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By G. G. Campbell

The Bureau of Mines initiated a field test of underground coal gasitication to investigate the technologic feasibility of gasifying a subbituminous coal. The test site is near the town of Hanna, Wyo., about 70 miles northwest of Laramie. Preliminary results of the experiment are described. The coal was ignited in the central well of a 16-well pattern. Both forward and reverse combustion techniques were attempted to prepare a path of sufficient permeability to permit the high air injection rat s necessary for gasification. Gasification between linked wellbores was sustained for periods as long as 3 months. Hydrogen-rich gas having a heating value of 100 to 150 Btu/scf was produced.

Jan 1, 1974

By Robert M. Cox

The objective of this study was to determine if significant relationships exist between coal mine roof stability and the time roof is left unsupported. Additional factors such as geology, opening geometry, and mining methods were also studied: to determine their relative influence on mine roof stability. The results of the study indicate that geologic factors such as shear zones (either joints or faults) and changes in roof rock lithology were the principal factors governing mine roof stability. The time lapse factor appeared to be of critical importance when poor mine roof conditions are encountered. The study pointed up the need for improved and permissible rock mechanics instrumentation for use in coal mine investigations.

Jan 1, 1974

By G. E. Rennick

A siphon-type laboratory airlift well was designed and operated by the Bureau of Mines to study the concurrent flow of air and oil in small-diameter pipes. Glass flowstrings ranging from to 1 inch in diameter and from L4 to 64 feet in length were equipped with various-sized air-entry jets. Liquid holdup volumes were used to correlate vertical-flow data, and empirical equations for computing gas requirements were derived. The effect of flowstring length on flow efficiency, oil- and gas-production rates, and gas-oil ratios was relatively minor at all flowing pressures. Air-jet sizes and flowstring diameters, however, had a marked effect on flow efficiency and oil- and gas-production rates. The small air-jet sizes increased maximum flow efficiency and its associated flowing pressures but decreased oil- and gas-production rates. An increase in flowstring diameter increased maximum flow efficiency with its associated flowing pressure and also increased the production rates of oil and gas.

Jan 1, 1965

By J. W. Griffith, J. L. Stauffer, L. M. Demers, D. C. Kuhn, S. Riliog

"The relative activation of eicosanoid production which results from the exposure of the alveolar macrophage (AM) to mineral dusts is thought to be a key factor in the pathophysiology of occupational lung disease. We compared in vitro basal and silicastimulated production of prostaglandin E2 (PGE2) and thromboxane A2 (TXA2) by AM from normal humans and non-human primates (Macaca nemistrina). In addition, we instilled mineral dusts directly into one lung of the non-human primate and evaluated AM eicosanoid production at two week intervals following dust instillation. Unstimulated AM from humans produce more PGE2 and TXA2 than do AM from M. nemistrina. However, in vitro exposure of AM from both species to silica dust produced a qualitatively similar increase in TXA2 production accompanied by no change in PGE2 production. Sequential analysis of AM eicosanoid production following a single bolus exposure to bituminous or anthracite coal dusts, titanium dioxide (Ti()i) dust or crystalline silica showed marked variability among individual non-human primates in qualitative and quantitative aspects of dust-induced eicosanoid production. However, the rank order of potency of the different dusts (silica> anthracite> bituminous) correlated with epidemiological evidence relating the type of dust mined to the incidence of pneumoconiosis. These studies suggest that the non-human primate may serve as a model for the study of both the role of eicosanoids in the etiology of dust-induced occupational lung disease and the biochemical basis for individual variability in the response of lung cells to mineral dust exposure. IntroductionOccupational inhalation of mineral dust can lead to chronic debilitating lung disease ( 1,2). One of the key components of the disease process is thought to be the interaction of mineral dust with the alveolar macrophage (AM) and the subsequent release by the AM of inflammatory and fibrotic substances (3,4). Chronic inhalation of mineral dust, depending on the type and amount of dust, may then produce a situation in which ongoing inflammation, accompanied by the destruction of functional lung tissue by products of activated AM and polymorphonuclear neutrophils, stimulates the production of nonfunctional matrix by lung fibroblasts.The AM produces several oxygenated derivatives of arachidonic acid (AA) which may play important roles in dust-induced lung pathophysiology (5,6). In previous studies in the rat, we found that prostaglandin E2 (PGE2). thromboxane A2 (TXA2) and leukotriene 84 (L TB4) were the major AA metabolites produced by AM (7). PGE2 is associated with pro-inflammatory activity (8) as well as anti-fibrotic activity since it downregulates interleukin -1 (IL-1) and tumor necrosis factor (TNF) release by AM (9-11). TXA2 is known to stimulate platelet activity, cause bronchial and vascular smooth muscle contraction (12) and to possess chemotactic activity (13). LTB4 is chemotactic for neutrophils and monocytes (14) and has been suggested as an additional regulatory factor in the release of TNF by AM exposed to silica dust ( 15)."

