Search Documents

By William Hawker, James Vaughan, Jeff Chen, Antony van der Ent

"Nickel agromining utilizes hyperaccumulator plants (“metal crops”) to extract nickel from low-grade soils, a process that yields high-grade nickel bio-ore. This feedstock is further processed into a range of nickel products. The bio-ore is relatively free of impurities that complicate the traditional processing of laterite nickel ores. In this paper, current primary nickel processing routes and proposed nickel bio-ore processing options are summarised. A novel pyro-hydrometallurgical route demonstrated at the laboratory scale is described. This process produces a precipitated nickel hydroxide product and takes advantage of the water-soluble basic compounds in the ash to minimise reagent requirements, thereby making it suitable for small-scale implementation in close proximity to the nickel farm. In this process, nickel is precipitated from the leach solution using the basic ash wash liquor. Leaching nickel from ash generated from open air burning requires strong acid and long residence times to obtain high recoveries due to its complex nature and distribution of nickel in multiple phases. This process can be improved by optimising the ashing process with respect to nickel leachability.INTRODUCTIONHyperaccumulator plants have the unique capacity to ‘biopurify’ and concentrate certain trace elements (e.g. nickel) from the soil into their biomass (Reeves 2003; van der Ent et al., 2015). Cultivating these plants as ‘metal crops’ by periodically harvesting and incinerating their biomass generates a high-grade bio-ore (Chaney et al. 1998; Li et al. 2003). This process is called phytomining or ‘agromining’ which is an emerging technology for extracting nickel from sub-economic resources (van der Ent et al., 2015). Potential near-term applications of the technology include implementation on land ahead of processing of the underlying ore-body (Willis 2015), as a mine-site rehabilitation strategy or as an alternative crop for farmers on land that is not suitable for normal food crops. In the longer term, nickel agromining could provide a significant supplement to the nickel supply chain. Critical to the success of agromining is effective bio-ore processing. Due to the unique chemical composition of this feedstock material, existing processes are not very efficient. Our current research efforts aim to develop new process options that overcome limitations of previously trialled routes. In this paper we summarise conventional nickel process routes and proposed new options for producing agromined nickel."

Jan 1, 2016

By E. S. Moore

DEEP oxidation and-secondary enrichment of ore deposits, although so important in many parts of the world, are comparatively rare in the Canadian shield. Intensive glaciation during the Pleistocene epoch accounts for their rarity. Glaciation has cost Canada much in the destruction of not only enriched ore deposits, but placers that must have been developed near our numerous gold deposits during the long period of weathering that pre-ceded the Pleistocene. There seems to be a very common misconception regarding the average depth of rock that has been removed from the shield by glaciers. These bodies of ice are usually given credit for the removal of the greater portion of the thousands of feet of rock that we know has been eroded from this large area since Precambrian time. As a matter of fact, the average thickness of solid rock removed can be measured in tens rather than even hundreds of feet, although very deep erosion has resulted in some sections where the glacial ice has been constricted in depressions, such as deep valleys and lake basins. On the other hand, there are few areas within the shield where the glaciers have not disturbed practically all of the mantle rock and some feet of the underlying bed-rock. The chances of finding deeply oxidized cappings and enriched ore deposits are therefore comparatively few and these have been found chiefly where favourable structural and topographic conditions for their formation and preservation have existed. Faulting has been responsible for several of these deposits, and easily decomposed rocks, such as. sulphides and carbonates, have been very important factors. Topographic features, such as high and resistant hills, favourably situated with respect to the ore deposits have, in a few cases, played a part in providing protection from glacial erosion and in furnishing head for the descent of surface waters. At least four cases of oxidation to depths quite abnormal in the Canadian shield have so far been found in Ontario. These are the Helen and Josephine iron mines in the Michipicoten district, the Keeley silver mine in South Lor-rain, and the Ross gold mine in Hislop township, Cochrane district. A deeply oxidized zinc deposit of unusual interest occurs in the Precambrian rocks in New York State, not far from the Canadian border, and there arc the well-known iron deposits in the Lake Superior region of the United States.

Jan 1, 1938

By Karina Forster

Open stope design depends on the ore body geometry, loading conditions and rock mass properties to estimate stope dilution and ground support requirements. Rock mass conditions for design primarily rely upon estimates of well established rock classification systems. Many sources of data exist for obtaining estimates for these rock mass classification values which include core logging, geotechnical mapping, geological mapping as well as linking one classification system to another through the use of empirically derived equations. The extent of mapping coverage can also vary significantly based on the data collection technique. This paper proposes an approach where individual components of rock mass classification systems are collected by the different available data collection techniques. Data from different rock types are also considered separately based on their alteration characteristics and general observation products. Data from the Cameco Corporation Eagle Point Mine is presented and an approach is outlined for obtaining average representative classification values for stope hanging wall characterization. The effectiveness of this approach is demonstrated through the analysis of a data base of hanging wall dilution information.

