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By Adrian Dance

Barrick Gold Corporation?s wholly owned subsidiary, Barrick (Granny Smith) Pty. Ltd. operates the Granny Smith operation in Western Australia and has been operating a SAG/ball mill (SABC) circuit for a number of years processing a blend of secondary crushed, open pit and underground material. With closure of the open pit in 2008, Granny Smith was considering different options to process underground only material at a lower throughput. Using the existing equipment available on site, a number of circuits were evaluated by Metso Process Technology & Innovation (PTI) through modelling and simulation. A single stage SAG mill circuit was selected based on power requirements and operating efficiency. In April 2008, Granny Smith started operating their SAG mill in single stage, processing primary crushed feed and using their existing pebble crusher for scats. Smaller cyclones were used to control the final grind size. PTI surveyed the new single stage circuit in July 2008 under normal and high rock load conditions to show the effect on final grind size. Granny Smith continued to operate this circuit until the end of 2009, when alternate feed sources resulted in a return to the complete SABC circuit at a higher tonnage once again. The variable speed, single stage SAG mill proved itself to be very efficient and flexible option to process the hard underground Wallaby Deeps material. This paper will review circuit performance following the conversion to single stage in comparison with the full SABC circuit.

Jan 1, 2012

By Saravarim A.

"The aim in flotation systems is to control the grade and recovery of the product., numerical method or sampling and analysis is used to achieve this goal. Weakness of measuring instruments, lack of process knowledge, deficiencies in management and data processing in the control of flotation cells, has led the academic and industrial units to use numerical models. In this regard, using the results obtained from the experimental design carried out in the DTP line of Gol Gohar industrial and mining complex, a regression model was developed based on the analysis of variance. To present this model, after variance analysis of factors and interactions, all models were investigated and the final model was created based on 75% of the data. The model was tested with the remaining 25% of the data to confirm the goodness of the fit. The coefficient of determination for training and testing resulted 71% and 74%. Moreover, a feed forward back propagation neural network with different layers and neuron was used to model the results. The best network structure was 6-27-1 and the coefficient of determination for this network was 99% and 98% for training and test respectively. Given the complexity of neural network models and the relatively low accuracy of the regression model, neural network has a priority assuming we have access to a specialist. In addition, the results obtained from neural network can be used as expert systems to control and optimize the flotation cells.INTRODUCTIONThe primary objective of the flotation cell control is to maintain the product's (in this case tailing) recovery and grade, which represents the index for process efficiency and product quality. Continuous estimation of these indexes requires a significant amount of maintenance, and calibration of the continuous analyzers, in order to maintain an acceptable level of accuracy. Weakness of measurement equipment, lack of process knowledge and the general deficiency in management and processing of data in the flotation cell control, will lead industrial units to use smart methods such as mathematical models, regression and neural networks in near future (Panahi, Abdollahzadeh, & Sam, 2010). Artificial neural networks are inspired by the very complex structure of human brain in which millions of nerve cells solve problems or store information by communicating with each other. The duty of neural networks learning. It should be noted that learning in artificial neural networks is limited, and what is practically considered is the computing power of the network. A neural network consists of units called neurons, and has the capacity to handle a set of input data to produce a desired output data set. Each of these input and output data sets can be assumed as a vector (Soltanmohammadi & Noparast, 2006)."

Jan 1, 2016

By Rodrigo Serna-Guerrero, Ted Nuorivaara

"As the demand of raw materials increases in a global scale due to demographic and economical changes, it is necessary to find technological solutions that improve current production processes in an efficient and sustainable manner. The main objective of this preliminary study is to evaluate the properties of foam produced with a cellulose-based molecule as an alterative to commercial frothing agents in flotation operations. There are two potential advantages identified with the use of cellulose-based additives for the proposed application: i) these chemicals can be produced from sustainable sources (i.e., non-edible crops), and ii) cellulose can be functionalized with chemical groups, in order to rationally modify its behaviour. In previous studies dealing with foam stabilization, it has been proposed that some functionalized cellulose species present a self-assembly mechanism at gas-liquid interfaces. Unlike typical surfactant-based frothers, cellulose molecules form networks around the bubbles that act as protective layers to the mechanical stress and to the occurrence of ionic species. This work studied the properties of foams produced in the presence of a partially hydroxylated cellulose molecule (i.e., hydroxypropyl methyl cellulose; HPMC) under various concentrations in a laboratory-scale column. A comparison with a commercial surfactant frother (i.e., Nasfroth 240) is presented, and a rationalization of the behaviour of HPMC in terms of foam properties (i.e., surface tension, bubble size, foam depth) is proposed. INTRODUCTIONThe search for green alternatives to chemicals produced from non-renewable sources has become a topic of major relevance in industry (Choi et al., 2015). As a chemical consuming industry, the mining sector faces now the challenge of adopting new processing technologies and strategies in order to achieve the future demands of sustainability. Evidently, a move towards green chemistry can only take place by identifying substitute molecules offering potential advantages in terms of recovery and grade."

