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By C Munro, S Emery, M Flynn, K Tan

"AEROPHINE® 3418A Promoter is a well-known and widely used collector and is an industry standard for its excellent selectivity and efficacy in the processing of complex polymetallic sulfide ores, particularly those containing silver. Until now, however, it has not found widespread use in primary nickel flotation.In an effort to increase nickel recovery without compromising selectivity over iron sulfides, Western Areas Forrestania Nickel operation trialled the use of AEROPHINE® 3418A as a secondary collector at low dosage. A series of ON/OFF trials were conducted, with the finding that a very low dose of AEROPHINE® 3418A increased nickel recovery by 0.6 per cent compared to using xanthate alone.This paper provides a brief operational history and overview of the Forrestania operations, a description of the trial and an analysis of the results.Citation:Emery, S, Flynn, M, Tan, K and Munro, C, 2016. Aerophine® 3418A Promoter as a Secondary Collector to Boost Nickel Recovery at Forrestania Nickel Operations, in Proceedings 13th AusIMM Mill Operators’ Conference 2016, pp 145–148 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Oct 10, 2016

By G Brudek, P Elestedt

Schalker Eisenhütte und Maschinenfabrik GmbH, Nordic Minesteel Technologies and Bombardier Transportation have developed an evaluation tool that considers the main cost drivers of the rail, truck and conveyor haulage systems on the market today. In almost every circumstance, the advantages of a haulage solution are clear. A haulage system is outlined that is fully automated, including driverless operation, and that provides increased tonnage, safety and equipment life and reduced maintenance downtime. The haulage system has been implemented by a number of companies, including Codelco, LKAB and Freeport’s Grasberg mine. CITATION:Brudek, G, Elliott, R P and Elestedt, P, 2016. Moving mORE for less, in Proceedings Seventh International Conference and Exhibition on Mass Mining (MassMin 2016), pp 535–542 (The Australasian Institute of Mining and Metallurgy: Melbourne).

May 9, 2016

By O Rojas

The Telégrafo copper – gold deposit is located in the Centinela district of the Antofagasta region in northern Chile. Telégrafo is a porphyry copper deposit of Eocene – Oligocene age which has a total mineral resource in measured, indicated and inferred categories equal to 2.6 billion tonnes with an average grade of 0.38 per cent copper.Currently the project is in the prefeasibility study phase, including an infill drilling campaign to improve the knowledge of the deposit that should result in an improvement of the mineral resource classification. In this context was decided to review the classification criteria in order to optimise the drill hole density necessary to support the project.This paper presents an application of conditional simulation to evaluate the risk related to drill hole spacing, using a geostatistical approach that mimics the process of evaluation of resources from the perspective of geological modelling and grade estimation. The first step of the approach is the generation of conditional simulations using the available samples to generate several plausible scenarios of the deposit in terms of copper grades and geological units. These scenarios are considered as the unknown reality of the deposit and sampled by synthetic drill holes in order to replicate the geological model process and copper resource estimation. In this way it is possible to establish differences between the possible scenarios and the generated resource estimation models for several simulated drill hole spacing alternatives. These differences or errors can then be quantified in terms of estimated mean, metal content and tonnage over different production volumes.The resulting errors were useful in assisting the decision making process related to the design of drill hole spacing for each category of mineral resource in the Telégrafo project, and to redistribute the budget associated to the drill campaigns for the next stage of the project.

