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By R. F. Stevens

A laboratory method for examining crude shale oil is described. The method uses only about 500 ml. of sample and a limited number of analytical determinations. Results provide information on the general characteristics and composition of an oil and serve as a basis for comparing different oils. However, the method does not provide for direct estimates of yields of commercial products. Analyses of 10 oils produced in the United States by different methods of retorting and of 10 shale oils from commercial-scale operations in 6 foreign countries are given. The shale-oil-analysis method presented in this paper is based on and employs the same equipment as the Bureau of Mines routine method for analyzing crude petroleum. As shale oil contains groups of compounds not generally found in petroleum, several modifications of the petroleum method that might increase its suitability for application to shale oil were investigated. The modifications included in the present method take into account the apparent poor heat stability of shale oil and the presence of large quantities of olefins and nitrogen compounds.

Jan 1, 1952

By Ralph Husack, J. W. Eckerd, G. A. Brady

The effect of gamma radiation on Pennsylvania anthracite and on reactions between anthracite and other materials was studied using a shielded , selfcontained 23,000 - curie cobalt 60 source . When anthracite was exposed to air at 65° C the reaction with oxygen was greater in the presence of radiation. than in its absence . Although drop- shatter tests indicated that exposure to radiation decreased the resistance to breakage of anthracite , this evidence of structural weakening was not supported by the results of grindability or particle- size studies . Irradiation caused definite changes in the gases evolved from evacuated samples of anthracite ; the percentages of hydrogen and carbon dioxide were increased, and the methane concentration remained unchanged . Carbon monoxide was evolved only from the unirradiated samples . Electron paramagnetic resonance (EPR ) measurements indicated large differences between evacuated samples and those exposed to air . There was little or no difference between irradiated and unirradiated samples , except that the free- radical content of unirradiated samples of anthracite increased progressively with higher temperatures of evacuation , but in the case of irradiated samples , no such behavior was found . Attempts to produce carbon disulfide and calcium carbide by reacting anthracite with sulfur up to 120 ° C , and with calcium oxide up to 400 ° C , were unsuccessful .

Jan 1, 1964

By N. A. Eilertsen

Eastern Aroostook County, Maine, contains an enormous tonnage of manganese widely distributed in manganiferous sedimentary beds composed of hematitic shale, hematitic slate, and laminated siliceous carbonate rock. The bedded deposits range in thickness from several feet to over 150 feet. Manganese minerals that occur as silicates and carbonate are so minute that they cannot be concentrated by present methods of ore dressing. From a hydrometallurgical standpoint, the deposits can best be classified by amenability to acid leaching. The deposits of Aroostook County are in three geographical groups (see fig. l), designated as the northern, central, and southern districts. At least 13 deposits are known to occur in the latter district, which covers an Ewes about 8 miles wide and 15 miles long. The Littleton Ridge deposit, on the northern boundary of the southern district, previously examined by geologists from the State and Federal Geological Surveys on the farms of Donald H. Haggerty and David A. Abernethy, was pointed out in reports as being possibly the richest and largest in the southern district. The Bureau of Mines sampled this deposit by surface trenching and diamond drilling from May 1 to September 30, 1951. A total of 23 trenches was bulldozed, aggregating 5,355 linear feet, of which 8 trenches were sampled by cutting 185 channel samples over a linear distance of 1,820 feet.

Jan 1, 1955

By J. F. Barkley

Field tests were made on the rate of corrosion of 30 materials used in air preheaters under regular operating conditions, and the buildup of deposits was observed. Twenty-three materials were tested with coal as the fuel on an underfeed stoker and seven with oil, including a short period with pulverized coal as fuel, The plant equipment is described, and pertinent plant operating data are tabulated. Figures 17 and 19 (pp. 24 and 27) give the results of corrosion tests on the uncoated metal test specimens. The information obtained from these tests follows the general pattern described in Bureau of Mines Report of Investigations 4996, Corrosion and Deposits in Regenerative Air Preheaters. The deposits were similar, and the corrosion rates of Cor-Ten and Mayari-R steel (previously found to be essentially the same at the Harding Street Station using coal) continued to show little difference at the Marion Generating Station using principally oil. The one high-alloy steel tested, type 321, showed a much higher corrosion rate than the low-alloy steel, Cor-Ten.

