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By B. S. Xakalashe

Keywords: Pyrometallurgy, silicon, solar cells Silicon has been the dominant material in the photovoltaic (PV) industry since its application in the space industry in 1958. This review focuses on crystalline silicon solar cells, primarily due to their dominance in the photovoltaic industry, omitting other photovoltaic cell technologies such as second generation (e.g. thin films) and third generation (e.g. nano-structured solar cells). The value chain for the production of crystalline silicon solar cells has been reviewed. The primary processing steps for the production of silicon solar cells from quartz are as follows: bulk production of metallurgical-grade silicon via carbothermic reduction in a submerged furnace, refining of metallurgical-grade silicon via the chemical means to polycrystalline silicon, or through the metallurgical route to solar-grade silicon, wafer manufacturing, and, lastly, silicon solar cell manufacturing. During downstream processing, solar cells are interconnected and encapsulated into solar modules (panels), which can be used individually or incorporated into a photovoltaic system for electricity generation and supply. The cost for crystalline silicon based solar cells is approaching one US dollar per watt peak ($1/Wp), while the most cost-effective solar modules in industry have reported costs below $1/Wp, and are based on CdTe thin films. Solar cell energy conversion efficiencies as high as 22% have been reported in industry for crystalline silicon solar cells.

Jan 1, 2011

By Walker G. S

A study of the crystalline materials on or near the surface of freshly made or "green" superphosphate granules and mature, "set" superphosphate granules was undertaken using X-ray diffraction, X-ray mapping, scanning electron microscopy and electron probe micro analysis techniques. Calcium sulphate (CaSO4), calcium sulphate hemihydrate (CaSO4 1/2H20), and mono calcium phosphate monohydrate (Ca(H2PO4)2H2O), were the only crystalline species present in the "green" superphosphate.In the set superphosphate however, additional compounds were present, namely complex iron and aluminium phosphates Ca(Fe,AI) H(HPO4hF2)2H2O, (Fe)3(H3O)H8 (PO4)6H2O and calcium sulphate dihydrate (CaSO4.2H2O).The complex phosphates tied up the major part of the Fe and Al in the system and were concentrated on or near the surface of the granule. An intimate mixture of CaSO4.2H2O, and CaSO4, along with the above mentioned complex Fe-AI compounds, crystallize close to the surface of the granule and cause the setting of superphosphate that takes place during storage.

Jan 1, 1980

By H. G. Hammon

Uranium miners have been shown to develop lung cancer in direct proportion to the time of exposure in the mine and the concentration of radioactivity (cumulative working level).1 Radon gas is continually evolved from the uranium ore, but because of its shoe half-life, 3.82 days, it is soon decomposed into particulate daughter products, which along with the dust in the mine, become deposited in the miners' lungs. At present, massive ventilation is the only effective method of reducing the radioactivity concentration in the mines. However, the Bureau of Mines is evaluating the possibility of using coatings on the mine wall that will have sufficiently low permeability to radon that the gas will decompose into the particulate daughter products before it can permeate the coating. Permanently trapped in the coating, the daughter products would be prevented from dispersing in the mine atmosphere. Lawrence Livermore Laboratory was asked to aid in this investigation. The direct determination of radon permeability is more difficult than that of the other noble gases because of the short half-life of the gas and radioactive contamination of the apparatus. We felt that it should be possible to estimate radon permeation coefficients from other noble gas permeation coefficients. It was noted that the log of the diffusion constants for helium, neon, argon, and krypton, as reported by Meares2,3 plotted to a straight line-against the square of-the gas molecularddia meter. The log of the permeation coefficients also plotted to a straight line against the square of the gas molecular diameter. Thus, by determining the permeation coefficients of such gases as argon and krypton through various films and coatings, it appeared likely that radon permeation coefficients could be estimated. In addition we felt it should be possible to find some relationship between polymer structure and he noble gas permeation coefficient that would aid in the selection of coatings materials as radon barriers.

