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By David A. Larson

The future exploitation of crust deposits will require a dependable characterization system. The U.S. Department of the Interior, Bureau of Mines (Bureau) initiated research to develop a new sampling dredge by conducting a series of cutting and physical property tests on previously collected cobalt-rich manganese crust and substrate samples. Using the engineering parameters derived from these tests, a large, heavy dredge was designed and tested. This heavy dredge was capable of fragmenting and collecting in situ crust, but it created handling problems for the research vessel, thus an aggressive cutting, light-weight dredge was conceived and fabricated. The light-weight dredge is capable of fragmenting and collecting crust and some talus. This dredge can be used on flat or rough seabed terrains. It can be easily retrieved from hang ups and reset to sample again.

Jan 1, 1991

By James R. Hein

Low- to intermediate-temperature, diffuse-flow hydrothermal fields and associated mineral precipitates have been found at many locations along oceanic spreading centers, back-arc basin spreading axes, and midplate hot-spots. However, this type of hydrothermal field has not been found in oceanic fracture zones until recently. We mapped and collected samples from an active hydrothermal field in the Blanco Fracture Zone (BFZ) located in the northeast Pacific. The BFZ connects the Gorda and Juan de Fuca spreading centers and is divided into east and west segments by Cascadia Depression, a small spreading center. Small pull-apart basins occur along both the east and west segments. A complex set of basins near the western end of the BFZ includes from east to west, Surveyor Depression, East Blanco Depression (EBD), and West Blanco Depression. The hydrothermal field described here is located in the EBD.

Jan 1, 2001

By Jonguk Kim

Hydrothermal sulfides were recovered from the16°50?S triple junction area in the North Fiji Basin, at a water depth of ca. 1900 m. The chimney samples can be divided into three groups according to their major metal contents: 1) type 1 (Fe-Cu-rich), 2) type 2 (Fe-Cu-rich with minor Zn), and 3) type 3 (Zn-rich) chimneys. Type 1 chimneys are mainly composed of chalcopyrite and pyrite, and are enriched in elements commonly precipitated under high temperature conditions (> 300°C), such as Cu, Co, Mo, and Se. Type 3 chimneys consist dominantly of sphalerite and marcasite with traces of pyrite and chalcopyrite, and are enriched in elements commonly associated with low temperature (150 to 250°C), such as Zn, Cd, Pb, As, and Ga. Type 2 chimneys show mineralogy similar to that of type 1 chimneys but their metal contents range between type 1 and type 3 samples. Trace element compositions of basaltic rocks indicate that magma generation in the triple junction area was influenced by two different sources: N-MORB and E-MORB. Sulfur and lead isotope patterns of the hydrothermal chimneys show distinct differences between the type 1 and type 3 chimneys. For example, type 1 sulfides are depleted in 34S and have lower Pb isotope ratios compared to type 2 and 3 chimneys. The d34S values (0.4 to 5.6?) of chimney sulfides are typical range of sulfur isotope composition of sediment free mid-ocean ridge hydrothermal system. Type 2 and 3 sulfides show slightly higher d34S values than type 1 sulfides, which can be explained by subsurface boiling of hydrothermal fluids followed by mixing of saline solutions with ambient seawater. Lead isotope compositions of the chimneys indicate that the Pb in type 1 and type 3 chimneys originates from hydrothermal leaching of N-MORB and E-MORB volcanic rocks, respectively. Considering that both these chimneys are located in the same area, our model suggests that type 1 chimneys formed by hydrothermal circulation controlled by an intrusion of N-MORB magma; the fluids were not influenced by boiling during the formation of type 1 chimneys. In contrast, type 3 chimneys are younger and were formed by hydrothermal circulation closely related to E-MORB magma intrusion at shallower depth. The necessary conditions for phase separation of the hydrothermal fluids that formed the type 3 chimneys might result from changed P-T conditions in a shallower high-temperature reaction zone beneath the hydrothermal venting site. Under these conditions the fluid may cross the two-phase boundary for seawater, ensuring subcritical phase separation. The mineralogical and geochemical properties of these chimneys suggest that type 1 and type 3 chimneys were probably black smoker and white smoker, respectively. Type 2 chimneys might be product of low-temperature replacement of type 1 chimneys, which is related to formation of type 3 chimneys.

