlab to isolate and measure geometric proper-ties of the bubbles in image sequences recorded at 2 ms interval; and these properties were compiled into a data structure. To track a bubble, the geometric properties and a matching criterion were applied on consecutive pictures to identify the bubble. The bubble trajectory was reconstructed from the data structure for the matched objects. The methodology is briefly described. The new technique was tested for bubbles produced at slot-type spargers (i.e., approximately 2-D swarms) in the presence of two frother types ('strong' and 'weak'). Two observations are discussed: a) that bubble motion in a swarm describes a velocity-size relationship dictated by the dominant bubble size class; and b) that surfactant type influences bubble rise velocity for bubbles in the range 0.1 mm to 4 mm. The latter suggests surface viscosity rather than surface immobilization determines bubble rise velocity.

Jan 1, 2014