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By K. K. Kelley

The collection and correlation of thermodynamic data concerning substances of metallurgical interest have constituted one of the major activities of the Pacific Experiment Station of the Bureau of Mines, at Berkeley, Calif., for the past several years. Earlier bulletins (32, 33, 34, 36, 36, 37, 38) s in this series are entitled: (1) Contributions to the Data on Theoretical Metallurgy. I. The Entropies of Inorganic Substances; (2) Contributions to the Data on Theoretical Metallurgy. II. High-Temperature Specific-Heat Equations for Inorganic Substances; (3) Contributions to the Data on Theoretical Metallurgy. III. The Free Energies of Vaporization and Vapor Pressures of In¬ organic Substances; (4) Contributions to the Data on Theoretical Metallurgy. IV. Metal Carbonates--Correlations and Applications of Thermodynamic Properties; (5) Contributions to the Data on Theoretical Metallurgy. V. Heats of Fusion of Inorganic Substances; (6) Contributions to the Data on Theoretical Metallurgy. VI. A Revision of the Entropies of Inorganic Substances-1935; and (7) Contributions to the Data on Theoretical Metallurgy. VII. The Thermodynamic Properties of Sulphur and its Inorganic Compounds. The present paper collects and discusses thermodynamic data relating to metal carbides and nitrides, with the view of obtaining usable heat and free energy of formation relationships. Pertinent data on both classes of substances are difficult to obtain experimentally and consequently are extremely rare; it is therefore necessary in many cases, if equations are to be derived, to introduce certain approximations and assumptions. Lack of adequate means of checking results by utilizing data of different types, such as was done frequently in the bulletins dealing with carbonates and sulphates, are readily apparent to anyone who has made even a cursory examination of the available information. Consequently, some of the relationships derived undoubtedly will be found to be inaccurate when more or better data become available. Nevertheless, in view of the importance of some of these substances, it appears worth while to consider the information available at present and to attempt the formulation of as complete a

Jan 1, 1937

By Regina Maria Pinheiro

This work has for objectives to characterize a waste generated in the form of sludge during the treatment of the effluent of a paper making industry and to evaluate the effect of its incorporation in the amount of 10 wt.% on the properties and microstructure of a clayey body used for brick production. For the characterization of the waste the following techniques were used: X-ray diffraction, X-ray fluorescence, differential thermal analysis and termogravimetric analysis. Incorporated bricks were produced in industrial scale before firing at 750°C in a Modified Caieira type furnace. The physical and mechanical properties evaluated were water absorption and compression strength. The microstructure of the fired ceramic was evaluated by optical microscopy. The environmental evaluation was made by solution test and atmospheric emission by monitoring the release of SO2, NOx and particulate material. The results showed that, in agreement with the characteristics of the waste, its recycling into red ceramic can contribute to decrease the consumption of fuel during the firing stage. The properties of the fired ceramic attend the norms. With respect to the environmental aspect, the incorporation of the waste did not impact the environment.

Jan 1, 2009

By David E. Nicholas

Design of underground openings is becoming more critical as the mine deposits become lower in grade, initial investments increase, ore depth increases, additional safety regulations come into law, and increased ore recovery is required for conservation of minerals. Stability of these openings is dependent on the strength of the rock mass and the pre-mine stress field. The rock mass is composed of solid blocks of rock (rock sub- stance) and structural features (faults, joints, bedding, etc.). Methods of testing the rock mass strength are improving and be- coming more common, however it is difficult to justify the high cost of large scale testing for an initial mine design. An alternative to testing the rock mass is to measure the rock substance and the structural features separately, and then combine them to estimate the rock mass strength. The rock mass strength will vary depending on the orientation of the opening with respect to the structural features. The other factor affecting the stability of underground open- ings is the pre-mine stress field. Methods are available to measure "directly" the pre-mine stress in competent and relatively massive rock. These methods are costly to employ, therefore, they may not be justified in an initial study. The pre-mine stress field can be estimated based on the structural relationships formed from past tectonic events.

