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By Z. Gxowa, L. H. Chown, U. Curle, G. Govender

This work evaluates the deformation behaviour, at warm working temperatures, of green particle-reinforced aluminium composites produced by powder blending in a high-energy ball mill. The work focuses on metal matrix composites (MMCs) based on the 2124-Al alloy, reinforced with 10 or 15 vol.% SiC and metal matrix nanocomposites (MMNCs) based on the 2124-Al alloy, reinforced with 5 or 10 vol.% Al2O3. Three batches for each powder were blended and powder properties such as particle size distribution (PSD) and shape were consistent after blending. It was observed that a more uniform distribution of the reinforcement phase in the aluminium alloy matrix was achieved in 2124-Al/Al2O3 than in 2124- Al/SiC composites. The powders (unreinforced 2124-Al and blended) were initially over-aged at 350°C for 2 hours to reverse any natural ageing that may have occurred prior to use. The over-ageing was incorporated to improve compressibility of the powders with the aim of achieving green compacts with higher integrity. Uniaxial compression tests performed at ambient temperature on a Gleeble® 3500 thermomechanical simulator were unsuccessful as the green compacts fragmented. Engineering stress-strain curves showed that green compacts of unreinforced 2124-Al, 10%SiC MMC and 5%Al2O3 MMNC deformed in a similar manner at ambient temperature and had the same compressive fracture stress of approximately 170 MPa. When the deformation temperature was increased from ambient to warm working temperatures (170–280°C) it was observed that electrical resistance heating (the heating mode of the Gleeble®) of unreinforced Al alloy, MMC and MMNC green compacts did not occur. This was attributed to the high electrical conductivity of aluminium, which resulted in poor heat generation due to the low electrical resistance in the samples. It was presumed that the small sample size (d=8 mm, h=12 mm) also caused rapid heat loss. After further experimentation, the green compacts were heated successfully by insulating the samples to retain heat. It was found that at 280°C, increasing the soaking time from 6 to 20 minutes decreased flow stress and improved plastic flow in the 2124-Al/10%SiC green compact.

Jan 1, 2016

By A. Tello

Variography was introduced by Dr. Pierre Gy to monitor a process, in the sixties. Later on, Francis Pitard extended this concept, building a complete system of variographic controls for different applications. Nevertheless, the existence of information about its use as a way to effectively control plants has been limited. There are infinite areas where variography and chronostatistics can be used. In this paper, two different cases related to gold and silver recovery, through well known but complex metallurgical routes are studied. The use of effective management of process variability software (EMPV) has shown to be a suitable solution to clarify problems at the plant and, consequently, a solution to the encountered problems has been proposed. Chronostatistics is like opening a new world to the metallurgist, making the process variability speak in a more comprehensive and in depth way. Once the ore has been extracted from the mine, sampling is necessary at each sequence of the metallurgical process involved. As a first example, leaching of the ore with cyanide in agitated tanks is another case of a complex metallurgy. The aim of the process is to know about residual values in the tailings in order to optimize process. As a second example, leaching of gold and silver in ore heaps, has to be optimized in terms of time, reagents consumption and, of course, in predicting a reasonable recovery. This last issue appears to be crucial. After cyanide leaching at the heaps, a carbon in columns process is involved, where there are a series of carbon loaded columns that are submitted to a dynamic process of load and unload, to finally deliver an enriched solution to the precious metal electrowinning plant. In both cases, variography has been a good approach to show metallurgists ways to improve the operation.

Jan 1, 2009

By S-J. Park

When evaluating mining investment opportunities, one should consider the risks associated with mineral exploration and development. These are commonly classified as technical, economic, and political risks, and are accounted for in the investment decision by changing the discount rate. Thus, a company may use different discount rates associated with varying risks in order to compensate for the variability of success. The discount rate has a tremendous effect on the economic evaluation of mineral projects. Even when all other factors used as inputs for calculating the NPV (net present value) are equal, the project under consideration may be accepted or rejected depending upon the discount rate. Determining a realistic discount rate for a given project is therefore the most difficult and important aspect of cash flow analysis. It should be determined with the consideration of proper technical, economic, and political conditions surrounding the specific project undergoing economic evaluation. One key problem for determining the appropriate discount rate is that it typically depends more on subjective perception of the degree of risk or other experience factors than on a systematic approach. Thus, this study aims to identify, analyse, and document the type, role, and impact of risk factors influencing the determination of discount rates, and then to determine discount rate by using the aforementioned factors.

