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By W. W. Culver

The paper explores the substance, circumstances and significance of the Whelpley and Storer Copper Process. The 1866 Whelpley and Storer patent specified a process combining mechanical and chemical engineering. The process called for a down-drafting shaft furnace with a horizontal flue connected at the bottom of the shaft. Powdered sulphide ore was roasted in the shaft and then sent forward fully oxidized to a bath of sulphuric acid and/or calcium chloride. The “water furnace” was developed in Boston, at a time when the city was home to most Michigan copper mining companies. The process was field-tested at Quebec’s Harvey Hill copper mine. In 1865 James Douglas, Jr. took over management of the Harvey Hill mine with the challenge of saving the family investment. He needed a way to make money from low-grade sulphides. Through his relationship with chemist T. Sterry Hunt, Douglas learned of a possible way ahead using the process developed by Whelpley and Storer. The paper confirms the centrality of publications, meetings, and networking in the advancement of metallurgy. The process is of interest historically, as much as anything, because it is one of the pillars of James Douglas’ distinguished career in copper. INTRODUCTION At the 1866 meeting of the American Association for the Advancement of Science (AAAS) in Buffalo, New York, T. Sterry Hunt (1826–1892) read a paper “On the Metallurgical System of Messrs. Whelpley and Storer.” The paper is part of a chain of events that constitute the foundation of James Douglas’ (1837–1918) success in the copper mining industry. To understand the career of Douglas over the early years of modern copper mining, we must necessarily start with Whelpley and Storer. Going back to Hunt’s paper, he concluded his remarks by asserting that the Whelpley and Storer Process was “capable of such wide and varied application, that it is probably destined to have a very important influence on the industry of the world” (Hunt, 1867a). He reached this conclusion reasoning that the process had overcome a critical metallurgical hurdle (Hunt, 1867a). Hunt, a geo-chemist in modern terms, recalled that the chemist of those years easily separated copper from “sulphuretted” ores by converting it to a soluble salt from which pure metal was precipitated by “an equivalent of iron.” The problem was to “…apply this principle in the working of copper ores on a great scale...” (Hunt, 1867a). Hunt noted that this very problem had “…engaged the attention of many metallurgists, and has given rise to various processes for obtaining copper by the moist way, many of which are nearly or quite perfect in their operation, but are lacking in practicability and cheapness” (Hunt, 1867a). Hunt thought Whelpley and Storer had overcome the low-grade sulphide hurdle with a commercially viable engineering breakthrough. Yet in the history of copper metallurgy, the process is missing. What happened?

Jan 1, 2019

By M. Leroux, S. R. Rao, J. A. Finch

"Poor Pb-Zn selectivity during Pb flotation in laboratory tests on a Mississippi Valley-type Pb-Zn ore was traced to apH effect. In the pH range, 9.5 to 11.0 sphalerite floated readily without copper activation. Compared to sphalerite flotation with copper activation this procedure gave equivalent selectivity but reduced flotation rate.Possible mechanisms of this sphalerite flotation without copper activation are discussed. Activation by Fe(OH)2 is suggested, the Fe- + ions being derived from superficial oxidation of pyrite in the ore. IntroductionGalena and sphalerite commonly occur together. A typical procedure, using xanthate collectors, is to float the galena first, at pH - 8, followed by flotation of sphalerite after activation with copper (II) sulphate at pH - 10 (to depress pyrite).Flotation tests following this procedure in an undergraduate laboratory course with a Pb-Zn ore from Polaris failed to achieve consistent selective flotation of galena. Occasionally a considerable amount of sphalerite, even though unactivated with CUSO4, floated. This was traced to accidentally high pH. A systematic study was carried out which revealed that sphalerite floated readily in the pH range 9.5 to 11.0 without activation by CuSO4 This paper describes the results of the study and discusses a possible mechanism of this flotation of sphalerite."

Jan 1, 1987

By Patrick Frenette

The Goldex Mine is an underground gold mine using a unique mining method where a single very large stope is being created. In order to maintain stability of the walls and roof of the stope which is 450m, 250m high and up to 120m thick, ore is left in the stope as long as possible and acts as backfill would do. At many occasions during the mining sequence, the walls will be exposed on height ranging from 30 meters up to 250 meters. A monitoring system comprising in-stope laser surveys, a seismic system and an array of extensometers and sloughmeters all remotely connected to surface is used to observe the shape and evolution of the stope. This paper will focus on the results obtained following some of the large blasts and on the long term monitoring of the stope.