Jan 1, 1975

By Victor F. Paterno

In December of 2007, a joint venture of J.F Shea, Skanska and Schiavone referred to as S-3II, was awarded a $1.15 billion (? 886,880,000) contract to construct the run-ning tunnels and station structures for the Number 7 Line Extension Project in New York City by the Metropolitan Transportation Authority Capital Construction (MTACC) and New York City Transit (NYCT). As part of the contract, a technically complex and critical connection of the new tunnel to the existing, operational 7 Line subway was required. This paper describes the innovative design approach that was conceived to carry out the underpinning and excavation works both within the east-west 7 Line subway tunnel and beneath the north-south, 4 track, 2 level Times Square Station for the A, C & E trains. This underpinning provided temporary support to the subway substructure as the grade of the tunnel invert was lowered up to 10 feet (3 meters) into the rock sub-grade to allow the future subway to pass under the basement of the world?s busiest bus terminal. In addition, the creation of a new portal connecting the existing subway tunnel and the subterranean level of the Port Authority Bus Terminal by means of underpinning structural footings and horizontal spiling/poling of existing ground will be discussed.

The mining industry is generally regarded as a high risk industry, mainly because of the difficulties in estimating the tonnage and grade of mineral resources, the fluctuations in metal prices, mining problems and other problems which occur with mining in offshore and remote locations, such as appropriation or disruption to supply. As a consequence, finance providers require a high reward from mining projects. In the past two decades, the development of "mega" projects has led to the packaging of the finance becoming more sophisticated. Some would see this move as a measure of the evolution of banking rather than an intrinsic facet of mining finance itself. Project financial managers now require a thorough knowledge of all the financial tools which are available and have to be aware of the funding options so that they can put together a finance package which minimises the cost of the financing with the risk spread adequately between the partners of the financing. The different sources and types of finance for mining projects are described herein along with the factors which determine their costs. To understand the ramifications of financing mining projects, it is essential to appreciate the fundamental difference between debt and equity, which illustrates the importance of gearing. Costs of finance are determined by the interaction of supply and demand forces. Bankers and other financiers have become more adept at isolating a wide selection of risk elements and have devised a formidable range of insurance mechanisms. There is still a lot of money looking for good project risks and if a good project is properly presented and structured, financing can be obtained in today's market.

Jan 1, 1990

By Peter Jackson

The dewatering of the large construction pits required for major infrastructure projects often has a significant impact on the environment. This is particularly so in urban areas and where groundwater resources are of interest. These environmental impacts are inter alia, groundwater lowering and the consequent effects such as settlement and deterioration of timber foundations, together with the impact of the dewatering on the groundwater quality. In order to minimise the environmental impact of the dewatering, the quantity of water to be abstracted and the amount of groundwater lowering in the surrounding area must be minimised. This paper describes the measures that have been taken on the Copenhagen metro project to achieve the objective of minimal environmental impact whilst still carrying out a major dewatering scheme.

Jan 1, 2000

By J. W. Town

The Bureau of Mines determined the physical properties of southeastern Idaho phosphate fines as related to mineral composition, particle size and liberation, beneficiation, and potential use in structural clay products. The phosphate mineral in the fines was identified by unit-cell dimensions to be essentially the same as the phosphate mineral fluorapatite identified in the coarser sizes. The mean particle frequency as determined by electron-microscopy and pipet-analyses was between 0.5 and 0.2 micron. Liberation of the phosphate could not be definitely determined because of the weathered condition of the minerals and their extreme fineness. No beneficiation scheme was developed that would concentrate the phosphate into a marketable fertilizer product; therefore, forming and firing tests were made to demonstrate that the fines can be used to manufacture structural clay products.

Jan 1, 1968

By I. W. Farmer

High horizontal stresses and high horizontal to vertical in-situ principal stress ratios in the plane of underground drifts and entries can damage weakly laminated roof rocks quite severely. Such stresses are difficult to measure accurately, as illustrated by case histories of in-situ stress measurement at Wistow and Lea Hall mines, in the UK. Their direction and relative magnitude can, however, be estimated from the absolute velocity vectors of continental plates. With the preliminary results from the World Stress Map project now available it is possible to indicate mining areas where regional horizontal stresses are low, such as Europe, and high, such as Australia and Asia

Jun 19, 1905

By Raymond J. Castelli

The paper provides a general overview of the numerous types of earth retaining systems currently available, and organizes these various systems by several classification methods. These classifications can be used as a guide in identifying the appropriate type wall or walls for any specific project application. As a further aid in sorting through the numerous wall alternatives for a specific design or construction project application, the paper suggests a systematic approach for wall selection, and presents helpful charts summarizing the general advantages and disadvantages, and typical limitations for the currently available wall systems.

