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By H. Zhong, S. Wang, Q. Sun

The flotation performance of 2-(benzylthio)-acetohydroxamic acid (BTHA) to diaspore was first evaluated by micro-flotation tests. The adsorption mechanism was further investigated through adsorption experiments, molecular dynamics simulation, zeta potential and X-ray photoelectron spectroscopy (XPS). The results demonstrated that BTHA had a stronger ability to collect diaspore in comparison with another diaspore collector, benzohydroxamic acid (BHA), especially under the condition of weak alkalinity, the flotation recovery can reach 90%. The more negative interaction energy (ΔE) between BTHA and diaspore from molecular dynamics simulation results revealed that BTHA had an easier adsorption ablity onto diaspore than BHA, which matched with adsorption results. The zeta potential and XPS revealed that Al atoms might bond with -C(=O)NHOH by formation of Al-O bonds. Keywords: Diaspore, flotation; adsorption; 2-(benzylthio)-acetohydroxamic acid

Jan 1, 2020

By T. Szendrei, S. Tose

The generally accepted view in rock blasting is that the sources of energy for the fracture and movement of rock reside in the shock wave and gas action resulting from the explosion, and yet the mechanisms by which these sources interact with the rock have remained unclarified. It has also been noted that up to 50% of the work capacity of an explosive released in a blast cannot be accounted for by field measurements of energy partitioning. In this study, we describe a physical model that details the response of rock to both shock wave and gas action. An analytical model based on momentum conservation is derived to describe the dynamics of shock-driven expansion of the blasthole. Radial expansion of the hole is the key parameter that permits the derivation of the following characteristics of rock response to shock loads: hole expansion time; volume of displaced rock; energy consumed per unit volume; expansion energy efficiency; stress wave pulse length; gas pressure in enlarged hole. Soon after the completion of hole expansion, the shock wave degenerates to an elastic stress wave that runs through the burden. Blasthole expansions of between 50% and 300% of diameter are completed in under 1 ms and, depending on rock properties, consume 32% to 42% of the detonation energy or about 55% of the available mechanical (Gurney) energy. Gas pressure in the enlarged holes in five rock types is between 35 MPa and 650 MPa, and drives the mass movement of burden rock.

Oct 9, 2024

By R. D. Alorro, B. Tadesse, E. Aghaei

Cinnabar (HgS) and native mercury (Hg) are the most common naturally occurring forms of mercury found in most gold ores subsequently released into the environment during processing. Mercury and its compounds are extremely toxic and recognised as serious health and environmental hazards. This research investigates the possibility of mercury (Hg) removal from waste solutions from gold processing using iron-aluminium (Fe-Al) bimetallic particles. The synthesis of Fe-Al bimetallic particles using zero-valent aluminium and ferric chloride as precursors were performed following the optimisation of influencing factors. The presence of both metals in the prepared bimetals was confirmed by XRD analysis. The experiments for mercury removal by bimetals were designed using the central composite design and Minitab software based on two variables including contact time and adsorbent dosage. The best result of Hg(II) removal (>90%) was achieved using 4 g/L bimetals and contact time of 75 min. However, the statistical analysis of results indicated that these parameters have only a minor contribution to the removal of Hg(II) by Fe-Al bimetals. Higher bimetal dosage and contact time resulted in a higher Fe dissolution from the Al surface which can be attributed to the presence of nitrate (# $) ions in the solution. However, adding 0.1 M NaCl to the Hg solution had a positive impact on Hg removal by improving the conductivity and electron transfer within the solution. The Fe-Al bimetallic particles are promising substances for further testing of Hg removal from gold processing waste solutions with different conditions and constituents. Keywords: Mercury removal, gold processing, Fe-Al bimetals, optimisation