May 1, 2011

By A. Mazhary

"Although ore sorting in mining is not a new concept, sensor-based sorting has failed to gain broad acceptance due to perceived challenges with the technology. In order to gain wider applications, this research focuses on treating waste rock and low-grade ore to identify and test appropriate sensors and to evaluate the response. Results showed that amenability of rocks to sensor-based ore sorting is both sensor and ore specific. It was also observed that the efficiency (recovery) of sorting is directly influenced by the degree of heterogeneity of the rocks. The overall outcome showed that with the right sensor, several of the materials tested are amenable to sensor-based ore sorting. Mining companies could benefit from multiple economic and design impacts, such as lower energy cost, lower transportation costs, higher metal recoveries and smaller footprints that lead to more sustainable mining. This paper will focus on the effects of heterogeneity of rocks on sorting potential and efficiency.IntroductionSensor-based ore sorting has been attracting more attention since the pressure for effective resource extraction and management has increased. An urge to make most of the current deposits, and to make the low-grade deposits economic to mine has ushered the technology to find new ways to overcome the new challenges. No matter the terminology used, such as coarse beneificiation, waste rejection, particle or bulk sorting, the purpose of sensor-based ore sorting is to remove low-grade rocks before the comminution circuit, increasing the feed head grade and quality while reducing the energy costs related to comminution.Despite nominal advantages, there have always been some concerns that have impeded the intorduction and acceptance of the technology. One of the most important shortcomings of ore sorting is their capability, or capacity, to keep up with the high-tonnage mining. Some other issues that have been mentioned as drawbacks to sorting include installation cost of such devices, feed preparation for effiecient sorting along with accuracy of sorting and probability of false negatives (Manouchehri, 2003)."

Jan 1, 2015

By Weng Fu, James Vaughan, Stefan Lakemond

Uranium bearing copper sulphide flotation concentrates produced from iron oxide copper gold uranium (IOCG–U) ore contains radionuclides such as 238U, 230Th, 210Pb, 226Ra, 210Po, which have the potential to reduce their marketability, thus posing a challenge to the industry. Thus, a two–stage leach process has been proposed in this study. In first stage, a sulphuric acid leach process effectively dissolve most of the 238U and 230Th into solution, but other radionulclides (mainly 210Pb, 226Ra and 210Po) remain associated with copper sulphide minerals owing to their low solubilities in sulphuric acid solution. In the second leaching stage, the use of methanesulfonic acid (MSA, CH3SO3H) is investigated to selectively dissolve the 210Pb, 226Ra and 210Po from the residue of the first stage. The results indicate that 96% of 238U, 87% of 230Th, 90% of 210Pb, 86% of 226Ra and 17% of 210Po are dissolved using 3 mol/L MSA solution at 90°C for 3 hours, which represents a dramatic decrease in the radioactivity of the copper concentrate. INTRODUCTION Australia is host to one of the largest iron oxide copper–gold–uranium (IOCG–U) deposits in the world. Most of the value in these deposits is associated with copper. In mineral processing, the gangue minerals are separated from copper sulphide minerals that report to a copper flotation concentrate. However, due to the strong association of uranium with copper minerals and hematite, even clean copper concentrates can contain significant amounts of uranium (238U) and its radioactive decay elements, of which thorium (230Th), radium (226Ra), lead (210Pb), and polonium (210Po) are the long life radionuclides. These hazardous radionuclides negatively affect the marketability of the copper concentrates. Customer copper smelters in China, Japan and Europe may consider the radionuclides penalty elements or may not be able to process the feed. Therefore, there is a strong motivation to remove radionuclides from copper concentrates at the mine site before shipping to custom smelters in global market. Hydrometallurgical leaching has been widely employed to remove radionuclides from different kinds of minerals such as copper concentrates (Ragozzini & Sparrow, 1987), zircon concentrates (Aral, Sparrow, McDonald, & Norgate, 2007), and coal ash (Lei, Qi, Sun, Xu, & Wang, 2014). Leaching using sulphuric acid (H2SO4) solutions is the most widely used process for the extraction of uranium from uranium ores due to the relatively low cost and wide availability of the acid (Bhargava et al., 2015; Gilligan & Nikoloski, 2015). The leach process involves treating ground ore slurry with sulphuric acid at elevated temperatures (typically 60–90 °C) under oxidising conditions in order to convert the uranium in the minerals 2+ from the relatively insoluble tetravalent form (UO2) into water–soluble hexavalent state (UO2), which then complexes with SO42- and forms UO2(SO4)22- in solution. The uranium oxidation is generally carried out in the presence of ferric ion (Fe3+), regardless of the reagent and oxidant used. The most commonly used oxidants for uranium include sodium chlorate, pyrolusite and oxygen (Ring, 1980). These oxidants act indirectly by converting ferrous sulphate, formed by the oxidation reaction of UO2 in slurries, into ferric sulphate. The presence of Fe–containing gangue minerals such as hematite in the ore usually provides sufficient Fe required for the oxidation of UO2. After sulphuric acid leaching, the locked thorium (230Th), radium (226Ra), lead (210Pb), and polonium (210Po) elements are chemically liberated from hematite and uranium mineral grains (Ciobanu, Wade, Cook, Schmidt Mumm, & Giles, 2013). However, the extraction rate of radium (226Ra), lead (210Pb), and polonium (210Po) in sulphate solution is very low due to the limited solubilities of (Ra, Pb, Po)SO4 (Bagnall & Freeman, 1956; Liu & Papangelakis, 2006; Nikitin & Tolmachev, 1933).