Nov 1, 1995

By R. J. Tocher

Uniaxial testing was performed on coal specimens to determine the time-dependent response. The testing was carried out on coal from six mine sites throughout the Western United States and Pennsylvania. Testing configurations were varied to allow analysis of moisture dependency, stress level and specimen orientation. Several theories were presented for the behavior of coal due to moisture diffusion. Experimental results showed the correlation between the theories and the actual material response. Coal deformation was found to be highly dependent on the moisture level of the testing environment. Moisture migration causes drying and shrinkage which lead to progressive degradation of the material. The coal tested experienced a rebound if saturated after a period of drying. This type of time-dependent behavior overshadows the dependence on the applied stress level, which, however, still produces a noticeable creep behavior. Analysis of one series of creep test results was performed. A relationship was developed on the basis of a simplified rheological model to describe the coal response to uniaxial stress. Previous empirical formulations in the form of power laws were compared and their deficiencies pointed out.

Jan 1, 1980

By C. H. Elder

Two degasification test boreholes were drilled to depths of 1,238 and 1,212 feet on Bureau of Mines property at Bruceton, Pa., as part of the Bureau's long-range coal degasification program. The holes provided detailed geologic information and geologic sections, which were correlated with regional stratigraphic cross sections prepared by the Pennsylvania Geological Survey. Gas content determinations and coal analyses were made on the Upper Freeport, Middle Kittanning, Clarion, Brookville, and Mercer coalbeds; gas content of the coalbeds ranged from 53 to 165 cubic feet per ton. Formation pressure and gas flow tests were conducted on selected coalbed intervals in borehole 1; formation pressures ranged from 292 to 473 psig. The middle Kittanning coalbed was hydraulically stimulated using very heavy gelled water, but gas production remained low because gel residue and formation water inhibited the flow of gas. Gas contents in the Clarion, Upper Brookville, and Mercer coalbeds were anomalously low owing to the proximity of porous sand-stones which act as reservoirs for gas migrating from coalbeds.

Jan 1, 1977

By E. J. Ostrowski, P. L. Woolf, J. P. Morris, Norwood B. Melcher

By injecting natural gas through auxiliary tuyeres into the smelting zone of the Bureau of Mines ' experimental blast furnace in January 1959 , the investigators succeeded in reducing the coke consumption by approximately one - third that of the base period . This caused a 30 - percent increase in pig iron production with no increase in wind rate . The maximum gas addition in these experiments was 4,665 cubic feet per ton of metal produced . Sharp reduction in gas consumption occurred when high hot blast and high wind rates were used , although the gas injection rate in percent of air blown remained constant . As the heat energy produced by burning natural gas to carbon monoxide and hydrogen is much less than burning coke to carbon monoxide , greater blast temperatures were required during the test runs . The gases produced from the methane were , however , more effective reductants ; so it was possible to increase the production rate while reducing the total heat requirements per ton of metal produced . During a base period with an all - sinter burden , before introduction of natural gas , a coke rate of 1,484 pounds per net ton of pig iron was attained , using an average blast temperature of 1,518 ° F. Gas was introduced gradually over a two -week period until an average 7 percent of the air blown was reached . During this period , the wind rate was adjusted downward to maintain a constant flow of gas in the bosh . The production rate of the furnace remained relatively constant . The quality of pig iron, however , improved as the sulfur load on the furnace was reduced as a result of the substitution of gas for coke . Blast temperatures were increased during this period from 1,518 ° F. to 1,939 ° F. , when the maximum gas addition was reached .

Jul 1, 1960

By R. V. Lundquist, H. Leitch

The solubility characteristics of mono calcium aluminate (CaO A₁₂ 0 ) in water and in NaOH , Na₂ CO₂ , and NaOH - Na₂ CO₂ solutions were measured by determining the changes in Al2O3 concentrations in solution over a period of time at a specified temperature . The monocalcium aluminate was synthesized by sintering its starting components for 72 hours at 1,375 ° C. Distilled water and aqueous solutions of technical grades of NaOH and Na₂ CO₂ were used as solvents . The extraction of alumina from the monocalcium aluminate was dependent on the composition of the solvent and partially dependent on temperature for leaching . About 98 percent extraction of alumina from the aluminate occurred in Na₂ CO3 solutions containing 10 to 12 percent NaOH . Other solution compositions produce lesser extractions .