Jan 1, 2011

By M. Steyn

The coordination compound tetrakis(1,3-diphenyl-1,3-propanediona to)zirconium(IV), [Zr(DBM)4], (DBM = dibenzoyl methane/1,3- diphenyl-1,3-propanedionol) was synthesized and characterized by single-crystal X-ray diffraction. [Zr(DBM)4] crystallizes in the monoclinic space group P21/c (a = 24.769(4) Å, b = 10.216(5) Å, c = 19.314(4) Å, and = 101.541(5)°). The coordination geometry around the zirconium atom, formed by the eight O-donating atoms of the four -diketonates, is found to be a near-perfect square antiprism. Crystal packing is stabilized by C?H... interactions throughout the crystal lattice. This structure is a noteworthy example of the application of ambient condition synthesis of zirconium compounds in N,N'-dimethylformamide (DMF) as reaction and crystallization solvent, highlighting the possibilities of aerobic condition metal purification through chelation.

Jan 1, 2014

By S. Subramanian, L. Mweene

A siliceous low-grade copper ore from Mpanda Mineral Field (MMF), located in south west Tanzania consisting of SiO2 (58.3%), Fe (10.4 %) and Cu (0.9 %) was initially subjected to selective dispersion-flocculation using sodium trisilicate (STS) as a dispersant and xanthan gum (XG) as a flocculant. Subsequently, the selectively flocculated fraction was floated using a collector combination of potassium ethyl and amyl xanthate (1:1) in the presence of poly-ethylene oxide (PEO) as a silica depressant, to get a copper concentrate. The mineralogical investigations confirmed that the MMF ore was mainly composed of quartz, chalcopyrite and pyrite. Adsorption studies indicated that the adsorption density of XG on MMF ore decreased with an increase in pH, while that of PEO was independent of pH. The adsorption isotherms of XG and PEO on MMF ore exhibited Langmuirian behaviour. The zeta potential studies of MMF ore indicated that the iso-electric point (IEP) was located at pH 2.6, presumably due to its high silica content. In the combined presence of XG and STS, the zeta potential of MMF ore became more negative, with an increase in the concentration of STS. However, in the presence of PEO, the zeta potential of MMF ore became less negative with an increase in the concentration of PEO beyond the IEP, without shifting the IEP. Selective dispersion-flocculation of MMF ore improved the flocculated chalcopyrite grade to 19.8 %, yielding a degree of flocculation and a maximum separation efficiency of 12.1 % and 85.7 % respectively, after three desliming stages in the presence of 30 ppm of STS and 30 ppm of XG. A copper concentrate of 29 % grade and 90 % recovery containing silica of 0.9 % grade and 1.7 % recovery was achieved by flotation of the selectively flocculated component, using PEO as a depressant for quartz. Keywords: Flotation kinetics, flotation machines, flotation bubbles, particle size