Aug 22, 2011

The Peko copper orebody is associated with a body of magnetite rock which it has partly replaced. The primary ore averages about 9 per cent. copper and 4 dwt. gold per ton and locally IS much richer. It consists essentially of chalcopyrite and unreplaced magnetite, with lesser amounts of pyrite, marcasite, pyrrhotite, cobaltite, bismuthinite, native bismuth and native gold. The earliest formed mineral is wolfram, and the latest formed is goethite, so that the temperature of deposition ranged from about 5000 C. to 1650 C. or lower.Oxidation extends to 270 ft., which is 100 ft. below the present water level. The oxidized ore consists of cuprite and native copper, and has replaced more or less massive chalcocite of a former zone of secondary sulphide enrichment. The present zone of secondary sulphide enrichment extends from about 270 ft. to 310 ft. depth.INTRODUCTIONThe Peko mine is about 6 miles south-west of Tennant Creek township in the Northern Territory, adjacent to a small outcrop of hematite rock that projects above an otherwise featureless "bull-dust" fiat.The copper-gold orebody being developed in this mine did not outcrop. It was first detected in 1950 by a surface diamond-drill hole (DDH.1), which intersected primary copper ore at a depth of 400 to 425 ft. This ore contained from 4 to 11 per cent. copper and 1 to 25 dwt. gold per ton. Since then a shaft has been sunk, and crosscuts and development drives have been opened on the 210..ft., 300-ft. and 400-ft. levels, which are also connected by winzes. Two diamond drill holes sunk from the 400-ft. level have intersected theorebody at about 450 to 460 ft., and a winze from the 400-ft. level intersected the lode from 445 to 500 ft. At this point it is 54 ft. wide, and averages 9 per cent. copper. More recently an inclined surface drill hole (Peko No. 1) has cut the lode at 856 ft. to 921 ft., equivalent to a vertical depth...

Jan 1, 1955

The nation of Fiji is located the South Pacific on the æRim of FireÆ some four hours flying time from the eastern sea board of Australia. It is a tourist destination situated on the main route from Australia to the Americas. Fiji is a developing country that has had a fewsetbacks but the country has able, happy people that are very resilient. Most importantly, the country is a safe destination for tourists and businesspeople as the local people are friendly, have good ethics, and most speak English. Fiji is a very willing nation, hungry for knowledge and advancement. The Fiji geological setting on the æRim of FireÆ, that runs from New Zealand across the Pacific through Fiji and on to Papua NewGuinea, has many large deposits of gold and copper. Fiji is an exciting destination for mineral explorers with discoveries of gold, silver, manganese, bauxite, iron and copper. Gold was first discovered in 1921 and the first two mines opened in 1935; one of which was Emperor Gold Mining Company (EGM) the other being Mt Kasi. EGM mines gold on the margin of the Tavua caldera, some 85 km north of the Nadi international airport. EGM has operated continuously for close to 70 years, producing approximately 6.9 million ounces of gold and has an underground reserve of 847 600 ounces with a total mineral resource of 12 335 600 tonnes at 10 g/t (as given in the Emperor Mines Limited Annual report 2003). The mineralisation in Fiji is very exciting and it is common to discover spectacular intersections and outcrops, which are typical for this type of epithermal narrow vein mineralisation, but be aware that the orebodies are variable and not easy to understand.

Jan 1, 2004

By S SSdbom

A comparison was made between chemical analysis and ocular mineral/rock classification in health-based risk assessment of historical mine waste produced between 1625 and 1975. Large parts of the mine waste are heavily weathered and secondary minerals are abundant. The field was divided into several areas from where composite samples were collected. Seventy-five mine waste samples were selected for chemical analysis (As, Cd, Co, Cr, Cu, Hg, Ni, Pb, V and Zn) and ocular mineral/rock classification (silicate, mica, granite/pegmatite, carbonate, iron oxide ore, sulfide ore, distribution between chalcopyrite, sphalerite and galena and distribution between pyrite and pyrrhotite). The waste has been produced in conjunction with mining a complex sulfidic ore with increasing iron oxide content (mainly magnetite) towards the northern part of the field. Elevated concentrations were found for Cd (average 26 mg/kg dw), Cu (average 3500 mg/kg dw), Pb (average 4100 mg/kg dw) and Zn (average 11 000 mg/kg dw). Large differences between average and median values indicated that the data was not normally distributed, ie the metals occur as discrete minerals (eg chalcopyrite, galena and sphalerite). The ocular classification indicated low carbonate content, chalcopyrite dominating over sphalerite and galena in most samples and an even distribution between pyrite and pyrrhotite. Both analytical and ocular mineral/rock classification data were combined into a common matrix that was evaluated using multivariate statistics. Principal component analysis (PCA) showed, for instance, that chromium and vanadium were mostly associated with harder minerals and rocks. PCA also indicated that a similar graphical picture could be obtained for chemical data and ocular mineral/rock classification data, respectively. The comparison indicates that ocular mineral/rock classification can replace or at least reduce the numbers of chemical analysis in health- based risk assessment of historical mine waste.