Jan 1, 1976

By John T. Cumberlidge, Frederic M. Chace

Nickel-bearing saprolite developed during the early Tertiary over a northeast trending ultramafic body of Jurassic age near Riddle in southwestern Oregon. The principal nickel mineral is garnierite, but other complex nickel minerals may be present. There are two main ore bodies, an upper (older) one associated with the Klamath peneplain, and a lower (younger) one on the Sherwood peneplain. Saprolite constitutes the bulk of the ore and was probably derived from peridotite and dunite through chemical decomposition by downward percolating meteoric groundwater. Decomposition took place by net loss of MgO, SiO2, and Fe without a change in volume. Faults and joints provided permeable zones which localized saprolite development, and faulting may have helped preserve some ore from loss by erosion. Garnierite-chalcedony boxwork ore was deposited by meteoric groundwater along faults, joints, and at the level of former water tables. Boxwork ore is entirely supergene, the chemical constituents having been derived from higher in the soil profile. The saprolites show evidence of both supergene and residual enrichment in nickel. Red and yellow soil occurs as a capping over saprolite and boxwork, and was derived from them by chemical and mechanical decomposition. The present deposits are probably truncated remnants of a formerly thicker and much more extensive deposit which probably included laterite at the surface. The deposits started to form in the early Tertiary due to deep chemical weathering under sub-tropical to warmtemperature conditions. Early Tertiary ero~ion surfaces of low relief probably contributed to the predominance of chemical weathering over mechanical erosion. Alteration under present climatic conditions favors the formation of soil from saprolite rather than the formation of new saprolite from peridotite.

Jan 1, 1968

By Sandra Lúcia de Moraes

O presente trabalho visou contribuir para o melhor entendimento do mecanismo inerente ao uso de agente coloidisante/dispersante no processo de pelotização de concentrado de minério de ferro. Avaliou-se a influência dos agentes coloidisantes em comparação aos aglomerantes Peridur e bentonita. Para este fim, foram realizados ensaios de bancada visando a identificação de possíveis ações destes agentes no grau de dispersão das misturas, bem como a sua influência na liberação/aglomeração dos finos. Os resultados destes parâmetros foram confrontados com os resultados de caracterização das pelotas confeccionadas com os diferentes agentes pelos quais foi possível identificar que os dispersantes tem forte atuação sobre o conteúdo de finos do concentrado de minério de ferro. A ação principal se dá pela remoção das partículas ultrafinas que recobrem os grãos mais grosseiros presentes na amostra e as dispersam, no caso dos dispersantes, aumentando a disponibilidade do conteúdo de finos <4 µm, principalmente os finos <1 µm (coloides). No caso do aglomerante orgânico, observa-se também essa ação, no entanto, os finos presentes são aglomerados na faixa entre 26 e 4 µm.

Aug 16, 2017

By Holger Witthaus

There is more than a century of experience in multiple seam mining in Germany. In several mines up to 20 seams had been excavated within the last decades. Due to the nature of the deposit and the history of technical development the older panels cause a complex stress distribution for the lower seams and the current longwalls in descending order of mining. The depth of the longwalls reaches up to 4000 ft. This causes a maximum vertical stress that reaches between 30 and appr. 60 MPa. To handle these conditions several support systems are applied for roadway heading. A central knowledge management system for ground control is used for design and dimensioning of support within the DSK. This paper gives an overview to the nature of German multiple seam mining and the solutions in matters of panel layout and support design. It describes the full lifecycle for roadways in the seam starting with the geological and geotechnical evaluation, the basics of roadway deformation in great depth, the development of planning tools and standards for German coal mines, the range of alternative of support systems and roadheading techniques, as well as the reinforcement measures and the processing of support at the T-junction of the face entry. This paper uses exemplary descriptions that are consolidated in a specialized reference book ?Gebirgsbeherrschung von Flözstrecken? ? ?Ground Control in Roadways? which summarizes the standards of ground control based on the development of the past 25 years in German coal mines.