Jun 1, 2012

By N. Dahata

Earlier research has indicated that an addition of titanium master alloy to aluminum alloys, results in improved fillability, grain refinement and finer pores. B206 alloy differs from other alloys used in automotive industry, with lower titanium level. This paper examines the effect of alloy chemistry (copper and titanium levels) and grain refinement (A1-5`)oTi- 1%B grain refiner) on grain size, microstructure and microporosity in B206 aluminum alloy. In this study, characterization of grain size, microstructure and microporosity was carried out using light optical microscopy (LOM) and scanning electron microscopy (SEM). Results have shown that the addition of 0.05 wt % titanium resulted in grain refinement of B206 alloy. With an increase in titanium to 0.25 wt further grain refinement, much reduced pore size and uniform distribution of pores resulted. These results suggest that B206 with proper addition of titanium has a promise as an alloy for automotive casting.

Jan 1, 2007

By S. Mohammadnejad, M. Olizadeh, B. Mehrabi

A new method using a combination of comprehensive mineralogical and analytical approach which includes optical and electrical microscopy and several analytical techniques with diagnostic leaching has been used to characterize the associations and distribution of gold in a variety of minerals from the Zarshuran refractory gold ore, NW Iran. Zarshuran ore with an average of 7.9 g/t Au-grade and about 8% arsenic with gold recovery less than 20% in direct cyanidation is considered as high arsenic, high au-grade refractory gold ore. In most of the refractory ores, gold is associated with arsenopyrite and co-para genetic ore minerals, while in Zarshuran ore; gold is associated with orpiment, realgar and arsenian-pyrite. Considering its mineralogy and As content, it can be considered as the most difficult refractory ore for characterization and processing. Results from the mineralogical examination and diagnostic leaches indicate that there is only a small amount of free gold (17-19%) that is present in cyanide-soluble sulfo-arsenides compounds, predominantly orpiment and realgar. Diagnostic leaches also indicate that little gold is occluded within the silicate structure (14%). Overall, the gold is mostly included in sulfides, arsenic sulfides and sulfo-arsenides (50%). The results also have shown how the technique can be used to gain a good initial understanding of potential metallurgical problems for a refractory gold ore.

Jan 1, 2005

By Dong-kil Lee

A ventilation improvement index (VII) was developed in an effort to propose an optimal ventilation improvement measure for a designated mine. The index was designed to incorporate both ventilation effectiveness and cost efficiency. To verify the effect of the index, a mine experiencing a ventilation problem was selected, the ventilation assessed and ventilation network analyses were conducted. In the selected mine, four areas with ventilation difficulties were detected and an improvement schemes for each area were proposed. These were simulated through network simulation and evaluated using the ventilation improvement index. As a result, an optimum ventilation improvement scheme was proposed. The improvement scheme with the highest VII value was incorporated in the design.

Aug 1, 2013

By R. ZapataN.

"In the following report, Altonorte Smelter owned by Xstrata will explain its experience with its denominated furnace called ""Continuous Altonorte Reactor"" since started up in March 2002. The Reactor is the main and only smelting furnace since the operation of Reverb Furnace was stopped (15 days after the start up of the Reactor) and it can be operate with dry concentrate for injection by tuyere and wet concentrated via Garr Gun when the injection system fails. From the started up of the Reactor, three operational campaigns have been carried out where in each one they have been increased their smelting throughput and availability. The flexibility reached by the technology bath smelting has allowed a high level of smelting of concentrate and revert materials. The high availability of the Reactor and overcoming problems that were considered of high complexity like the extraction of white metal and slag, refractory campaign, etc. has allowed the Altonorte smelter to project to smelting 1,200,000 tonnes per year with its only Reactor in next year."