Jan 1, 2020

By J. E. Xu, J. Y. Zhang, M. Q. Sheng, K. Wan

"SynopsisThe densities of selected CaO-Al2O3-MgO slag systems were measured at 1823K by the Archimedean method. Thirteen different slag compositions were chosen based on different levels of the MgO content and the mass ratio of CaO/Al2O3. The results indicated that the density of the slag decreases with increasing MgO content (from 0–3.78 mass%), but increases with further increases in MgO content up to 11.33 mass%. At a fixed MgO content of 5.5%, the trend of density change with CaO/Al2O3 in the slag is similar to that for changes in MgO content. On the basis of the regular solution approximation rules of excess molar quantities, an attempt was made to estimate the molar volume of the slags investigated. The application of the molar volume model confirmed that the present expanded approximation rules are applicable to predict the molar volumes of the melts discussed.IntroductionDensity is one of the most important fundamental properties of slags, which influences metallurgicaly phenomena in many ways. Density is sensitive to the nature of the chemical bonds and the species in the melt, and is of great importance not only for theoretical research on the structural properties of molten slags, but also for industrial applications. Density is also required to estimate other key properties used to assess the behaviour of high-temperature molten oxides, e.g. viscosity, surface tension, and thermal conductivity.Liquid calcium aluminate slags that contain magnesia are the basis of most ladle slags for secondary refining processes. The CaO-Al2O3 binary phase diagram (Hallstedt , 1990) shows the eutectic composition (50 wt% CaO and wt% Al2O3) has the lowest melting temperature. The main emphasis of this study is on the 12CaO·7Al2O3 refining slag with MgO additions. The CaO-Al2O3-MgO ternary system is of considerable importance in industrial metallurgical processes, and is fundamental to the understanding of metallurgical slags, ceramic materials, and geological phenomena."

Jan 1, 2015

By J. Witley

"Narrow tabular platinum group element deposits in the Bushveld Complex of South Africa are typically evaluated by diamond core drilling from surface. Several short deflections are drilled from each mother hole in order to obtain multiple intersections at a close spacing (less than 1 m). Examination of the intersections from deflection drilling revealed the importance of these deflections in understanding the representivity of the borehole, obtaining an estimate of the nugget effect, and mitigating the undesirable effect of the high grade variability at the ultra-short range that is a characteristic of these deposits. The use of deflections in estimation was investigated by means of a number of techniques and scenarios in order to find the most appropriate way to use them in an estimate. A significantly improved level of confidence was gained from using multiple close-spaced intersections rather than a single borehole intersection. IntroductionThe Upper Group 2 chromitite layer (UG2 or UG2 Reef) is known for its remarkable geological continuity, being traced almost uninterrupted for tens of kilometres. However, what is often less well emphasized is the high variability in platinum group element (PGE) grade and thickness (and therefore PGE content) and internal reef stratigraphy over very short distances (several metres or even tens of centimetres).This paper examines the application of short drill-hole deflections in evaluating UG2 PGE mineral resources at Marikana in the western Bushveld Complex of South Africa."