Jan 1, 2003

By Beatriz Luberiaga Bezerra, André Ben-Hur da Silva Figueiredo, Leticia dos Santos Aguilera, Ana Carolina Accioly Monteiro, Thainá Lucciola Hipolito de Lima, Barbara da Costa Araujo, Ana Luiza Buse da Silva

Cerâmicas porosas foram produzidas com nanopartículas de ferrita de manganês através da técnica de freeze casting, sendo possível obter poros direcionados. Foram produzidas duas amostras dessas cerâmicas tendo como ligante-dispersante o PEG-4000 e PEG-8000, ambos em 8%p. Por MEV foi possível observar as estruturas porosas das cerâmicas. O método de Arquimedes foi utilizado para obter as medidas de porosidade e densidade aparentes e de densificação. A ferrita pura e as amostras sinterizadas foram caracterizadas por DRX e foi identificada apenas a presença da fase ferrita, para as amostras antes da sinterização e transformação de fase da ferrita para óxidos de Mn e Fe após tratamento térmico. Tais resultados possibilitam indicar a aplicação dessas cerâmicas como elementos filtrantes.

Mar 1, 2019

The timber township of Powelltown, Victoria lies N.E. of Yarra Junction, 60 miles east of Melbourne and in the site of the mill of the Victorian Hardwood Company Proprietary Ltd.A lift gauge railway owned by the company connects Yarra Junction on the Warburton line, with the township through two or three smaller mill centres on the way.The company has been operating for some 12 years. In the divide, about four miles from Powelltown, between the Little Yarra and Latrobe rivers, cutting was continued with material being handled by winch and double incline haulage over the divide. A small bush locomotive dealt with the traffic between the divide and the cutting site.In order to reduce costs, which were heavy at the haulage, the company decided to make a continuous railway from Powelltown to the bush by means of a tunnel through the divide.Hand bore holes were put down on the proposed line of tunnel and showed that the divide at this point consisted of decomposed depth of about 100 ft. towards the eastern or Latrobe side - and that the undecomposed granite summit lay to the west of the surface summit.The bores also served to locate the underground water line, this was afterwards found to rise and fall with wet and weather.To avoid tunnelling in hard and heavy water, the grading of the was laid out with the summit of the hard granite the point in the line.

Jan 1, 1925

By H. C. Fowler

Hydrogen sulphide associated with the gasps and vapors from certain crude oils now produced in the United States has forced a serious health and safety problem upon the petroleum industry. Although the presence of hydrogen sulphide in or occurring with Mexican crudes has been known for some time, it was not until recently that crude oils which give off poisonous amounts of hydrogen sulphide have been produced to any extent in the United State. The injurious effects of this poisonous gas were first recognized by the refiners along; the Atlantic and Gulf Coasts upon receiving shipments of crude petroleum from Mexico. The problem of combating the hazards of the gases and vapors given off by this petroleum become more important as the use of Mexican crude increased. In 1925, the Bureau of Mines and Public Health Service under cooperative agreement with the American Petroleum Institute, studied the causes rend effects of hydrogen sulphide poisoning. Bureau of Mines Bulletin 2312 is report of this investigation, and although written with special reference to refineries, it nevertheless contains much information that is of value to the producer of petroleum.