Jan 1, 2008

By H Rossiter, A Maddever, J Market, P Jeanneau, A Virani

It is generally acknowledged that the head grade of the world’s copper resources is declining. Accordingly, there is an increase in the volume of resource material being mined and processed to maintain copper production. This has led to increases in cost base accompanied by reductions in Life of Mine (LOM) Net Present Value (NPV). The higher tonnages of material mined are driven by increased quantities of lower grade material required to satisfy the short term mine model. In turn, this has brought an increased focus on sampling and assay methods, since any error associated with estimating the grade of each block and determining its correct destination serves to magnify the losses that will occur. Presently most open-pit copper mining operations use blasthole sample assays to feed their shortterm model. The problematic nature of blasthole sampling is well documented (Engström, 2017), particularly the poor timeliness of the data and the significant errors that are inherent to the technique. Methods to improve grade control, such as drilling a separate grade control grid, have been proposed but come with their own cost, logistical, and accuracy shortcomings. A recent development in grade estimation is the Pulsed Fast and Thermal Neutron Activation (PFTNA) downhole logging probe. Deployed on an efficient semi-autonomous platform, PFTNA is being aggressively adopted in the Australian iron ore industry. The technology provides in-situ elemental analysis of the geological formation, delivering high accuracy, high efficiency, near realtime data from a sizeable measurement volume. In this paper we consider the application of the technology to copper. Whilst there are several operational components to such a value proposition, we focus on the benefits of improved gradeestimation. A simulated copper mine is used to model the quantum of improvement expected from a reduced grade-estimation error, which reduces the likelihood of misallocating material to the wrong destination, which in turn increases NPV.

Nov 10, 2020

By Weber W

Methods of calculation of the reliability of process computers are getting more and more important. The paper presents long period observations of 21 process computers with online applications in the iron and steel industry. About 5000 failure events during 10 years have been systematically recorded and evaluated. On the basis of these long time observations it is possible to develop a probability model of the failure behaviour of process computers.This failure model is constructed with four different states of the process computer:Working phase, working phase with undetected reasons, repair phase, failure phase resulting from external influences.The model is defined by differential equations for the probability of one of these four phases. Long time observations show, that all of these four phases are closely correlated with the capa-city of a process computer, restarting without detection of failure reason, changes of programs and software, costs and time of repair. So the result of this analysis is a model of failure for process computers, which allows to predict breakdowns of process computers on the basis of external parameters.

Jan 1, 1985

The base metal ore from the hanging wall of White's orebody at Rum Jungle, N.T., is composed of copper and oth.er sulphides in a rock described as a phyllite,.which consists essentially of micaceous minerals with a little graphite.Fast selective flotation was obtained in acid circuit below pH 3·5. In neutral or alkaline circuit flotation was generally slow and selectivity very poor due to the ready flotation of part of the sericite. However, it was found that fast selective flotation could be obtained in neutral or alkaline circuit by either of two treatment methods following pre-conditioning in acid circuit; firstly by decanting or filtering a substantial part of the circuit liquor, and secondly by neutralizing with soda ash or lime, providing the collector was added before neutralizing. Otherwise pre-conditioning with acid brought about no improvement whatever.To explain this behaviour, three possible reasons for the flotation of part of the sericite are examined. There is evidence that some sericite floats because of thin films of either sulphides or graphite, but it seems likely such particles will float under all the conditions investigated.On the other hand, if it is assumed that part of the sericite floats because it is activated by metallic ions derived from the circuit water, a reasonable explanation can be given for the variations in flotation behaviour.INTRODUCTIONWhite's uranium orebody at Rum Jungle, N.T., sixty miles south of Darwin, is mined and treated by Territory Enterprises Pty. Ltd. (a subsidiary of Consolidated Zinc Pty. Ltd.), who are managers of the Rum Jungle project on behalf of the Australian Commonwealth Government.This ore contains a significant quantity of copper sulphides, and a flotation plant recovers a copper concentrate from the tailing remaining after the uranium has been extracted.In contact with the hanging wall of the uranium-copper orebody, a further mass of non-uraniferous sulphide ore occurs, and the present paper relates to the behaviour in flotation of this base metal ore.

