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By M. J. King, A. Weissenberger, W. G. Davenport

Keywords: Pyrometallurgy, sulphuric acid, sulphur dioxide The raw material for sulphuric acid manufacture is clean SO2 gas. It comes from (i) burning molten by-product sulphur; (ii) roasting or smelting metal sulphide concentrates, and (iii) decomposing contaminated organic chemical process sulphuric acid catalyst. Efficient gas cleaning is required for metallurgical and contaminated acid decomposition gases, especially the former. Sulphuric acid is made from SO2 gas by (i) oxidizing the SO2(g) to SO3(g) in contact with supported liquid-phase catalyst then (ii) reacting the resulting SO3(g) with the water component of 98.5 mass% H2SO4, 1.5 mass% H2O acid. This paper discusses the reasons for these process steps and indicates how acidmaking can be controlled and optimized. Special emphasis is placed on SO2(g) oxidation efficiency and how it is influenced by feed gas composition, feed gas temperature, catalyst composition, catalyst bed pressure, number of catalyst beds, and double versus single contact acidmaking. In addition, a review of various other treatment methods for SO2-bearing gases is provided. A brief description of each process is included along with commentary on their technical and economic applicability for use at metallurgical facilities.

Jan 1, 2006

A description is given of preliminary work done to identify the problems inherent in electrochemical oxidation of metal sulphides, and particularly in the use of powder compacts as anodes in electrolysis. Lead flotation concentrate pressed into a compact can serve as an anode for direct electrowinning of lead according to the reaction PbS -7 Pb2+ +So +2e. No pYrometallurgical step is required, and sulphur is recovered in elemental form.In the experimental work, electrical conductivity of the compacts was achieved by addition of 5·5 per cent of graphite. After compaction at 10-20 tons/sq. in. the anodes were strong and remained intact throughout the electro-oxidation period. Perchlorate electrolyte was used, but fluosilicate electrolyte is also applicable. A sheet of pure lead formed the starting cathode.As anode potential increased above 1·0 V (v. SHE) PbS04 was formed in increasing amount. At 0·90 V, Pb2+ extraction efficiency was 85 per cent. Anode potential was kept low by electrolysing at 60°C and 15 mA/sq. cm., and by improving the porosity of the compact. Other metal sulphides (Zn, Fe, Cu) in the flotation concentrate also oxidize and release metal ions to the electrolyte, which would need to be purified prior to deposition of lead.Power requirement in a laboratory cell was about 0·24 kWh per lb of lead extracted.

Jan 1, 1972

By J. C. Schneider, G. Van Weert

Hydrochem Developments Ltd. has developed and put into full scale operation a novel type of vertical flotation column incorporating a multiplicity of mechanically agitated stages. Characteristics of this flotation column include a low height to diameter ratio, high upgrading factors and the possibility of modifying geometry and operation to specific flotation requirements. A commercial unit is currently handling up to 100 tpd rougher concentrate at Dickenson Mines Limited, Balmertown, Ontario. Design parameters and plant performance will be discussed.

Jan 1, 1988

By Brian Fulcher

In April 1997, Kiewit/Parsons Brinckerhoff (K/PB) completed the 7,600-m (25,000-ft) primary access tunnel for the Yucca Mountain, NV proposed high-level nuclear waste site. K/PB then began boring an exploratory east-west cross drift tunnel at the site. The 2,681-m (8,796-linear ft)East-West Cross Drift Tunnel was excavated through volcanic tuffs having zones of incompetent rock using a rebuilt Robbins 5-m (16.4-ft)hard-rock tunnel boring machine(TBM) with a special arrangement of supporting equipment. This portion of the Yucca Mountain project was completed in eight months.

Jan 1, 2000

R. W. Raymond, New York, N. Y,:—Since the presentation of my note on this subject at the New York Meeting, Professor Louis has pointed out an error in my statement of his conception of " pitch "—namely, he understands the pitch, in the restricted sense which he proposes, to be the angle of inclination of the axis of an ore-body, measured on the vertical plane drawn through the body; whereas, I represented him as proposing to define " pitch " as the angle of inclination of an oblique body, measured on the plane of the dip, in the direction of the strike. The difference will appear upon consideration of the accompanying isometric projection, Fig. 1, in which ABCD represents the plane of the inclosing ore-deposit (vein or bed), and AC the axis of the oblique ore-shoot. ABE is the angle of the dip, as universally understood; and ACE

Jan 1, 1909

The reactions between molten aluminium and cryoIite have been determined from a material balance of all components involved in the process. The interpretation of results were supported by x-ray diffraction studies of the evolved vapours, quenched electrolyte samples, and side-reaction products.The most important reaction involves the formation of both Na2F (sodium subfluoride) and chiolite in the fused electrolyte. The Na2F accelerates vaporization of the melt. Some AIF (aluminium monofluoride) may also be formed but the proportion of this is much less than for the former subvalent compound.