Jan 1, 1963

By H. R. Batchelder

The Bureau of Mines Gas Synthesis Demonstration Plant at Louisiana, Mo., includes apparatus for the gasification of pulverized coal with oxygen and superheated steam. A pebble heater constructed by the Babcock & Wilcox Co. is used to superheat nominal 5-pound steam for the gasification process, usually to temperatures of 1,600° to 2,300° F. with flow rates of 1,400 to 2,300 pounds per hour. Heaters of this sort have been described. So far as is known, the Babcock & Wilcox Co. is the sole commercial manufacturer of equipment of this type. Units have been built with capacities above 18,000 pounds of steam per hour.

Jan 1, 1951

Australia is tightening its rules governing mineral processing and the purchase of rural land by foreign investors" Rural land purchasers in the future will have to demonstrate to the Foreign Investment Review Board, the applicable governing body, that they will introduce new techniques or developments that will benefit Australia. In mineral processing, the criterion will be the availability of maximum opportunities for Australian equity capital. The changes are designed to discourage absentee landlords and speculators from abroad. A diamond field discovered several years ago in the northern section of Western Australia, known as the Kimberley region, is now thought to be one of the largest in the world, according to Conzinc Riotinto of Australia Ltd. (CRA). Figures released late in 1981 by CRA indicate that the main orebody of at least 100 million metric tons contains possibly 500 million carats of diamonds with a conservative market value of $8 billion. The diamond stones in the 100-acre deposit are about 10% gem-quality, 30% near gem, and 60% industrial. Initial production is expected to be about 17 million carats annually, which could be expanded to 25 million carats annually. World production of natural diamonds has been about 40 million carats per year from a reserve base of about 700 million carats.

Jan 1, 1982

By John W. Buch

At a meeting of the Anthracite Investigations Advisory Committee in July 1944 at Washington, D. C., the initial work and objectives of the Anthracite Mechanical Mining Section of the Federal Bureau of Mines were discussed. It was learned that interest existed in an improved performance of mining thin, steeply pitching beds above the gangway by mechanical methods. One company offered the use of one of its mines for experimental work, and this offer was accepted. Following acceptance, an effort was made by Bureau engineers to devise a mechanical method with a performance better than that of a new hand method proposed by company engineers for an actual mining condition. The method proposed by the Bureau was to drive 30-degree slant chutes across a 10-foot bed pitching 85 degrees. These chutes were to be advanced by using a lightweight, compressed air-powered, shearing machine of German origin that had been tried in a flat Pennsylvania anthracite bed in 1934, and which did not then prove successful because of blasting difficulties. An attempt was made to obtain one of these machines from England, where it was known machines of this type had been used. Shortly thereafter John W. Buch was sent to Europe as a member of the Solid Fuels Mission to the European Theater of Operations organized by the Technical Industrial Intelligence Committee of the Joint Chiefs of Staff. Through his efforts the Bureau of Mines obtained two such machines, known as the Eickhoff model DEK, one from England and one from Germany. This report covers the preliminary testing of these machines in order to obtain mechanical operating data for use in determining the power requirements for cutting anthracite with machines of this design.

Jan 1, 1949

By Mackenzie Burnett

Quick-Fix Blowout Stoppings were evaluated in several underground mines as an alternative to conventional ventilation control bulkheads. Blowout stoppings offer considerable savings in bulkhead construction and repair costs if the 0.1 inch H20 of differential pressure required to inflate them is available. The Quick-Fix Blowout Stoppings were utilized successfully in uranium mines in the Southwestern United States where savings in bulkhead construction and repairs to blast damaged bulkheads are estimated to equal $9,500 over the projected 2 year average life of a blowout stopping. Two types of material were evaluated. Five methods of anchoring the stoppings to drift walls were evaluated. Three methods of anchor attachment to the stopping material were evaluated. Blast pressure measurements were made in conjunction with the evaluation of the blowout stoppings.

Jan 1, 1978

By G. L. Gates

Five possible sources of water for waterflooding of petroleum reservoirs in the arid San Joaquin Valley of California were considered. Three of them (water produced with petroleum, water from a shallow saline aquifer, and waste irrigation water) were analyzed chemically; laboratory information for one (sea water) had been developed during a previous study. A series of laboratory tests made on the fifth source (fresh water) determined the solubility of calcium sulfate dihydrate in water. Laboratory analyses included the following: Chemical analyses of water produced with petroleum and waste irrigation water; solubility of calcium sulfate dihydrate in water and brines; the effect of excess sulfate on the solubility of calcium sulfate in brines; the presence of sulfate-reducing bacteria; and the permeability of cores from a petroleum reservoir to air, to water from other petroleum reservoirs, and to waste irrigation water. The results showed that most of the waters and mixtures of waters are compatible with petroleum reservoir waters and are generally suitable for injection. The calcium content of some of the formation waters is quite high, and care must be taken to prevent precipitation of calcium sulfate dihydrate. The permeability of the few cores tested was about the same to water and brines as to air, indicating that formation damage due to clay swelling will not be serious. The waters most likely to be available for injection are water produced with petroleum, water from shallow saline aquifers, and waste irrigation water.