Jan 1, 1959

By T Wambeke, J Benndorf

A risk-robust development of a heavy mineral resource requires an assessment of the geological uncertainty and spatial variability of the key factors impacting the mining and processing operation. Attributes of interest are the total heavy mineral grade, the slime content and the amount of oversized particles. The modelling of a mineral sand deposit presents two main challenges. Firstly, the exact location of the geological boundaries are obscure due to the complex interaction of the deposit formation processes. Secondly, the properties of interest exhibit a rather complex transitional behaviour across the so-called soft boundaries. Traditionally, the modelling exercise is restricted to a consecutive stochastic simulation of distinct geological facies and orebody properties. This results in different zones separated by hard boundaries, ignoring the typical transitional behaviour.This contribution presents an alternative approach which models the entire sand body as a single domain while accounting for the complex trends present. Error curves are used to infer covariance model parameters without the need of a prior removal of the trend. The principle is based on minimising the differences between empirical and theoretical errors resulting from two methods of prediction calculated for different rings of influence. The added value results from the unambiguous decomposition of the spatial variation into a deterministic trend and a stochastic residual. The trend model neither overfits nor underfits the data. The calculated residuals are thus unbiased and the uncertainty can be correctly assessed.The effort results in a characterisation of the resource uncertainty which provides a more realistic image of the spatial variability of the key properties in and across the geological domains of an existing heavy mineral sand deposit.CITATION:Wambeke, T and Benndorf, J, 2014. Optimal inference of modelling parameters to simulate complex trends across soft boundaries – a case study in heavy mineral sands, in Proceedings Orebody Modelling and Strategic Mine Planning Symposium 2014 , pp 73–84 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 24, 2014

By S Q. Zhao, J H. Wei

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation. The Xitieshan lead-zinc deposit is located in the north margin of the Qaidam Basin, Qinghai Province, China. It is one of the largest massive sulfide deposits in China and is supposed to be of the sedimentation-exhalation (SEDEX) type. Based on the main ore mineral and sulfur isotopic compositions in sulfides found in the wall rock, the S of the deposit is considered to originate from the mantle, but the fluid potentially mixed with sea water during the hydrothermal circulation exchange. The study of lead isotopes shows that the metallogenic material is characterised by the mixture of orogenic and upper crust sources. The lead isotopic signature of the wall rock is similar to that of the ore, which shows synsedimentary characteristics. According to the composition of the rubidium and strontium isotopic signature, the value of 87Sr/86Sr is lower than the average value of that in the crustal rock, which is larger than that of the mantle. Hence, the metallogenic materials of this deposit mainly originate from the crust, which is related to materials of volcanic rocks activation and migration of the deep hot circulating water. The process of the metallogenic fluid circulation shows continuous interaction with crustal material and lead to continuous enrichment of the ore forming fluids. From the study of the fluid inclusion microthermometry of the ore and the associated minerals combined with the C, H-O, Si isotopes, it is believed that the metallogenic fluid is mainly coming from the mantle or the deep magma chambers. The rising deep fluid then mixes with the sea water. The carbon dioxide escaping and mixing with sea water during the hydrothermal exhalation process leads to the rapid precipitation of the hydrothermal fluid to deposit metal. That is proposed as the principal formation mechanism of the Xitieshan deposit. Further studies are proposed, including obtaining geochronology data from this deposit.CITATION:Zhao, Z X, Wei, J H, Liang, S N and Zhao, S Q, 2015. Advances in research on metallogenic mechanisms for the Xitieshan sedimentation-exhalation lead-zinc deposit, Qinghai Province, China, in Proceedings PACRIM 2015 Congress, pp 487–494 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

