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By M. L. Young, J. B. See

Effective thermal conductivities of packed beds of chromite ores by M. L. YOUNG, B.Se. (Rand), M.Sc. (Rand) (Visitor) and J. B. SEE, B.Sc. (Hons), Ph.D. (New South Wales), M.I.M., M.I.M.M. (Member) The effective thermal conductivities in stagnant air of packed beds of fines, lumps, and indurated and pre-reduced pellets of two chromite ores with different chromium-to-iron ratios were determined in the temperature range 300 to I 100°C by the heat-sink technique. Packed beds of fines, whether of the size fraction between 20 and 65 mesh, between 65 and 100 mesh, or between 100 and 150 mesh, were found to have the same values of effective thermal conductivity. For one ore, the effective thermal conductivities of packed beds of fines between 20 and 48 mesh at tem peratures above 600"C were higher than those for finer particles. This difference is explained as being due to the increase in importance of radiation heat transfer, but no definite conclusions are reached about the relative contributions of conduction and radiation heat transfer to the effective thermal conductivities of packed beds of fines between 20 and 48 mesh. Two published models were used for the theoretical prediction of values for thermal conductivities of the indurated and pre-reduced pellets as well as of lump ore. The experimental and theoretical results were in good agreement in view of the uncertainties in the assumed values of emissivity and thermal conductivity of the chromite ore.

Jan 12, 1976

By V-P. Takalo, M. Natsvlishvili, M. Hicks, S. Khizanishvili

"The complexity of copper-gold ores leads to large variations in recoveries and concentrate grades in the processing plant. Detailed chemical and mineralogical studies revealed considerable variation in the ratios of chalcopyrite, chalcocite, and oxidized copper minerals in the ore types studied. The end-member ore types are chalcopyrite-dominated and chalcocite-dominated, while most of the ore types plot between these end-members. In addition, increasing amounts of copper oxide and sulphate minerals result in a decreased response to flotation. Good recoveries and concentrate grades can be achieved from the chalcopyritedominated ore type, while the more altered chalcocite-dominated ore type is more challenging to enrich. IntroductionRich Metals Group (RMG) Copper in Georgia (Figure 1) produces copper-gold concentrates from two open pit mines, Madneuli and Sakdrisi, both located in the Bolnisi mining district in South Georgia. RMG and Outotec began a cooperative project with the aim of improving the recoveries and metal grades in concentrate by gaining an increased understanding of the ore variability and developing more efficient procedures for ore blending, grinding, and flotation. This type of mineralogy-led approach has already been used for other complex ores such as iron oxide copper-gold ores (Hunt, Berry, and Bradshaw, 2011), for iron ores (Lund, Lamberg, and Lindberg, 2013), and for Kupferschiefer ore deposits (Rahfeld et al., 2018).The project started with process audits and mineralogical and chemical characterization of process samples, followed by detailed chemical and mineralogical characterization of six different ore types with simultaneous flotation test work on the same samples. Since neither the recoveries nor the concentrate grades correlate with the head grades of the ores, the modal mineralogical composition, together with the ore hardness, proved to be the most promising approach in developing the geometallurgical classification of these ore types."

Apr 1, 2019

By J. Keyser

The realization of an Integrated Technical Resource Asset Management System (ITRAMS) has so far evaded all software developers in the mining industry. The major factors that have prevented the development of such a system are limitations on software, hardware and network systems. Several factors have come together at Venetia Mine, which has made the undertaking of such a project both possible and desirable. This has led to the formation of a strategic partnership between Venetia Mine and Gemcom Software International Inc. This partnership is dedicated to develop and provide an Integrated Technical Resource Asset Management System based on Microsoft Back Office architecture, Gemcom for Windows™ and the MinRas system. This paper will elaborate on the phased approach of the integration of systems into the core repository, mechanisms of integration, the functionality of the system, final results, techno-economic benefits and general project management issues.