Jan 1, 1970

By Will H. Coghill

This paper on milling methods and costs at a flat river (Mo.), mill is one of a series of information circulars on milling methods and costs which is being prepared by the United States Bureau of Mines, The mill under consideration treats 5,000 tons of load ore daily by table concentration and flotation. It is 25 years old, and yet it is a new mill. Research has been in continual progress at the plant since its beginning, and accordingly a day never passes without a record of change for advancement. The changes have been so orderly that no evidence of obsolete equipment remains.

Jan 1, 1932

By John D. Sullivan

In leaching copper ores knowledge of the rate of dissolution of the copper minerals and of the impurities is desirable. With knowledge of these two factors and data as to what minerals are present in the ore the metallurgist has an excellent start on planning a leach¬ing cycle to fit that ore. The rate of dissolution is rather difficult to predict, and the time required to leach a given ore may differ markedly from that required by another ore. The whole study as related to mixed oxidized and sulphide ores is one of relative rates of dissolution of the different copper minerals and the impurities in sulphuric acid and in ferric sulphate. The aim of leaching is to choose a cycle and strength of solvents to ex¬tract a maximum amount of copper and a minimum of impurities. The consumption of reagents per unit of copper dissolved is a function of the strength of the reagents used and the relative rates of attack on copper minerals and impurities. An opportunity may exist of ob¬taining the kind of electrolyte wanted for electrolytic precipitation and yet of saving on the consumption of reagents by modifying the strength of ferric sulphate and of sulphuric acid during the cycle to fit the time needed for dissolving the sulphide and oxidized minerals present. Former papers have considered the rate of dissolution of azurite, malachite, tenorite, chrysocolla, cuprite, chalcocite, boruite, and covellite in common leaching solvents. A paper soon to be written will consider some of the less important copper minerals. The present paper considers the rate of dissolution of copper from ores of the Southwest in sulphuric acid of varying strength and the ratio of sulphuric acid consumed to copper dis¬solved. In this study two ores containing the copper principally in an oxidized condition were used. A study of other ores, especially those containing high percentages of sulphide copper minerals, would be desirable, but since consumption of acid has paramount interest,

Jan 1, 1931

By Jr. Watts, B. K. Cantrell, D. H. Carlson, K. L. Rubow

"The use of diesel equipment in underground coal mines is controversial because ""whole diesel exhaust"" is regarded as ""a potential occupational carcinogen"" by the National Institute for Occupational Safety and Health (NIOSH). Threshold limit values (TLVs) are recommended for the gaseous pollutants; CO, CO2, NO, NO2, SO2, and some hydrocarbons emitted in diesel exhaust. There is, however, no TLV recommended for diesel exhaust aerosols (DEA) nor is there a standard method for sampling these aerosols.The University of Minnesota and the Bureau of Mines have collaborated to develop a personal diesel exhaust aerosol sampler (PDEAS) which utilizes size selective, inertial impaction and gravimetric analysis. During the field tests of this sampler, numerous air quality measurements were conducted in underground coal mines using diesel equipment. The objective of this report is to present these data and to assess the impact of diesel face haulage equipment on mine air quality.Air quality data were collected in four underground coal mines using continuous mining methods with diesel haulage equipment. Daily samples were collected at the section intake, haulageway, and on haulage vehicles. Both full-and partial-shift samples were collected using a variety of aerosol instruments, including the PDEAS and the micro-orifice, uniform deposit impactor (MOUDI) which sample the mine aerosol diesel exhaust fraction. Two of the mines were also monitored for the major gaseous constituents found in diesel exhaust CO, CO2, NO, NO2, and SO2. These measurements were made by either collecting bag samples for subsequent gas analysis or by Palmes dosimeters.The concentrations of CO, CO2, NO, NO2, and SO2, were well below regulated levels. The mine average DEA concentration determined by the PDEAS in the haulageway for the three mines surveyed using this instrument was 0.79 mg/m3, with a standard deviation of 0.19 mg/m3. DEA contributed 65% of the respirable aerosol, at this location. These results were the same as the mean DEA concentrations calculated from size distribution measurements obtained using the MOUDI. This was 0.78 mg/m3, with a standard deviation of 0.22 mg/m3."