Jan 1, 2016

By M. N. Vu, G. Armand, A. Noiret, D. Seyedi

Extensive experimental observations have been performed around drifts and shafts at the Meuse Haute-Marne (North-Eastern France) Underground Research Laboratory (URL) to assess the extent and pattern of the induced fracture networks in Callovo-Oxfordian claystone. Two types of fractures can be distinguished, namely; shear (mode II) and extension unloading (mode I) fractures. The main goal of the present paper is to provide insights on the extent of damaged zone around the drifts by numerical simulations. A two-step approach is considered. First, 2D elastic calculations are performed for simulating the excavation of a drift following the direction of the major in situ horizontal stress. The evolution of the stress and strain tensors around drifts are calculated by applying an elliptic convergence function on the drift wall. Two failure criteria are then verified for the induced damage. An equivalent strain and an elastic energy based damage criteria are considered. The obtained results show that the employed simplified approach provides rather good results for the extent of the damaged zone for drifts parallel to major horizontal stress. However, post-processing elastic results leads to overestimating the vertical extent of the damage zone and underestimating its lateral extent, where the in situ stress state is quasi-isotropic in a section of drift. Nevertheless, the obtained results show that an energy based damage criterion could be considered as a potential way for reproducing the extent of the damaged zones if a convergence function can be defined for the drift.

Jan 1, 2015

By C. Mawdsley

The Tata Steel mill at Skinningrove in the North East of England produces top hat sections for mineshaft guides in sizes 102 and 150 mm. The top hat section is the technically preferred shaft guide choice for modern deep mine shafts. This paper explores the relative service performance of top hat and square hollow section guides in service. Comparative corrosion performance is reviewed and the paper describes work commissioned by Tata Steel (as Corus) undertaken by Aker Kvaerner Engineering to evaluate relative winding speeds, relative loads and fatigue life in service. The experience of supply to UK Potash mining is discussed and the future view of high capacity hoisting and larger section size market need and availability is assessed.

Aug 1, 2013

By A. Alwasel

Musculoskeletal disorders (MSDs) threaten the wellbeing and livelihood of a large number of construction workers incurring a significant cost to society. We present a new method to monitor and diagnose MSD risks in the workplace. The sensing unit of the system is an optical encoder encompassed within a non-intrusive exoskeleton to measure the joint angle of interest. This sensor can be applied to ball-and-socket and hinge-type joints of the human body, such as the shoulder, elbow, and knee joints. The system is contactless and does not require markers or cameras. Angle measurements are acquired directly without mathematical post-processing, thereby avoiding numerical noise and drift challenges. The system is a simple, robust, and deployable, but it currently lacks resolution of parallel degrees of freedom.