Jan 1, 2005

By Kaihui Yang

Volcanogenic massive sulfide deposits are generally considered to have been formed by hydrothermal fluids that leach ore metals out of footwall rocks. However, the necessity for a metal-rich magmatic component in the ore-forming fluid of "giant" ore deposits has been debated over the decades. The solution to this issue is important not only for metallogenic models but also for the mineral exploration. In the hydrothermal leaching model, massive sulfides at mid-ocean ridges are deposited from hydrothermal fluids containing 80 ppm Fe, 6 ppm Zn, 2 ppm Cu, 350oC, and 0.7 g/cm3 density (average data for 21oN East Pacific Rise). A simple calculation demonstrates that such a dilute fluid is unlikely to have been responsible for the formation of the largest ancient massive sulfide ores of greater than 100x106 tonnes, such as Kidd Creek, Brunswick No. 12, Neves Corvo, and Rio Tinto. For such a deposit consisting primarily of pyrite, sphalerite, galena and chalcopyrite (other minerals, including gangue, might account for an additional 10-20%) and even assuming 100% precipitation and retention of the sulfides, more than 790 km3 of vent fluid would be required. For typical water-rock reaction ratios of about 2, this fluid would have to have reacted with about 395 km3 of rock to acquire its metals by conventional leaching processes. This estimate, however, conflicts with the observation that even a giant massive sulfide ore body is usually underlain only by a few cube kilometers of obviously altered rocks. Moreover, this model is not consistent with the observation of hanging wall alteration in many large massive sulfide deposits. The close spatial association between massive sulfides and volcanic rocks, in both ancient and modern sea floors, suggests that direct magmatic contribution should be taken into account in the genetic model. Magmatic fluids, capable of carrying abundant ore metals and volatiles and escaping from magma by depressurization, are well known from modern active volcanoes on land. High concentrations of metals occur in CO2-rich magmatic fluid trapped in felsic volcanic rocks nearby large presently-forming VMS deposits in the eastern Manus Basin (Pacmanus, Suzette) and also in the footwall rocks of Ordovician giant Brunswick #12 deposit in the Bathurst district, New Brunswick. Only 1% of such metal-rich magmatic fluid mixed with heated sea water, that has leached its metals from rocks, would contribute 85% of the total metals to form an orebody. Such magmatic fluids are most likely to be formed from volatile-rich felsic magmas that are prevalent in back arcs, and, if added to the normal circulation system, the fluids could be responsible for the formation of "giant" ore deposits. If this is true, then the study of magmatic fluids in the seafloor volcanic rocks may provide criteria for the exploration of large ore deposits.

Jan 1, 2011

By Tobias Hens, Andrew Frierdich, Barbara Etschmann, Joël Brugger, Barrie Bolton

"Ferromanganese (Fe-Mn) nodules and crusts are prime targets for future deep-sea mining ventures due to their unusual enrichment of critical metals, such as Ni, Co, Cu, Ti, Te, Zr, Hf, Nb, Y, and REE. These metals are used in an ever increasing variety of high- and green-tech applications such as alloys, batteries for hybrid cars, fiber-optic cables, or liquid-crystal displays.1 Recovery and processing of these deposits will most likely be cost-intensive and require new solutions.2 Thus, innovative approaches towards the development of sustainable metallurgical processes represent one component that can positively affect the marine mining value chain. Dynamic mineral recrystallization of Fe- Mn oxide phases is a geochemical process that may have notable potential for future hydrometallurgical applications.Our research focuses on Mn oxides – potent trace metal scavengers with high sorptive capacity3 – and biogeochemical mechanisms that control Fe-Mn nodule and crust formation, alteration, and trace element enrichment. Biogeochemical redox cycling of Mn is characterized by microbial oxidation of aqueous Mn(II) to Mn(III,IV) oxides and (a)biotic reduction of these oxides to Mn(II)aq. During this cycling dissolved Mn(II) is in direct contact with solid-phase Mn(III,IV) oxides and can back-react via abiotic pathways (e.g., 4 and references therein). This results in continuous dynamic recrystallization of the Mn mineral substrate through coupled dissolution (trace metal release) – reprecipitation (trace metal incorporation) processes.4 We recently demonstrated in new experiments, that Ni is cycled during manganite recrystallization. It has been shown that, although Ni readily undergoes mineral-fluid repartitioning in the absence of Mn(II)aq, dissolved Mn(II) significantly catalyzes Ni exchange between solid phase and solution. Over a period of 50 days about 30 percent of the Ni atoms in Ni-substituted manganite (natural abundance composition) were exchanged with a 62Ni(II)aq isotope tracer at pH 7.5. Based on these outcomes we employed similar techniques to investigate the impact of dynamic recrystallization on Mn oxide phases in deep-sea ferromanganese nodules and crusts from three circum-Australian locations (South Tasman Rise, Lord Howe Rise, Coral Sea) and the Central Pacific Basin."