Jan 1, 2019

By Glenn Lyle

CEMI Introduction ? Introduction of the CAF VOD Project ? Who are our partners ? What were the Outcomes What is next

May 1, 2011

A comprehensive axial test program has been undertaken at the WASM Dynamic Test Facility on the performance of 20mm threadbar. The threadbar tests had a double embedment configuration, with variation to the encapsulation lengths, debonded length and surface hardware and fixtures to examine failure mechanisms. Performance was significantly affected by the collar embedment length and type of fixture nut used. Results ranged from thread shearing occurring between the nut and bar at 1kJ of energy dissipated, to control plastic deformation of a central debonded length dissipating 22kJ.

May 1, 2009

By Fred W. Brackebusch

"The use of paste technology for surface tailings disposal may offer economic, technical, safety, and environmental advantages for both underground and surface mining operations. Paste is a non-Newtonian fluid having some shear strength during transport and placement. The strength is augmented after placement by consolidation, water loss, and by addition of chemicals. Economical dewatering systems are necessary to the success of surface paste tailings disposal. In an underground mine, the paste backfill plant can produce paste for surface disposal about 50% of the time because only about 1/2 of the tailings are needed for backfill. The distribution of paste to the surface stack involves expensive pumping equipment and thus a nearby location of the stack is desirable. The viscosity of paste can often be manipulated by modifying pH. Placement of the paste in a designed stack configuration depends on topographic and climatic factors as well as paste properties.INTRODUCTIONThe use of paste technology for mine backfill is becoming accepted for underground mines mainly because of ground control and economic reasons. Paste technology is just starting to be applied for tailings disposal with only a few hardrock metal mines worldwide using the technology; however, it has been used extensively for red mud disposal in the aluminum industry. The disposal of dry tailings is very attractive from environmental and safety points of view because of limited water which might potentially escape and pollute river systems. Dry stacking systems, however, are expensive because of filtration and truck transportation costs. Paste can be produced from most tailings streams by special types of thickeners. Furthermore, it can be transported in pipelines, therefore paste technology may be more economic than dry stacking but still have some of the major advantages. Understanding of paste technology has improved through experience with operating underground backfill systems in recent years and because of testwork and research programs by mining companies, consultants and equipment vendors. Thus we may be on the verge of taking a new look at tailings management using paste technology."