Jan 1, 2007

By Kenneth Gavin

The accurate prediction of the shaft capacity of drives piles in sand continues to present problems for foundation designers. Research in this field has been carried out for many years and has yielded a wide range of design approaches -some of which have been shown by recent experimental work to be based on questionable assumptions. This Paper reviews some of the current popular design methods for piles in sand in the context of recent information obtained from high quality field tests conducted by institutions such as Imperial College London. A database of driven piles in cohesionless soils has been compiled from well documented (and reliable) case histories that have been reported in the literature. The measured shaft capacities of the piles in this database are compared with predictions made by the various methods and an assessment is made of the predictive performance and reliability of each method

Jan 1, 1996

By John L. Mero

"The ocean has served humanity as a source of raw materials for thousands of years, but only on a minimal scale relative to its potential. Exploration programs have shown the ocean to contain a large number of mineral deposits of great extent and attractive grade. Recent research has indicated that a number of these deposits can be economically exploited with present-day technology and that the cost of winning many industrially important minerals from the oceanic deposits is potentially much less than that of winning similar minerals from land deposits. Although the finding of mineral deposits in the sea is a relatively simple matter at the present time, the exploitation of many of these deposits has lagged due to the lack of the availability of specific mining techniques for the individual deposits. Within the past two years, however, several developments have taken place in the design and testing of ocean mining systems in depths of water as great as 12,000 feet which indicate that the problem of mining in the ocean may soon be solved.Within the next decade, the ocean should prove to be a major source of many minerals for society and should come to dominate as a source of such metals as copper, nickel, cobalt, manganese, etc. Within a few years of the initiation of the mining of the deep-sea metalliferous nodules, land sources of such metals as nickel, cobalt, copper, manganese, etc. will be seriously affected and it is conceivable that the present structure of the world mining industry will undergo a substantial change in character."

Jan 1, 1972

By W. J. Fene, G. W. Grove

An important activity of the Safety Division of the Bureau of Mines , in its efforts to reduce accidents , is the safety inspection of mines . Inspections are made at the request of the operators and are not connected with the inspections by the various State departments of mines . The operating management is furnished with a confidential report of the results of the Bureau's inspections , with recommendations for elimination of the hazards found . These mine - safety inspections include a study of mining practices , conditions , and equipment and in some cases the sampling and analysis of mine air and coal dust . The Bureau of Mines has no regulatory powers , therefore the recommendations made in these reports are merely suggestions , and operators are not required to adopt them . Mine inspections are a check on safety standards , methods , and practices and are essential to any accident -prevention program . A foreman or superintendent may be sincere in his efforts to operate a mine safely and believe that he has done everything possible to attain this end . However , experience has shown that because of his familiarity with the mine and the consequent " nearness " of its various features many unsafe conditions may be , and in most cases are , overlooked ; an inspector , particularly an outsider who is trained to look for hazards , can point out the unsafe conditions overlooked by the foreman or superintendent . Some companies employ safety engineers who make regular inspections of their mines , report substandard conditions and hazards found , and make recommendations for correcting them . Unless these recommendations are carried out the inspections have little value . In making recommendations , due consideration should be given to the feasibility of carrying them out ; the management may and very often does consider a recommendation impracticable because of the

Mar 1, 1935

By R. T. DeWoody, J. W. Chester, W. C. Miller

The work was done to develop a relatively efficient muffler for quieting the exhaust of a rock drill . The exhaust of a pneumatic rock drill is the source of the major part of the noise generated by the drill . The exhaust noise can be reduced in a number of different ways , but this study involved only reactive mufflers . The reactive muffler can be simulated by an electrical circuit . Information obtained from analogous electrical circuits was used to design an efficient exhaust muffler for pneumatic rock drills . Electrical analogies proved to be a valuable tool in the design of mufflers .

Jan 1, 1964

By A. G. Doll

"This paper expands the SAG mill survey database published by the Author at Procemin 2013. The new database includes 49 published SAG/AG mill surveys and includes mills from all over the world. The paper will compare the survey database to SAG mill models by Austin, Morrell and Hogg & Fuerstenau with the purpose of demonstrating the degree of fit of the models to surveys and validating any empirical “fitting factors” used in the models.SAG mill power draw models are used in mill design and grinding circuit modelling to predict how much power will be consumed by a particular mill geometry and operating configuration. The importance of conducting surveys suited to model calibration will be highlighted because the review of literature shows that survey information important to modelling is often missing or omitted. A recommendation for the collection of data during a mill survey is presented, along with some assumptions used by the Author in the absence of certain data. The benefit to mining companies of publishing their survey data, and thereby allowing modellers to improve their model calibration, is discussed.The comparison of models requires a discussion of the measurement of power in a mill drive system as the models use slightly different position in the electrical network for ""where power is measured"". The benchmarking of models against plant operations requires a similar discussion of power measurement."