Jan 1, 1968

By Peter Grundy

La eficiencia de los recursos en los procesos transparentes de gestión de las empresas permite aumentar el valor de los accionistas. En ese sentido, el presente texto señala el uso de la RCM como estrategia en el funcionamiento de un equipo que se centra en la confiabilidad. RCM es un proceso lógico que involucra aspectos técnicos y de negocio, capaz de producir resultados a muy corto plazo. Este proceso concluye con una recopilación de documentos fiables y totalmente óptimos para el desarrollo de las funciones de mantenimiento. Su uso correcto en la evaluación de los requisitos de mantenimiento de los equipos existentes, genera un mantenimiento menos costoso, confiable y eficaz. Asimismo se disminuye los costos de mantenimiento y se relaciona los aspectos ambientales y de seguridad.

Jul 17, 2000

Like it or not, CPD is upon us. As from 1 January 2006, all registered engineering professionals, i.e. professional engineers, professional engineering technologists, professional certificated engineers and professional engineering technicians, were required to undertake CPD in order to keep their professional registration current. The rules regarding CPD have been gazetted under Government Gazette No. 28328, Board Notice 131 on 23 December 2005, and they also appear on the ECSA website?www.ecsa.co.za. For the convenience of our members they are reproduced in full in this issue of the SAIMM Journal.

Jan 1, 2006

By Takefumi Takuma, Masashi Nagano, Christopher DellAringa

Multiple agencies in Southern California are retrofitting and upgrading their levees to catch up with ever-advancing urbanization affecting the requirements for existing channels and levees in this seismically active zone. Pressed-in sheet piles have been specified on some of these projects to minimize noise and vibration problems associated with sheet pile installation. This paper will study three Southern California levee and sewer pipeline retrofit projects that utilized pressed-in sheet piles in hard soil conditions with N-values higher than 50. BACKGROUND Southern California is home to numerous drainage channels fortified with earthen levees. In spite of the region’s semi-arid climate with varying annual precipitation from year to year, winter storms can bring in heavy and continuous rainfall to the area which overwhelms the levees’ capacities at times. Some levees are running through densely populated areas with homes and other sensitive structures such as underground utilities and bridge piers. Conventional sheet pile driving utilizes either percussive or vibratory pile driving methods, both of which generate high levels of noise and vibration, causing nuisance and potential damage to nearby structures. On the other hand, the press-in piling method utilizes a hydraulic force to push piles into the ground, thus practically eliminating the noise and vibration issue. Although there are types of press-in piling systems mounted on tall leaders on large crawler-base machines, they are less frequently used due to its much larger size and more limited drivability than the type discussed hereunder. The other type of press-in machine sits on top of already installed piles and is anchored with its own weight and additional counter weight when starting off as shown in Figure 1. Once the first few piles are pressed in, the equipment grips on top of the installed piles and moves forward on its own as the pile installation progresses. See Figure 2. This method does not use a vibratory or percussive force to install piles.

Jan 1, 2018

By H. Tveit, E. H. Myrhaug, J. K. Tuset

Silicon metal as a commodity material is produced by carbothermic reduction of quartz in electric submerged arc furnaces, where CO2 forms as a by-product. Since 1997 the Norwegian Ferroalloy Producers Association have been engaged in research programmes aiming for reduced CO2-emissions associated with fossil carbon in their processes. One important issue has been to study how charcoal and wood chips perform compared to coal and coke in the silicon process. The ability of the carbon-rich reduction materials to react with SiO-gas is commonly assumed to be of large importance to the performance of the process. Based on laboratory experiments with different carbon materials, combined with estimation of parameters in a mathematical model of the reaction between carbon and SiO-gas, a foundation for a theoretical study of the performance of the carbon materials in a silicon furnace is established.

Jan 1, 2004

By William D. Spielvogel

The Massachusetts Highway Department awarded the Porter Street Outfall Project to the J.M. Cashman Company in November 1991. Timely completion of the Project in one and one half years is critical to the start of the subsequent Third Harbor Tunnel North Approach project. Existing subsurface conditions and the Project's location at Boston's Logan International Airport significantly increases the difficulty of construction. The major contractual work involves relocating a reinforced concrete double box culvert supported on a continuous wood pile foundation. This existing culvert crosses and interferes with the future Third Harbor Tunnel North Approach alignment. Two parallel culverts constructed approximately 20 feet from either side of the future Third Harbor Tunnel alignment replace the existing double box culvert structure. Under the original contract design, approximately 3,100 feet of 14 ft. by 15 ft. reinforced concrete culvert is cast in place adjacent to the west side of the Third Harbor Tunnel and is located in the center of the Airport's main service roadway, Harborside Drive. This culvert is the Porter Street Combined Sewer, PSCS, which handles a combined flow of sewerage from the East Boston community and storm water runoff from Logan Airport. In addition, approximately 2,230 feet of 17 ft. by 15 ft. reinforced concrete culvert is cast in place adjacent to the east side of the Third Harbor Tunnel and is within 20 feet of an active aircraft taxiway and heliport. This culvert is the Bird Island Flats Storm Drain, BIFSD, which handles storm water runoff from the Logan Airport airfield. The existing outfall, on the west side of the Third Harbor Tunnel alignment is to remain in service and is to be connected to the new PSCS and BIFSD culverts. Therefore, a portion of the BIFSD culvert is designed as a bridge to span 128 ft. across the Third Harbor Tunnel excavation during construction.

