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By R. E. T. Hill

"A laboratory study was undertaken to determine the condensed equilibrium phase relations at 600°C in that portion of the quaternary Fe-Ni-Cu-S system which lies in the neighbourhood of the monosulphide solid solution (MSS). The study sought to determine to w hat extent copper affects the temperatures of stability and compositions of iron-nickel sulphides in bulk compositions similar to those of massive Fe-Ni-Cu ores. Experimental data, including stable phase assemblages and phase compositions, are presented.In the quaternary system at 600°C MSS forms stable phase assemblages with pentlandite, chalcopyrite solid solution, pyrite and vaesite. Over the range of bulk compositions displayed by natural ores copper as well as metal/sulphur ratio have a significant effect on the thermal stability of pyrite and pentlandite. Errors therefore accompany the widespread practice of ignoring copper or chalcopyrite when the mineralogical and compositional changes that have accompanied the initial cooling of primary magmatic sulphides or their subsequent homogenization during isochemical metamorphism are being deciphered. These errors are most significant for ores the bulk compositions of which lie tow ard the sulphur-deficient side of the cupriferous MSS. Temperatures as much as 300°C above the copper-absent value are possible for the interpreted upper stability limits of pentlandite in these ores.The experimental data show that up to 2.0 at% copper can occur in pentlandite stable at 600°C in a bulk composition equivalent to natural magmatic ores. This is equivalent to nearly 10 vol% chalcopyrite. Pentlandite contains more copper than coexisting MSS and the copper content of both phases increases with increasing iron."

Jan 1, 1984

By D. F. Ball, P. R. Dawson, J. T. Fitton

Report of discussion at December, 1970, IMM general meeting (Chairman: M. J. Cahalan, President) and contributed remarks on the paper published in Transactions/Section C (Mineral Processing & Extractive Metallurgy), vol. 79, September, 1970, pp. C189-96, plus the authors' replies. Contributors included Cohen E., Hope B., Wasse D.G., Shakespeare A.G., Burwood D.S., Jones H.A., Dartnell J., Carter G.C., Henderson T.A., Relf G. and Clark S.W.

Dec 1, 1971

By A. D. Read

Selective flocculation was investigated as a possible method of recovering values from mineral slimes which are too finely divided to be treated by conventional mineral processing methods. It has proved possible to flocculate selectively either haematite or a silicate from a stably dispersed mixture by varying the anionic character of the high-molecular-weight, partially hydrolysed polyacrylamide employed. Different separation methods have been developed for hard and soft water media. Electrokinetic and infrared techniques have been employed to elucidate the mechanism whereby selectivity has been attained in the different cases. The following influences on the various selective flocculation parameters have been investigated: (a) the level of the different reagent additions and (b) the shear conditions during and after flocculant addition. A feature of the particular system studied was the high solids content at which it was possible to achieve good selectivity. Probable reasons for this are advanced, and the possibilities and potentialities of the process are discussed.

Dec 1, 1971

By Ruddle R. W.

Magnetite occurs in the reverberatory furnaces, blast furnace and converter (a) as the result of its presence in the materials charged, and (b) as the result of oxidation of the FeS in the charge in the absence of sufficient SiO2 to slag the FeO as it is produced and thus prevent its subsequent further oxidation. Magnetite is reduced by FeS according to FeS+3Fe3O4=10FeO+SO2 and similar reactions. This reaction is markedly affected by temperature and does not proceed to any important extent below about 1200°C. To ensure comparative freedom from magnetite it is therefore necessary to raise the temperature of the furnace to the highest practicable figure and to use plenty of siliceous flux. Since the maximum operating temperature is likely to be limited by the resistance of the refractories to attack by the slag, investigation of the factors affecting this attack should be helpful. It is reasonable to suppose that the formation of magnetite might be minimized by ensuring intimate admixture of matte and slag during conversion so that silica is readily available for combination with ferrous oxide as the latter is formed. The literature gives no clue to the importance of this factor and some experimental work on this aspect might be fruitful

Jan 1, 1953

By D. G. Skinner, J. H. Griffiths, F. T. Williams, A. G. Withers

"The absence of homogeneity, in dust-clouds underground indicates the use of a method in which the volume of air sampled is an appreciable proportion of the total volume under consideration. Of the available methods, only the impinger and gravimetric techniques seem to comply with this requirement. In practice, greater efficiency of collection of the smaller particles is possible by the use of a gravimetric filter than with the impinger. For this reason if, as seems desirable, a standard method of sampling be sought, the adoption of a gravimetric technique is to be recommended.Provided that the amount of dust collected is reasonably large, the paper filter would seem to be preferable to the solid crystal type of filter on account of its greater convenience in use.Alternative methods of sampling are desirable to cover the wide range of practical conditions."