Jan 1, 2016

To ensure that its voice is heard in the development of policies and plans under the Resource Management Act, the mining industry is challenged to participate in their preparation. This paper outlines a number of practical ways in which the industry can participate in debate on sustainable management and how it can be put into practice within the industry.

Jan 1, 1992

By Stig O. Olofsson

The problem of overbreak in underground construction and mining is normally approached by a variety of smooth blasting methods. Numerous small diameter, low velocity explosives have been developed specifically for blasting the contour line. Increased mechanization in rock excavation has led to the development of several methods of mechanical explosive loading. A new mechanically loaded smooth blasting explosive was developed in Sweden . However, several limitations were realised, which after several trials resulted in a hybrid smooth blasting method, The Suaer Cautious Contour Blasting Method which will be discussed in this paper.

Jan 1, 1994

This field guide is designed for use in planning pollution control and reclamation activities on small sand and gravel operations. Its purpose is to assist operators in selecting environmentally desirable pollution control and reclamation procedures based upon their particular mining situation. The guide includes information on interpreting physical and cultural factors that must be considered in planning and implementing a mining and reclamation program, achieving environmental protection objectives, and improving community/industry cooperation. Included as appendices are a summary of state laws and a list of additional readings on the subject.

Jan 1, 1981

By R. Hamar, G. Lamanthe

"To realize complex shaped pieces, like turbine blades, superalloys are cast with the lost-wax process. The end properties of these parts depend upon their microstructure as well as upon the occurence of casting defects such as micropores and hot tears. Such features are governed by the local solidification conditions which may be describe by the calculation of thermal transfers between alloy and mould. It needs the evaluation of numerous parameters which are fitted from experimental measurements in real castings. In further simulations, any parameter may be changed, in order to determine its influence. Such a single modification is quite impossible to realize in real castings, which shows that numerical modeling is a very good way to study casting processes.This modeling technique of casting is applied here to the real study of a typical low pressure turbine blade of a civil engine.IntroductionAircraft engine manufacturers use superalloys to produce turbine blades. They have to obtain a given microstructure and to avoid solidification defects to give good mechanical properties to theirs castings. For example, microporosity is induced by a large shrinkage that cannot be completely fed with the remaining liquid alloy .The optimization of casting processes needs a good Knowledge of the solidification process, that must be controlled at every place in the casting, and at every time of its freezing. Material and heat transfers that occur during the solidification, can be estimated from rather complex calculations. To model these physical phenomena, the evaluation of many parameters must be made. In this aim, some casting experiments are fitted with numerous thermal captors. The identification of experimental and computed thermograms let us estimate these parameters.A long-range scientific cooperation between SNECMA and INPG has enabled the realization of such studies on this topic. From all of them, this paper describes an experimental and computed investigation which has been led on a typical low pressure turbine blade of a civil engine."

Jan 1, 1986

By Bruce F. Grant

This report discusses research being done by the Petroleum and Natural Gas Branch und the Applied Physics Branch of the Bureau of Mines to deter-mine the most effective uses of explosives in shooting oil and gas wells, as measured in terms of rates of production from the wells. An experimental investigation of the effects of detonating explosives in shallow holes drilled in rocks, chosen to be similar to those forming oil and gas reservoirs, forms the basis of this study. Records obtained from strain gages placed in the rock around the experimental shots permit determination of the generation and propagation characteristics of the strain wave. Water-injection tests made on the test holes before and after shooting allow the increase in fluid conductivity resulting from the shot to be determined. By rotating these data to the physical properties of the rock, and by conducting shooting experiments over the range of rock types common to oil and gas reservoirs, it is expected that relationships between the fluid conductivity and the properties of the explosive and rock can be developed and used for designing efficient shots for oil and gas wells. Four series of experiment.al tests were completed during the summer of 1949 and are described herein. The results of these tests confirmed the feasibility of the experimental approach and permitted outlining the plans for future research discussed in this report. This report is presented to acquaint industry with this research program and the progress to date, so that the Bureau may have the benefit of suggestions from interested readers.

