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By K. K. Kelley, W. W. Weller

This report contains experimentally determined heat capacity data for four crystalline sulfides -- AsS , GeS , NiS , and Ni3 S₂ -- over the temperature range from 50 ° to 298.15 ° K. The heat capacity data were used to evaluate the entropies of the sulfides at 298.15 ° K. Entropies of formation from the metals and rhombic sulfur and from the metals and diatomic sulfur gas are also included .

Jan 1, 1964

By J. H. Field

Results of studies by the Federal Bureau of Mines on a pilot-plant scale for removing hydrogen sulfide and carbonyl sulfide from gas mixtures by the hot carbonate system are given in this publication. Gases containing up to 10 pet. hydrogen sulfide and 48 grains carbonyl sulfide per 100 cu.ft. were treated. In most tests carbon dioxide also was present and was removed simultaneously with the sulfur compounds. Because the rate of absorption of hydrogen sulfide is much more rapid than that of carbon dioxide over a wide temperature range, selective removal of hydrogen sulfide occurred in the bottom section of the absorber near the point of gas entry. Hydrogen sulfide was removed to pipeline specifications with carbonate solutions by using split-stream flows in the absorber and regenerator.

Jan 1, 1960

By Clarence O. Babcock

This Bureau of Mines publication presents guidelines for mining near surface and underground bodies of water. The guidelines were based on information developed under contract in three phases of study, as follows: (1) Collection and documentation of data from worldwide sources; (2) application of existing guidelines, foreign, Federal, and State, to case histories of previous inundations; and (3) development of recommended guidelines for underground coal mining near bodies of water aimed at maximum efficient utilization of underground coal resources consistent with minimizing inundation hazards. While the contract guidelines were for the mining of coal seams, they may also be used for mining any tabular sedimentary mineral deposit. Tables are given for the determination of the size of coal pillars needed; for other bedded deposits, similar tables could be determined based on their strength properties.

Jan 1, 1977

By R. S. Fowkes

Jetstream pressure distributions and coal cutting rates were determined for a number of nozzles and under different operating conditions. The jetstrearn pressure distribution data were fitted to an assumed curvilinear equation by the utilization of a numerical least-squares technique with the aid of a digital computer. Subsequent manipulation of the approximation equation showed that the total force of the jetstream, rather than its maximum pressure or total kinetic energy per unit Lime, was the most significant quantity affecting the coal cutting rate. A shorter method for assessing the ability of a nozzle to cut coal was found.

Jan 1, 1968

By Michael J. Magyar

The Federal Bureau of Mines has developed a hydrametallurgical method to recover aluminum, aluminum oxide, and fluxing salts from aluminum salt slags. The slag is leached with water at room temperature to produce a saturated brine slurry. Screening of the slurry yields an aluminum-rich fraction that can be returned to the dross furnace. The remaining slurry is vacuum filtered, yielding a clear brine solution and an aluminum oxide filter cake. Evaporation of the clear filtrate produces a high-purity fluxing salt for reuse in the dross furnace. Over 80 pct of the metallic aluminum is recovered in the aluminum-rich oversize fraction, while essentially all the fluxing salts are recovered by evaporation. This report contains the final results of an investigation on a process research unit scale, an economic evaluation of the method, and recommendations to further improve the process.

Jan 1, 1979

By F. D. DeVaney

[In the course of the investigation by the U. S. Bureau of Mines and the Missouri School of Mines and Metallurgy at the Mississippi Valley experiment Station at Rolla, Mo., on the beneficiation of the low-grade manganese ores of the country, some samples from the Cuyuna District, Minn., have been examined. The work was done under the direction of W. H. Coghill, supervising engineer of the Mississippi Valley Experiment Station. Josoph and Kinney5 in venting about the relative importance of Minnesota deposits of low-grade ore compared to the total reserves say:]

Jan 1, 1930

By Robert H. Bedford

The New Almaden mine was discovered in 1824, and since that date production of quicksilver has exceeded 1,000,000 flasks. Because of this high production record, the New Almaden area was, upon passage. by Congress of the Strategic Minerals Act of 1939, immediately considered by the Bureau of Mines as a promising location for exploration. In 1941, the Federal Geological Survey undertook a survey of the entire district. R. R. Trengove, an engineer of the Bureau of Mines, made a preliminary study for a project in 1942, and in August 1943 the Bureau, in close cooperation with the U. S. Geological Survey, began the development project described herein. The Bureau of Mines drilled 36 holes, totaling 6,807 feet of diamond drilling, along the contact between the serpentine and Franciscan, sandstones and other sedimentary formations. The ore bodies are found along this contact and occur in the carbonate-silica rock. This report briefly describes the location, history, and ore deposits of the property. The recent operations are outlined, and the work performed by the Bureau is explained in detail.