Jan 1, 2017

By Carlos Almeida, Bruno Matias, Stef Kapuskiak, Eduardo Silva, José Miguel Almeida, Alfredo Martins

Underwater intervention operations have been supported by robotic systems such as remotely operated vehicles (ROV) for a long time. In particular challenging scenarios such as the deep sea, the use of ROV systems for environment awareness is in fact the main tool of choice. With the technical advances in autonomous robotics, there is an increased effort in substitute ROVs whenever possible for autonomous underwater vehicles (AUV). These systems don't have tether and thus provide large advantages from the operations and logistic point of view. However the limited options for underwater communications render them impracticable for many tasks were real time environment awareness and direct human control is needed. Emerging applications in underwater mining, both at sea [1] and in inland flooded mines [2] pose additional requirements in terms of operation support needs and environment restrictions. Two main tasks are to be addressed by assisting robots in these underwater mining operations: providing adequate environment awareness for human operators and obtain precise realtime 3D environment modelling (particularly relevant for the mining planning). The use of ROVs with umbilical cable, has in this case large limitations due to the nature of the mining cutting (performed by dedicated systems) that limit manoeuvrability and pose high risk of cutting the cable or damaging the vehicle. In this paper we present EVA (Exploration VAMOS AUV) an innovative hybrid ROV/AUV system developed for operations support in inland underwater mining operations. This robot is always operated without tether, and the can be used in a wireless ROV tele-operation mode using very short range high bandwidth underwater communication systems and in autonomous AUV mode.

Jan 1, 2018

By Toru Yamasaki

"Bimodal lithostratigrafic assemblages are of significance in volcanogenic massive sulfide (VMS)-hosted lithology. The largest deposits are either bimodal-siliciclastic or maficsiliciclastic, and the presence of a significant siliciclastic component in the host stratigraphic succession favors large VMS deposits (e.g., Franklin et al., 2005; Barrie and Hannington, 1999). In the case of modern sub-seafloor VMS deposits in arc-related settings, the majority of deposits have been discovered in association with calderas or cauldrons (Halbach et al., 1993; Ishibashi and Urabe, 1995; Iizasa et al., 1999). These features are formed by the explosive eruption of silicic volcanoes, so that silicic host rocks and/or pumiceous volcanic clasts are generally observed around the ore deposits (e.g., Binns and Scott, 1993; Fiske et al., 2001). Caldera-like and graben-like morphological features therefore attract attention in geophysical surveys. However, silicic lithologies (dacite and rhyolite) normally contain only small amount of metallic elements (e.g., a few ppm to a few dozen ppm of Cu), whereas mafic rocks, such as basalts and basaltic andesites, contain significant amounts of metals (e.g., a few hundred ppm of Cu). Thus, the origin of metallic elements in VMS deposits associate with the silicic host rock remains unclear.The Iheya North Knoll is a volcanic complex in the middle of the Okinawa Trough. It is located in a young and actively spreading back-arc basin that extends for 1200 km behind the Ryukyu arc-trench system (Lee et al., 1980; Letouzey and Kimura, 1986). Several active hydrothermal fields have been recognized in the Iheya North Knoll. Mineralization at the Iheya North Knoll is characterized by relatively juvenile features consisting of VMS deposits with associated hydrothermal alterations to various degrees. Massive sphaleriterich sulfides at this site, recovered for the first time from beneath an active seafloor hydrothermal system, strongly resemble the black ore of the Kuroko deposits of the Miocene age in Japan (Takai et al., 2011). From February 11 to March 17, 2016, the SIP CK16-01 (Exp. 908) D/V Chikyu cruise was conducted at Iheya North Knoll and the rifting center of the Iheya Minor Ridge area, middle Okinawa Trough. The Iheya Minor Ridge area is also an active hydrothermal field, located ~30 km southeast of the Iheya North Knoll. In this area, basaltic rocks are widely distributed, and drilling has confirmed that the basaltic materials continue to ~120 m below the seafloor (Kumagai et al., in prep)."