Jan 1, 1959

By David S. Brown

What troubles me so often about debates over the environment, which I have heard since I entered government in the late 1960's, is that the issues are so often presented as a false dilemma--the either-or fallacy in logic. The either-or fallacy allows only two possible choices: Either protect the environment or exploit it. In reality, however, there may be a few more options. The diverse, often competing, values that the Earth offers require us to weigh and balance those options through a range of policy options. A quality environment and economic growth and opportunity are not mutually exclusive. First, let me acknowledge that I support a set of resource values recognized in U.S. laws and deemed important down through history for the success of free, progressive, and secure societies: the importance of access to raw materials. Increasingly, however, mineral raw materials have been viewed at best as not particularly relevant to a sophisticated, technologic society, and at worst monstrously destructive of our natural environment. Both perceptions, in my judgment, are wrong.

Jan 1, 1989

By T. M. Romslo

The Lake Shore property, located in the early 1880's, contains copper-bearing deposits that have been developed by surface excavations, underground workings, and churn-drill holes. Operation of the property ended in 1929 with a total recorded production of 280,000 pounds of copper. The property is near the foot of the Slate Mountains, which are made up mainly of probably the Pinal formation of pre-Cambrian age. In the mine area there are a few outcrops of granite, which is exposed over a large area east of the property. Other outcropping rocks on the property are limestone, quartzite, and diabase. The limestone and quartzite probably are the Mescal and Troy formations of pre-Cambrian and Cambrian age, respectively. The predominant copper mineral is chrysocolla, a hydrous silicate that occurs mainly as fracture filling in bedded schist. It is also, the principal copper mineral in the shear zone at the schist-granite contact and in limestone southeast of the main workings. Investigation of the Lake Shore property by the Bureau of Mines included both topographic and geologic mapping, exploratory drilling, and metallurgical test work. One diamond-drill, hole and five churn-drill holes were completed for a total of 2,872.5 feet. Drilling started January 19 and was completed May 13, 1949.

Jan 1, 1950

By R. E. Campbell

Uranium metal of improved purity was prepared by electrorefining commercial magnesium-reduced uranium in a molten sodium chloride-uranium trichloride electrolyte. The best operating conditions for the preparation of refined metal were established as follows: an electrolyte containing 8.7 to 13.3 weight-percent uranium; initial cathode current densities from 300 to 1,500 amp/sq ft; and a molten salt temperature of 860° C. Ingots produced from electrorefined uranium crystals prepared with these operating conditions were substantially free of metallic impurities. The only impurities in the refined and consolidated metal were present in low or undetectable amounts.

Jan 1, 1965

By Sidney Katell

This study estimates capital investment, operating costs, and selling prices for four underground bituminous mines producing coal with annual production ranging from 1.06 to 4.99 million tons. It is assumed that the mines have a 20-year life. Wages and union welfare payments are considered as of December 6, 1974, under the Bituminous Wage Agreement of 1974, and costs for material and equipment are based on 1975 indexes. Initial capital investment ranges from $23,629,500 for the 1; 06- million-ton-per-year (MM tpy) mine to $79,907,500 for the 4.99-MM-tpy mine. Total capital investment ranges from $35,336,500 to $1 18,863,500 for the same mines. Corresponding selling prices for the coal range from $13.57 to $11.36 per ton, assuming a 15-percent discounted cash flow rate of return after Federal income taxes.

Jan 1, 1975

BIBLIOGRAPHY Allen, C.A, Analyses of Utah Coals, United States Bureau of Mines Technical Paper 345, 1925, pp. 90. Allen, J.E. and E.M. Baldwin, Geology and Coal Resources of the Coos Bay Quadrangle, Oregon, Oregon Department of Geology and Mineral Industries Bulletin 27, 1944, pp. 160. "Aluminum Boom Raises Productivity", Coal Age, Vol. 82, No.6, June, 1977, pp. 103.

Jan 1, 1978

By Paul T. Allsman

The Salt River range vanadium deposits are situated 3 to 6 miles east and southeast of Afton, Lincoln County, Wyo. The vanadium occurs in a continuous bedded shale zone of the Phosphoria formation extending from the vicinity of Afton into southeastern Idaho. The Bureau of Mines explored several of these vanadiferous-shale deposits between December 1942 and December 1943 and conducted metallurgical tests on the ores. The areas investigated were west Swift Creek, the Dry Creek, and the Cottonwood Creek. The vanadiferous-shale beds have been folded sharply into a series of tightly compressed, eroded anticlines and synclines, which form the Salt River range. The vanadium occurs in a series of narrow shale or mudstone beds contained within the phosphatic-shale member of the Phosphoria formation. Exploration by the Bureau of Mines consisted of surface trenching and underground work over 18 miles of outcrop of vanadiferous shale with an average assay value of 0.866 percent V2O5.