Jan 1, 1950

On December 16, the General Services Administration (GSA) suspended weekly sales of surplus silver from the national defense stockpile because Congress approved the Defense Appropriation Act, which contained an amendment to halt silver sales. The amendment, introduced by Senator James A. McClure (R., Idaho), prohibits sales for 6 months while the impact of the sales and alternative methods of disposal are evaluated. The GSA sold 2 million troy ounces since sales started October 14. 46.5 million troy ounces were authorized to be sold during this fiscal year and an additional 58.6 million troy ounces were authorized to be sold over the following two fiscal years. The stockpile held 139.5 million troy ounces of silver when sales began in October. Brush Wellman, Inc., a vertically integrated producer of beryllium products announced plans to modify its Delta, Utah beryllium concentrate processing facility to utilize beryllium concentrates containing as little as 7% beryllium oxide. The company plans to invest $2.5 million for this modification with completion expected in mid-1983. Implementation of this plan to consume lower grade beryllium minerals will significantly increase world reserves of beryllium concentrates.

Jan 1, 1981

By D. Harrington

Although it is impossible to give definite final figures at this time on Nation-wide accident occurrence in 1933 , enough data are at hand to indicate that the progress in safety in the mining industry, which first became apparent in 1930 and was accentuated in 1931 and 1932 , was continued and much improved in 1933. This improvement was of considerable magnitude in mining both bituminous coal and anthracite but was not so great in other branches of the mining industry . While the volume of work done in all phases of mining increased in 1933 over that in 1932 , the exact amount of the increase is not yet known . Usually increased activity in mining is accompanied by even greater increase in the rate of occurrence of accidents to the workers , but happily it appears that this " rule " was not operating in 1933 --at least in the coal -mining industry .

Oct 1, 1934

By K. K. Kelley, W. W. Weller

Heat capacity measurements of akermanite ( Ca,MgSiO ) , cordierite (Mg2A14 Sig018 ) , gehlenite ( Ca₂Al₂ SiO ) , and merwinite ( Ca ,MgSiO ) were conducted over the temperature range from 50 ° to 298.15 ° K. The entropies at 298.15 K ( expressed in cal / deg mole ) were evaluated as follows : Akermanite , 50.0 ± 0.5 ; cordierite , 97.3 ± 0.9 ; gehlenite , 47.4 ± 0.4 ; and merwinite , 60.5 ± 0.5 . All four compounds have positive entropies of formation from their constituent oxides at 298.15 ° K ; the values range from 4.6 cal /deg mole for akermanite to 10.1 cal / deg mole for cordierite .

Jan 1, 1963

By Alan J. Fejes

As part of its mine subsidence research program, the Bureau of Mines and the American Electric Power Co. cooperated on a study, conducted at the Price River Coal Co. No. 3 Mine, directed toward developing the capability to estimate the surface subsidence resulting from longwall mining in a geologic, topographic, and mining environment common to coalfields in the Western United States. Subsidence was monitored at the No. 3 Mine over two adjacent longwall panels. The subsidence study area was reduced when the two planned panels were reduced in length because of equipment failure and a mine fire. Subsidence was measured for 21 months. Subsidence continued for 6 months after mining had been completed. A maximum of 2.2 ft of subsidence occurred over the two longwall panels mined at an overburden depth ranging from 300 to 1,500 ft.