Jan 1, 2017

By C. W. Devey, K. S. Lackschewitz

The mineralogy and geochemistry of hydrothermally altered wall rocks from different modern basaltic- and felsic-hosted hydrothermal fields at seafloor spreading centers and convergent margins have been studied to determine the characteristics of different types of alteration and to calculate the magnitudes of elemental exchanges between seawater and wall rock.

Aug 24, 2006

By Takashi Ito

Numerous studies have examined the distribution of deep-sea manganese deposits throughout geologic history. Here I summarize the recent results, focusing on the frequency of occurrence, burial age and mechanism, and the paleoceanographic implications.

By Will Roberts, M. E. Williamson

After verification of methodology and testing of prototype systems during 2005/06, Nautilus Minerals expanded their Papua New Guinea (PNG) operations to a full commercial exploration program in 2007. Included was the deployment of sensors and survey systems to locate, characterize and verify massive sulfide deposits with potential as mine sites within the tenements held by Nautilus in PNG. This presentation discusses some of the gear developed and operated during the 2007 PNG investigation.

By Simon McDonald

The Neptune Group was established in 1999 to apply for exploration permits within New Zealand’s 200nm EEZ. These applications were to investigate and commercialise hydrothermal Seafloor Massive Sulphide (SMS) deposits identified by international researchers and to locate others. SMS are volcanically related seafloor accumulations of copper, lead and zinc with high levels of gold and silver. Neptune has three granted exploration licenses within the New Zealand EEZ and has application in other jurisdictions. Neptune undertook the world’s first commercial drilling exploration work of SMS in December of 2005.

Aug 24, 2006

By Masaru Nakamizu, Tetsuya Fujii, Tatsuo Saeki, Ken-ichi Yokoi

Methane hydrate, a solid compound formed from methane and water, occurs naturally in permafrost regions on-land and in deep continental slopes offshore and has been examined as future energy resources. The existence of methane hydrate in the eastern Nankai Trough region, offshore Japan, was confirmed by drilling the MITI well “Nankai Trough” in 1999. Aiming commercialization of methane hydrate production, the Research Consortium for Methane Hydrate Resources in Japan (MH21, core associations: JOGMEC[*1], AIST[*2] and ENNA[*3]) under METI [*4] has been executing geological and geophysical surveys around the eastern Nankai Trough since 2001 as a nation project.

By Hunsoo Choi, Sang-Mo Koh

Manganese nodule, the aggregate of fine grained manganese oxide minerals, is very brittle and fragile. In exploitation of manganese nodule, manganese nodules are easily broken into small pieces or powder during collecting and lifting from the sea floor. The broken manganese nodule under few millimeters and bottom sediment pumped up with manganese nodule affect to the lifting process. In this study, we tried to understand the physical properties of the powdered manganese nodule and bottom sediment, and to know the effect which may be rised to the actual mining of manganese nodules.

By Curtis Clement

Williamson & Associates, Inc. has developed a marine mineral exploration tool using an induced polarization technology (IP) under license from the US Geological Survey. Developed by Jeff Wynn at the USGS, this method has gone through several prototyping stages and is now in commercial use to map offshore ilmenite deposits. Preliminary results of a recent resource mapping program are discussed as well as potential applications in the detection and quantification of other minerals in marine sediments.

