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By Jerry W. Ramsey

The Bureau of Mines examined a low-, a medium-, and a high-volatile Pennsylvania anthracite by densimetric methods using four mesh si.s of each anthracite. Using high-pressure mercury the macropore volumes and distributions of these pore volumes determined, densities in mercury were calculated, and specific pore vo1.r. ware obtained from these mercury densities in conjunction with helium densities. The helium densities were also used with the ultimate analyses of these anthracites in calculating structural parameters by statistical densimetric methods. The effect of 106 or 108 rads of gamma irradiation in the presence of air and in vacuum upon the properties studied with two mesh sizes of each anthracite. Results of the statistical densimetric method seem to show some breakdown of condensed ring structural units at the lower irradiation level, with subsequent polymerization at the longer period of gamma irradiation. The structural parameters obtained also indicated that in going from high- to low-volatile anthracite, either the number of condensed rings per structural unit increased, or the degree of polymerization increased.

Jan 1, 1965

By Albert L. Toenges, Theodore R. Jolley

"The development of Alaska depends on the existence of an adequate fuel supply in the Territory. The need to investigate coal deposits was recognized as early as 1911, when the first investigations were conducted in Alaska by engineers of the Bureau of Mines.Conditions existing in the Bering River and Matanuska coal fields, as found by Dr. Robert A. Holmes, former Director of the Bureau of Mines, are described by the Honorable W. L. Fisher, former Secretary of the Interior.4/Following Dr. Holmes' investigation, a party of Bureau of Mines engineers headed by R. Y. Williams visited the Bering River field in 1912 in cooperation with the Navy Department. A detailed examination was made of the Bering River field, and 855 tons of coal were mined from three prospects on Trout Creek. This bulk sample was delivered to the Navy for steaming and other tests. A description of the work of the field party and results of tests of the coal by the Navy Department and the Bureau of Mines has been published.During 1920 to 1922, the comparative steaming properties of Alaska bituminous coal, lignite, and wood were determined by the Bureau of Mines.6/In the early 1920's, the Bureau of Mines established a coal laboratory at Anchorage, where Alaska coals were analyzed. Subsequently, this laboratory was transferred to the Alaska Railroad and was used by the railroad for coal and other tests.Since 1910, the Bureau of Mines has made analyses of coal from Alaska, and the results of these analyses have been published.7/ The coal analyzed was obtained from mines, tipples, delivered lots, and face samples of coal deposits, and these samples were obtained in the field by engineers of the Bureau of Mines and geologists of the U. S. Geological Survey.Because of the shortage of petroleum and petroleum products in Alaska during the war, low-temperature carbonization assays of coals from the Broad Pass, Forty-Mile, Matanuska, and Nenana fields were made by the Bureau of Mines, and the results were published.Coal beds in the Matanuska field contain interbedded impurities in the form of shale, clay, and bone. The coal should be cleaned mechanically to obtain a satisfactory fuel. A coal-preparation study of bituminous coal from the Eska and Evan Jones mines was made by engineers of the Bureau of Mines, and the results were published.9/Coal production in Alaska is less than the requirements, and coal is imported to make up the deficiency. The cost of this imported coal is high. Greater production is necessary to supply coal for Army installations, industry, and homes. At present, there is only one bituminous coal mine (Evan Jones) in Alaska. The output of this mine is used at Fort Richardson, Anchorage, and by the Alaska Railroad. The economic life of this mine is limited (reported to be 3 years), and its closing, because of accidents or exhaustion, will cause great hardship to the inhabitants of Alaska. There is need to develop new, modern mines for the production of bituminous coal in the Matanuska field."