Jan 1, 2020

By M. Bryson, J. Taguta

The Prieska deposit, mined between 1971 and 1991, is one of the world’s top thirty volcanogenic massive sulphide (VMS) base metal deposits. The Prieska Copper Mine in the Northern Cape Province was closed by Anglovaal when underground mining had extended to depths which did not allow for safe and economic extraction of the deposit at the time. The mine has a recorded historical production of over 1 Mt of zinc and 430 k tonnes of copper from 46.8 Mt of milled sulphide ore, achieving life-ofmine metal recoveries of 85% for copper and 84% for zinc into high quality concentrates (refer ORN ASX release 15 Nov 2019). Orion Minerals Ltd is currently investigating the feasibility of developing a new mine in the footprint of the historical Prieska Copper Mine, using the extensive remaining infrastructure, with the intent of extracting the unmined zinc-copper mineralisation from the Prieska deposit. This paper reports results on the flowsheet development philosophy on the hypogene ore, and challenges encountered in the process. This study initially failed to replicate historic copper and zinc recoveries employing the historic production flowsheet and reagent conditions unmodified on bench scale, as the copper and zinc were co-floating. Flowsheet modifications were therefore made to improve differential flotation and recovery, resulting in achieving comparable saleable products and recoveries from processing the hypogene ore on bench scale. Flotation variability test work on the hypogene ore focused on the use of the original flotation procedure and reagent suite using a sodium cyanide-zinc sulphate depressant system on the copper circuit, and it generated a saleable copper product of 20-26% Cu grade at 80-86% recovery. The zinc circuit generated a saleable zinc product grading at 48-55% Zn at 80-94% recoveries. Some zinc losses were due to the deportment of some zinc in sauconite. It is recommended that further test work may further improve the copper grades and recoveries. Keywords: Prieska, flotation, hypogene ore, flowsheet development, sulphide flotation, reagents

Jan 1, 2020

By A. M. Croll

The efforts to mechanize narrow reef tabular orebodies unique to this country, are not new. They began in the early 1900s and have over the last century seen varied rates of progress and success. Efforts to mechanize with the use of scraper winches can be regarded as a success. The scraper winch replaced the hand lashing of ore and development waste into hoppers. The initiatives by Anglo Gold and the then JCI to implement trackless mining equipment into these environments had limited success but in general were looked upon as a failure?at least this is the perception. The Chamber of Mines Research Organization (COMRO) in conjunction with various mining houses tried to make a success of the impact ripper. Diamond wire cutting of the stope face is another, which has been tried and tested. The use of high-pressure water to cut rock has also been trialed. These attempts, amongst others, are just a few of the efforts that have not been successful in the quest to make life at the face safer, more productive and easier for our employees. Against the backdrop of an emerging South Africa, the associated high expectations of historically disadvantaged people within the country, a strong rand, demands for better safety, lower cost of production and more efficient operations, mechanization has the chance to make a difference to Anglo Platinum?s business. Mechanization has certainly changed the way other commodities such as coal, base metals and diamonds are won from the earth. Mining?s image is still one of people crawling around in stopes?a dirty, ?low-tech? business. Anglo Platinum?s latest journey to mechanize its underground operations began in earnest in1998 and has enjoyed some successes and failures. The opportunity to change the way mining is done within the company is there. Technologies are evolving, and the implementation of mechanization can certainly assist with the achievement of the goals referred to above. When mechanization commenced, targets were set for the company to achieve but these have been revised in the light of recent events relating to the strengthening rand and a slow-down in expansion plans. However, the intent to mechanize appropriately in Anglo Platinum still exists.

Jan 1, 2004

By P. Saayman

The mining industry has much potential for automation. A great deal of work has been done on this subject and is still ongoing. With automation comes the possibility for optimization, because more information is available and actions can be repeated with more accuracy. This paper looks at possible solutions to the problem of optimizing the autonomous vehicle dispatch system in an underground mine. Possible optimization strategies are evaluated using a simulated environment. The majority of the results indicate that improvements on current methods are possible. Keywords: mining automation, simulation, vehicles, dispatching strategy, optimization.