Jan 1, 2002

By Luke Keeney, Stephen Walters

"The start up of a new mining and metallurgical facility is a crucial step in the life of any mining project. The mining industries record is poor when evaluating processing plant operation relative to design capacity predictions made during feasibility studies. Multivariate geometallurgical orebody characterisation, using principle component analysis, is a method developed for improving predictive processing performance models during feasibility stages of mine development. This paper outlines the application of multivariate geometallurgical characterisation to the Cadia East deposit located in New South Wales, Australia. Cadia East is a low grade high tonnage copper-gold porphyry system in advanced stages of feasibility analysis. A dataset of ~32000 measurements and 150 comminution parameters (A*b and BMWI) has been used to develop class-based characterisation and modelling methodologies. The results of this study outline the development of class-based ore characterisation and provide a technique for analysing and interpreting large and complex geometallurgical datasets for prediction and optimisation of processing performance. The results enable sophisticated population modelling to be conducted which displays deposit scale processing variability, aiding circuit design specifications and predictions during feasibility studies.INTRODUCTIONA feasibility study is the major technical report on which the decision to proceed to production and on which financing is based (Shillabeer & Gypton, 2003). The mining industry’s record is not very good when actual construction time, costs, and operating performance are compared to the projections made in feasibility studies (Ballard, 1983; Gypton & Ward, 2000; Gypton 2002). A study by McNulty (1998) found that of 41 mineral processing and chemical plants built between 1965 and 1995, only 56% achieved design capacity within two years of commissioning and three were closed after failing to achieve design capacity within 36 months of start up (Shillabeer & Gypton, 2003). McNulty (1998) related this underachievement and failure of start up performance to the use of innovative process technology without appreciating and managing technical risk. Factors contributing to technical risk include inadequate pilot plant testing, scaled up prototype equipment without backup, design flaws and poorly understood complex process chemistry."

Jan 1, 2009

By Antônio Peres, Rogério Guimaraes, Lauro Takata, Harold Wyslouzil

"Serrana’s concentrator, in Araxii, has capacity of producing approximately 800,000 tomes of phosphate rock per year, with a P205 grade of 36%, from ores grading between 13% and 14% P205. The annual mining rate is around 3.5 Mt and the apatite is concentrated according to the following sequence: crushing, grinding, desliming, flotation and low and high intensity magnetic separations.Two industrial flotation columns (3.0 m x 4.5 m x 14.5 m) were commissioned in 1993 as a replacement for circuits of barite and apatite fines flotation. In 1994, four additional flotation columns of the same dimensions were put into operation, replacing 42 Wemco mechanical cells (300 ft3 each), in the barite pre-flotation, coarse apatite (two columns) and tailings regrind flotation Circuits. Overall, 66 mechanical cells (300 ft3 each) were replaced by only six flotation columns, designed by Cominco Engineering Services Ltd - CESL.The present paper describes the stages of process development, pilot plant testwork and implementation of the industrial project, highlighting the most relevant aspects of each of them. The results achieved are related to improvements in flotation selectivity, gains in P205 recovery and better process control, resulting in better quality products and lower production costs. Other benefits included a decrease in flotation reagents, electrical energy and maintenance materials consumption. These factors contributed to a significant decrease in the cost of phosphate rock production at Serrana, in Araxa - M G."

Jan 1, 1999

By Robert Gannicott

??A mining company without the burden of operating a mine ??Management focused on marketing a high-quality, run-of-mine range of Canadian diamonds ??Robust revenue stream ??Specialist diamond knowledge ??Canadian exploration and development expertise ??BUT ??Single asset revenue base from depleting ore reserve ??Limited influence on production plans

Apr 1, 2005

By A. Dave Mackintosh

In 2001, at the CIM AGM in Quebec, a paper discussing poor ground conditions in a newly opened area at Agrium?s Vanscoy Potash Operation?s, suggested load transfer around old workings as a possible reason for the early room failure. High closure rates are expected in deeper regions however the rapid failure of walls immediately behind the face resulted in protective guards being mounted on and behind the borer. The high closure and early rib failure continued well past any reasonable distance to be explained by load transfer around old workings and investigations continued into possible reasons other than simply depth. Detailed investigations into the mineralogy and crystal fabric of the ore zone provided one possibility, which combined with a changed borer cutting profile are now believed to have contributed greatly to the poor conditions.