By A Cheatle

GoldcorpÆs Musselwhite mine in north-western Ontario, Canada has in recent years become a world-class deposit. Initially discovered in the early 1960s by Alan and Harold Musselwhite, the then marginal mine eventually started production in 1997 and has to date produced 2.6 Moz of gold. Two million ounces of gold are currently classified as Mineral Reserve and a further 1.2 Moz of gold are classified in the Mineral Resource category for a total gold inventory approaching 6 Moz. Growth of the mineral inventory has been achieved through the successful implementation of strategic planning that sought to extend the mine life through discovery of additional economic zones and increased mined tonnages. Accelerated exploration activity commenced in 2001, at a time when gold price was at its lowest in decades. Focus was placed on building, developing and retaining a highly skilled geological team, maintaining purpose, conducting external reviews and developing a new geological model through research partnerships. Ongoing collaborative research between Lakehead University and Musselwhite mine has seen the development of new structural and geological models through post-graduate and academic studies. Research has included lithogeochemical, stable isotope and structural and metamorphic studies and has led to the evolution of a new mineralisation model (for the mine) and the recognition of brittle and ductile deformation regimes within the mineralised horizons. Exploration drilling continues to provide support for the new geologic model. Gold discoveries have extended known mineralisation 2.3 km along strike from mineral reserves and laterally into parallel zones. The exploration potential to further increase production rates, Mineral Reserves and Resources remains very positive and increases in overall gold inventory are likely. Musselwhite mine has significantly exceeded initial projections for a ten year life-of-mine and a marginal existence.

Jan 1, 2009

By Tzung-mow Yao, S Ki, J Word, J Vinson

Properly designed evapotranspirative (ET) cover systems can greatly reduce the amount of infiltration and groundwater recharge (deep percolation) into potential acid generating mine waste. In arid and semi-arid environments, infrequent precipitation, low measurable subsurface fluxes, spatial variability within mine waste and cover material, and evapotranspiration from below the cover system create challenges to monitoring moisture flux in these systems. Sloped ET single-layer (monolayer) cover depths and a variety of reclamation treatments are being studied at a copper tailing impoundment in Arizona, USA. To monitor the performance of different ET cover systems in response to precipitation patterns, four different test plots consisting of two different cover depths and two different vegetation densities were instrumented with heat dissipation sensor nests. The sensors measure the soil water pressure potential and allow hydraulic gradients to be determined within and below the cover systems to depths of 180 cm. Three replicate sensor nests were installed in each test plot to account for variability in materials and test plot treatments. Data collection occurs twice daily and is ongoing. Weather during the 26-month monitoring period was characterised by two months of greater than normal precipitation followed by nine months of normal precipitation and 15 months of abnormally dry conditions. Monitoring data indicate that deep percolation occurs in response to periods of extended precipitation, however, drying was observed to depths of six feet below the surface in all test plots. Using conservative assumptions regarding tailing hydraulic properties, one-dimensional downward flux predictions based on the monitoring data indicate very low (Additional long-term monitoring and installation of deeper and replicate monitoring sensors into tailings without cover systems are recommended to evaluate the long-term ET cover system performance and develop a better understanding of deep percolation rates at the sites.

Jan 1, 2003

By Fletcher A. E W

Ever since it made its debut in 1962, in the form of a Robbins 31R, the raiseborer has become an accepted tool in the mining and civil construction industries. The first raiseborer to be used in the Witwatersrand goldfields made its appearance in 1968. This was a Robbins 42R which could raisebore 185m deep holes to 1,22m diameter. From 1968 to 1973 capability increased with the introduction of first the 61R, then the 71R and finally the 83R, which could raisebore 610m deep holes to 3,66m diameter. This created a demand for larger holes but the cost of bigger, more powerful machines requiring larger, stronger drill pipe, cutters and other accessories was prohibitive. To avoid replacing existing models such as the 71R, and in order to increase their capability, the concept of reaming in two stages sequentially was developed jointly by a German drilling equipment manufacturer, Wirth, their South African subsidiary, Transbor, and a local contractor, Rocbor Raiseboring and Mining Contractors. The result, the Sequential Reaming Head, proved most successful and existing machines, normally limited to 2,44m diameter holes, could now ream to 3,66m diameter. This created a demand for even larger holes. In order to maximise the use of the sequential reaming head to meet this demand the HG330, and subsequently the HG330SP raiseborer were developed. Using a 4,26m/6,02m cutting head, these machines have raisebored holes 1000m deep in hard rock. The raise- boring of the first major hole to be excavated by this combination, the 484m deep x 6,02m diameter surface shaft at Premier Mine is described. Reference is also made to six other shafts which have been completed or are under construction.