Jan 1, 2017

By J. Pelders, G. Nelson

"Fatigue is a significant concern in the mining industry as it is a causal or contributing factor in many incidents and accidents. Fatigue can be caused by work- and non-work-related factors. There is a lack of information about associations between demographic and other non-work factors, and fatigue. This study aimed to assess associations between demographic, work, living, and socioeconomic conditions, and lifestyle characteristics, and fatigue at a platinum smelter in South Africa. Eight interviews with management and two focus groups with production workers were conducted, and 75 questionnaires were completed by production and other workers. Both work- and non-work-related factors were considered to be causes of fatigue. These factors included overtime, shift work, high workloads, activities performed outside of work, age, race, housing tenure, diet, sleep disorders, stress, and job satisfaction. In general, higher levels of fatigue were reported by younger participants, those who rented accommodation, ate less healthily, had a sleep disorder, and those with high levels of stress and low job satisfaction. As various demographic, lifestyle, and wellness-related factors were associated with fatigue, both work and non-work contributors should be addressed in fatigue management plans. BackgroundFatigue may be defined as ‘a state of impaired mental and/or physical performance and lowered alertness arising as a result of, or a combination of, hard physical and mental work, health and psychosocial factors or inadequate restorative sleep’ (BHP Billiton, 2005). Williamson et al. (2011) define fatigue as a biological drive for recuperative rest. Sleepiness and fatigue are related, and the terms are often used interchangeably. However, sleepiness, more specifically, can be defined as sleep propensity, or a person’s tendency to fall asleep (Hossain et al., 2003; Shen, Barbera, and Shapiro, 2006).Increasing levels of fatigue and sleepiness are associated with lapses in attention, errors, response slowing, fluctuations in alertness and effort, and impaired attention, working memory, long-term memory, decision-making, and creativity (Alhola and Polo-Kantola, 2007; van Dongen and Dinges, 2000). Fatigue is also associated with adverse effects on mood and impulsive behaviours (Alhola and Polo- Kantola, 2007; Minkel et al., 2011; Schwarz et al., 2013). It is a significant concern in the mining industry as it is commonly identified as a causal or contributing factor in many accidents and injuries (Schutte, 2009). Fatigue can also lead to long-term health problems, including digestive problems, heart disease, stress, and mental illness (Shaw, 2003)."

Mar 1, 2019

By D. V. J. W. Groenewald, T. M. Louw, L. Auret, S. M. Bradshaw, A. V. Cherkaev

Unexpected equipment failures lead to financial losses due to production disruption. Time-based maintenance, based on checks over regular time periods, has been employed to minimise disruption. However, the improvements it can offer are limited as it may lead to unnecessary service of healthy equipment or missed failures occurring between service intervals. Condition-based maintenance (CBM) provides a further improvement to equipment reliability by detecting faults and predicting remaining useful life (RUL) based on equipment health monitoring. Its application in the mineral processing industry is hindered due to the high cost of health monitoring equipment. In this study, two stochastic process models, the adaptive auto-regressive model and the gamma process, are compared in their ability to forecast the degradation state and to provide RUL prediction. The gamma process model was found to be effective in both tasks. Due to its simplicity and minimum hyperparameters requirements, it is proposed to use the gamma process as a baseline for comparison with other models. Keywords: Condition-based maintenance, remaining useful life, slurry pump, adaptive autoregressive mode, gamma process

Jan 1, 2020

By J. Petersen, H. Naderi, H. Zare, M. H. Nikzad, M. Karimi

In the copper electrorefining process, the dissolution of anodes is significantly reduced or even stopped when the passivation phenomenon occurs. The results of this phenomenon are increasing energy consumption, residual formatting, and voltage levels in the cell. In this study, the electrochemical behaviour of blister copper in the presence of sodium persulfate (PDS) was studied. The electrochemical methods of LPR, Tafel, and Electrochemical Impedance Spectroscopy (EIS) were used. The results showed that the addition of sodium persulfate activates the electrode surface and increases the open circuit potential. In the presence of PDS, the polarisation resistance of the electrode shows an increasing or decreasing tendency, based on the PDS concentration. This tendency is probably due to the formation of surface layers (such as slime layer or copper sulfate) and dissolution of this layer at various concentrations of PDS. The lowest polarisation resistance of 1.8 ohms and the highest corrosion current of 60.6×10-3 and 36.6×10-3 A/cm2 from LPR and Tafel techniques respectively were obtained at the concentration of 40 g/l PDS. Based on the results of potentiodynamic and electrochemical impedance spectroscopy tests, the addition of sodium persulfate to the solution reduces the corrosion resistance, therefore the passivation time of the blister copper anode increases. Keywords: Blister copper, electrorefining, sodium persulfate, anodic passivation