Jan 1, 1986

By J. H. Jacobs

The first authorization, in November 1940, was for a plant of only several hundred pounds capacity at Boulder City, Nev. Improvements in the process and subsequent additions to some sections have enabled the plant to produce more than 2,000 pounds of manganese per day for substantial periods. By the time pilot-plant operations were suspended in June 1945, over 1,500,000 pounds of metal had been produced. The future of electrolytic manganese production obviously depends not only on satisfactory development of methods but on availability of raw material and demonstration of valuable uses. Investigations of manganese-ore deposits in this country, made since 1938 by the Bureau of Mines, have revealed large amounts of ore suitable for making electrolytic manganese. At first the pilot plant was operated on ore from the Three Kids mine near Las Vegas, Nev. After practical features of the process had been worked out, other ores from throughout the United States were tested in the pilot plant. The purpose of this paper is to compare the results obtained on the following ores: Three Kids; Ladd mine, Tracy, Calif.; Chamberlain, S. Dak., nodules; and ore from Metals Reserve stockpiles at Deming, N. Mex.; Cushman, Ark.; and Philipsburg, Mont.

Dec 1, 1947

By R. H. Nafziger

The Bureau of Mines evaluated 18 domestic titaniferous materials with widely varying compositions, mineralogy, and physical properties in electric-arc furnaces, Techniques were devised to recover both the titanium and iron values contained in these materials so that the reliance of the United States on foreign sources of higher grade ilmenites and rutile might be decreased. Most of the tested titaniferous materials responded well to lower grade or byproduct reductants, such as bituminous coals, charcoal, and coke breeze. Sufficient slag fluidity was realized by maintaining from 8 to 12 wt-pct iron in the slags; no contaminating fluidizers were required. Fluid slags containing up to 79, 70, and 54 wt-pct Ti02 were realized from east coast ilmenites, a rock ilmenite, and a titaniferous magnetite ore, respectively. A carbon-lined furnace shell is recommended for minimum slag contamination. Good results also were obtained during extended submerged-arc furnace tests.

Jan 1, 1980

By GLADYS G. HEFFNER, William H. Waggaman, Edwin A. Gee

Thallium is one of the rare and relatively neglected elements that has recently assumed conspicuous importance. This element is widely distributed in nature but occurs in such minute quantities in most rocks and minerals that its recovery at present is only commercially feasible as a byproduct of other industries. World War II, with its unprecedented demand for products having special or unusual properties, led to a study of a number of the rarer elements that previously had been given comparatively little attention for one or more of the following reasons: 1. 2. Limited knowledge of properties. Small quantitios present in available raw materials. 3. High cost of concentration and recovery. Some of those rare elements, either alone or in the form of compounds, have already proved of such value for certain military and industrial purposes that their extraction from ores and waste products, oven at high cost, is fully justified. On the othor hand, further investigation of their character- istics, discovery of more adequato sources, and improvement in methods of con- centration and recovery would greatly broaden their field of usefulness and establish new and expanded industries. The current market for some of these elements exceeds the available supply. One of the functions of the Bureau of Mines is to study the properties of such elements in greater detail, locate the most promising raw materials from which they can be derived, and work out methods of extraction that will render the recovery of such elements more economical. The purpose of a serios of information circulars on the raror elements is to present in condensed form the facts and data so far available. This information may serve as a basis in planning more complete investigations loading to a full utilization of such elements.

Mar 1, 1950

By Thomas J. Peters

The Snowbank study area, which had been proposed as Wilderness, lies about 5 air mi southwest of Cascade, Idaho, and about 60 air mi north of Boise. The eastern boundary of the north-south-elongate study area lies 1-to 2-mi east of Cascade Reservoir; the western boundary is contiguous, in part, with the western boundary of Valley county. The 8,200-acre study area is underlain by Cretaceous granitoid rocks of the Idaho batholith. Three prospects were found in or near the study area during a library and field search. Gold occurs at one 30-ft adit, but the gold-bearing structure appeared too narrow to contain resources. Two other prospects appeared essentially unmineralized. No evidence of geothermal activity was observed. Rock in the area is not potentially useful as dimension stone because it does not split into flat slabs. To be used as aggregate, the rock would require crushing and hauling to distant markets. One of 18 alluvium concentrate (placer) samples contained free gold, worth $1.07 per cubic yard of gravel (at a $350 per oz gold price). No alluvial bars were seen; deposits were too small to contain gold resources or be considered gravel resources.