Jan 1, 2006

By R. Simon, P. Pagé, L. Li, P. Yang

The Mathews-Potvin stability method is widely used in the Canadian mining industry as a starting point to determine the maximum dimensions of mine stopes. However, it cannot be applied to inclined (more frequently encountered) mine stopes without conducting numerical modelling to obtain the stress factor A, defined as a function of the ratio of unconfined compressive strength of intact rock to the induced principal stress on the exposed stope walls. The need to conduct numerical modelling significantly limits the application of the Mathews-Potvin method. In addition, given its empirical nature and main application for preliminary design, it is deemed undesirable to conduct numerical modelling, especially elaborate modelling. Alternatively, theoretical methods can provide a much simpler and quicker way to estimate stresses around stopes and the corresponding stress factors. Over the years, a large number of studies have been conducted to estimate stresses around openings excavated with various crosssections. However, theoretical or graphical solutions remain unavailable for mine stopes that typically consist of horizontal floor and roof, and two parallel inclined walls (hangingwall and footwall). To remedy this situation, a series of numerical simulations is first performed for openings with vertical and inclined walls, including typical stopes commonly encountered in underground mines. A group of empirical solutions is then formulated to estimate the induced principal stresses at the roof centre and mid-height of the stope walls. The validity and predictability of the proposed solution have been verified using additional numerical simulations. The proposed solution can thus be used to calculate stresses and the resultant stress factors A around typical mine stopes with any inclination angle and height to width ratio, under any in-situ stress state, without conducting numerical modelling.

Aug 1, 2021

South Africa?s now a member of this body, tailored on the World Bank, and headquartered in Abidjan-Cote d'Ivoire. As a funding agency for capital projects within 59 member countries of the ADB it is to be expected that there are guidelines to the requirements for funding application and for project management and control.

Jan 1, 1996

By F. Mwaura

"The aim of the audit was to determine whether the mining project environmental impact assessments (EIAs) in Kenya are undertaken according to international best practice. A sample of 50 EIA reports for the 2007–2016 period was evaluated using 18 criteria in the Environmental Law Alliance Worldwide (ELAW) guidelines. The findings showed that only two criteria were considered ‘excellent’ according to the ELAW guidelines, namely baseline environmental assessment and prediction of physical impacts. Six criteria were found to be ‘satisfactory’, including prediction of social impacts, analysis of alternative options, and impact mitigation. The reports were quite weak in terms of: consideration of all phases in the mining cycle, environmental regulatory framework, prediction of biological impacts, stakeholder consultation and engagement, integration of human right issues, and integration of climate change and cost-benefit analysis. It is therefore recommended that the Kenyan National Environment Management Authority (NEMA) should consider tightening the EIA terms and conditions in the approval of statutory terms of reference (ToR) for full-scale mining EIAs to ensure improved performance of EIA as a tool for environmental protection. IntroductionThe nexus between society and the environment has continued to generate interest because the environment is the source of goods and services that sustain the various needs of human beings as outlined in the UN sustainable development goals (SDGs) (Armstrong and Peart, 2000; Sutton 2004; Chakrabarti 2007; Strange and Bayley 2008). All the five generic categories of societal needs, namely physiological needs (food, water, clothing, medicines, etc.), residential and occupational needs (shelter, transport, energy, etc.), economic needs (tradeable goods and services), leisure and recreational needs (tourism), and cultural and spiritual needs (e.g. sacred resources and ecosystems) (Mwaura et al. 2016) are addressed by the environment. Consequently, a wide range of development sectors have been established around the world in order to address the above needs (Lederer, Galtung, and Antal, 1980; Rammelsberg et al., 2006; Noonan, 2014). All these development sectors rely entirely on the environment for their proper functioning, as shown in Table I."

May 1, 2019

By M. S. Moholwa, J. D. Steenkamp, H. L. Rutto

Manganese ores are the major source of manganese for the production of manganese ferroalloys. There is a gap in the knowledge of the decrepitation behaviour of manganese ores, which presents a problem in the operation of smelters. Decrepitation, which is the breakage of the ore particles upon heating, is an important quality parameter for these ores. The purpose of this investigation was to determine the extent to which South African manganese ores decrepitate during preheating in a rotary kiln. The effects of temperature, rotational speed, and particle size decrepitation were investigated. Manganese ores were heated in a laboratory-scale rotary kiln at temperatures of 600, 800, and 1000°C, and rotational speeds of 3, 6, and 12 r/min. The size ranges were +6-20, +20-40, and +40-75 mm and the residence time was constant at 30 minutes. The decrepitation index (DI) is quantified as the ratio of the mass of <6 mm particles after pre-heating to the total mass of the sample. It was found that the DIs for all ores used were proportional to the temperature and the rotational speed and inversely proportional to the particle size range with temperature being the most important parameter. Ore A was the most susceptible to decrepitation followed by ore C and ore B; this was mainly to the decomposition of kutnohorite, the content of which was the highest in ore A and the lowest in ore B.