Jan 1, 2020

By E. D. Musin, S. S. Gudkov, A. V. Epiforov, S. V. Balikov

The standard technology for processing of gold-bearing sulfide raw material has many problems associated with the use of cyanide as a gold lixiviant. Therefore, many tests to find alternative gold recovery methods are being undertaken. This paper describes some technological solutions, which can become alternatives to cyanide technology in the future. Pressure oxidation (POX) of refractory gold-bearing sulfide concentrates from five different Russian gold deposits were investigated. Concentrate 1 was gold-copper concentrate. Concentrate 2 was gold-pyrite concentrate. Concentrates 3-5 were pyrite-arsenopyrite double refractory concentrates. The POX tests were at temperatures of 110, 200 and 220 °C and oxygen pressures of 1.5, 2.4 and 3.0 MPa were carried out. Gold lixiviants, such as chloride, thiosulfate, sulfite and thiocyanate were tested. The recovery of gold from sulfide gold-bearing concentrates by non-cyanide methods was 97- 99%, and from double refractory concentrates, 86-93%. The tested reagents are less toxic than cyanide, and their use will reduce of the cost of gold production. These methods make it possible to recover gold in acidic media, and eliminate the washing operation and POX slurry neutralisation. In addition, precious metals recovery from POX cakes using lead reduction smelting was investigated. It was shown that the “POX-pyrometallurgical” technology for double refractory concentrates processing could be used with recoveries of gold and silver of 97 and 96%, respectively. Keywords: Recovery of gold, refractory sulfide gold-bearing concentrates, double refractory concentrates, pressure oxidation, non-cyanide lixiviants of gold, chloride autoclave leaching, thiosulfate leaching, thiocyanate leaching, sulfite leaching, reduction smelting, POX-pyrometallurgical technology

Jan 1, 2020

At the Annual General Meeting of the Chamber of Mines of South Africa, held in Johannesburg on 29th June, 1982, the following leading members of the mining industry were elected to office for the 1982-1983 term: Mr W. W. Malan President Mr C. T. Fenton Vice-President Mr G. Y. Nisbet Vice President William Wouter Malan was born in Springs on 7th November, 1928, and was educated at the Springs High School and the University of the Witwatersrand, where he obtained a B.8c degree in mining engineering. Diamond Mines. Mr Nisbet became a consulting engineer of the Anglo American Corporation in 1972, and a deputy managing director of the Gold Division in 1974. George Young Kisbet was born in Benoni in 1923 and was educated at Pretoria Boys High and the University of the Witwatersrand. Mintek reports Report 2010D A process for the recovery of rare-earth oxides from monazite. (First published 16th March, 1979). Report 2073D A preliminary investigation of the concentration process at Ucar Minerals Corporation. (First published 19th September, 1980). Report 2092D The recovery of pyrite from gold ore by gravity separation. (First published 28th November, 1980). Report M13 Factors affecting the production of fines during the screening and handling of highcarbon ferromanganese.

Jan 1, 1982

By Turgay Gurun

"Digital simulation can be used as an analytical tool to optimize the design of crushing plants without need for large-scale experimental programs.General mathematical description of a crushing operation permits the simulation of a crushing plant flowsheet under various operating conditions. The process model encompasses multistage open- and closed-circuit crushing of hard and soft rock. Crushing balances are analyzed in the light of crusher and screen performance and a comparison of different closed-circuit arrangements is made in terms of process and layout criteria.The simulation model allows comparison of process alternatives to be made in terms of equipment selection and capital and operating cost estimation. It thus provides the pertinent practical information to maximize plant efficiency, and to minimize expenditures in such items as equipment, structures, power consumption, and so on."

Jan 1, 2014

This paper examines the new water-hydraulic (hydropowered) drill rigs that have been developed and proven in the last decade primarily in tabular, shallow-dipping, narrow-reef hard-rock South African mines. These include drill rigs for flat-end tunnel development, narrow inclined raises and winzes, large inclines and declines and longhole-based developments such as ore passes and vent raises. The hydropower technology rigs offer advantages both in safety and performance over traditional compressed-air-powered, hand-held development, and are generally more cost-effective than imported oil electro-hydraulic drill rigs. Furthermore, hydropowered rigs are inherently energy-efficient. The benefits of hydropower are discussed and a ?comprehensive development model? is presented which demonstrates that ore-bodies can be accessed in significantly shorter times. ?Localized? half level hydropower systems are introduced and a range of ancillary equipment available is listed.