Jan 1, 1949

By C. N. Rosenecker

The power required to circulate a gas-solids suspension was determined using a centrifugal compressor and a closed system. The suspension consisted of 18- to 40-micron glass beads in a mixture of 89 percent N2 and 11 percent CO2 at 20 psig. Solids-to-gas (S/G) ratios w re O to 2.2 lb/lb; gas flow rates were l.2 to 2.5 lb/min. Power requirement was found to follow the relationship hp t = hp(. + l), where hp t = the total power, and hpg = the power required for pure gas.

Jan 1, 1967

By R. G. Meara, O&apos

The land-pebble district of Florida, which in 1928 supplied 96.7 per cent of the phosphate production of that State and 82 per cent of the domestic requirements of the United States, is centered in Polk and Hillsboro Counties about 30 miles east of Tampa The deposits are unconsolidated sediments occurring as beds of phosphate matrix overlain by a mantle of barren sands and clays. The matrix consists of a mixture of Sand (quartz grains), clay, and phosphate rock in which the coarsest sand is much finer than the coarsest phosphate; that is, the sand is segregated in the fine material. Before the introduction of classifiers the concentration consisted of log washing, and screening at about 20-mesh, which was usually the finest size that could be taken to maintain commercial grade, 66 per cent B. P. L. (bone phosphate of limey or more. When classifiers were introduced some of the fines that had escaped at the head of the washery and some of the minus 20-mesh material isolated during the rushing and formerly lost supplied the feed.

Jan 1, 1931

By W. L. Crentz

San Juan County, which occupies the extreme northwest corner of New Mexico, contains large reserves of coal in the Fruitland formation and in the Menefee formation of the Mesaverde group. The coals have bright luster, are brittle, and break easily in handling. All mines sampled are in the La Plata-Fruitland and Rio Chaco districts of the Durango-Gallup coal field. This large area, all within San Juan County, contains numerous coal beds 5 to 15 feet thick. Ellis2/ mentions the Carbonero (Fruitland in this report) bed in the La Plata-Fruitland district attaining a thickness of 36 feet. This bed has been correlated with the Carbonero bed, formerly mined at Carbon Junction, near Durango, Colo. During the field investigation covered by this report, no operating mine in the Fruitland bed was working a bed thickness of more than 15 feet.

Jan 1, 1957

By E. C. Lane

This paper is a preliminary report of the results of the Bureau of Mines' twenty-second semiannual survey of motor gasoline marketed in the United States. A more detailed discussion of the whole survey is in preparation and will be published as a companion, report. The second paper, in addition to giving a more complete summary of the data included in this report, will present results of the determination of copper-strip corrosion (method 530.22),5 color (method 10.11),6 sulphur content (method 520.11) copper-dish evaporation residue (method 520.11),7 and gum content as given by the Bureau of Mines steam oven method.9 The retail price at the time the sample was taken and try will also be stated for each sample. The present paper deals specifically with data relating to gravity, vapor pressure, and distillation.

Jan 1, 1930

By William H. King

The Mining Division of the Bureau of Mines has been making development and power-requirement studios for the Interior Department Missouri Basin Field. Committee. The studies by the Bureau of Mines have as their purpose, the summarizing of potential future power requirements in the mineral industry within the Missouri Basin, special emphasis being placed on possible expansion of these requirements through construction of new mining enterprises by private capital. In preparing a proposal for the production of phosphoric acid from phosphate rock near Lander, Wyo., it was found that the basic information on the physical and chemical characteristics of the phosphate beds to determine costs of mining and treatment was lacking.

Jan 1, 1949

By L. C. IlsLey

A list of permissible mine equipment approved by the Bureau of Mines before January 1, 1940, was published in Bureau of Mines Information Circu- lar 71103. Information Circular 71584, published as a supplement thereto, listed equipment approved during the calendar year 1940. The present list contains the information given in those two circulars, as well as approvals issued during the calendar year 1941. It embraces electrically operated air compressors, coal drills, conveyors and loading machines, electrical equipment for mine fans, mining machines and trucks, mine pumps, rock- dust distributors, room hoists, storage-battery gathering and haulage locomotives, storage-battery power trucks and shuttle cars, mine telephones, junction and distribution boxes, electric cap lamps, flame safety lamps, electric hand and trip lamps, electric flood lamps, flashlights, methane detectors, and single- and multiple-shot blasting units. The equipment listed is not approved by the Bureau of Mines until found by inspection and test to comply with minimum standards of safety as outlined in "schedules" prepared upon the basis of many years of ex- perience in dealing with safety problems confronting the coal-mining in- dustry. The use of such equipment in mines that are known to be gassy,. as well as in those that may become so, is earnestly recommended in the interests of safety. This circular is published so that the industry may be kept informed as to the many types of machines, devices, and lamps that are available for reducing explosion and other hazards incidental to coal mining.