Apr 1, 2005

By P. W. Jensen

Gold deposits in Interior Alaska are commonly coincident in time and space with reduced, mid-Cretaceous granitoids. The True North deposit of the Fairbanks district is several km from such granitoids, but yields mineralization ages indistinguishable from the Fort Knox granite-hosted deposit. True North, however, resembles sediment-hosted epithermal Au, demonstrating the variability of intrusion-related Au deposits in metamorphic rocks. The True North deposit (14M tons at 1.5 gpt) is hosted within a carbonaceous thrust complex separating eclogite facies from amphibolite facies rocks, located > 5 km from mineralized granite outcrops. The ores contain anomalous Sb, As, and Hg (stibnite is the most common sulfide) with ankerite-sericite alteration in steep NE-striking ?feeder? shears and low angle thrust shears. Nearest hornfelsed rocks are located > 1 km away, and across several high-angle faults. Fluid inclusion data indicates trapping temperatures of ~250C from low-density, low-salinity fluids at P < 0.5 kb. Au was originally present as solid solution in sulfides; minable ores are restricted to the oxidized upper 100 m of the deposit. The considerable differences between this deposit and the temporally equivalent Fort Knox intrusion-hosted deposit indicate no one description adequately characterizes this deposit type.

May 1, 2003

By Brian Reid

"This paper studies the progress made by hydraulic shovel manufacturers over the last few years, particularly in the areas of productivity increase and operating cost reductions.Five years ago, it was widely considered that the unit production cost for a hydraulic shovel in a mining application was double that of a cable shovel in the same application. The hydraulic machine manufacturers have taken up this challenge, and modern improvements in design, coupled with changes in maintenance techniques, have narrowed the gap to the point where it is valid to ask the question ""will the cable shovel exist in ten years&apos; time?"".Historical BackgroundThe history of the cable shovel goes back to the early 19th century and the industrial revolution. Early machines were steam-powered and ran on rails.The ""power shovel"" and the ""dragline"" were the only mechanical means of mass excavation until the early 1950s. Rail-mounted units gave way to crawlers, which increased flexibility considerably. Some shovels were redesigned as backhoes, and some became extremely large when designed as stripping shovels primarily used in North American coal mines.In the early 1950s growth in hydraulic technology spawned the introduction of the hydraulic excavator, which soon began to replace the smaller cable shovels and backhoes used in the construction industry. They were completely self-contained with either a gasoline or diesel engine and, being much lighter, were more readily transportable.As the excavators grew in size from its early models of 0.5 m3 or less, many of the cable shovel models were discontinued. This was not surprising for several reasons, but the most obvious is that both were often made by the same manufacturer."

Jan 1, 1988

By Alan Galley

CMIC Mandate CIM Annual Meeting, Toronto, May 6, 2013 To increase mining research, innovation and commercialization efforts in order to strengthen Canada?s pre-eminent role as a global leader in mineral exploration, mining and knowledge-based services and technologies. To increase the supply of highly qualified graduates from mining and earth sciences faculties to meet the significant demand today and into the future of industry, governments and academia. The CMIC initiative is intended to develop long term research strategies that extend five or greater years. Such a research plan will underpin fundamental research and innovation and the training of HQP

May 1, 2013

By A. Lewis, J. Zachwieja, M. Widell, P. Zhou, W. W. Geissler, M. Svensson, A. Movahedi, H. Nordberg