Aug 1, 2013

By F. Sorenson, P. A. Castellarini, F. Garbarino, M. N. Garcia

"Recently, significant efforts to improve productivity from the tight intervals of the Mulichinco Formation within the Sierra Chata Field in the Neuquén Basin have been ongoing. Because conventional high quality reservoirs were being developed in this field, a proper reservoir understanding and completion approach was applied. After developing these high permeability reservoirs, the operator began evaluating the tight intervals and new areas within the field, but a completely different approach was necessary to achieve motivating production improvement.An extensive study to help enhance reservoir understanding and identify key factors controlling productivity of these tight intervals (which tend to be in the range of 5 µD) has been ongoing. Some of the issues discussed in this study are 1) petrophysical review, 2) rock properties calibration, 3) geomechanics understanding, 4) faulting and micro faulting/lineaments description, 5) stimulation and completions review and, 6) understanding key production drivers.As in many other tight reservoir projects, a considerable area of the reservoir must be effectively stimulated during the hydraulic fracturing process to achieve economic productivity. Two critical issues hinder these objectives. First, the low permeability in addition to a pore pressure close to or even lower than hydrostatic are critical characteristics when attempting to flow back the well and clean up fractures. Second, very high horizontal stress anisotropy resulting from a strike slip stress regime promotes the generation of simple planar bi-wing fractures. It is well-known that this fracture geometry will contact much less reservoir area compared to more complex fractures, as the operator would normally intend to create at very low permeability reservoirs.This paper discusses these issues and how they were addressed. A pilot drilling and completion program was initiated during 2012 to validate this study. Key factors include well location relative to formation unconformities, their orientation relative to the far field principal stresses, hydraulic fractures generated, and overall completion design."

Jan 1, 2015

By J. E. Nesset

Significant progress has been made over the past few years on characterizing and understanding the hydrodynamic properties of frothers and collectors and their effect on flotation performance. This new understanding of the relationship between chemistry and hydrodynamics has dramatic implications for how flotation circuits should be controlled and optimized. Previous work has shown that choosing a frother of the right 'strength' is critical to the optimization process, and the work and discussion presented here serve to strengthen the argument. In addition, we know that collector chemistry may also influence hydrodynamic properties and needs to be taken into consideration. To achieve the desired outcome, the overall system of reagents and operating parameters must be considered. This paper describes and discusses some of the findings from recent research on frother and collector chemistry effects (on hydrodynamics), and how this knowledge can be used to improve flotation performance. Examples from plant experience are discussed.

Jan 1, 2009

By J. B. Hadaway

The operation at Phu Kham commenced design and construction in early 2006 and was commissioned in May 2008. This paper will examine and discuss the project from the inception of flow sheet development and equipment selection, equipment design and manufacture, construction, commissioning and ramp up to full production. The paper will touch on the strategies employed to achieve a short schedule and the efficient use of capital, but with the main emphasis on the grinding circuit. Various challenges during the early years of operation will be discussed including the effect of ore characteristics, including competency, on the performance of the grinding circuit. Actions to overcome these challenges and to enhance performance will also be discussed. Finally, current and future plans to improve the performance of the grinding circuit and the overall plant will be summarised.

Jan 1, 2012

By Jun Wang, Bo Zhang, Wenqing Qin, Guanzhou Qiu, Xiaozhen Ma, Key Lab of Biohydrometallurgy of Ministry of Education, Fen Jiao, Central South University, Yansheng Zhang

"Arsenic contained in minerals sulphides such as enargite and tennantite can represent not only a significant penalty element in base metals production, but also a disadvantage to the environment through producing the toxic emissions to the atmosphere. The achieving separation of arsenic bearing minerals either at an early stage in floatation or from the floatation concentration is significantly beneficial to the economic. However, there was no feasible commercial method of separation at the flotation stage because of its similar flotation properties with many other copper sulphides. In this work, the selective floatation of enargite from copper sulphide concentrate containing maily covllite, chalcoctie, bornite and enargite was investigated. A low arsenic concentrate with As 0.2%, Cu 22% and a high arsenic bulk concentrate with As 7.65%,Cu 33.65% were obtained. It was indicated that Ca(ClO)2 is the effective depressor and the optimum floatation condition was obtained. Most enargite could be floated at pH 11 and controlling the pulp potential at 290 mV SHE. Furthermore, the arsenic removal from the high arsenic bulk concentrate by hydrometallurgy methods was study. The results showed that the reaction temperature and the concentrations of NaOH were the most important variables affecting the rate of arsenic removal. A low arsenic concentrate with As 0.24%, Cu 37.80% was obtained in the optimum leaching condition.INTRODUCTIONArsenic is mainly produced as a by-product of base metals smelting, in particular copper concentrate. China has imposed an upper limit of 0.50% arsenic for concentrates entering (Long et al., 2012). Arsenic amount of copper concentrate within 0.40% has also been imposed in China, and above which will be introduced about 50 RMB penalties per ton for each 0.10% increasing by smelters now. Therefore, it is necessary to remove arsenic from the copper concentrate.In copper concentrate, arsenic is mainly in the form of arsenopyrite (FeAsS), enargite (Cu3AsS4) or tennantite (Cu12As4S13). There are two types of arsenic in the separation of copper and arsenic: arsenopyrite and arsenic bearing copper mineral. It is easier to separate arsenopyrite from the copper sulphide by flotation in comparsion with the separation of enargite or tennantite from non-arsenic copper minerals (Pineda et al., 2015). The main difficulty in the separation of arsenic copper mineral from non-arsenic copper sulphides is their extremely similar floatability, which depends on the fact that tennantite and enargite contain high copper content (Pineda et al., 2015)."