Jan 1, 2012

By L. A. Cisternas, R. I. Jeldres, D. Calisaya

"Flotation of copper-molybdenum sulphide ores in seawater entails critical challenges such as selective recovery of molybdenite, effective pyrite depression, and reducing the lime addition required to reach highly alkaline conditions. It is essential that laboratory flotation tests aimed at solving these problems give reliable, reproducible results and indicate the correct approach for industrial operations. Rougher flotation of coppermolybdenum sulphide ores in seawater was investigated using two different cells: a modified Denver cell and a standard commercial cell. The effect of an organic reagent on the flotation performance was tested, and the fast/slow-floating model was used to describe the results. The modified Denver cell significantly improved the reproducibility of the flotation test results, due to technological enhancements such as the impeller being driven from below without a stator, which enables the whole froth surface to be scraped with a paddle at a constant depth and rate. Organic reagents are a promising alternative to inorganic reagents for depressing pyrite in seawater. However, further studies should be conducted to investigate their impact on molybdenite recovery, as well as to evaluate the possibility of depressing pyrite after molybdenite separation. The fast/slow-floating model was found to be appropriate for describing the flotation kinetics of the copper-molybdenum ores. The parameters are useful for comparing the performance at different conditions. IntroductionOwing to the increasing scarcity of fresh water, the use of seawater mining and mineral processing is becoming increasingly important (Cisternas and Moreno, 2014). Seawater can be desalinated by reverse osmosis, but this involves considerable costs, limiting it to the big mining companies (Akgul et al., 2008; Leidner et al., 2012; Ghaffour, Missimer, and Amy, 2013). Furthermore, desalination has environmental consequences (Lee, Arnot, and Mattia, 2011); for example, a desalination plant designed to process 2.5 m3/s requires an electrical energy supply of around 30 MJ/s. To supply this power demand, a thermoelectric plant burning bituminous/sub-bituminous coal mixtures at a thermal power generation efficiency of 35% might release around 1200– 1500 t of CO2 per day. Furthermore, the effluents from desalination plants are typically discharged into the sea, and their high temperature and ionic content inevitably modifies the marine environment, with unknown consequences. The direct use of seawater is, therefore, more attractive, but it also poses major challenges since seawater contains ions that adversely affect mineral recoveries. In particular, in the flotation of sulphide ores in seawater, the floatability of molybdenite is depressed (Castro, 2012; Laskowski, Castro, and Ramos, 2014)."

Jan 1, 2017

By B. Friedrich, A. Birich

Gold has been a metal of special importance for mankind for several thousand years. Its outstanding chemical resistance is an important property of this noble metal, but becomes a disadvantage when it comes to gold recovery. The established processes are based on highly aggressive and toxic reagents. Different alternative leaching reagents with a significantly lower toxicity proved to be promising alternatives in the last decades. Major research activities in this field focused on gold ores, so that leaching of secondary resources were not described sufficiently. Based on literature research and extensive experimental investigations, a reagent assessment was conducted for hydrometallurgical gold recovery from electronic waste. It was found that besides thiourea and halides, thiosulfate in particular represents an alternative of major relevance. A variety of different electronic waste (e-waste) specimens were investigated to identify suitable leaching conditions. As a result, an almost complete and selective gold recovery in less than 48 hours from different electronic waste types and components was achieved by thiosulfate leaching. Within the experiments conducted, it was found that the leaching behaviour of cyanide alternative lixiviants differ strongly from leaching of primary ores. Keywords: Gold leaching, cyanide alternative, thiosulfate, electronic waste