Jan 1, 1993

By L. B. Pankratz, R. Barany, W. W. Weller

Experimental determinations were made of the heats of formation at 298.15 ° K of cuprous ferrite and cupric ferrite ; the heat capacity of cuprous ferrite was measured over the temperature range from 50 ° to 298 ° K and the entropy at 298.15 ° K was evaluated ; the heat contents of cuprous ferrite and cupric ferrite above 298.15 ° K were measured to 1,500 ° K and 1,100 ° K , respectively . These thermodynamic values were combined with other pertinent data to obtain heat and free energy of formation values at high temperatures . The stability of the two ferrites with respect to their constituent oxides is discussed . Thermodynamic values are included for the decomposition of cupric ferrite to form cuprous ferrite , magnetite , and oxygen .

Jan 1, 1964

By N. A. Eilertsen

Among the numerous Low-grade manganese deposits in eastern Aroostook County, Maine, the Dudley deposit near Mapleton in the northern district is one of the few known to contain an appreciable tonnage averaging above 10 percent manganese. The ore body, consisting of stratified manganiferous hematitic shale, is over 5,000 feet long and ranges in width from 30 to 175 feet. The deposit was extensively explored during 1942-44 by the Manganese Ore Co., a subsidiary of M. A. Hanna Co. of Cleveland, Ohio. Data obtained from this work were made available to the State and Federal Geological Surveys for estimating ore reserves. An estimate by the Maine Geological Survey, using a 10-percent manganese cutoff and to a depth of 200 feet, shows 609,000 long tons of manganese metal in material averaging 12.6 percent manganese. By lowering the cutoff limit to 5 percent manganese, the estimate was increased to 919,000 long tons of metallic manga¬nese in material averaging, 10.4 percent manganese,

Jan 1, 1957

By Lloyd Williams

1. Reserves have been estimated for three coal beds in Bledsoe County, Tenn.: Morgan Springs, Lantana, and Sewanee. The Richland and Nelson beds occur in Bledsoe County also, but there was not enough information on them for making an estimate of reserves. 2. Known measured and indicated reserves for all beds, based on a minimum thickness of 14 inches and on 1,800 short tons per acre-foot of coal in place, are estimated at 43 million tons as of January 1, 1954. Of this total, 22 million tons represents coal 28 inches and more thick. Areas in the beds were omitted from the estimate because available data relative to the bed characteristics were insufficient for making an estimate conforming with the definitions of measured and indicated coal adopted for this study. Should future drilling or development prove reserves in these areas, such reserves should be added to the total estimated reserves deter-mined by this investigation.

Jan 1, 1956

By L. F. Willmott

The production operation of a Kerpely gas producer at Louisiana, Mo., is described. This unit, originally designed for airblown operation was modified to permit using oxygen in the blast in place of air. The first runs J for test purposes, were made in June 1950. After this, seven production runs were made and these are the subject of this report. Total gasification time was 245 days. In each run, Nut or Pea coke or mixtures of both at a rate varying from 1,700 to 2,300 pounds per hour was converted with oxygen and saturated steam to produce synthesis gas - primarily carbon monoxide and hydrogen -approximating a predetermined rate of 80,000 to 95,000 cu. ft. per hour and a predetermined hydrogen-carbon monoxide ratio, The requirements per 1,000 std. cu. ft. of (CO + H2) were 21.6 to 30 pounds of coke, 213 to 267 std. cu. ft. of oxygen, and 3L4 to 47.B pounds of steam.

Jan 1, 1955

By Raymond L. Lowrie

For many years it has been considered that an average of 50 percent of the coal in the deposits exploited has been recovered. Owing to many changes in mining methods during the past two decades, this study was initiated to obtain an up-to-date measurement of recovery percentage and thus establish part of the basis from which presently recoverable reserves may be estimated. Recovery percentages were determined within mined areas of 200 underground coal mines. These comprised a statistical sample selected to be representative of operating mines in relation to their significance to depletion of reserves. The results ranged from 29 to 91 percent and averaged 57.0 ± 1.7 percent (95-percent confidence limit). Six factors were identified mathematically as significantly affecting recovery percentages: (1) Pillaring system, (2) top rock and conditions, (3) bottom rock and conditions, (4) marketability, (5) coalbed thickness, and (6) productivity. Skill and attitude of mine operators toward recovery, although not measured, were probable factors. Five other variables that were tested did not show any significant relationship with recovery percentages. Also, five mining equipment features were identified, through discussions with mine officials, as affecting adversely recovery percentage at some mines.

Jan 1, 1968