Jan 1, 1994

By E. P. Youngman

This paper presents one of a series of digests of foreign mining legis- ation and court decisions that is being prepared in advance of a generel report elative to the rights of American citizens to explore for minerals and to own nd operate mines in various foreign countries. This interpretation of the laws of Demark and her possessions, has been prepared entirely from answers made by Ernest L. Ives, American charge d'effaires, Copenhagen, to a questionnaire ini- isted by the United States Bureau of Mines and transmitted through the courtesy of the Department of State.

Jun 1, 1932

By J. Brian Anderson

Jointed micropiles were investigated to support bridge foundations where shallow rock was present. In this application, micropiles would have some amount of unsupported length, and would be subject to nominal lateral loads. Five lateral load tests were conducted on micropiles to demonstrate the impact of casing joints and rock socket embedment on lateral behavior. Load tests were simulated with FB-Multipier, a hybrid-finite element program for analysis of deep foundations, for proper design of the loading apparatus and instrumentation. The micropile sections were 2 m (6.56 ft) long, 273 mm (10.75 in) in diameter, 13 mm (0.5 in) thick walled, with a 50-mm (2-in) long threaded joint. Micropiles were made of one to three casing sections and were embedded 0.3, 0.6, 1.5, or 3.0 m (1, 2, 5, or 10 ft) into rock. In each test, two identical micropiles were pulled together using a simple frame until the weaker pile failed. All micropiles were instrumented with inclinometer casings while two contained strain gages at 0.76 m (2.5 ft) intervals. Load and displacement were measured at the pile heads. Tests showed the embedment of 0.6 m, 1.5 m, and 3.0 m (2 ft, 5 ft and 10 ft) sufficiently carried lateral loads over 180 kN (20 tons). The piles embedded 0.3 m (1 ft) were not able to maintain lateral load. In general, all micropiles tested to failure exhibited a brittle failure mode where there is small lateral deflection followed by a sudden failure at the casing joint. This was demonstrated in three of the load tests. In most cases, the micropiles were stiffer and stronger in the load tests than originally predicted numerically. The final test, where piles were not loaded to failure, verified that embedding vibrating wire rebar strain meters in the grout captured the bending moment profile of the micropile. The results showed the maximum moment in this case being carried directly across the threaded joint as predicted by the preliminary models. The results of these tests were used to calibrate the FB-Multipier numerical model. Using a load test that included bending strain measurements for a match, the soil properties were adjusted to produce reasonable matches for all of the load tests.

Jan 1, 2011

Electricity will play a major part in providing energy services in the 21st century. Ecologically Sustainable Development (ESD), that is accommodating the needs of the present without compromising the needs of future generations, will provide a focus for optimising the use of electrical energy. Environmental externalities may redefine the cost structure of electricity. Strong corporate environmental management will ensure that current environmental objectives are met and that future ones, identified by the ESD process and environmental externalities accounting, can be developed and implemented by receptive business managers. This paper addresses the current environmental issues of electricity production. It outlines a management strategy for the SECV becoming a community leader in protecting the environment. ESD is discussed in terms of using non-renewable resources wisely, extending their availability and putting in place mechanisms which ensure their ultimate substitution by renewable resources and conservation. The paper explores options for dealing with costing environmental externalities, particularly in relation to greenhouse emissions.

Jan 1, 1992

By G. S. Pauley

Paper presented at a meeting on: Artificial intelligence in the minerals sector, held in Nottingham, UK, 20 April 1993 (original title: Case-based reasoning can be a catalyst for improvement). A new computer software technology known as Case Based Reasoning (CBR) can be used to produce small decision support systems that are economically viable. This is because the knowledge that they contain can be owned and maintained by their users. A CBR tool has been used to perform a pilot study with Anglesey Aluminium Metal Ltd. The results are encouraging. They suggest that a combination of CBR and participative design and implementation techniques (such as Checkland's Soft System Methodology) can achieve sustainable improvement in mineral processing functions. An explanation is presented of why traditional, rule based systems are often an ineffective way to implement support systems. It is shown that CBR may provide an appropriate technology solution. Methods of achieving sustainable benefit are indicated. The pilot study with Anglesey Aluminium Metal is used as a practical illustration of the development of a CBR application. A review of potential application areas and some observations about the implementation are presented