Sep 1, 2001

By C. C. E. Pretorius, V. M. Mathoho, A. van Zyl, R. J. Mostert

The in-service degradation of the mechanical properties of steel components through the damage mechanism of high temperature hydrogen attack (HTHA), is a topic of concern in the refining and green hydrogen industry. This damage mechanism occurs in susceptible steels operating in environments at high temperatures and hydrogen pressures. The current investigation deals with the indirect monitoring of mechanical degradation via tracking of the swelling strain in affected structures. An autoclave with an AISI 316 shell was utilized to simulate accelerated HTHA damage at 550 °C and 46 bar for exposure times ranging from zero to 700 hours. The progress of the HTHA damage was tracked using encapsulated high-temperature strain gauges. The correlation between the swelling strain and mechanical property degradation was studied to develop a methodology for the continuous monitoring of embrittlement. The tensile sample orientation of the carbon steel plate was included as a variable, i.e., samples parallel, transverse, or perpendicular to the plate rolling direction were included, since it has been shown that the sample orientation influences the HTHA damage features. For the through-thickness orientation, and upon exceeding a threshold value of exposure time, all tensile properties were severely degraded, with values in the order of a 90 per cent reduction being observed. It was found that the degradation of carbon steel mechanical properties can be correlated to the swelling strain measured during exposure. The critical point for mechanical property degradation in the plate through-thickness orientation, whereafter a severe decrease in the ductility of the material occurs, was found to be in the order of 1% of the total swelling strain measured during exposure, equivalent to 65 microstrain. This threshold was found to be significantly lower than that expected from the literature, where limits of 400 to 1000 microstrain were postulated.

Nov 27, 2024

The relationships between backfill-transportation parameters (solids concentration, velocity, and pipe diameter) and the wear rate of backfill-transportation pipelines is well understood. However, the degree of wear experienced by a pipeline depends not only on the transportation parameters, but also on the characteristics of the solids making up the backfill, i.e. the particle-size distribution, hardness, shape, and sharpness of the particles. Therefore, unless data corresponding to the specific wear rate of the solids are available, the determination of the wear rate for pipes transporting an uncharacterized backfill is largely guesswork. This paper describes an evaluation of particle characteristics with special reference to particle sharpness so that pipe wear rates can be correlated with solids of different size distributions and sharpnesses.

Jan 1, 1993

By R. J. Dippenaar, W. H. Van Niekerk

The relationships between coal properties, the strength of coke, and the performance of a blast furnace were investigated by means of correlation studies, and a linear programming model was developed for the prediction of a coal blend based on these relationships. The unique feature of this approach is that it utilizes a knowledge of the minimum blast-furnace coke requirements, rather than the maximum attainable coke quality. The model predicts the least expensive coal blend that would still comply with the minimum coke-quality requirements of blast furnace. The study also confirms the existence of a relationship between the rank and caking parameters of coal, and the hot strength of coke. The effect of coke-oven operating parameters on coke quality is also discussed.

Jan 1, 1991

By R. C. Urquhart, D. D. Howat, R. I. L. Guthrie

Heat losses from ladles during teeming by R. C. URQUHART, M.Eng. (McGiII), Ph.D. (Visitor). R. I. L. GUTHRIE, B.Sc. (Eng.) (London), A.R.S.M., Ph.D., D.I.C. (Visitor), and D. D. HOWAT, B.Sc. (Glas.), Ph.D. (Fellow) In an investigation of the loss of temperature by liquid steel during a teeming operation, a numerical technique was used to calculate the heat flows and the rate of temperature drop over the entire teeming operation. The calculations show that, before teeming, approximately 50 per cent of the heat loss is into the ladle wall at the level of the metal. As teeming progresses, the amount of heat lost by radiation to the wall above the metalline increases. The effect of variables, such as initial metal temperature, the preheat of the ladle and ladle cover, and delays, on the rate of temperature loss by the metal were determined.