Jan 1, 1947

By M. J. Russell, W. E. Stephens, D. B. Mohamad, A. B. MacKenzie

Redox front processes in rocks are important in the context of both radioactive waste disposal and the development of orebodies. Results are presented from a study of the distribution of uranium and thorium and the natural decay series equilibrium about redox fronts in a granite at the Criffel pluton and Craignair quarry, Dalbeattie in southwest Scotland. The results are considered in the context of large scale uranium aqueous transport in the region and compared with those from a previous study of highly developed redox fronts at Pocos de Caldas, Brazil. Results show that the Criffel pluton has experienced a recent and rapid removal of uranium from the uppermost section of the granite whereas thorium has remained relatively immobile. The radium and uranium distributions indicate that diffusion processes probably control the distribution of radionuclides about the front. These processes are similar to those observed at Pocos de Caldas. The trends of concentration and activity ratio about the Dalbeattie redox front are less pronounced than those at Pocos de Caldas owing to the shorter time available for the process and the lower intensity of weathering at Dalbeattie.

Jan 12, 1992

The following procedure was used to determine cut-off grades: define the orebody profile; plan the stope layout and quantify the work involved; formulate equipment-performance norms; calculate unit costs; input process recoveries and metal prices; and calculate the cut-off grade. Use of the method is illustrated using data from a copper mining complex in India. Results from the study led to the following conclusions for underground mines in general. Cut-off dependent costs vary significantly with the stoping method employed, orebody thickness, the degree of mechanisation and the working efficiencies of the workforce and equipment. This applies even within the same deposit. Sub-level stoping and its variants can be operated at a lower cut-off grade than cut-and-fill and its variants. Thinner orebodies affect cut-off grades adversely, but with thinner orebodies very little further reduction in cut-off grade can be achieved once a certain minimum width has been exceeded. For the same stoping method and in the same mine the cut-off grade varies with the degree of mechanisation. Labour-intensive methods require higher cut-off grades. An allowance for working efficiency should be made when calculating cut-off grades. Higher process recoveries allow a significant lowering of cut-off grades

Jul 1, 1996

By S. K. Chaulya, R. S. Singh, B. B. Dhar

Two prominent local species, Dendrocalmus strictus (bamboo) and Saccharum spontaneum (kashi), and two exotic species, Cymbopogon citratus (lemon grass) and Vetiveria zizanoides (vetiver), were selected for growth trials on dumps at Mandaman, Chora, Mudidih, South Balanda and Ghugus. The climate at these sites is dry tropical and the surface soil layer a slightly acid to neutral sandy to clayey loam 10-11 cm thick, impoverished in major plant nutrients. After two years bamboo had grown the most, up to 325 cm in height, and contributed the greatest biomass, 638 g/m2 of plant. The local kashi species had a very good regenerative capacity, which was lacking in the lemon grass and vetiver. The grasses had very good soil-binding capacity and could also provide income if used as cash crops

Jun 21, 1905

By D. J. Wall, T. D. Johnson, M. T. Parry, G. R. Heath

In coal-fired power stations coal is ground to a fine powder and then transported pneumatically at 25-30 m/s velocity to remote burners. Wear of the conveying pipework is a well recognised problem and traditional lining materials are Nihard and basalt. In many cases these are being replaced by alumina tiles in order to improve life and reduce the frequency of replacement. A programme of laboratory testing of candidate aluminas with AIO, contents between 85% and 99-5% has been undertaken and the results compared with field experience. This gives confidence in the erosion tests, which were designed to replicate most of the field conditions. However, it has not proved possible to draw correlations between the laboratory erosion rates and any of the materials’ bulk properties. SEM, TEM and microanalysis studies have therefore been made in order to look for microstructural aspects that could be influencing erosion rates and it has been shown that intercrystalline cohesion, the matrix phase and porosity appear to have most influence on wear performance. It is necessary to quantify these microstructural parameters if reliable erosion performance is to be obtained. This paper was read at the Institute of Ceramics Annual Convention at the University of Durham, April 1988.