Jan 1, 2016

By B. R. Bowerman, W. J. Thoburn, M. J. Humphris

"Nickel granules are produced for carbonylation by pouring a molten stream into a path of high pressure water. Granules and water are separated in dewatering bins. The overflow, which contains up to 0.1 weight percent solids, was initially cooled and recycled to the granulating step. However, the rate of buildup of these solids in the handling system was intolerable. A lamella thickener was installed to solve the problem by removing solids from the dewatering bin overflow. Its description, application and performance to date are discussed.The lamella thickener treats a slurry containing about 0.1% solids of which about 30 weight percent is less than 325 mesh. It recovers 80 to 90 percent of the input solids in an underflow slurry containing 90 weight percent solids. Since its installation the frequency of cleanout of the recycle water handling system has dropped from about once per month to about once or twice per-year."

Jan 1, 1977

By Daniel Lachapelle, Nuri Hmidi, Turgut Yalcin

"Simulation can serve as a convenient tool in studying the behaviour and performance of grinding circuits by facilitating the evaluation of various scenarios and identification of optimum operating conditions. This technique was applied to the St Andrew Goldfields Ltd.’s Stock Mine Mill which is a 1300 tpd gold milling facility, offering custom milling services as well as processing the Company’s own ores. Lack of adequate instrumentation in the mill poses a challenge in attaining optimum performance especially with changing ore types and characteristics. The grinding process is monitored essentially by manual measurement and adjustment of pulp densities at various streams. A simulation program was designed to assist in the effective implementation of this mode of grinding control. Product sizes from both the primary and secondary grinding circuits were correlated empirically to relevant process variables using a database formed from the results of past sampling campaigns. The simulator was created in Microsoft Excel whose data analysis and optimization tools coupled with its Visual Basic Programming capabilities were found to provide an excellent environment for the development of a cost-effective, efficient and user-friendly simulation program.INTRODUCTIONGrinding is often a very costly unit process in milling operations, mainly due to the excessive energy consumption associated with it. For example, for a Canadian copper-zinc flotation mill, grinding was listed as being the most costly item taking up 30.4% of the total milling expenses, followed by the flotation cost at 2 1 .O% (Kidd Creek Mines Ltd., 1982). A survey on 45 copper flotation mills around the world showed the average grinding cost to be 34.5% of the total milling cost (Weiss, 1985).Overgrinding aggravates the cost issue, while insufficient grinding either causes loss of valuable minerals to tails or results in low-grade concentrates. Therefore, it is essential that grinding circuits be carefully controlled and monitored. To this end, a great deal of effort has been devoted over the years to the modelling and simulation of grinding systems in order to assist in the efficient running of these processes."