Jan 11, 1973

By J. Zwartendyk, A. Azis

Optimizing the public gains from the exploitation of mineral resources By Dr A. AZIS and Dr J. ZWARTENDYK Every nation must decide how it should exploit its mineral resources so as to contribute most to its national objectives. It is argued that the present value of the future corporate income tax flow derived.from mineral exploitation may serve as a useful indicator in moving toward a taxation policy that would contribute optimally toward the greatest public benefit. The future stream of corporate income taxes depends largely on the mineral endowment, consisting of deposits now being mined, known unmined deposits, and unknown deposits. Unknown deposits may be estimated by geological inference. Both known and unknown deposits can be categorized according to grade and size, and divided into economic and uneconomic deposits on the basis of certain prices, costs, rate of return and taxation levels. Computer simulations can be run of discounted cash flow models at various taxation levels to showthe impact of taxation changes on future tax revenues.

By C. Chapman, M. G. Reading, M. P. Amsden

Computer control of flotation at the Ecstall concentrator By M. P. AMSDEN, C. CHAPMAN, and M. G. READING Ecstall Mining Limited, a subsidiary of Texas Gulf Sulphur Company, operates the Kidd Creek Mine, a 10000 tons per day base metal producer, near Timmins, Ontario. Two different types of ore are mined and milled: copper-zinc and silver-lead-zinc. At the highly automated Ecstall concentrator the ores are processed by selective flotation in three individual circuits. One of the most important metallurgical tools for process control is a sample system incorporating continuous on-stream X-ray analysis. Recently this system was automated further by the addition of computer control of reagents for two copper-zinc flotation circuits. The computer programs, utilizing optimum seeking methods and smelter contract terms, have increased copper recovery by 1,1 per cent, zinc recovery by 1,4 per cent, and have reduced reagent costs by 16 per cent. Although not expected, copper and zinc concentrate grades were improved slightly as well.

O.F.S. Branch Proceedings of the Annual General Meeting on Wednesday, 30th July, 1975 The Aromal General Meeting of the Branch was held at the St. Helena Club on Wednesday, 30th July, 1975 at 7.45 p.m. Mr D. A. Smith (Chairman) was in the Chair. There was also present: Professor R. P. Plewman, President of the S.A. Institute of Mining and Metallurgy. Conference on Vacuum Metallurgy The Fifth International Conference on Vacuum Metallurgy is to be held in Munich from 11th to 15th October, 1976. Excavation and tunnelling A conference on 'Rapid Excavation and Tunneling' is to be held in Las Vegas from 14th to 17th June, 1976. Book reviews Mine filling. Queensland (Australia), Mt. Isa Mines, Limited, ] 973. 293 pp. $A20,00 incl. postage. Young, R. S. Cheml:cal phase analysis. London, Charles Griffin, 1974. 126 pp. £4.50. NIM reports Report no. 1714 The efficiency of the fire-assay procedure with nickel sulphide as the collector in the determination of platinum,silver, gold, and iridium. Report no. 1721 A preliminary investigation into the mechanism of depression in the flotation of sulphide minerals at the Prieska Copper Mine. Report no. 1725 The determination of silica in fluorspar by 14 Me V neutron-activation analysis. Report no. 1736 The determination, by atomic- absorption spectrophotometry and liquid extraction, of antimony (parts per million) in ores and concentrates. Report no. 1741 South African costs of equipment for the metall'urgical industry(1975}. Report no. 1744 The refining of the platinum-group metals . Report no. 1746 The determination, by atomic-absorption spectrophotometry, of minor elements in zinc, lead, and copper sulphide concentrates. Report no. 1747 Magnetohydrostatic separation of gold from gravity concentrates. Report no. 1750 A review of the present and future development of sulphur production in South Africa. Report no. 1754 A new three-dimensional anodic electrode for reduced power consumption du,ring the electrowinning of metals. Report no. 139 A preliminary survey of goldrecovery problems arising in the production of pyrite. (9th Feb., 1967, re-issued Jun. 1975.) 16 pp. Report no. 140 A preliminary mineralogical investigation of pyrite from the K imberley and the Main Reefs, VogelstruisbuU Gold Mine. (13th Feb., 1967, re-issued Jut 1975.) 11 pp. Report no. 165 Gold recovery from pyrite flotation mill products by cyanidation. Progress made up to 1st May, 1967. (5th May, 1967, re-issued Jun. 1975.) 8 pp. Report no. 133 Gold recovery by cyanidation from mill products obtained after pyrite flotation. Progress made up to ht July, 1967. (18th Jul., 1967, reissued Jun. 1975.) 14 pp. Report no. 219 A review of some of the mineralogical factors influencing the flotation of pyrite. (29th Nov., 1967 reissued Jun. 1975.) 20 pp. Report no. 278 Gold recovery by cyanidation from mill products obtained after pyrite flotation. (24th Jan., 1968, re-issued Sep. 1975.) 51 pp. Report no. 306 The effect of preaeration on two samples of thickener under flow from the Venterspost Gold Mine. (30th Mar., 1968, re-issued Jul. 1975.) 14 pp. Report no. 317 Results of tests carried out at the Loraine Gold Mine during the period 5th to 7th February, 1968. (21st Mar., 1968, re-issued Jul. 1975.) 11 pp. Report no. 321 Aeration of ore from the Loraine Gold Mine before theaddition of cyanide.(17th Apr., 1968, reissued Jul. 1975.) 30 pp. Report no. 380 The effect of aeration, before cyanidation, of pulps of gold ores containing xanthate. (14th Aug., 1968, re-issued Jul. 1975.) 44 pp.