Apr 1, 1942

By Margaret R. Egan

The U.S. Bureau of Mines conducted experiments in the intermediate-scale fire tunnel to assess the influence of air velocity on the gas production and smoke characteristics during smoldering and flaming combustion of Pittsburgh seam coal and its impact on the detection of the combustion products. On-line determinations of mass and number of smoke particles, light transmission, and various gas concentrations were made. From these experimental values, generation rates, heat-release rates, production constants, particle sizes, obscuration rates, and optical densities were calculated. Ventilation has a direct effect on fire detection and development. The results indicate that, in general, increased air velocity lengthened the onset of smoke and flaming ignition, increased the fire intensity, but decreased the gas and smoke concentrations. Increased air velocity also lengthened the response times of all the fire sensors tested. Rapid and reliable detector response at this most crucial stage of fire development can increase the possibility that appropriate miner response (fire suppression tactics or evacuation) can be completed before toxic smoke spreads throughout the mine.

Jan 1, 2010

By Mark L. Chatman

The U.S. Bureau of Mines studied mineral resources of the Dragoon Mountains Unit, Coronado National Forest (54,264 ac), Cochise County, AZ. This study involves literature and field investigations with a focus on mine and prospect sites, which were inventoried and mapped; maps are contained in this report. Rock-chip samples were taken from mineralized zones and from some mine dumps; assays of the 477 samples are in appendixes. Mineral deposits are genetically and spatially related to Tertiary-age granitic intrusive activity. Most metallic mineral deposits are also strongly fault-controlled. Colored marble resources (270,000 st) are valued at approximately $6.5 million, if all were to be developed and sold as landscaping material in the form of-marble chips. However, with current demand, it is unlikely that regional markets could absorb all this material. Economic modeling of copper-zinc-silver skarns suggests none would be profitable to mine and capitalize at early 1993 commodity prices, mainly due to the small estimated size of the deposits (30,000 st to 40,000 st maximum). In the entire Unit, 140,000 st of inferred subeconomic skarn resources were estimated by USBM on five different skarn trends; measured subeconomic resources are negligible. Exploration by industry, 1992, was small-scale (on 2 skarn trends and 1 auriferous fault zone).

Jan 1, 1993

By Robert W. Geehan

The Bureau of Mines has been developing deposits of critical and essential minerals in the United States since 1939. A preliminary examination of the Union lead mine was made in November 1944 and January 1945 by W. T. Benson, a Bureau of Mines engineer, who recommended development by diamond drilling. The Bureau conducted a drilling project at the mine from February 12 to May 16, 1947. The property is in sec.12, T. 17'N., R. 19 E., Mount Diablo Base and Meridian, in. southern Washoe County, Nev., about 15 miles south of Reno. The Union lead mane, also known 4s the Commonwealth mine, has been an intermittent producer of zinc-lead-silver ore since 1860. During World War II, ore was shipped to smelter& near: salt Lake City, Utah. The Bureau drilled 21 diamond-drill holes having a total length of 1,549 feet and 20 long percussion-drill holes with a total length of 359 feet. The program was designed to test for horizontal and vertical extensions of the ore body and to prospect for parallel ore bodies. As a result of this program, extensions of the ore zone were established, but no parallel ore-bearing structures were found. The areas drilled were limited by drill sites available.

Jan 1, 1950

By Boyd Guthtrie

[Methods of distilling topped crude oils and distillates under vacuum, accompanied by good fractionation, have taken a place of major importance in the refining industry. In the refining of petroleum products it is generally desirable to produce a distillate of good quality, and this objective is attained by fractionation of a high degree. The laboratory and commercial practice have proved chat by varying the amount of fractionation the quality of the distillate car be changed, and refiners are cognizant of the advantages of good fractionation. Distillation-under high vacuum, however, is a relatively new practice in petroleum refining, and only during the last few years has there boon an indication that that this method ray become a general practice in the industry. Vacuum distillation offers many advantages over older methods of distilling petroleum products. Vacuum combined with steam distillation, for example, is replacing straight-stream distillation because the quality of the products of vacuum and, steam distillation surpasses that of those produced by straight-steam distillation. Although the injection of varying amounts of steam in a vacuum unit is common practice, the amount of steam used is becoming less as the vacuum within the unit is increased. This report describes tie construction of a visible-action laboratory batch still and fractioning; column and. gives curtain data pertaining to the operation of the apparatus under vacuum for the production. of lubricating distillates. The apparatus was designed and built to produce lubricating distillates under as nearly ideal conditions as possible, in order that a subsequent study of the characteristics of the distillates could be made.]

Jan 1, 1932