Jan 1, 2007

By R. A. L. Drew, G. Mendoza-Suarez, J. Filipi, R. Vintila, J. A. Kozinski

Economics and environmental considerations along with the increasing demand of hydrogen encourage development of novel technologies such as plasma processing of hydrocarbons and thermal cracking of natural gas. Plasma discharges, either in thermal or non-thermal regimes are expected to allow low temperature and fuel flexible on-site hydrogen generation. The main drawback of thermal plasma reformers is the high-energy consumption resulting from high-temperature operation. On the other hand, non-thermal plasma, generated by dielectric barrier discharge (DBD), is able to simulate the chemical reactions employing much lower energies than those required by thermal treatment processes. The non-thermal plasma process allows for instance, a direct conversion of methane into hydrogen and carbon black with no CO2 release. The focus of this research was on the GHG-free method of H2 generation in compact non-thermal plasma reactors using low, medium and high permittivity dielectric ceramics. A stable, non-thermal plasma was generated by placing a dielectric ceramic between two electrodes with a 25 thou gap and applying an alternating current of 1-5kHz and voltages of 4-8kV. In order to ensure energetic efficient plasmas, experiments were conducted to analyze the behaviour of different permittivity ceramics. It was found that the dielectric properties of a ceramic, when used in a DBD reactor, have a strong influence on the discharge characteristics, which in turn influence the power consumption. Higher dielectric constant resulted in higher conversion rates of methane (higher yield of hydrogen and carbon). At the same time, the mechanical properties of the dielectric material, which are closely associated with its processability, influenced its resistance to electron bombardment, as well as thermal and mechanical damage. Therefore a reliable ceramic should have good dielectric properties, in addition to good thermo-mechanical stability.

Jan 1, 2004

By H. Salamanca

Recently, the mining industry has become one of the leading target markets for the technology industry as they need to innovate in their productive processes in order to boost productivity, reduce operation costs, increase operation safety, and improve the quality of life of their workers. This work presents the technological developments that HighService has done in different stages of the mining productive processes to include robotic manipulators in their automation solutions as well as the development of new equipment and sensors. The robotic technology integration is presented in different applications such as handling and selection of cathodes in E-W machines, automation of base plate maintenance, automation of cathode stripping machine, and multi-tools handler for liner bolt replacement in SAG mill liner maintenance activities. The proposed solutions show technical and economical viability with low initial investment and short implementation period of six (6) to ten (10) months. The results have been validated in plant, obtaining higher production rates and availability.

Jan 1, 2007

By W. Dong

This paper presents the fundamental study of the temperature distribution in a reforming planar solid oxide fuel cell (SOFC) using mathematical modeling and experimental testing approaches at Versa Power Systems (VPS). In order to investigate the on-cell temperature distribution under high rates of Natural Gas direct internal reforming (DIR), both the computer simulation approach and the experimental testing approach have been developed. In this work, comprehensive in-house DIR and SOFC models were developed and employed for the computational fluid dynamics (CFD) based 3D computer simulation. The current SOFC module has been corrected to take into account both the on-cell electrical leaking effect and the stack stage structural resistance. Meanwhile, an instrumented single-cell test jig with multiple thermocouples was built, and a series of experimental tests were performed at various conditions. The numerical results based on the single-cell jigs are in very good agreement with the physical test results.

Jan 1, 2005

By M. Maldonado

This work details the application of a decentralized control strategy to a pilot flotation column working with a two-phase system (water-air). The process is represented by a multivariable system composed of three inputs and three outputs. The selected control variables are the froth depth, the air hold-up and the bias rate, whereas the corresponding manipulated variables are the set-points of the local flow controllers of tailings, air and wash water. All controlled variables are estimated using electrical conductivity based techniques. In particular, the results of a new method for estimating the bias rate, based on the measurement of the volumetric fraction of wash water under the interface, is presented. This method reduces the coupling problem associated to the bias estimation as a difference between feed and tailing water rates. Moreover, the nominal system transfer matrix can be represented by an upper triangular matrix, in such a way that the closed-loop system stability reduces to the stability of the independent control loops. The experimental results show that the closed-loop system performance, particularly that of the bias rate loop, is strongly dependent on the air flow rate, reaching in some cases the saturation point of the controller.

Jan 1, 2007

By Michael S. Moats, Prashant Bagri

"In recent years with increasing concerns about energy consumption in hydrometallurgical processing, there is an ongoing attempt to use Catalytic Titanium Anodes (CTAs) for copper electrowinning. For this work, anodes with IrO2 - Ta2O5 coatings were prepared in the laboratory with the same total coating loading but varying the number of layers by changing the speed of withdrawal in dip coating. A second set of CTAs were fabricated on niobium, Ti Grade 1, Ti Grade 7 and Ti Grade 36 metal substrates. All the anodes prepared in the laboratory were characterized using standard electrochemical techniques and subjected to accelerated life testing. It was found that the coating would not adhere to the niobium substrate, the grade of titanium had a minimal to no effect on the life of the anode, and it is observed that as the coating speed slows, there is an increase in the electrochemically active surface area of the coating which seems to directly contribute to an increase in the Tafel slope of the anodes. There was inconclusive evidence on the effect of coating speed on anode lifetime.INTRODUCTIONLarge scale hydrometallurgical extraction of copper has become widely practiced over the last 40+ years. The hydrometallurgical route entails leaching, solvent extraction and electrowinning. With the increasing desire to process refractory sulphides like enargite and chalcopyrite through the hydrometallurgical route, use of hydro-processing of copper is expected to remain high.In conventional electrowinning, copper is deposited on the cathode and an inert anode is used for oxygen evolution. Presently, the most common anode material is rolled lead-calcium-tin and the cathode is 316L stainless steel (Robinson et al., 2013). This lead alloy is fairly inexpensive and is robust, providing lifetimes typically of 4+ years. The main drawbacks of lead alloys are their relatively high oxygen evolution overpotential, the need for cobalt in the electrolyte to reduce their corrosion, the contamination of cathode product by lead, and the generation of harzardous by-products (Hiskey, 1999)."