May 1, 1949

By Robert H. Bedford

The New Almaden mine was discovered in 1824, and since that date production of quicksilver has exceeded 1,000,000 flasks. Because of this high production record, the New Almaden area was, upon passage. by Congress of the Strategic Minerals Act of 1939, immediately considered by the Bureau of Mines as a promising location for exploration. In 1941, the Federal Geological Survey undertook a survey of the entire district. R. R. Trengove, an engineer of the Bureau of Mines, made a preliminary study for a project in 1942, and in August 1943 the Bureau, in close cooperation with the U. S. Geological Survey, began the development project described herein. The Bureau of Mines drilled 36 holes, totaling 6,807 feet of diamond drilling, along the contact between the serpentine and Franciscan, sandstones and other sedimentary formations. The ore bodies are found along this contact and occur in the carbonate-silica rock. This report briefly describes the location, history, and ore deposits of the property. The recent operations are outlined, and the work performed by the Bureau is explained in detail.

Jan 1, 1950

By Jack D. Ramsdell

The objective of this investigation was to make a preliminary evaluation of titanium-vanadium-zirconium, alloys using room-temperature tensile properties as criteria for selecting promising alloys for future critical studies. Arc-melted titanium-vanadium-zirconium alloys ranging in composition from 5 to 20 a/o (atomic-percent) vanadium and 5 to 30 a/o zirconium, were investigated to evaluate hardness, hot workability, and room-temperature tensile properties. Metallographic examination coupled with hardness measurements were used to follow structural changes and aging response. Room-temperature tensile properties were criteria for evaluating mechanical and engineering properties of the alloys.

Jan 1, 1960

By Thomas V. Falkie

The new international fact of life that has emerged in the 70's is that foreign energy sources can no longer be considered either reliable or low in price. As a result, the United States is turning its full attention to its domestic energy resources. The figures about proved domestic reserves are often used to reassure us about the Nation's energy future: assuming a 50 percent recovery factor, there are at least 219 billion tons of recoverable bituminous coal and lignite, of which 31 percent is available by surface methods; proved reserves of crude petroleum and natural gas liquids total 34.3 billion barrels and 6.4 billion barrels, respectively. There is also about 4 billion tons of recoverable anthracite coal, a premium low-sulfur fuel of high heating value, which is all but priced out of the market because of the high costs of producing it. Total fossil fuel resources are even larger, although there are no guarantees concerning how much might become usable, and when, and at what cost. The figures, however, are impressive. They include the equivalent of about 200 billion barrels of oil potentially recoverable from high grade oil shale; 100 billion barrels in "heavy oil" deposits; and the equivalent of 25 to 35 billion barrels of oil in domestic deposits of "tar sands," and substantial quantities of conventional oil and gas resources. There is also the prospect of a significant increase in electric power generation

Jan 1, 1975

By Henry C. Meeve

This report describes work done in the Creede Mining district, Mineral County, Colo., in 1965-66 as a part of a Bureau of Mines study of the silver production potential of the United States. The ruining history of the district is briefly covered, and representative former and current mining operations are described. Mining and milling costs of the Emperius Mining Company's operation are given in some detail as being representative of the cost of mining typical Creede ore bodies under current technology. An estimate of the silver reserves and resources of the district is presented, subject to many uncertainties stemming from inaccessibility of old workings, lack of mining records, and low level exploration activity, all of which limit the opportunity to accurately evaluate ore potential. The report concludes with an analysis of future silver production trends in the Creede district. An increase of silver production to as much as I million ounces yearly is projected, possibly starting in 1969. As long as ore bodies in the zone of enrichment, in which silver is a major constituent, contribute a substantial part of Creede production, silver price will affect overall production rates appreciably. As the richer are bodies become depleted, an increasing portion of production again will be coming from primary sulfide ores in which silver is a byproduct of lead and zinc. When this occurs, the level of silver production will be governed chiefly by lead and zinc production and prices and can be expected to decline to the 1960-66 level, which amounts to an average of 240,000 ounces per year.