Nov 30, 2022

By J. J. Botha

As a Demand Side Management (DSM) Project, money was granted for the procurement and installation of a 3-Chamber Pipe Feeder System (3-CPFS) at AngloGold Ashanti?s Moab Khotsong Mine in the Vaal River Area, Orkney. The first submission was done to ESKOM in December 2002 and the contract was signed in September 2006 at a cost of R 57-million with an envisaged reduction in power of 7 Megawatt per month based on a 90% utilization factor. The project was finally commissioned in December 2008. The technology is not new, but the intent of the paper is to share with others the experience gained by using the technology in a deep-level mine in order to reduce overall power consumption.

Jan 1, 2009

A Special General Meeting, followed by the February General Meeting of the Institute, was held in Kelvin House, Johannesburg, on 18th February, 1970, at 4.30 p.m. Mr J. K. E. Douglas (President) was in the Chair. There were also present 24 Members: Messrs A. R. C. Fowler, R. C. J. Goode, Prof D. D. Howat, Messrs D. G. Maxwell, J. A. Nixon, P. W. J. van Rensburg (Council Members), C. A. Border, J. C. Fritz, E. K. Gibson, P. L. Grimbeek, S. D. Hill, D. A. Immelman, P. J. Uoyd, M. Mrost, C. S. Macphail, D. G. Malan, W. D. Ortlepp, R. S. Pearson, A. J. H. Pole, Dr W. S. Rapson, L. W. P. van den Bosch, R. A. von Maltitz and Dr A. Whillier. Eight Associate Members: Dr M. I. Brittan, Messrs J. Brett, I. E. Clarke, C. L. de Jongh, W. B. Evans, D. Loubser, R. C. More O&apos;Ferrall and G. R. Still. One Graduate: Mr T. J. Kotze. One Student: Mr J. A. Cruise. Nine Visitors: including Dr N. G. W. Cook, Messrs M. D. Labuschagne, A. Nicoll, S. Sadowski, Dr A. M. Starfield and Dr H. Wagner. Secretary: Mr D. C. Visser. Total present: 45. SPECIAL GENERAL MEETING The President: "You will have received notices of the Special General Meeting and I declare it duly constituted. In keeping with the trend of overseas and local institutes, your Council recommends that we should change our membership classification as indicated in the notes of the meeting. The new grades are proposed to replace those presently in the Constitution and By-Laws. In terms of Clause 4.8 of the Constitution a special general meeting must be held for the purpose of considering and, if approved, adopting with or without amendments, the revision of the undermentioned clauses of the Constitution, which Council now recommends should read as follows. Clause 2.2 &apos;Corporate Members shall comprise the grades of Honorary Life Fellow, Fellow and Member&apos;, these being the equivalent of Honorary Life Member, Member and Associate Member. Clause 2.6. &apos;Non-Corporate Member shall comprise the grade of Honorary Fellow, Graduate, Associate and Student.&apos; Are there any questions in regard to this proposal? If not would someone propose that these clauses be amended and adopted?" Proposer: Mr A. J. Nixon. Seconder: Prof D. D. Howat. The motion was then adopted. The President: "It is recommended that Clause 2.15 should read, &apos;A Corporate of the Member of the Institute shall be entitled to use the following authorised letters designating the grade of Membership in Honorary Life Fellow and Fellow, F.S.A.I.M.M. and Member, M.S.A.I.M.M.&apos; Previously we used the letters M.S.A.Inst.M.M. and your Council considered that we should adopt the simpler lettering. Could I ask someone to propose that this amendment be adopted?" Proposer: Mr R. C. J. Goode.