Jan 1, 2016

By William G. Pariseau

"This contribution describes linkage of stress concentration at the face of tabular excavations, for example, longwall coal mine panels, at a meter scale to surface subsidence at a kilometer scale. Joints are considered according to orientation and spacing at an intermediate scale. A new dual-node, dual-mesh technique based on first principles uses a multi-scale technique that allows for computing whole mine surface subsidence while also allowing for computational details of stress, strain and displacement about main entries and pillars, panel entries, and bleeder entries. The technique is implemented in a conventional continuous Galerkin finite element program that has been in use for many years.The advantage of the dual-node, dual-mesh technique is the capability to do a whole mine analysis that takes into account interaction between all sections of a mine where stress transfer over long distances is often the rule rather than the exception while at the same time allowing for details of stress concentration at working faces where caving is initiated and subsidence begins. The technique, outlined recently during ARMA 2014 (Pariseau, 2014), is applied to an underground coal mine in central Utah where mines are developed from outcrops in steep canyon walls. Meshes contain over 10 million, three-dimensional nodes; runtimes are typically overnight, as a practical matter. Results compare favorably with mine subsidence measurements made over a period of several years and show the capability of this new technique to provide useful design guidance for tabular deposits such as underground coal mines. The role of variability or uncertainty in strata properties is illustrated in element safety factor distributions about development, bleeder and main entries and pillars. Such details are new in this contribution. Energy tracking for mine-induced seismicity is also new. Results show a high correlation between number of events and failed elements and suggest a simple index to mine induced seismicity."

Jan 1, 2015

By L. A. Gomieroa

The Caetité-Brazil uranium facilities produce about 340 t/y of uranium from an ore averaging 0,25 U %. The process steps are ore crushing, heap leaching with sulfuric acid, U separation and purification by solvent extraction with tertiary amine followed by stripping with sodium chloride solution and precipitation as ammonium diuranate that is dryed. A change in the milling process is being evaluated to increase the production and the uranium recovery. Heap leaching will be changed to conventional tank agitated leaching of the ?590 ground ore slurry in sulfuric acid medium. The replacement of the stripping reagent is also being considered.

Aug 1, 2010

By V. Loya

Metallic foams (MF) are relatively new materials with a combination of attractive properties (permeability, high surface area, thermal and chemical stability, etc,), They can be produced from different materials and can be manufactured using various processes, Due to their unique properties, they find applications in different sectors of engineering, such as energy absorption, filtration, heat dissipation, etc, For many applications, the permeability is an important parameter to characterize and optimize, Most of the recent literature on the subject studied the permeability in the low velocity range. The present study was carried out to have a better understanding of permeability for greater velocity ranges, An equipment was designed and built for this purpose, Pressure drop measurements were made across the thickness of open-cell nickel foams, Pore and window sizes were measured by image analysis on SEM micrographs, The experimental results are in relatively good agreement with the Hazen-Dupuit-Darcy model (R2>98%), The permeability is affected by pore size, porosity and the normalized projected area of the connecting pores (ie. windows).

Jan 1, 2005

By J. J. Quinn

Several mineral flotation plants utilize process water with high soluble salt content. The processing of semi-soluble minerals, the use of recycle streams, sea or well water give rise to this situation. It is unclear as to the overall effect on flotation response though there does seem to be evidence of bubble size reduction, increased froth stability and reduced reagent dosage. The present work aims to quantify the effects of salts present in process water on gas dispersion (bubble size and gas holdup) and froth properties. The salts examined were NaCI, CaCl2, Na2SO4, Na2S2O3 and Al2(SO4)3. Tests were conducted to determine the effects of salt type and concentration on gas holdup and bubble size distribution. The salts containing multivalent ions had a greater impact than the monovalent ions, in keeping with the literature. A relationship between gas holdup and ionic strength was established. The concentration of frother (methyl isobutyl carbinol, MIBC) giving equivalent gas holdup was determined. The effect of salt and frother combinations was also explored.Proposed mechanisms for coalescence inhibition in salt solutions are briefly reviewed in light of the current findings.