Jan 1, 1950

By Patricia Martínez Nicolás

Nickel and ferronickel are some of the major components in the production of special alloys; however, the energy consumption for their production greatly increases their price. A cheaper option could be to use NiO and a reducing agent. This work presents experimental and theoretical analysis to estimate the effect of slag basicity and amount of reducing agents on the NiO reduction from the slag which interacted with molten steel at 1600 °C in an EAF. The slag system contained CaO, SiO2, CaF2 and NiO together with a reducing agent, ferrosilicon or carbon. The NiO content in the slag was 25 mass%. The amounts of the reducing agents (Si and C) were 1 to 4 times the stoichiometric mass to reduce NiO. The CaO/SiO2 ratio was 1.5 and 2.5. The kinetics of the process was very fast since after few minutes the maximum nickel yield was obtained. The slag basicity had a negligible effect on the reduction of NiO.

Jan 1, 2006

By J. W. Bridge

Triaxial compression tests at various confining pressures and temperatures, as well as tangent modulus tests using ultrasonic waves, were conducted for wax-coated granular composite materials. The material used is a surface for Thoroughbred horse racing. The purpose of these tests is to examine how track shear strength and tangent modulus at a range of loads respond to changing temperatures. Previous work has shown that a wide range of operational temperatures are experienced which have been reproduced in the lab. Using differential scanning calorimetry, it is confirmed that these operational temperatures correspond to distinct thermal transition regions for the wax that is used to coat the sand in these surfaces. Preliminary results show that both shear strength and tangent modulus are sensitive to temperature changes with maximum strength and modulus correlating with major DSC wax transition regions.

Jan 1, 2010

By K R. Vining, T E. Norgate

A study was carried out to compare the environmental impacts of the two major iron ore agglomeration processes, sintering and pelletising, using life cycle assessment (LCA) methodology. The following agglomeration processing routes, with the fuel options shown, were investigated:sintering with combined natural gas/coke breeze or charcoal as fuel, grate-kiln pelletising with combined natural gas/coke breeze as fuel, and straight-grate pelletising with combined natural gas/coke breeze as fuel. Inventory data for each process derived from the literature, and in some instances supplemented by additional simulations and calculations, were used in the study and the environmental impact categories considered were gross energy requirement (GER), global warming potential (GWP) and acidification potential (AP). The results of the study showed that the GER, GWP and AP for a sinter plant are higher than those for a pellet plant for the same amount of metallic iron in the agglomerated products. These results are partly due to higher consumption of solid fuel and flux in the sintering process. However, it should be pointed out that the study only compared substantially fluxed sinters with acid pellets that may require additional flux (and hence potentially more greenhouse gases emissions) to be a balanced blast furnace feedstock. Extending the LCA to the blast furnace process stage was beyond the scope of the current study. Within the sinter plant, the sintering stage itself is the largest contributor to the GER, GWP and AP. In the case of pellet plant, the pellet induration stage is the largest contributor to the various environmental impacts. The GER and GWP of a straight-grate pellet plant are marginally higher than those of a grate-kiln pellet plant due to the higher electrical power required by the straight grate system. The substitution of coke breeze with charcoal in the sintering process results in an increase in GER but a decrease in GWP. However, a substantial proportion of the GER is derived from renewable sources (wood), resulting in a decrease in the non-renewable components of this environmental impact. Given the source of the inventory data and the assumptions and approximations made in carrying out the LCAs, it is emphasised that the results presented in this paper should be considered as indicative rather than as definitive results for the two iron ore agglomeration processing routes considered.

Jan 1, 2006

By Oliver Bowles

ASBESTOS is a name applied to a group of naturally fibrous minerals. As indicated in a later section devoted to a detailed discussion of the early history of asbestos, the tern may be defined as a. fibrous form of serpentine or amphibole. It does not include fibrous forms of other minerals, such as wollastonite, nemalite (fibrous brucite), or the fibrous forms of calcite or gypsum. A material that has the characteristics of silk or cotton and at the same time will not burn is unique. Because it combines these qualities with other advantageous properties, asbestos has specialized uses for which no substitutes are yet available. Asbestos furnishes a major raw material for a great variety of essential products and their manufacture constitutes a vast industry. The United States leads all countries in the manufacture of asbestos products. The value of such commodities manufactured in 1952 exceeded $332 million. They are not only of vast importance to budding construction and industry but axe absolutely, essential to certain important fields of use, for example, steam packings and friction materials, such as brake-band linings on automobiles.

Jan 1, 1955