Jan 1, 1968

By Steven A. Fechner

In 1984 the Bureau of Mines cunducted mineral investigations of specific sites within the Yentna Mining District. One hundred eight placer and rock samples were taken. Reconnaissance placer samples were collected from drainages in the Talkeetna, Susitna, and Yentna River basins. The highest placer gold values were found in the historic placer gold producing creeks of the Cache-Peters Creek area. Samples taken from an outcrop in the Middle Fork of Iron Creek in the Talkeetna Mountains contained previously unreported high lead, zinc, and silver values.

Jan 1, 2011

By A. W. Henderson

This investigation was performed to develop chlorination methods for extracting tungsten from scheelite and from an ore concentrate containing a mixture of scheelite and wolframite. On a laboratory scale with proper temperature control using elemental chlorine, over 90 percent extraction of tungsten is achieved. Carbon and sulfur dioxide were studied as reducing agents. The effects of salts such as calcium fluoride and sodium chloride were studied as additives to increase extraction and to reduce impurities in the volatile tungsten chloride product. Sodium chloride reacts with ferric chloride to form a nonvolatile double salt; whereas the chlorides and oxychlorides of tungsten are volatile and consequently condense free of iron. Separation of tungsten from molybdenum from an equal molar mixture was successful by fractionally distilling the oxygen-free chlorides and by selectively condensing the oxychlorides. Yields of 60 and 80 percent, respectively, were achieved for separating the less volatile tungsten chlorides containing less than 0.5 percent molybdenum.

Jan 1, 1965

By F. F. Aplan, J. A. Gutierrez-Rodriguez

"Contact-angle and flotation techniques were used to evaluate the influence of oxygen - both that inherent in the coal and that introduced by ambient temperature, aqueous oxidation - on a wide range of coal ranks. Oxidation was found to decrease the hydrophobicity and floatability of coal; with the effect being minor for coals of high rank but becoming increasingly important as the rank of coal is reduced. As an approximation, oxidation makes a coal behave as if it were one of lower rank. Frother only flotation' of coal· correlates with the captive-bubble contact angle whereas when oil is used as a collector, the flotation appears to follow the pattern shown by the water sessile drop on a fresh, un-reagentized coal surface. Coal recovery lost through oxidation may often be recovered by use of a variety of collectors, of which No. 2 foe! oil is among the best of those reagents tested. A simple alkali-extraction test may be used to estimate the influence of oxidation on coal preparation processes and use.INTRODUCTIONThe hydrophobicity of coal is not only a function of its rank but also of the extent of oxidation of the coal during and subsequent to its formation. Weathering and oxidation processes may proceed in-situ for coal deposits that outcrop near the earth's surface, or the oxidation of the coal particles may occur during mining, stockpiling or processing. Such oxidation, whether it affects the bulk-coal sample or on1y a thin outer layer on the coal surface, can dramatically influence the wettability of the particle and hence such processes as flotation, filtration, flocculation and dispersion.Many of the studies made on the oxidation of coals ·were designed to study its effect on flotation, coking or pyrolysis. The. present study 'is directed exclusively toward the effect of oxidation on the hydrophobicity and floatability of the coal. One of the first studies of the effect of oxidation on coal flotation was that of Sun [l] who found that as oxidation proceeds, coal becomes progressively more hydrophilic. Low-temperature oxidation (100-150°C for 250 h) generally lowered the coal floatability with an oily collector only slightly, but more extensive oxidation (200- 3500 C for 250 h) reduced coal floatability seriously. Sun also found that cationic amines were effective collectors for the oxidized coal which infers that oxidation makes the coal more negative in solution. He attributed the loss of floatability to be due to the accumulation of water-insoluble oxidation products at the coal surface. Gayle et al. [2] found that oxidation adversely affected coal flotation when an aliphatic-alcohol frother was used, though a small amount of oxidation appeared to improve the floatability of some coals using a kerosene-pine oil, collector-frother mixture in pilot-plant testing. Prolonged oxidation adversely affected the flotation recovery of the coals tested, the effect being more pronounced when an alcoholic-type frother only was used. They also noted that the reduction in floatability of lower rank bituminous coals was more affected by oxidation than was that of higher rank bituminous coals."