Jun 12, 1905

By T. Guyaguler

An analytical technique using computer-based multiple-regression methods was employed to determine the relation between the dust-producing index and inherent rock properties of typical samples from a coal-producing area, one of the aims being to provide a preliminary predictive tool for practical use. The investigation demonstrated that factors varied in their influence under different conditions, the brittleness:toughness ratio and the hardness being the most significant inherent properties with hardness showing the highest positive correlation coefficient

Jun 13, 1905

Discussion of the paper presented at the North Staffordshire Institute of Mining and Mechanical Engineers' general meeting held in Stoke-on-Trent, March 27th 1916, with Mr. John Gregory, President, in the chair, included contributions by Gregory J., Cadman J., Hartley J.W., Wain E.B. and Henshaw A.M., followed by the author's reply

Dec 1, 1916

By NA NA

In the third of its features on the new owners of the British coal mining industry, Mining Technology reports on the newest company in the field, Midlands Mining.

Jan 2, 1997

By A. C. Dunham, Y. D. Drakapoulos, P. W. Scott

The Pt and Pd occur alloyed with copper in small, irregularly-shaped grains, 0.25-5.0 micrometers in maximum dimensions. Grains of unalloyed native copper are also present. The grains are completely surrounded by or marginal to magnetite with inclusions of Ni-Fe-Co sulphides and native Ni-Fe, which is apparently a product of the serpentinisation process. Crystallisation of the Pt-Pd-enriched copper probably occurred at the same time, at low temperature, but the previous form of the Pt and Pd is unknown as no earlier PGE phases have been found. While Pt and Pd minerals are usually important in early-magmatic base-metal sulphides, Pt alloyed with Cu is extremely rare and apparently occurs only very late in the paragenetic sequence. A Cu alloy with Pd dominant over Pt and only minor amounts of other elements appears not to have been reported

Jun 14, 1905

By R. W. Ruddle

The advent of new methods of roasting, “flash roasting and fluidisation”, which are now under development, combined with the use of oxygen-enriched air, may markedly increase the SO2 content of roaster smokes. Skogmo suggests that the production of smokes containing as much as 50 per cent SO2 should be feasible. The use of flash smelting processes may well enable a similar increase in the SO2 content of smelter smokes to be made. In this event the recovery of sulphur would be greatly cheapened and the process might well be much more economic, even if allowance is made for the cost of generating the oxygen

Jan 1, 1953

By V. E. Ross

A comparison was made of three methods for determining the contributions of true flotation and entrainment during batch flotation tests. In the first method size-by-size recoveries are measured in both the presence and the absence of a collector, a frother being present in both tests. In the second method the mass of solids and water recovered after a chosen time of flotation is varied by changing the rate of froth removal and the depth of the froth. The third method uses a transfer factor to describe the classification of solids and water, and hence the changes in the composition of the pulp, during a single flotation test. Batch flotation tests were carried out with artificial mixtures of pyrite and gangue, the amount of floated material recovered being calculated according to each of the three methods. The discrepancies betweeen the calculated amounts are analysed in terms of the assumptions that are made for the various methods and the most suitable conditions for the application of each method are identified

Dec 1, 1991

By K. El-Barawi, Hussein M. Kamal

Chlorination was performed of iron-rich chromite ore from Barramyia, United Arab Republic (UAR), together with its concentrate. The effects of change of grain size, chlorine gas flow rate, time and temperature were studied. The extent and mechanism of chlorination were followed through chemical and structural analyses of the feeds and complete chemical analysis of the chlorination products. By conducting the chlorination process for short periods at 600°C or lower temperatures, products having high Cr-Fe ratios suitable for ferrochrome production can be obtained.