Jan 1, 1987

The segment of the Upper Cenozoic volcanic chain (CVZ) located on the western border of South America (16-28¦S lat.) is constituted by an association of strato- volcanoes and ignimbrite sheets, with high K calco-alkaline affinities. Strata-bound volcanoes, mainly of andesitic and dacitic composition, present along the whole chain, and various hydrothermal alteration zones, on the slopes and in the cores of eroded volcanic structures. Some of these altera- tion zones bear epithermal precious metal ores and sulphur deposits, which at present are being exploited. The studied Salar de Gorbea area, located in the Andes of northern Chile (25-26¦S lat.) contains a numer- ous group of Miocene to Quaternary stratovolcanoes, with advanced argillic and extreme silicification hydrothermal alteration in their cores and on their slopes, favoring the formation of great volumes of alunite within altered zones and sulphur deposits in the higher parts of the volcanic edifices. Simultaneously, siliceous hydrothermal breccia of the phreato-magmatic type, with evidences of hydromag- matic explosions are recognizable, allowing, in some cases, the ascent towards the surface of rock fragments belonging to the Paleozoic pre volcanic basement. Radiometric ages obtained in some of the hydro- thermal alteration zones (K-Ar in alunite) are slighty young- er than the unaltered rocks which constitute the strato- volcano. Trace element (Hg, As, Sb, S, Au, Ag, Cu, Pb, Zn, Mo) patterns in orientative rock samplings show that the studied alterations zones correspond to high sectors of the cpithermal system, without evidences of metallic minerali- zation on surface. The weak erosive action due to the ex- tremely and climatic conditions in this segment of the Andes, has not allowed the cropping out of deeper areas of the hydrothermal alteration zones, in contrast to other Miocene more eroded volcanic edifices and Miocene vol- canic terranes of the Andean Range.

Jan 1, 1987

In an area north of Mowit Ica chip sampling of limonitic outcrops on a regional scale led to the investigation of a number of areas considered to be geochemically anomalous for copper and zinc. These areas were closely gridded,end where geochemical results were favourable, they were subsequently drilled or ro¦titeaned Che results indicated that for copper Lne anomalies were mainly associated wiL_ ironstone formed in areas of faulting. is suggested that copper is able to move considerable distances by ground water movement and is likely to be fixed under conditions of low pH. The movement of zinc is more difficult to explain but it appears to have an affinity for iron and is only deposited in areas having a high pH (i.e. doioiirific scdimet=Cs).

Jan 1, 1973

By G Richmond, J R. Glen

Western Metals Mt Gordon Operation is a copper mine and processing plant situated 120 kilometres north of Mt Isa. The unique Mt Gordon copper process utilises a whole of ore acid/ferric pressure leach to produce copper cathode from the Esperanza massive sulfide copper orebody. Esperanza ore contains chalcocite, covellite and minor chalcopyrite hosted in a massive pyrite matrix. These ore stocks will be depleted in late 2003. Recently the process circuit has been upgraded to allow the treatment of lower grade Mammoth ores. These include the installation of a ball mill to complement the existing SAG mill, a single stage rougher flotation circuit and a tailings thickener. The leach bleed neutralisation plant was also upgraded at this time. Commissioning of these new circuits occurred in March 2003 and involved all the challenges of ensuring current production levels were successfully maintained while new process steps were incorporated into the whole circuit. This paper explains the background flow sheet of the patented Mt Gordon process and the reasoning behind the enhancements required for an already successful copper leaching circuit. Included are discussion of the influences of the new ores on individual process components such as comminution, leach chemistry and solid/liquid separation. Longer term ore processing options are also discussed.