Jan 1, 1989

By V. R. Miller

The Bureau of Mines investigated methods for testing the tensile and sheer strength of cast specimens of bulk solder and of soldered joints in order to increase the strength and extend the useful temperature range of soft solders. A spread-area test for determining the wettability of solder on copper surfaces was developed. Mannitol was used as a flux in spread tests to control spreading and to avoid plating, etching, and other side effects of regular fluxes. Data on commercial and high-purity solders obtained by these methods show more consistency than those reported by others from similar tests.

Jan 1, 1967

By Robert K. Koch

The reactions of alumina and alumina monohydrate with wet hydrogen fluoride gas were studied by the Federal Bureau of Mines to determine the feasibility of producing commercial-grade aluminum fluoride from offgases generated by pyrohydrolysis of siliceous fluorspars. The test results showed than an aluminum fluoride reactor operating at maximum efficiency could retain 96 percent of the fluorine contained in off-gases generated by pyrohydrolysis of siliceous fluorspar. The requirements are a reactor temperature of 200° C. and a reactor entrance gas containing 5 mole-percent hydrogen fluoride. Partial pressure equilibrium constants were determined for the reaction of alumina monohydrate and wet hydrogen fluoride gas from 200° to 350° C. and for the reaction of alumina and wet hydrogen fluoride gas from 350° to 700° C. Both reactions are reversible, and they proceed in directions that are dependent upon the temperature and the relative HF:H2O concentration. Logarithms of the equilibrium constants were used to plot the reaction isobars; these can be used to calculate the theoretical maximum efficiency of a reactor processing wet hydrogen fluoride gas between 200° and 700° C. The theoretical maximum efficiency decreases with increasing temperature.

Jan 1, 1961

By R. K. Koch

The Bureau of Mines produced several series of titanium castings in order to investigate the feasibility of producing commercial-grade titanium castings in bentonite-bonded olivine or zircon sand molds. The use of these molds for titanium casting was investigated as a possible alternative to the industrially used rammed graphite process. Parameters investigated were mold mixtures, mulling, gating, venting, drying, and mold washing. The investigators found that castings with superior ductility and fatigue life, compared with rammed graphite castings, could be made by fume-free pro-cesses in molds bonded by western bentonite, using either olivine or zircon sand. Zircon molds were satisfactory for both light-and heavy-sectioned castings. However, olivine molds were suitable only for light-sectioned castings because the mold-metal reaction became excessive during the pouring of heavy-sectioned castings.

Jan 1, 1981

By Noel N. Moebs

Five LANDSAT lineaments in the coal mining region of southwestern Pennsylvania were investigated by the Bureau of Mines to determine their geologic character, relation to subsurface conditions, and the means of discriminating one from another. The investigation included earth resistivity and very low frequency (VLF) electromagnetic traverses, soil moisture sampling, and a correlation with coal mine roof conditions. The lineaments could not be detected by the methods used, suggesting that they might be a surface phenomenon unrelated to subsurface geologic structures or roof stability in coal mine workings beneath.

Jan 1, 1987

By L. B. Pankratz

High-temperature heat-content values of pure lutetium sesquioxide and dysprosium sesquioxide were measured over the temperature range from 298° to 1,800° K. Similar data for cerium sesquioxide were calculated from measurements of a mixture of cerium sesquioxide and dioxide and known values for cerium dioxide. The results for lutetium sesquioxide are regular. Dysprosium sesquioxide has a minor thermal anomaly near 1,590° K, the extra heat absorption being 220 cal/mole, Hexagonal cerium sesquioxide undergoes a transformation around 1,050° K, which is only slowly reversible; consequently results were obtained for both the low- and high-temperature varieties. The original heat-content data are reported, and smooth values of heat content and the corresponding entropy increments are tabulated. Equations were derived to represent the heat-content values.