Jan 10, 1975

1. Books from Elsevier The folowing are available from Elsevier Applied Science, Crown House, Linton Road, Barking, Essex IGl 8JO, OK. . Driling wastes, edited by F.R. Engelhardt, J.P. Ray, and A.H. Gilam. 1989. 872 pp. £95. Geothermal resources, by R. Bowen. 2nd ed. 1989. 468 pp. £60. The fate and efects of oil in freshwater, edited by J. Green and M.W. Tret. 1989. 340 pp. £42. Mining and the freshwater environment, by Martyn Kely (with contributions by W.J. Alison, A.R. Garman, and C.J. Symon). 1988. 228 pp. £32. 2. Books produced by Metal Buletin The folowing are available from Metal Buletin PLC, Park House, Park Terace, Worcester Park, Surey KT47HY, England. Prices and data 1990. £41 (airmail). Foundry directory and register of forges 1989-1990. £52 (airmail). 2. Canadian Publications The folowing two publications are available from the Canadian Government Publishing Centre, Supply and Services Canada, Otawa, Canada KIA 059. Mining and mineral processing operations in Canada. Mineral Buletin MR 224. $23.70. Canadian minerals yearbook 1989. Review and outlook. Mineral Report 38. $47.95. Technology developments The Mintek Pyrosim Simulator Pyrosim is a computer program for the steady-state simulation of pyrometalurgical processes?.

Jan 1, 1990

1. Book review . Australasian coal mining practice, edited by C.H. Martin. Reviewer: R.B. MacGilIivray This book is an extremely comprehensive coverage of coal-mining practice in Australasia, the countries covered being Australia, New Zealand,and Papua New Guinea. 2. From The Institute of Metals The folowing are available from The Institute of Metals, 1 Carlton House Terace, London SWl Y 5DB. Physical and elastic characterisation, edited by M. McLean. 1989. 228 pp. £25.00. High nitrogen steels, edited by J. Foct and A. Hendry. 1989. 461 pp. £49.50. Proceedings of the First International Calcium Treatment Symposium. 1988. 116 pp. £15. New cored-wire injection techniques, particularly as Design for recyc/ability, by Michael E. Henstock. 1988. 150 pp. £15. Solidification processing. 1988. 549 pp. £45. Marine engineering with copper-nickel. 1988. 103 pp. £18. Characterisation of High Temperature Materials. 3. New journal FMJ International Publications Lid have announced a new quarterly publication, Aluminium Today. 4. Other new publications Algorithms in real algebraic geometry, edited by Denis S. Arnon and Bruno Buchberger. London, Academic Press, 1988. 274 pp. £15.95. Proceedings, Foundry and Heat Treatment 88. R150 per set of 5 volumes, or R40 per volume.