Mar 1, 1992

By L. B. Pankratz, R. Barany, W. W. Weller

Experimental determinations were made of the heats of formation at 298.15 ° K of cuprous ferrite and cupric ferrite ; the heat capacity of cuprous ferrite was measured over the temperature range from 50 ° to 298 ° K and the entropy at 298.15 ° K was evaluated ; the heat contents of cuprous ferrite and cupric ferrite above 298.15 ° K were measured to 1,500 ° K and 1,100 ° K , respectively . These thermodynamic values were combined with other pertinent data to obtain heat and free energy of formation values at high temperatures . The stability of the two ferrites with respect to their constituent oxides is discussed . Thermodynamic values are included for the decomposition of cupric ferrite to form cuprous ferrite , magnetite , and oxygen .

Jan 1, 1964

By C. W. Owings

The Bureau of Mines has conducted a survey to determine potential exposure of mine workers to dust produced in connection with intermittent rock drilling in coal mines. Eighteen mines in 3 states were visited, and 30 different operations were observed, as follows: 10 drilling in draw slate, 8 drilling top rock for brushing or grading, 2 drilling in the coal face, 4 drilling in the bottom, 2 drilling top rock for overcasts, 2 drilling in faults or boulders, 1 drilling for roof bolting, and 1 drilling for trolley hangers. Dust respirators were worn by drilling crews during 16 of the 30 operations. Three hundred thirty-two samples of air-borne dust were collected during the survey. ACKNOWLEDGMENTS The information in this report is based on samples collected and observations made in bituminous-coal mines. Operating officials at these mines have contributed to this study, and their cooperation is gratefully acknowledged. All samples were counted by Thomas B. Kirby, chemist, and Dominick A. Ambrosia, scientific aid, and were analyzed by Gretta S. Baur, physicist, and Patricia M. Gussey, scientific aid, of the Health Branch of the Bureau of Mines.

Jan 1, 1953

By Charles L. Harness, A. T. Coons

Sodium carbonate, Na2CO3, more commonly known as soda ash, is the most important of the alkalies. Sulfuric acid is the only heavy chemical, Soda ash enters the market either as the natural product or as a manufactured derivative of common salt. Notwithstanding their common occurrence in closed basins of the Western States, natural sodas are produced at present by only four firms, all in the same California area, and satisfy only 4 percent of domestic demand for soda ash; soda ash made from salt supplies 96 percent of the requirements. The impossibility in wartime of routing all westbound American shipping through the Panama Cami.l has curtailed Pacific Coast receipts of soda ash and-increased the importance of local resources of natural carbonates. One of the most promising of ·these is the recently discovered trona (sodium sesquicarbonate)· deposit 2o·mnes· west of Green River, Wyo. Reserves are likely to run into hundreds ·of million·s of tons, and the deposit probably could be worked by the room-and~pillar· system of mining, like common salt or coal. • • Raw materials ·ne·cessary for manufacturing synthetic soda ash occur closely associated in m·afiy parts· bf the United 8tates. Almost unlimited resources of salt in brines and in rock-salt depbsits are located near limestone quarries in many areas. The· limesto'ne furnishes the carbon dioxide for the manufacture of soda ash arid the lime f o'r the recovery of ammonia. used in one step of the process. Expansion of the industry to meet wartime needs depends chiefly on availability of trained labor, materials, and equipment necessary for the erection of additional units.

Jun 1, 1942

By John D. Sullivan

In leaching copper ores knowledge of the rate of dissolution of the copper minerals and of the impurities is desirable. With knowledge of these two factors and data as to what minerals are present in the ore the metallurgist has an excellent start on planning a leaching cycle to fit that ore. The rate of dissolution is rather difficult to predict, and the time required to leach a given ore may differ markedly from that required by another ore. The whole study as related to mixed oxidized and sulphide ores is one of relative rates of dissolution of the different copper minerals and the impurities in sulphuric aoid and in ferric sulphate. The aim of leaching is to choose a cycle and strength of solvents to extract a maximum amount of copper and a minimum of impurities. The consumption of reagents per unit of copper dissolved is a function of the strength of the reagents used and the relative rates of attack on copper minerals and impurities. An opportunity may exist of obtaining the kind of electrolyte wanted for electrolytic precipitation and yet of saving on the consumption of reagents by modifying the strength of ferric sulphate and of sulphuric acid during the cycle to fit the time needed for dissolving the sulphide and oxidized minerals present.

Jan 1, 1931