Flotation collectors for sulfide minerals has been traditionally based on xanthate, thiophosphate, thiophosphinate and thiocarbamate, all derived from sulfur chemistry. Tecflote™ is a new family of patented collectors based on nitrile chemistry which can supplement or replace thiol collectors, depending on the ore types. A steep grade-recovery curve typical of Tecflote™ collectors was observed when using Tecflote™ as the main collector for the rougher and cleaner steps allowing a better recovery compared to current thiol collectors while maintaining the desired grade. Additional recovery increase has also been observed by the addition of scavenger steps using Tecflote™ collector in combination with current thiol-based collector. The selectivity seen in the lab is transferred to full scale trial and is clearly seen in the rough flotation where the increase in the rough concentrate grade of 5% after pumping Tecflote S11 directly into the tank cell. The mechanisms for Tecflote’s selectivity towards sulfides are currently under investigation and will be discussed. Results of TOF-SIMS analysis will be presented, demonstrating the collector’s selective affinity to different mineral surfaces in flotation. INTRODUCTION The history of collectors used today started in 1882 when Zeise first made xanthates. It was first used in flotation in 1925 – Cornelius Keller’s first patent (Fuerstenau, Jameson, Yoon, 2007). Between 1928 and 1930 American Cyanamid filed 7 patents for dithiophosphate, including flotation and chemical synthesis of the reagent, the first of which was filed by Christmann in 1928 (Christmann, 1933). Synthesize of thionocarbamates for mineral flotation was filed in 1954, by Dow Chemical Company (Harris, 1954). Now that the head grades have been declining over the last decades the need to find more selective collectors to extract difficult and complex ores has pushed the industry to look at different chemistries. Thiol collectors standard to the industry rely on the sulfur in the collector molecule to bond to the mineral surface. The electronic property of this group is modified by the adjacent chemical groups, such as additional S, P or N have the effect of changing the selectivity of the collector (Wills & Finch, 2016). In the case of xanthate the length of the hydrophobic group also has an effect on the selectivity with some minerals such that the ethyl xanthate is more selective against pyrite and pyrrhotite than the long chain xanthates (Wills & Finch, 2016).

Jan 1, 2019

A series of fault slip seismic events have occurred at Garson mine. The events have occurred during development advancement exposing faults, after the extraction of single stopes due to mining induced stress change, and due to time effects after delays of many days during which no mining had been conducted. This paper discusses the study completed consisting of a global or holistic approach aimed at mitigating some of the risks associated with the structurally controlled rockbursts at Garson. Background Garson mine is located in the south east area of the Sudbury Basin (Ontario, Canada). Mining occurs in two main ore bodies (the #1 Shear and the #4 Shear) which are copper-nickel-sulphide and occur within shear zones that (as well as the ore bodies) strike approximately east-west and dip steeply south. From the north (footwall), lithologies progress (Figure 1a) from norite (NR), to greenstone (GS), and finally to meta-sediment (MTSD). A generally WNW-ESE striking, bifurcated sub-vertical dyke of olivine diabase (OLDI) cuts the series. The current active mining block at Garson is between 4700L and 5100L (levels denote depth in feet below surface).

May 1, 2009

By H. F. Letient, D. C. Johnson

At the 25th Annual B.C. Mine Reclamation Symposium in September 2001, Huckleberry Mines Limited received the Jake MacDonald Reclamation Award for its exemplary mine waste management plan, conceived to prevent the onset of acid rock drainage (ARD) and facilitate reclamation of the site. The mine is an excellent example of a total mine waste management plan, with all materials scheduled in detail for the life of the mine. The filling plan for the waste management facility takes into consideration the requirement for permanently flooding the potentially acid-generating rock. From an acid generation point of view, the tailings fall in the zone of potentially acid-generating material. To avoid long-term ARD concerns, it is planned to float pyrite out of the tailings toward the end of the mine life, thereby generating a non-potentially acid-generating tailings stream which will be used to cap the deposited mine waste. The pyrite-rich tailings will be discharged into the deeper portion of the impoundment. On closure, a permanent water cover will be maintained over the mine waste. Only beaches of non-potentially acid-generating tailings will remain exposed. Mining will be phased to also allow one of the pits to provide storage for potentially acid-generating rock and to be flooded at the end of mine life.

Jan 1, 2004

By A. H. Winckers

"The San Nicolás deposit is a complex fine grained polymetallic volcanogenic massive sulphide deposit located in central Mexico.Metallurgical testwork was carried out in 1999 and 2000 to develop a flowsheet. During the course of the metallurgical testwork it became evident that it would be impossible to develop an accurate head gradehecovery based model for the projection of metallurgy. It was suspected that variability in mineral texture was a predominate factor affecting metallurgy. For this reason it was decided to evaluate the applicability of QEM*SEM technology to this test program.This paper summarizes the metallurgical testwork and describes the evaluation and subsequent application of the QEM*SEM technology to characterize the mineral texture throughout the deposit. Finally it is shown how the QEM*SEM data are used in the mine block model to project the metallurgy.The QEM*SEM (Quantitative Evaluation of Minerals by Scanning Electron Microscopy) is an automated image analysis system developed by CSRO which provides quantitative numerical estimates of the compositional and textural properties of the mineral suite which govern the concentration process.INTRODUCTIONThe San Nicolás deposit, was discovered in 1997 through the application of geological and geophysical techniques. The property lies 60 km southeast of the city of Zacatecas on the central Mexican plateau as shown in Figure 1."