Apr 1, 1994

By P. A. Plunkert, D. E. Morse, Pui-Kwan Tse, W. D. Menzie, Lucy McCartan, J. F. Papp

China’s burgeoning economy is responsible for a major share of recent world mineral consumption increases. In addition to factors traditionally recognized in market economies1 and factors unique to specific commodities, Chinese consumption now plays a major and increasingly important role in energy and mineral markets for many commodities, such as aluminum, copper, iron and steel, and oil. China has the world’s second largest economy after the United States. And its long-term importance to the minerals markets is even greater than indicated by its gross domestic product (GDP), which is currently less than two-thirds of that of the United States (Table 1). This is because China’s rising standard of living is accompanied by rapid industrialization and urbanization. Its consumption of mineral materials for infrastructure development for its very large population is significantly greater per capita than that of such developed economies as the United States, the European Union and Japan. In other words, China’s per capita production is rising at a rapid rate and will probably continue to do so for many years.

Jan 1, 2006

By John D. VandeKraats

Yielding rock bolt support systems have been developed to accommodate ground movement in shifting ground such as in coal operations; in creeping ground such as salt, trona, and potash; and in swelling ground associated with some clays. These systems, designed to remain intact despite ground movement, should enhance mine safety and help contain costs in areas where rebolting of rigid non-yielding systems is typically required. Four such systems were tested in straight tensile pulls in the laboratory. They include the Slip Nut System from Dywidag Systems International USA, Inc., Ischebeck's bolt mounted Titan Load Indicator, Rocky Mountain Bolt Company's Yielding Cable Bolt, and a rock bolt installed variation of the yielding steel post developed by RE/SPEC Inc. The first two systems are currently marketed products and the latter two are prototype systems. Each system responds to load and displacement by yielding in a unique manner. All are designed to yield at predetermined loads. A description of each system and its yield function is provided. Each system was tested over its prescribed yield range in a test machine. At least five tests were performed on each system. Each system yielded and continued to provide support according to its design. Each shows promise for ground control use in shifting or creeping rock. This work helps to illustrate the comparative differences in performance between these specialized systems and the applications where they may be most useful.

Jan 1, 1996

By Steve Kral

Despite low commodity prices and mining industry cutbacks throughout the world, Peru remains one of the industry’s bright spots. The country’s remarkable economic turnaround during the 1990s remains a model for other developing nations to follow. And the Peruvian government has not forgotten the industry that was instrumental in that turnaround. True, the country has not been spared the effects of the mining industry’s retrenchment that has occurred in other parts of the world. However, foreign mining companies remain committed to doing business in Peru. And the government remains committed to attracting foreign investment and maintaining a strong mining industry. This commitment was evident in September 1999during the 24th Convention of the Institutos de Ingenieros de Minas del Peru in Arequipa, Peru. More than 3,000 mining industry professionals from around the world attended the convention. And Extemin, the accompanying exhibit, featured more than 450 companies, many from the United States, Canada, Australia, South Africa and other countries.

Jan 1, 2000

By Erdal Ünal

The computer program introduced in this paper is based on design guidelines developed for selection of support systems used in mine roadways. The support types considered include rock bolts as well as rigid and yieldable steel arches. Using the computer program, the design engineer can select the type, pattern and specifications of the support systems suitable for various roof conditions. The concepts utilized, assumptions made, support selection criteria and description of the computer program, developed for the PC, are included.

Jan 1, 1989

By Christopher Mark

Pillar recovery continues to be one of the more hazardous activities in underground coal mining. Safety requires that the roof above the intersection remain stable until after the pillar has been extracted. Artificial supports (timbers and Mobile Roof Supports) arc essential to roof stability, but so is the final remnant stump or pushout. Traditional mining practices usually called for the complete extraction of the final stump, but the recent trend (both in the U.S. and internationally) seems to be towards mining plans that leave a remnant stump. For this study, a sample of roof control plans from the Mine Health and Safety Administration (MSHA) Coal Districts were analyzed to determine current pillar recovery practices. Both full- and partial- extraction plans were included. Special attention was paid to whether plans require that a final stump be left, and whether requirements regarding the dimensions of the remnant stump are included. Foreign experience with final stumps is also summarized. It seems that the risk of major pillar falls can often be reduced by leaving final stumps that are large enough to protect the intersection, but small enough that they do not inhibit the caving of the gob. Because final stumps are often irregular in shape, a new approach for estimating their strength is described. Analyses were conducted to assess the effect of seam height and depth of cover on the potential variation in the size of remnant stumps.

Jan 1, 2001