By Christian Müller, Hermann-Rudolf Kudrass, Christian Reichert

Recent studies estimate the depletion mid-point (dmp) for conventional natural gas to be reached around year 2022, and for conventional oil to be reached around year 2017. These numbers are based on simplified assumptions of unchanged demand and do not include increasing reserves from discovery of new fields and also do not include a shifting of resources to reserves e.g. due to an increasing oil price (Gerling et al., 2005). Anyhow, these prospects require conventional hydrocarbons to be substituted in the near future.

Aug 24, 2006

By Luana Karvel, Lars Kullerud, Morten Sørensen, Øystein Halvorsen, Øivind Lønne, Elaine Baker, Tina Schoolmeester, Joan Fabres, Yannick Beaudoin

The UNEP Shelf Programme (USP) is the access point for a collaboration of international organizations with expertise in marine geoscience and maritime law. It was established in response to a United Nations resolution, stating that the United Nations Environment Programme (UNEP), working through the Global Resource Information Database (GRID) system, should work in conjunction with Intergovernmental Oceanographic Commission of UNESCO (IOC) and the International Hydrographic Organization, to assist coastal States, and in particular developing States and small island developing States (SIDS) with submissions to establish the outer limits of their continental shelf under Article 76 of the United Nations Convention on the Law of the Sea (UNCLOS).

By Alan Foley

The Portable Remote Operated Drill was developed in Sydney, Australia in the 1990’s. The device is a platform for many in-situ seabed sampling and coring tasks. The range of tools developed for use in PROD’s magazine now includes gas detectors, vane testers, penetrometers and corers. This paper presents aspects of the soils testing undertaken in deepwater since 2005, focusing on testing of methane hydrates and reefal accumulations. The varied selection of tools carried in PROD’s magazines allow the unit to perform several functions from the seafloor in one deployment.

Sep 24, 2006

By Timothy F. McConachy, Christopher J. Yeats, Ray Binns

Various kinds of sediment-hosted polymetallic sulfide deposit are known on land in ancient marine sequences, many tending to be larger and more valuable than massive sulfide deposits genetically associated with volcanic host rocks. Often such deposits are attributed to subhalative or shallow sub-seafloor precipitation processes, and structural control by faulting is commonly evident. Apart from the famous but anomalous Red Sea metallic oozes and several NE Pacific sites (Middle Valley, Escanaba Trough, Guaymas Basin), however, modern analogs of the sediment-hosted polymetallic sulfide category are lacking. Some deposits hosted by volcaniclastic rocks, such as JADE (Okinawa Trough) and Suzette (Eastern Manus Basin) are strictly sediment-hosted, but their formation is associated with the igneous activity and they are better considered a variant of the more abundant volcanic-associated polymetallic sulfide deposits.

Aug 24, 2006

By Hjalmar Thiel

Issues of deep-seabed mining are discussed since four decades and extensive efforts have been invested in oceanographic studies related to environmentally sound harvesting of polymetallic nodules. Because mining on the deep seafloor seems to range from large-scale, two-dimensional dredging or scooping up of the ore from the uppermost surface sediment layer to more localized drilling or deeper digging into a three-dimensional ore body, it appears to be justified to reconsider some concepts for environmental impact evaluation. Based on the experience gained during preceding years in environmental studies related to polymetallic nodule mining, some interrelated hypotheses and proposals will be presented. It is suggested that these proposals be considered in future plans for environmental impact evaluation and that observations on community re-establishment be conducted before massive sulphide mining or other ore extractions enter the commercial mining phase.

Aug 24, 2006

By Robert Heydon

With the United Nations Conference on Sustainable Development fast approaching it is timely to reflect on the integral role seafloor polymetallic nodule mining will play in facilitating sustainable development and alleviating global poverty. Polymetallic nodule mining presents mankind with a unique opportunity to advance the world?s sustainable development aspirations, particularly given the ultimate beneficiaries from polymetallic nodule mining will be the billions of people around the world that require greater access to more affordable minerals for their social and economic development. This paper discusses the importance of polymetallic nodule mining in the context of sustainable development and forecasted growth trends, supply and demand dynamics, the decreasing grade and quality of terrestrial mineral resources, and the Green Economy, as well as in light of a comparative analysis that demonstrates polymetallic nodule mining offers a socially and environmentally advantageous alternative to terrestrial mining.

Jan 1, 2011