By M. R. Khalesi, Y. Kianinia, A. Seyedhakimi, F. Soltani

"The feed ore to Agh-Darreh gold processing plant (Takab City, Iran) contains 2 ppm Au, 7 ppm Ag, and 120 ppm Hg. After cyanide leaching of the feed at pH 10.4, 80% of the total mercury (in the form of cinnabar and metacinnabar) goes to the tailings dam. In this research, separation of mercury from the tailings by flotation was investigated. The effects of collector type and dosage, pH, and the number of cleaner stages were studied. The results showed that after two stages of cleaning a 40–62% recovery of Hg at a grade of 14.3% Hg is attainable. Recycle water from a test in which 50 g/t amyl xanthate and 30 g/t pine oil was used in the flotation stage showed no adverse effect on the leaching and adsorption of gold onto activated carbon.IntroductionMercury, most commonly found in the nature as the mineral cinnabar (HgS), is a hazardous substance because of its mobility and toxicity (Kyle et al., 2012). Roasting is the wellestablished treatment method for mercury ores, in which the sulphur is burned and volatilized and mercury recovered subsequently by cooling and condensation. However, for low-grade ores, flotation is mainly applied for primary concentration due to its comparatively low costs, low environmental hazards, and flexibility regarding feed variations (Bulatovic, 2007). Particularly, cinnabar can be easily recovered by flotation using pine oil and a collector such as xanthate (Bulatovic, 2007; Crozier, 1991). Floatability of cinnabar is reduced due to surface oxidation when it is exposed to the atmosphere after crushing. This problem can be eliminated by adding copper sulphate and lead nitrate or acetate. The best pH for cinnabar flotation is in the range of 6.5 to 8.5 according to Erspamer and Wells, (1954), who reported that cinnabar and stibnite can be floated with long-chain xanthate collectors and an alcohol frother, with cumulative recoveries of 97.8% and 94.7%, respectively. Lead acetate was used as an activator."

Jan 1, 2017

By K. J. Craig, M. A. Swart, Q. G. Reynolds, L. Hockaday

A solar reflector soiling study was carried out at a ferromanganese smelter in South Africa to assess the soiling rates at different locations around the plant. Several meteorological parameters were monitored to give insight into the conditions that lead to increased soiling. Mineralogical characterization of dust samples collected from the reflectors and the atmosphere revealed that only a certain size fraction is of importance with regard to soiling, and that the dust can be attributed to both raw materials and smelter products. Proximity to the dust source was the primary driver for increased soiling. The site that experienced the most soiling was very close to raw material heaps; this was deemed an outlier and was excluded from the summary statistics. The secondary driver for increased soiling was location relative to the smelter dust sources and the wind’s direction and speed. The reflector set at the best location experienced 13.1% less soiling than the set at the ‘worst’ (but still feasible) location, represented by an averaged mean daily reflectance loss of 0.0186. The study revealed that while there are periods of intense soiling at this particular site, proper planning of reflector location in relation to the smelter dust sources can significantly mitigate the soiling rate.

Jun 5, 2023

By B. Amankwaa-Kyeremeh, W. Skinner, R. K. Asamoah, C. Greet

With the continuous increase in ore mineralogical complexity coupled with decreasing head grades, there is a need for mining industries to process large tonnages of material to meet global metal demands. Smarter, cheaper techniques are required to better map ore mineralogical variations proceeding to pre-concentration (flotation) stages for higher performance and metal recoveries. This paper is aimed at briefly reviewing previous studies on different selected ore mineralogy, with the focus on their pulp chemistry, to identify relationships which aid quicker flotation feed variation monitoring. Very little published work exists linking pulp chemistry parameters to flotation feed mineralogical variation. A successful application implies maximising grades at higher metal recoveries and reducing the cost of reagent for a better performing flotation circuit. Keywords: Mineralogical variation, flotation, pulp chemistry