Jan 1, 2001

By H. -L. Heikkilä, E. Peuraniemi

"Boliden Harjavalta Oy has a long tradition in the Finnish metal industry starting from the 1930's. The Smelter consists of copper and nickel flash smelting lines. Off-gases are captured in the acid plant to produce sulfur products. During the early years of production, the surrounding environment suffered from high SO2 and dust emissions. The first acid plant started in 1947, a few years after commissioning of the smelter. The flash smelting method was developed and commissioned in 1949. This created the basis for today’s environmentally sound metal production. Recent air emission reductions are related to treating lean ventilation and granulation gases. Emissions from the stacks are monitored with continuous measurement devices. SO2 and PM10 concentrations are also measured from the residential area and reported online in cooperation with Harjavalta community and other local industry.INTRODUCTIONProductionBoliden Harjavalta Oy smelts copper and nickel concentrates and refines copper in the western part of Finland. The copper concentrates come from external copper mines mainly in South America and Europe. Concentrates are unloaded at the Pori harbor and transported to Harjavalta by train from a distance of about 60 km. Boliden Harjavalta Oy has operations in Harjavalta and Pori. The smelter in Harjavalta produces copper anodes that are transported via railway to the copper refinery in Pori. The anodes are electro-refined into copper cathodes and by-products like Se, Ag, Au and Pt/Pd concentrate. In the Harjavalta smelter SO2 containing gases are delivered to a sulphuric acid plant where sulphuric acid and liquid sulphur dioxide are produced.Our nickel smelter smelts nickel concentrates on a tolling basis to produce nickel matte for customer needs. SO2 containing off-gases are delivered to the sulphuric acid plant for sulphur capture and modification into products.All our operations are certified according to the Quality, Environmental and Occupational Health and Safety Standards ISO 9001, ISO 14001 and OHSAS 18001. Boliden Harjavalta Oy was the first company in Finland operating in the metal and technology industry to be certified according to the Energy Management Standard EN 16001, currently this certification is done according to ISO 50001."

Jan 1, 2012

By M. O. Makwarela, M. W. Erwee, K. Bisaka

"Energy efficiency in mining and minerals processing forms part of Mintek’s long-term research strategy which includes a specific programme designed at overcoming the challenges faced by the South African pyrometallurgy industry.The electric smelting industry is currently severely constrained by the global economic downturn as well as by the availability and increasing cost of electricity. Efficient utilisation of electricity through energy recovery systems and improved smelting process flowsheets can significantly contribute towards creating sustainable operations.Apart from efficient engineering design and solid process control, smelting of either cold or hot pre-reduced ores has been shown to decrease furnace electricity consumption by more than 40%. Various methods of solid-state reduction tests have been carried out at Mintek in order to select the most appropriate process option in the context of the South African industry. This paper summarises a subset of the results obtained, specifically on pre-reduction tests done on South African chromite and manganese ore pellets.In this set of tests, it was found that the use of an organic binder, together with B2O3 as flux, promotes manganese ore pre-reduction, but retards the pre-reduction of chromite. By pre-reducing the manganese ore feed, significant cost savings can be achieved in subsequent smelting processes and there is potential to minimise manganese losses as a result of fuming, due to possible lower operating temperatures."

Jan 1, 2016

By Martin Grenon

This paper presents two case studies where fracture set orientation was quantified using three methods: a simple fracture pole grouping, a Fisher distribution and a Kent distribution. The three fracture orientation representations were then used as inputs for kinematic slope stability analysis. Differences showed up in the probability of sliding for all instability modes considered.

Aug 1, 2013

By G. Scamans, J. Lazaro-Nebreda, Z. Fan, J. B. Patel

"Melt quality is crucial for both continuous and shape casting of light alloys and in order to improve it, removal of excessive inclusions, accumulated impurities and unwanted gases becomes necessary. To address this problem, a new multi-purpose high shear liquid metal treatment technology, based on intensive melt shearing by a rotor/stator unit, has been developed. The device ensures achieving uniform temperature and chemical composition and an efficient dispersion of gas and solid phases in the melt with minimal disturbance of melt surface, and can be used, among other things, for de-gassing and de-ironing of Al-alloy melts. Efficient degassing is achieved by dispersing each argon bubble into many small ones, which significantly increases the overall surface area of the bubbles and the time they remain in the melt capturing hydrogen before reaching the surface. This allows using much lower inert gas flow and mixing times than conventional rotary degassing. When applied to Al-alloy scrap, with accumulated iron, the high shear melt treatment speeds up the nucleation and growth of primary Fe-rich intermetallic particles, allowing a faster removal rate. Therefore it reduces processing times, increasing recycling productivity, and facilitates full metal circulation of secondary Al-alloys.INTRODUCTION Aluminium and magnesium alloys are widely considered in various industrial sectors for the purpose of weight saving (Polmear, 1995). In particular, they are used in the automotive sector, where components are mostly manufactured by high pressure die casting (HPDC) because of its simplicity and relatively low cost, but efficiency and mechanical properties are quite low compared with other processes. To date, the main focus to overcome this problem has been for improving the HPDC machinery (Dahle, 2001) but little attention has been paid to the opportunities of controlling the nature and quality of the molten metal supplied to the die. In this way, liquid metal treatment, which involves a variety of physical and/or chemical processing methods to improve melt quality prior casting, is crucial for both continuous and shape casting products."