Jan 1, 1927

By M Saghaeian, A H. Baladastian, A Dehghani Ahmadabadi, V Sheikhzadeh, R Hejazi

This research was done to reduce silica from mixed hematite concentrate of Barfkar Iron Ore Sample and increase Fe grade using reverse flotation method (Depressing Hematite and floating Silica). The used sample in the reverse flotation tests was a mixture containing two types of hematite concentrates (Spiral cleaner concentrate and Slon-VPHGMS cleaner concentrate) with the percentage of 16 per cent and 84 per cent, respectively. Fe grade of two samples was 59.31 per cent and 57.52 per cent and SiO2 grade was 5.83 per cent and 6.71 per cent, respectively. After mixing, the Fe and SiO2 grade of the mixed sample was measured at 58.10 per cent and 6.20 per cent. For flotation tests, effect of variable operational parameters including feed size distribution (d80 = 130 microns and d80 = 53 microns), pulp solidity (25 per cent and 30 per cent w/w), pH (9.70, 10.20 and 11), Sodium silicate as a dispersant (500, 1000 and 2000 g/ton), Starch as a depressant (500, 1000, 2000 and 3000 g/ton) and EDA as a collector (180, 300, 400 and 500 g/ton) were investigated. For evaluating the influence of Sodium silicate and Starch dosage, initial flotation tests were performed on the main sample (d80 = 130 microns). These two parameters had no significant effects on the yield, Fe, and SiO2 grade of flotation concentrate based on test results. In the next step, screen analysis was carried out on the main sample for mineralogical studies. Accordingly, the suitable size distribution for releasing Fe and SiO2 particles was smaller than 53 microns. Therefore, the sample was crushed until d80 = 53 microns. Then, supplementary tests were performed on the crushed sample for studying the pH range, pulp solidity, and EDA collector dosage. After doing silica removal flotation tests based on the designed pattern and comparison of the results, the conditions consisting of size distribution d80 = 53 microns, pulp solidity 25 per cent, pH 10.20, Sodium silicate 1000 g/ton, Starch 1000 g/ton, and EDA 500 g/ton was selected as optimum values. In the last test, Fe and SiO2 grade was measured at 60.00 per cent and 3.93 per cent, respectively, and Fe recovery was obtained at 74.93 per cent.

Aug 24, 2022

By D. Harrington

Seldom, if ever, has any mining hazard presented itself that some method has not been devised to control it to some extent; the degree of success of such control depends largely upon the intensity of desire to prevent suffering, injury, and death. The economic saving to be realized and the more definitely this is realized by all concerned, the more quickly and effectively will the hazards be handled is an important incentive to prevention of accidents. Preventing coal-mine explosions is by no means a complex problem; all that is necessary is sensible, conscientious, sustained effort. The fact that explosions can be prevented has been well-demonstrated by the record of the post few years; the average annual death toll from explosions for the 5 years 1906-1910 was 438, and for the 20 years prior to 1929 it was 265: during the past 4 years an average of only 32 deaths per year resulted from this cause, although the annual production during that time varied but slightly from that of 1906-10. This is a truly remarkable reduction, and if other types of mine accidents had been reduced in the same ratio only about 300 would be killed annually in our mines instead of the nearly '1,300 killed in 1936 and the approximately 2,000 killed annually for many years. Although frequency of occurrence of explosions has not lessened greatly during the last decade, their severity decreased markedly, which would indicate that effective means are being taken to prevent the spread of explosions, even though ignitions and their causes are not being handled nearly as effectively as they might or should be handled. Several large coal-producing States, which in the past have experienced numerous disastrous explosions, have been free from such disasters for continuous periods as long as 8 years in the relatively recent past. The application of rock dust to underground surfaces has been an important factor in preventing widespread explosions; some of the mast dangerous mines have been rock-dusted fairly adequately, and this has been amply repaid in the reduced severity of explosions, as heretofore indicated; however, many have applied rock dust apparently without giving much consideration to the amount required to prevent

Jan 1, 1938

ABSTRACTRock stresses can be modified by physicochemical processes.If rock pores allow the ingress of water and oxygen, but are not large enough to permit the exit of larger molecules of weathering products, anomalous rock pressures develop. Rock masses may also be subjected to osmotic pressures developed as water diffuses into pores and joints filled with saline water. Anomalous rock pressures may also develop as gels filling pores undergo syneresis and as salts crystallize from pore solutions.