Jan 1, 2020

By L. Robles-Stefoni

"Multiple-point simulation (MPS) methods have been developed over the last decade as a means of reproducing complex geological patterns while generating stochastic simulations. Some geological spatial configurations are complex, such as the spatial geometries and patterns of diamondbearing kimberlite pipes and their internal facies controlling diamond quality and distribution.Two MPS methods were tested for modelling the geology of a diamond pipe located at the Ekati mine, NT, Canada. These are the single normal equation simulation algorithm SNESIM, which captures different patterns from a training image (TI), and the filter simulation algorithm FILTERSIM, which classifies the patterns founded on the TI. Both methods were tested in the stochastic simulation of a four-category geology model: crater, diatreme, xenoliths, and host rock. Soft information about the location of host rock was also used. The validation of the simulation results shows a reasonable reproduction of the geometry and data proportions for all geological units considered; the validation of spatial statistics, however, shows that although simulated realizations from both methods reasonably reproduce the fourth-order spatial statistics of the TI, they do not reproduce well the same spatial statistics of the available data (when this differs from the TI). An interesting observation is that SNESIM better imitated the shape of the pipe, while FILTERSIM yielded a better reproduction of the xenolith bodies. IntroductionThe simulation of geological units poses several technical problems that challenge the capabilities of available geostatistical simulation approaches and their ability to deal with spatial complexity of categorical variables. The spatial geometry of diamondbearing pipes and their internal facies controlling diamond distributions are a specific and well-known difficult modelling problem. The geometry of a kimberlite pipe is typically like an inverted cone (Figure 1); the wider part is known as the crater and is located near the surface, and the narrower, deeper part is known as the diatreme. Xenolith bodies can also be found inside the pipe. A very important contribution to the geological modelling of the contours of the pipe is the measure of uncertainty about the location of the contact between the kimberlite pipe and the host rock."

Jan 1, 2016

By S. W. Robertson, M. T. Golela, S. Mxinwa

South Africa has one of the largest Cr-related industries in the world and generates large amounts of Cr-containing smelter dusts. It is normal practice to scrub Cr from the furnace off-gas in water, and to recover the Cr by adsorption, followed by recycling of the loaded adsorbent into the furnace. A study was conducted to find a low-cost adsorbent that is capable of removing sufficient Cr from the solutions generated by scrubbing. The test work focused on the evaluation of different clay minerals (attapulgite, bentonite, and kaolinite) as adsorbents for Cr. Cr(VI) could only be adsorbed after prereduction with e.g. ascorbic acid (ASA). An 80% removal of Cr(VI) could be achieved from a solution containing 20 mg/L Cr using bentonite clay after reduction with ASA. Attapulgite and kaolinite adsorbed less than 55% Cr after reduction with ASA. Both ASA and ferrous salts were found to be suitable reducing agents. The use of acid mine drainage (AMD) was also investigated as a low-cost alternative reducing agent, as AMD usually contains iron. The Cr(VI) reduction potential of the AMD was determined by redox titration against a solution containing 50 mg/L Cr(VI). Studies show that AMD can potentially be used as a reducing agent in a Cr removal process if it is available on site.

Feb 12, 2024

By L. Chanderman, C. E. Dohm

"Mineral Resource estimation (MRE) and classification are highly dependent on the confidence in the model of the orebody geometry, known as the geological model, within which the estimates are constrained. An understanding of the geology of a deposit is thus fundamental to the Mineral Resource evaluation process. The geological model is a function of the structural and depositional complexity of the geology captured by drilling information, which is limited in the early stages of a project. The information effect has a significant impact in terms of the interpretation of the geology as well as the estimation of grade continuity and the resultant risk associated with the Mineral Resource estimate and classification.Therefore, as new drilling information becomes available, it is necessary to update and refine the geological model to appropriately constrain the resource estimates. The grade information is also updated, including statistics and the spatial correlation characteristics. This refinement is based on geological interpretations derived from the drillhole information that becomes available throughout the life of the mine; orebody knowledge that comes from working experience of the deposit, as well as familiarity with the software package used for modelling, is also important.In updating, the potential to identify new resources in previously unknown areas may be realized. The opposite may also occur where previous interpretations of ore continuity are refuted. Both scenarios could result from a better understanding of the geology of the deposit and thus a more realistic MRE, which reduces geological risk. This paper describes how newly drilled advanced grade-control holes for a gold deposit in Mali were used to refine the 3D geological model for the deposit in an attempt to identify the potential for additional oxide ore using conventional geostatistical evaluation techniques."

Jan 1, 2017