Jan 1, 2018

By 13409, B. Arjang

"Ground stresses are one of the significant factors in the context of rockbursts and underground instability at some hard rock mines in Canada. Overcoring strain relief measurements using triaxial strain cells were performed at several mine sites to provide stress data for stability evaluations and mine design. Pre-mining stress determinations carried out at depths between 60 m to 1890 m resulted in the following average stress gradients:Maximum horizontal stress, s Hmax = 8.18 + 0.0422 MPa/m depthMinimum horizontal stress, s Hmin = 3.64 + 0.0276 MPa/m depthAverage horizontal stress, s Ha = 5.91 + 0.0349 MPa/m depthVertical stress, a; = 0.0266 ± 0.008 MPa/m depthThe maximum and minimum horizontal compressive stresses, with an average ratio of J.75 ± 0.45, prevail in east-west and northerly directions, respectively. Horizontal compressive stresses in excess of vertical overburden load were determined, indicating large variations in ratios to a depth of about 1000 m with decreasing trend toward depth.From present data, a particular regional zoning for the magnitude and direction of horizontal stress fields cannot be outlined.A common feature at mines with near vertical orebodies is that the maximum horizontal stress acts perpendicular to strike while the minimum horizontal stress is aligned on-strike. The vertical stress components approach the gravitational overburden load."

Jan 1, 1991

By P. K. Kaiser, C. D. Martin, F. Amann

"This article focuses on the uniaxial compressive strength (UCS) of homogeneous and heterogeneous rocks. Critical factors impacting the UCS of rocks are reviewed and then separate assessments of UCS data from homogeneous and heterogeneous rocks are presented. The variability (coefficient of variation) of UCS test results for homogeneous rocks is found to be generally <25% while for heterogeneous rocks the variability is >35%. Failure mode variation is found to be the cause of the variability of UCS test results in heterogeneous rocks. Empirical engineering design methods that use UCS as an input parameter are discussed and suggestions are provided for selecting appropriate UCS values.INTRODUCTIONThe UCS is one of the most commonly used rock engineering parameters whether for rock mass classification or for strength determination. The mean UCS and its variability are often assumed to represent a reliable rock material property. For the reasons discussed in this article, UCS is rarely representative of the intact rock UCS. The UCS test simply records the collapse load during uniaxial loading of a cylindrical specimen. As suggested by many, the UCS is an index rather than a unique engineering parameter. The UCS is thus a proxy for rock strength which depends on the loading rate (e.g., Bieniawski 1967), specimen geometry (e.g., Hudson et al., 1971), specimen size (e.g., Bieniawski 1968), and many other factors. Furthermore, the UCS is not the same as the Hoek-Brown strength criterion parameter sci.There are differences in opinion on what is commonly considered to be ‘intact rock’. When sampling ‘intact’ pieces of core from drillholes crossing blocks of rock bound by block forming discontinuities, samples will be ‘intact’ but some samples will be veined, others will be damaged, and others will be neither. According to Hoek (1983), intact rock pieces are “the unfractured blocks occurring between structural discontinuities in a typical rock mass” and the sci parameter for intact rock is determined using the fitting procedure proposed by Hoek and Brown (1997) based on the data requirements outlined by Hoek (1983). Studies (e.g., Bewick and Kaiser 2014; Kaiser and Kim 2014) have shown that independently determined UCS and sci values for the same rock type are not equivalent. Thus, UCS data cannot be used as a replacement for sci."