Jan 1, 1963

By William R. Wayment, David E. Nicholson

A modified percolation - rate test is proposed for use in determining flow rates through hydraulic backfill ; in contrast to the conventional test , a percolation- rate versus void - ratio relationship is established . requirements and a detailed test procedure are described . Equipment Results of a conventional test are compared with those of the proposed modified test . The proposed modified test method yields more accurate , realistic , and usable percolation- rate ( permeability ) data . The significance of obtaining accurate percolation rates for use in analyzing waterflow through hydraulic backfill is discussed .

Jan 1, 1964

By Jacqueline A. McClaskey

The U.S. Bureau of Mines (USBM) Information and Analysis Directorate collects worldwide data on virtually every commercially important nonfuel mineral commodity. These data form the base for tracking and assessing the health of the minerals sector of the U. S. economy. The USBM's data collection activity was instituted by the 47th Congress in an appropriations act of August 7, 1882 (22 Stat. 329), which placed the collection of mineral statistics on an annual basis. The most recent authority for the USBM survey activity is the National Materials and Minerals Policy, Research and Development Act of 1980 (Public Law 96-479, 96th Congress). This act strengthens protection for proprietary data provided to the U.S. Department of the Interior by persons or firms engaged in any phase of mineral or mineral-material production or consumption.

Jan 1, 1994

By Maria I. De Rosa

Table 19 and figure 7 show the number of fires and fire injuries for surface metal/nonmetal mines by state during 1990-2001. Table 19 also shows the injury risk rates, employees' working hours, and lost workdays. A total of 79 fires occurred in 16 states during 1990-2001 for these mines. Forty-five of the fires caused 44 injuries and 2 fatalities (including 9 fires and 7 injuries involving contractors). The yearly average was 6.6 fires and 3.7 injuries. Sixty-five fires with 31 injuries and 2 fatalities occurred at metal mines, and 14 fires with 13 injuries occurred at nonmetal mines. The Ewhr value was 546 x 106 hr (In = 0.016), and the LWD value was 13,134. Nevada and Arizona had the most fires (19 fires, 10 injuries, and 1 fatality; and 19 fires and 11 injuries, respectively). They were followed by Minnesota (11 fires, 4 injuries, and 1 fatality) and Alaska (6 fires and 4 injuries). Of these states, Alaska had the highest injury risk rate value (In = 0.079). Table 20, partly illustrated in figure 8, shows the number of fires, fire injuries, fire fatalities, risk rates, employees' working hours, and lost workdays by time period. The number of fires increased during the second period, then decreased during most of the remaining periods. The number of fire injuries decreased during most of the periods (a small increase is seen during the last period), accompanied by a decline in employees' working hours during most of the periods (a small increase is seen during the third and fourth periods). The In values follow patterns similar to those shown by the number of fire injuries. Tables 21-26 show the number of fires by ignition source, method of detection and suppression, equipment involved, location, and burning material by time period. Figure 9 shows the major variables related to fires for 1990-2001. Table 27 shows the number of fire injuries per number of fires causing injuries and total fires by year, ignition source, equipment involved, and location.

Jan 1, 2004

By H. M. Cooper

Many analysts have had difficulty in obtaining accurate and consistent determinations of the volatile matter in low-temperature coke when the usual standard method for coal was followed. The tendency is toward too-high results, due to mechanical losses which are extremely difficult to avoid or control. With cokes there also may be an error due to excessive oxidation of the fixed carbon. Much of the earlier experimental work on the volatile-matter determination in coal, such as that of Parr, Fieldner and Davis, and others, has been on the effect of time, temperatures, shape and size of crucibles, method of applying heat, and type of furnace, all of which data has evolved the present A.S. T. M. standard method for volatile matter in coal and coke. It is not the purpose of this investigation to deal directly with the above phases of the procedure, but rather to study some of the factors affecting the results in those types of fuel which give erroneous results due to mechanical losses. This mechanical loss is usually designated as "sparking." There are two kinds of sparks or incandescent particles which may appear: particles of soot from partially condensed carbon from the burning gases, and unburned particles of the material itself which escape. The first type does not affect the accuracy of the volatile matter results, and is therefore negligible. The second type, however, causes appreciable loss and results in showing higher volatile percentages than actually exist.