Jan 1, 1968

A drive, 3,500 ft long, was planned to explore mineralization exposed by diamond drilling. A rate of advance of 150 ft per fortnight, approximately double previous Broken Hill rates, was required. Subsequent to the completion of this drive its extension for a further 6,200 ft was planned to provide a main haulage way along which ore could be transported from a newly acquired lease back to the main hoisting shaft, a total distance of 13,500 ft.This paper describes the working conditions, relationships, manning and costs, and gives details of the cycle and equipment used to achieve rates up to 170 ft per fortnight.OBJECTIVEDiamond drilling from the 1,000 ft level at the Delprat Shaft section had indicated that the zone of mineralization, about 150 ft wide, which had been explored on the 1,000 ft level for a length of 2,600 ft, continued downwards with a westerly dip. The drilling results showed that within this wide zone there were arrower lenses of mineralization of possibly payable grade (see composite plan, Fig. 1).Diamond drill holes of 2,000 ft and over, particularly through heavily sheared areas of sericite schist, had been found to be costly, slow, and inadequate in testing the potential and trends of these smaller concentrations of mineralization.It was therefore decided that an exploratory drive should be advanced from the northern limit of the 1,480 ft level into the western mineralization, and that from this drive diamond drill holes should be drilled at dose intervals to outline the ore.The 1,480 ft level was chosen for the following reasons.1. It had the greatest northerly reach of the accessible levels at No. 7 Shaft section below the 1,000 ft horizon and therefore would enable the test to be made most quickly.

Jan 1, 1965

By John V. Beall

BROMO Seltzer blue has gone to war. The blue of the Bromo Seltzer bottle is a product of cobalt, the Nation's No. 1 strategic metal. When the National Production Authority, on Nov. 21, 1950, ordered a 70 pct cutback in domestic use of cobalt, a stab of pain was felt in the hearts of the glass, porcelain enamel, steel, paint, pottery, and electrical and electronic equipment industries. The reason: A full-scale wartime economy with astronomical requirements for jet engines, high velocity projectiles, armor plate, electronic equipment, and the many products needed to win a war. There is little potential comfort for cobalt users in nonessential manufacturing, and the military will be pinched for optimum supplies of the metal. However, if proper measures are taken immediately and current plans are completed, in two years there will be far more cobalt available than ever before. When normal times return, cobalt supplies should be sufficient to meet peacetime military requirements, and greatly expanded domestic requirements that will result from new technological development for wartime but adaptable to peacetime products. The pres-

Jan 1, 1951

By Richard Rittenhouse

This program was to develop a new base line system for automated continuous room and pillar type mining. The primary requirement estab¬lished for this machine is that the machine be capable of mining and bolting simultaneously. Additionally, this machine was to provide temporary and permanent roof control, have a productive - full - face semi-automatic mining system, leave a clean entry outby the machine, provide maximum operator protection, provide effective dust suppression and provide air scrubbing to restrict respirable dust to permissible levels. The machine has effectively demonstrated the ability to mine and bolt simultaneously. Additional above ground operation, testing, and time studies are recommended to further verify the machines abilities. Design improvements are recommended for future generation AES machines. These relate to marginal design areas such as side loading on vent duct lift cylinders, etc., that will not impair additional testing of the existing machine.

Jan 1, 1983

By W. L. Garrison

Improvements continue to be made in rapid excavation and tunneling technology. There are several ways to examine the impacts of such improvements. The most common procedure is to monitor current developments and to evaluate prospects for expansion of present types of uses. Other approaches are called for, however, if the technology might be used in ways not now imagined, if the search is for information for managers of technology development, and if the issue is that of the wise use of the technology by society. The first section of the paper will pose these matters as questions. These questions will be examined from the point of view of the processes of technology development and utilization, and then further examined against the backdrop of processes at work within the urban area. Such an examination will provide insight into the way technology developments should proceed. The final section will present some comments that may be useful to those guiding the development of the technology and to those who might provide leadership for its wise utilization. THE QUESTIONS Three questions are posed: 1. Are there uses for the technology beyond further penetrations of its present markets? 2. Can information be supplied to managers of technology development so that they may improve the assignment of priorities among development choices? 3. How can society make wiser use of the technology?

Jan 1, 1974

By Simón D. Strauss

El presente estudio revisa la evolución de la producción de los principales minerales (plomo, cobre y plata) en Estados Unidos desde la década del 70, asi como su repercusión en Chile, Perú y algunos países latinoamericanos. En esta perspectiva, se pronostican algunos datos sobre los cambios políticos, sociales y económicos que ocurrirán dentro de los próximos 28 años y que afectarán la demanda de productos minerales y la capacidad para producirlos.

Nov 20, 1972