Jan 1, 2020

By A. F. Silva, J. M. G. Sotomayor, V. F. N. Torres

Geotechnical monitoring plays an important role in the detection of operational safety issues in the slopes of open pits. Currently, monitoring companies offer several solutions involving robust technologies that boast highly reliable data and the ability to control risky conditions. The monitoring data must be processed and analysed so as to allow the results to be used for several purposes, thereby providing information that can be used to manage operational actions and optimize mining plans or engineering projects. In this work we analysed monitoring data (pore pressure and displacement) and its correlation with the tension and displacement of the mass of an established failure slope calculated using the finite element method. To optimize the back-analysis, a Python language routine was developed using input data (point coordinates, parameter matrix, and critical section) to use software with the rock mass parameters (cohesion, friction angle, Young’s modulus, and Poisson’s ratio). For the back-analysis, the Mohr-Coulomb criterion was applied with the shear strength reduction technique to obtain the strength reduction factor. The results were consistent with both the measured displacements and the maximum deformation contours, revealing the possible failure mechanism, allowing the strength parameters to be calibrated according to the slope failure conditions, and providing information about the contribution of each variable (parameter) to the slope failure in the study area.

Oct 1, 2021

By D. H. Diering

Definition of mineral resources and reserves forms the basis for effective mine planning and reliable public reporting of mineral assets. Historically the mineral resource and reserves declaration process has been the domain of the geology and surveying disciplines, with the declaration of the reserves by the surveyor being based on the application of modifying factors to the declared resources available for mining. As part of an ongoing process to improve efficiency, reliability, and reproducibility of results, this approach has been revised and enhanced through the introduction of a revised process and reconciliation tools. The revised approach to reserve definition is based on the definition of scheduled resources, at an appropriate confidence estimate in the context of an approved business plan, over the anticipated life of the mineral asset being applied to define reserves. This planning and scheduling is developed, during the annual business planning process, by the mine planning department using tools such as CADSMine?. The scheduled area together with the application of revised modifying factors is tabulated in the BME (basic mine equation) and reflects the mine production plan over time. Simplification of the modifying factors to dilution and losses underpins the simple yet robust approach to improved definition of reserves in this process and in the basic resource to reserve equation (BR2RE). Dilution intrinsically affects grade but not metal content, whereas the losses reflect both the efficiency of mining and planning and are reflected in metal losses, area losses, or both. Reconciliation of the derived ?resource converted to reserve? area, (which is based on the business plan from CADSMine?), versus the ?resource available for mining?, (which is derived from Datamine?), underpins the robustness and auditability of the reserves declaration. This R&R accounting and reconciliation approach is transparent and facilitates interrogation of the logic and rationale of long-term business planning and project strategy. These numbers are processed and reported in the logic of the basic resource equation (BRE), which also addresses aspects such as white areas (future and historic), tail management, and partial extraction (non-scheduled pillars, etc.) in compliance with SAMREC definitions. Areas that do not have the necessary confidence and data support to be declared as resources find their space as pre-resource (outside the domain of public reporting), outlining existing potential for future extraction and reporting. Use of the BRE leads ultimately to a complete, refined accounting and reconciliation-oriented approach for all production entities. The revised resource and reserve process includes the discipline of mine planning as intrinsic to the definition and declaration of resources and reserves. Subsequent to the change in process, the resources and reserves have truly become the domain of the mineral resource management discipline. This paper defines the logic of the basic resource equations and outlines their application in the definition and reconciliation of mineral resources and reserves at Anglo American Platinum Limited.