Jan 1, 2015

By N. Saracoglu, J. P. Golightly, R. H. Wallis, J. J. Brummer

"The McClean uranium deposits are located 11 km west northwest of the Rabbit Lake Mine. Their average grade is 1.8 % U3O8 , and they contain 6. 350 tonnes of uranium oxide in seven pods of variable grade and mineral assemblage. They are hosted by both basal Athabasca Group and the regolith developed on the underlying crystalline basement. The major mineral facies are: sulphide, arsenide, 'bleached', and hematite, with the important uranium minerals being coffinite, uraninite and pitchblende. Abundances of carbon and sulphur isotopes are consistent with their derivation from pyritic graphite in basement gneisses. Isotopes of oxygen and hydrogen suggest equilibration at temperatures of about 200°C. Ar39/ Ar40 age determination of illite associated with ore suggest mineralization began about 1300 m.y. ago and that significant alteration had ceased by about 1170 m.y. ago though Pb/ U data suggest the deposits continued to evolve into the Mesozoic.IntroductionThe McClean deposits lie on the eastern side of the Athabasca Basin of northern Saskatchewan where they are part of a cluster of uranium deposits lying west of Wollaston Lake (Fig. 1). The general stratigraphy is schematically portrayed in Figure 2 which emphasizes that mineralization is hosted by both the Athabasca Group and the underlying regolith and also that the deposits are preserved at depth and have not suffered from preand post-Pleistocene weathering and erosion. This circumstance, combined with their simple shape and the presence of seven separate zones of mineralization (pods) allows a description, based on over 450 fully cored drill holes, to be made of the wide variation in chemistry, grade, alteration patterns and position relative to the sub-Athabasca Group unconformity. Ar39 / Ar40 age determinations have been made of illites associated with regolith, Athabasca Group and mineralization and studies are in progress on C, S, 0 and H isotopes of mineralized material and host rocks. Only some of these data have been published; Brummer et al., (1981); Golightly et al., (1982); Bray et al., (1982); and Saracoglu et al., (1983). The only other published data on McClean geology are by Tremblay (1982, 1983)."

Jan 1, 1986

By M. A. Vasina, I. A. Matveeva, E. A. Naumova, V. V. Doroshenko, N. A. Belov

"Using the calculated (Thermo-Calc software) and experimental methods (SEM, TEM, EMPA, DSC, XRD, etc.) the phase composition, structure and hardening of aluminium alloys of the Al-Ca-Zn-Mg system were studied in the following range: 2. 5%Mg, up to 10% Ca, and up to 14% Zn (wt%). Fragments of this quaternary phase diagram in the aluminium corner were constructed, including the liquidus surface, as well as some vertical sections. It was shown that the relatively large amount of zinc enters in the Ca-containing phase, which formula can be described as (Al,Zn)4Ca. An increase of Zn content leads to formation of Al4Ca primary crystals at lower concentrations of calcium. The eutectic (Al)+(Al,Zn)4Ca has a fine structure and aluminide particles are capable to spheroidization during the heat treatment at temperature 500 C. The maximal level of hardness observed on calcium containing alloys was higher than 200 HV, what gives the reason to expect good strength properties. With an example of an Al-9% Zn-2,5%Mg-3,5% Ca model experimental alloy based on the (Al)+(Al,Zn)4Ca eutectic, a principal possibility of manufacturing thin rolled sheets was demonstrated.INTRODUCTION Aluminum alloyed with calcium was first studied in 1970-80s by such authors as Piatti (1976), Moore (1978, 1980), Il'enko (1985), Swaminathan (1990), and Perez-Prado (1997) as superplastic materials. In particular, the alloy systems Al-Ca-Zn were studied (Il'enko, 1985, Swaminathan, 1990, Perez-Prado, 1997). For some time there was no new published works concerning the aluminum-calcium alloys. During the last years many works were published dedicated to the calcium alloying of magnesium alloys (Kim, 2011; Xu, 2011; Aljarrah, 2008; Bakhsheshi, 2014). This urged the authors (Belov, Naumova & Akopyan, 2016) to start studying cast and wrought aluminum-calcium alloys for construction (2008–2014). There is almost no information in the literature concerning triple and more complex diagrams of the aluminum-based system states with calcium and other elements. In recent work, parts of the state diagrams are plotted for the aluminum angle zone: Al-Ca-Mg-Sc (Belov, Naumova & Bazlova, 2016), Al-Ca-Ni-Sc (Belov, Naumova & Bazlova, 2017), Al-Ca-Si-Sc (Belov, Naumova & Akopyan, 2017) and others. Special attention was paid to the study of the system Al-Ca-Zn-Mg (Naumova, 2017). Based on this system creation of advanced extra-high tensile alloys is planned. Wrought extra-high tensile alloys series 7??? based on the system Al-Zn-Mg-Cu are well studied."

Jan 1, 2018