Jan 1, 2002

By K. G. Thorne, L. J. Cabri, L. R. Fyffe, D. R. Lentz, D. Hoy

"Mineralization at the Main zone of the Clarence Stream gold deposit in southwestern New Brunswick occurs within a parallel series of quartz veins that occupy a NE-trending, steeply north-dipping, brittle-ductile shear zone related to the nearby terrane-bounding Sawyer Brook fault. This deformation zone cuts volcaniclastic sedimentary and volcanic rocks of the Silurian Waweig Formation, and is intruded by mantle-derived East Branch Brook gabbroic dikes and a number of felsic dikes. Intermittent shear-zone reactivation during local magmatic activity induced heterogeneous deformation and alteration of the country rocks and dikes. The terminal phase of shearing is associated with narrow pegmatite-aplite dikes that grade laterally into granophyric granite, and into an auriferous quartz vein. Gold, aurostibite, and gold-antimony intergrowths, predominantly with vein quartz, are associated with a low ƒO2 sulfide mineral assemblage (pyrrhotite, arsenopyrite, and berthierite) that has a sulfur isotopic signature consistent with a magmatic source. Gold saturation and deposition occurred episodically between 300° and 360°C at low activity of sulfur, predominantly in response to pressure reduction during brittle failure combined with the effects of decreasing temperature and sulfidation reactions during fluid-wall-rock interaction. Geochronological studies demonstrate that the timing of the emplacement of the pegmatite-aplite dikes and associated auriferous veins overlap with that of the Early Devonian Magaguadavic granite. Moreover, the composition of the dikes is consistent with their derivation from this granite as late fractionates. The Main zone of the Clarence Stream deposit is therefore interpreted to be intrusion-related, with the Magaguadavic granite being the ultimate source of the gold-bearing fluids. La minéralisation de la zone principale du gisement aurifère de Clarence Stream dans le sud-ouest du Nouveau Brunswick occupe une série de veines de quartz parallèles dans une zone de cisaillement fragile-ductile de direction NE et à pendage abrupt vers le nord apparentée à la faille de Sawyer Brook avoisinante qui délimite deux terranes. Cette zone de déformation recoupe les roches volcaniclastiques et volcaniques de la Formation de Waweig d’âge Silurien et est recoupée par les dykes de gabbro d’East Branch Brook, d’origine mantellique, ainsi que par divers dykes felsiques. La réactivation intermittente de la zone de cisaillement durant l’activité magmatique locale a entraîné la déformation et l’altération hétérogènes des dykes et de l’encaissant. La phase finale du cisaillement est associée à de minces dykes d’aplite-pegmatite qui passent latéralement à des granites granophyriques, puis à des veines de quartz aurifères. L’or, l’aurostibite et les intercroissances d’or et d’antimoine principalement associées aux veines de quartz sont associés à un assemblage minéral de sulfures à faible ƒO2 (pyrrhotite, arsénopyrite et berthierite) présentant une signature isotopique du souffre compatible avec une source magmatique. La saturation en or et la précipitation a eu lieu épisodiquement entre 300° et 350°C dans des conditions de faible activité de souffre, principalement en réponse à la baisse de pression durant la rupture fragile ainsi qu’aux effets de la baisse de température et aux réactions de sulfuration durant l’interaction entre le fluide et l’encaissant. Les études géochronologiques indiquent que l’âge de la mise en place des dykes de pegmatite-aplite et des veines aurifères qui leur sont associées coïncide avec le granite de Magaguadavic, d’âge Dévonien Précoce. De plus, la composition des dykes est compatible avec une origine provenant de ce granite sous la forme de phases fractionnées tardives. Le gisement principale (Main zone) de Clarence Stream est ainsi considéré comme étant associé aux intrusions, le granite de Magaguadavic étant la source ultime des fluides aurifères."

Jan 1, 2008