Jan 1, 2012

1. Books from Elsevier The folowing are available from Elsevier Applied Science, Crown House, Linton Road, Barking, Essex IGl 8JO, OK. . Driling wastes, edited by F.R. Engelhardt, J.P. Ray, and A.H. Gilam. 1989. 872 pp. £95. Geothermal resources, by R. Bowen. 2nd ed. 1989. 468 pp. £60. The fate and efects of oil in freshwater, edited by J. Green and M.W. Tret. 1989. 340 pp. £42. Mining and the freshwater environment, by Martyn Kely (with contributions by W.J. Alison, A.R. Garman, and C.J. Symon). 1988. 228 pp. £32. 2. Books produced by Metal Buletin The folowing are available from Metal Buletin PLC, Park House, Park Terace, Worcester Park, Surey KT47HY, England. Prices and data 1990. £41 (airmail). Foundry directory and register of forges 1989-1990. £52 (airmail). 2. Canadian Publications The folowing two publications are available from the Canadian Government Publishing Centre, Supply and Services Canada, Otawa, Canada KIA 059. Mining and mineral processing operations in Canada. Mineral Buletin MR 224. $23.70. Canadian minerals yearbook 1989. Review and outlook. Mineral Report 38. $47.95. Technology developments The Mintek Pyrosim Simulator Pyrosim is a computer program for the steady-state simulation of pyrometalurgical processes?.

Jan 1, 1990

By J. A. L. Napier

It has been established that significant time-dependent stope convergence may occur over time periods of hours and days in certain hard-rock gold and platinum mines. The source of this time-dependent behaviour appears to be associated with both pre-existing discontinuities and with mining-induced fractures that form near the stope face. These induced fractures may be associated with blasting processes and may also be formed in response to high stress concentrations in the unmined regions immediately ahead of the stope face. In shallower platinum mining operations, time-dependent behaviour is, however, observed to be much less marked unless some form of specific mining-induced fracturing occurs. One particular case of considerable interest is the time-dependent behaviour that is found to be associated with the formation and deployment of crush pillars. The purpose of the paper is to present a simple limit-equilibrium computational model of this behaviour that is sensitive to both the formation sequence and the size of planned crush pillars in a mine layout. This model provides a useful means to optimize the sizing of crush pillars, and at the same time may be used to identify potentially hazardous circumstances in which pillars may not crush in a stable manner.

Jan 1, 2012

By M. de Beer

The conversion of carbon-containing feedstock into liquid fuels can proceed via the Fischer-Tropsch synthesis, which is catalysed using supported cobalt catalysts. These catalysts contain noble metals to facilitate the reduction of oxidic cobalt species in the catalyst precursor to metallic cobalt, which is the catalytically active species for the Fischer-Tropsch synthesis. This is thought to occur via hydrogen spillover, i.e. the diffusion of atomic hydrogen over the support from the noble metal to the oxidic cobalt moieties. Noble metals may also affectthe dispersion of cobalt in the active Fischer-Tropsch catalyst. The economic aspect of the addition of noble metals to the Fischer-Tropsch catalyst is discussed.

Jan 1, 2014

The two methods for calibrating the parameters K and (alpha) for use in Gy’s equation for the Fundamental Sampling Error (FSE)–, Duplicate Sampling Analysis (DSA) and Segregation Free Analysis (SFA)–, are described in detail. A case study using identical broken reef material from a Witwatersrand-type orebody was calibrated using the DSA and SFA methods and the results compared. Classically, the form of Gy’s equation for the FSE raises the nominal size of fragments given by dN to the power of 3. A later modification of Gy’s formula raises dN to the power (alpha), the latter term being calibrated with the coefficient K in the DSA and SFA methods. The preferred value of for low-grade gold ores used by sampling practitioners in the mining industry is 1.5. A review of calibration experiments for low-grade gold ores using the DSA and SFA methods has produced values of K that vary between 70 and 170 and values of in the range 0.97 to 1.30. The average value for is shown to be 1, rather than 3 as originally proposed in the classic form of Gy’s equation or the industry-preferred 1.5. It is suggested that for low-grade gold-bearing ores the equation for the FSE should raise dN to a power of 1. Such an equation for the variance of the FSE greatly simplifies the characterization of gold ores, now requiring only the calibration of K for a given mass and established fragment size. The implications of the simplified equation for the heterogeneity test are that, provided the fragments have been screened to within a narrow size range, any particular size will return a value for K that is acceptable for use in the sampling nomogram.

Jan 1, 2017