Jan 1, 2006

By G. P. Gu, B. Fang, R. W. Revie, M. Elboujdaini

Stress-corrosion cracking (SCC) tests were conducted in the near-neutral pH standard solution, NS4, and in an actual soil solution, using four-point bending at high a stress ratio and low frequency conditions very similar to those of operational pipelines. Pitting incubation appeared first and then pitting initiated and grew in both solutions although there were many more pits on the specimen tested in soil purged with 5% CO2 + 95% N2 than in the specimen tested in NS4 solution purged with the same gas. These observations show that samples in soil solution are more susceptible to pitting than those in NS4 solution. When the pit reached a critical size, the increased stress concentration around the pits, resulted in the transition to a crack.

Jan 1, 2005

By W. van der Merwe

With the gold industry looking to process more complex ores, the online measurement and control of cyanide addition to the gold leaching circuit has become more crucial. This paper compares the two commonly employed "free" cyanide online analysis methods (amperometric and potentiometric end-point silver nitrate titration) with the common site laboratory rhodanine endpoint silver nitrate titration and ion selective electrode methods. Measurement differences between these methods are presented and discussed for cyanide solutions containing copper and zinc with varying cyanide to metal ion ratios. The resulting cyanide available to leach gold is also compared with these measurements.

Jan 1, 2011

By Mosquera. J.

Tailings Storage Facilities (TSFs) are vast structures that respond to site-specific characteristics, rate of production, placement techniques, and the physical and mechanical properties of tailings. As a common denominator, TSFs are in some degree vulnerable to failure due to liquefaction, poor management, slope instability and/or unusual climatic events. In practice, stability of TSFS is determined by calculating a minimum Factor of Safety (FOS) using the Limit Equilibrium Method (LEM). However, it has been proven that relying exclusively on the limit equilibrium approach is not accurate because it is basically a static method that does not take into account the stress-strain distribution and displacement experienced by the constitutive materials of a TSF. In order to overcome these limitations of the LEM, the finite element method - Shear Reduction Technique (SRT) has been used as a more reliable tool for TSFs stability assessment. This paper presents a comparative stability analysis between an upstream tailings storage facility (UTSF), and a water retention tailings dam (WRTD) under static and pseudo-static states using simplified and rigorous LEMs and the SRT. Additionally, and taking into consideration the intrinsic uncertainty of tailings properties, sensitivity and probabilistic analyses in the form of Monte Carlo Simulation (MCS) and the Point Estimate Method (PEM) are applied to determine the Probability of Failure (Pf) and Reliability Index (ß) of each TSF. It is shown that the friction angle of UTSF?s foundation and the core?s cohesion of the WRTD are the main variables that govern stability. Further analysis shows that the WRTD has a higher reliability index and a lower probability of failure than the UTSF.

Aug 1, 2013

By Atsushi Sainoki

Blast vibration induced by mining activities, such as stope production blasts, could lead to the initiation of seismic events that inflict damage to mine openings. In this paper, the effect of stope production blasts on nearby fault is examined. First, validation of blast vibration attenuation is performed with a numerical model representing a single blast hole through comparison with that calculated from charge-weight scaling law derived from in-situ data. Subsequently, a mine-wide scale model with a fault parallel to a steeply dipping, tabular ore deposit that is mined out with sublevel stoping method is generated, and the stopes are extracted and backfilled with static analysis to simulate burst-prone conditions on the fault. Based on the stress states, dynamic analysis is performed, in which blast vibration is applied to grid points on a stope wall on the hanging wall side. This assumes 9 blast holes located close to the wall, and blast-induced particle velocities that consider the positional relationships between the assumed blast holes and the stope wall are applied. During the dynamic analysis, blast sequence is considered, and stress states and shear displacement on the faults are examined. It is found from results that, after a rise in normal stress on the fault due to compressive waves induced by the blasts, the normal stress decreases because of the reflection of the compressive waves on the fault. The reduction in the normal stress due to the reflected waves is found to be large enough to cause the fault to slip. The results also show that the level of normal stress eventually keeps decreasing with time as the blast sequence proceeds and that an increase in shear displacement on the fault is accompanied by a decrease in normal stress. This study clarifies the mechanism by which blast vibration causes the fault to slip. In addition, the simulation technique to apply blast vibration that takes into account blast sequence and the locations of blast holes to a stope wall is developed.

Aug 1, 2013