Dec 1, 1971

By L. Wade, R. Wang, M. A. Horton

Laboratory methods to find the mechanical properties of rock are inherently biased towards stronger strata, which best survive the sample preparation process. Geophysical techniques are not subject to such bias and may be used to predict mechanical properties rapidly and cheaply. Samples (151) were obtained from a borehole that had been comprehensively geophysically logged. The mechanical properties of the samples were established in the laboratory and correlated with the geophysical responses of the strata from which they came. The results indicate that, for homogeneous strata at least, it is possible to predict the unconfined compressive strength reasonably well from sonic travel time measurements made in the field. Predictions of static Young's modulus may also be made from this data source, but with a lesser degree of confidence. A multivariate regression equation is presented which relates down-hole sonic travel time to unconfined compressive strength, depth and the frequency of fractures in the rock mass. This equation may offer potential for the prediction of the mechanical rock properties of fractured and layered strata.

Jan 4, 1993

By A. G. Waters, N. J. Bristow

A comparative study was made of an untreated and a heated haematite ore and a sinter produced from a feed consisting of 100% ore, to study the influence on reduction behaviour of sinter bonding phases such as SFCA (silico-ferrite of calcium and alumina). Under low-temperature reduction conditions the order of increasing reducibility followed that of increasing porosity and surface area but under similar conditions at 900 degrees C the sinter exhibited higher reducibility than the ores even though the total porosity and chemical reducibility of the individual phases were lower. This behaviour can be explained in terms of the higher total porosity of the natural ore at low temperatures and the higher level of fine pores in the sinter at high temperatures due to the presence of SFCA, which acts to support the fine (c.0.1 micrometre) pores created by the reduction process. This leads to the conclusion that the main role of SFCA in sinter during high-temperature reduction is to maintain a high level of fine porosity. Some implications of this work for granule design and sintering practice are discussed

Apr 1, 1991

By R. Trueman, D. B. Tyler

Numerical modelling was used to determine the magnitude and direction of stresses around drives both adjacent to and distant from open stopes in the South Crofty tin mine. Modelling predicted that drives near the stopes are situated in a stress-relaxed zone. The peripheries of drives that are sited in solid rock away from the influence of stoping are in compression. Key-block modelling was used to determine the typical geometries of critical blocks and distinct element modelling was used to determine block stability. The conclusions derived from modelling fitted the observational data. This indicated that key-block theory is a valid tool for analysing the stability of roadways in the South Crofty mine. The support requirements for drives located next to stoped-out areas were formulated using a risk analysis approach to key-block formation. The results were compared with support guidelines derived using empirical design methods. Good agreement was obtained for the roofs of the drives but not for the sidewalls. The concept of a critical excavation width was formulated: once an excavation is larger than the critical size the length of rockbolts need not be increased as the excavtion dimensions increase. This may be the case in all rock mases.

Jan 4, 1993

By A. H. G. Mitchell

Gold-poor and gold-rich porphyry and epithermal gold-silver deposits of Caenozoic and Cretaceous age in the western Pacific and central and eastern Europe are confined to predominantly andesitic continental margins and island arcs. The arc volcanic rocks overlie a complex non-oceanic basement of stacked nappes, the uppermost of which is often ophiolitic. The emplacement of ophiolite triggered a reversal of tectonic polarity, subduction and arc magmatism. Andesitic volcanism and the formation of a strato-volcano were followed by the ascent of magma and porphyry copper mineralisation. Regional propylitic alteration came from convecting, predominantly meteoric fluids. Magmatic degassing caused advanced argillic alteration. This is commonly unmineralised in perched water tables, but may sometimes host high sulphidation gold or enargite gold at deeper levels within the propylitic zone. The onset of extensional stress after the andesitic volcanism allowed meteoric water to circulate to depths of 5 km or more, with consequent cooling of an ascending magma body at depth and the development of low sulphidation epithermal gold mineralisation near and immediately above the sub-volcanic basement surface. All andesitic arcs are mineralised. Regional controls on their ore potential include the level of erosion and geological features in the basement that focus the ascent of fluids. Differences between the mineralisation of the European and the western Pacific arcs may reflect the presence of older, more granitic basements in many of the European arcs.

Jan 12, 1992