Jan 1, 1932

By R. V. Ramani, R. Stefanko, G. W. Luxbacher

C THRM 1 C CALCULATION OF MINE HEAD LOSSES FROM ALTIMETER SURVEY DATA TURN 2 C PENNSYLVANIA STATE UNIVERSITY - MINERAL ENGINEERING DEPARTMENT THRM 3 C THRM 4 C THRM 5 C THIS PROGRAM CALCULATES PRESSURE LOSSES USING THERMODYNAMIC RELATION- THRM 6 C SHIPS BASED ON POLYTROPIC FLOW BETWEEN STATIONS. FOR REFERENCE SEE THRM 7 C "A NEW TREATMENT OF MINE BAROMETER SURVEYS" BY M. J. MCPHERSON IN THRM 8 C 'THE MINING ENGINEER' NO. 109, VOL. 129, P 23. THRM 9 C THRM 10 C THRM 11 C THRM 12 C IDENTIFICATION OF ARRAYS THRM 13 C NOTE THE PROGRAM HAS BEEN DIMENTIONED FOR FOURTY (40) DATA POINTS THRM 14 C BASEC(6;2) BASE INSTRUMENT TEMPERATURE CORRECTIONS THRM 15 C TRAVC(6,2) TRAVERSE INSTRUMENT TEMPERATURE CORRECTIONS THRM 16 C BASER(I) BASE INSTRUMENT READING THRM 17 C TRAVR(I) TRAVERSE INSTRUMENT READING THRM 18 C TDRY(I) DRY BULB TEMPERATURE AT TRAVERSE STATION THRM 19 C TWET(I) WET BULB TEMPERATURE AT TRAVERSE STATION THRM 20 C ELEV(I) ELEVATION AT TRAVERSE STATION THRM 21 C VEL(I) AIR VELOCITY AT TRAVERSE STATION THRM 22 C TBDRY(I) DRY BULD TEMPERATURE AT BASE STATION THRM 23 C BASC(I) BASE READING CORRECTED FOR INSTRUMENT TEMPERATURE THRM 24 C TRAV(I) TRAVERSE READING CORRECTED FOR INSTRUMENT TEMPERATURE THRM 25 C BBASE(I) TEMPERATURE CORRECTED BASE READING IN BAROMETRIC THRM 26 C PRESSURE THRM 27 C BTRAV(I) TEMPERATURE CORRECTED TRAVERSE READING IN BAROMETRIC THRM 28 C PRESSURE THRM 29 C BTRAVS(I) BAROMETRIC TRAVERSE READING CORRECTED FOR ATMOSPHERIC THRM 30 C CHANGES THRM 31 C RELHUM(I) RELATIVE HUMIDITY THRM 32 C ASW(I) AIR SPECIFIC WEIGHT TURN 33 C R(I) GAS CONSTANT FOR MOIST AIR THRM 34 C STPRES(I) STATIC PRESSURE CHANCE BETWEEN STATIONS (I) AND (1-1) THRM 35 C TOPRES(I) TOTAL PRESSURE CHANCE BETWEEN STATIONS (I) AND (I-1) TURN 36

Jan 1, 1977

By T. Kessler

As part of a respirable mine-dust research program at the U.S. Bureau of Mines, spark-source mass spectrometry has been used for the semiquantitative determination of trace elements (200 ppm weight or less) in raw coals. In addition, several minor and major elements have been determined using this technique. Sixty-four elements ranging in concentration from 0.01 to 41,000 ppm weight were determined in one anthracite, two mvb, four lvb, and six hvab raw coal samples. The samples represented 10 coal seams located in Pennsylvania, West Virginia, Virginia, Utah, and Colorado.

Jan 1, 1973