Jan 1, 2003

By S Tyrrell, B Jackson, K Matson

Northern Star Resources Limited Jundee Gold Mine in Western Australia operates a comminution circuit that consists of a primary crusher, 3.85 MW semi-autogenous grinding (SAG) mill, 1.8 MW ball mill and pebble recycle crusher. In 2017, a secondary crushing circuit was installed to remove the SAG mill throughput bottleneck and increase production of highly competent underground ore from 1.35 to a minimum of 1.7 Mt/a.This paper discusses the findings from the trial phase, the circuit design, project delivery, site optimisation, and the plant performance.CITATION:Matson, K, Tyrrell, S and Jackson, B, 2018. The application of secondary crushing at the Jundee gold mine, in Proceedings 14th AusIMM Mill Operators' Conference 2018, pp 485–496 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 29, 2018

By Golding S. D, Price P. L

The Early Permian Aldebaran Sandstone is the main hydrocarbon reservoir in the Denison Trough. Contained hydrocarbon gas has a wet gas index (C1/CI - C4) of between 0.87 and 0.97 (N=10), and constituent methane has 813CPDB values ranging from -51.5 to -36.2% (N=10). These values clearly indicate that the gas is thermogenic rather than biogenic. Considering the predominantly humic nature and maturity of all organic source material for the gas, the methane 813C values are anomalously low, with typical values for humic methane present in natural gas formed at similar maturity levels significantly higher at -26 ¦ 5%o. This suggests that, in addition to disseminated organic matter in underlying marine mudrocks of the Cattle Creek Formation, methane substantially more depleted in 13C was derived from coal seams of the Reids Dome beds, a thick coal measure sequence which underlies the Cattle Creek Formation and, in the south, the Aldebaran Sandstone. This methane is likely to have S13C values of between -75 and -40 oo, based on the known isotopic composition of dry gas trapped in humic coals of similar rank in the Sydney Basin and elsewhere in the Bowen Basin. In addition to the low methane S13C values, the contribution of coal seam methane would explain the fact that, (1) methane S13C values do not show the normal increase with decreasing gas wetness, and (2)013C%o (ethane-methane) values do not show the expected decrease with decreasing gas wetness. The presence of co-existing, isotopically heavy CO2 (S13C = +2.0 to +3.4%0, N=3) in the Glentulloch and Merivale Fields is consistent with the view that natural gas in the Aldebaran Sandstone is in part coal seam derived.

Jan 1, 1991

By J Pan, Q H. Li, D Q. Zhu, C C. Yang, X Wang, Z Q. Guo

Al2O3 in natural iron ores generally occurs in goethite, kaolinite, gibbsite, hematite and iron carbonate. When the content of alumina in sinter increases from 1.11 per cent to 3.50 per cent, the reducibility of sinter decreases with the addition of four different types of alumina. When gibbsite and kaolinite are added, the low temperature reduction disintegration (RDI+3.15 mm) of sinter increases with the increase of Al2O3 content in the range of 1.5 per cent to 3.5 per cent. Furthermore, when adding pure reagent alumina, the increase of Al2O3 content in the range of 1.5 per cent to 3.0 per cent will increase the RDI+3.15 mm of sinter. The addition of ferric oxide–alumina spinel with the Al2O3 content in the range of 1.5 per cent to 2.5 per cent, also increases the RDI+ 3.15 mm of sinter. The influence difference is results from the change of the mineral composition and microstructure of sinter because of the occurrence state of Al2O3. Under the condition that Al2O3 content of sinter is 2 per cent, the porosity of sinter with kaolinite is 37.26 per cent, and the shape is irregular. When gibbsite and ferric oxide–alumina spinel are added, the porosity of sinter is about 16 per cent, and the pores are round. When pure reagent alumina is added, the porosity of sinter is 17.49 per cent, and the pores are regular and small. When kaolinite, gibbsite and ferric oxide–alumina spinel are added, platy calcium ferrite is mainly formed in the sinter, and some of it is columnar calcium ferrite. On the other hand, when pure reagent alumina is added, in addition to platy columnar calcium ferrite, acicular calcium ferrite is also formed in the sinter.

Nov 8, 2021