Jan 1, 1989

1. Book review . Fundamentals of fracture mechanics, by J.F. Knot. London, Buterworths, 1981 (reprint). Reviewer: G. Leadbeater The present reviewer approached the above book as a relative novice on the intricate details of fracture mechanics. Thus, the review is based to a great extent on how easily the information presented can be assimilated and understood, and how the book's format and content facilitate this. Note was taken of the preface comments about jumping ahead, in chapters, to ease understanding, and this was found to be a common occurence. 2. New publications Mechanical testing. London, The Institute of Metals, 1988. 357 pp. £25 Mining potential in northern and southern Canada: Guidelines for regional development policy, by Leo J. Verleun and Brian W. Mackenzie. Centre for Resource Studies (Queen's University, Kingston, Canada K7L 3N6), 1988. 225 pp, $20 Pricing of metals, by Margaret E. Slade. Centre for Resource Studies (see previous item). 149 pages, $20 CRS Perspectives, no. 29.Nov. 1988. Issued by the Centre for Resource Studies (see previous item) Introduction to the modern theory of metals, by Sir Alan Cotrel. London, The Institute of Metals, 1988. 456pp. £18 Mine winding and transport, by S.C. Walker. Amsterdam, Elsevier, 1988. 546pp. Dfl. 275.

Jan 1, 1989

By J. Rowe

The attrition of activated carbon, and the loss of gold associated with it, is of significant economic importance to the operation of a CIP/CIL circuit The focus of this study was on activated carbon recovered from an elution circuit which was deemed too fine for reuse. Results of cyclosizer and laser particle size analysis identified that most of the carbon was contained in the larger size fraction suggesting formation by abrasion. Digestion and AAS analysis of the individual size fractions identified a disproportionate concentration of gold in the finer size fractions which was identified by scanning electron microscopy to be due to the presence of fine metallic gold formed as a result of the acid washing process. Attempts to strip the remaining gold using sodium hydroxide or sodium sulphide based solutions proved unsuccessful due to poor elution efficiencies and re adsorption of gold. Upgrading of the material by froth flotation was also investigated using various conventional flotation reagents which had some success in concentrating the free metallic gold, however, grade and/or recoveries were considered less than desirable. Greater success was ultimately found in the transfer of gold from the fine carbon material onto coarser virgin activated carbon using a caustic cyanide solution. Sodium sulphide, sodium chloride and ammonium chloride based solutions were also trialled but proved less successful owing to their inability to mobilise metallic gold or gold cyanide species. Repetition of the transfer process proved capable of stripping 97% of the gold contained on the carbon fines for abed volume ratio of 6:1.

Jan 1, 2009

By P. De Kock

Strategic mine planning is concerned with the decisions that determine the value of the business, while tactical planning deals with the tasks to realize that value. When tasked with formulating a strategic mine plan, the mining engineer often turns to commercially available software. However, these software packages have limited applicability to the RBM situation. Adopting a simpler, back to basics approach founded on a deep understanding of the economics of the orebody has the advantage of providing a clear logic to guide tactical planning. By creating a coherency between strategic mine planning, and tactical planning the likelihood of successfully executing the plans and attaining the value promised by the strategic plan is increased. This paper describes the reasons why RBM embarked on a strategic mine planning process, the rationale of choosing the process, and the process itself.

Jan 1, 2007

By R L. Bowers, D S. Smit

In light of soaring commodity prices, Nkomati has investigated the potential of processing additional low grade nickel ores to add to their reserves. The Chromititic Peridotite Mineralised Zone (PCMZ) was identified as one ore type with the potential of producing a high grade nickel concentrate. In addition to the nickel, copper, cobalt and PGM?s, the ore also contains a significant amount of chromite which adds substantial value to the project. Pyrrhotite, pentlandite, chalcopyrite and chromite are the dominant minerals within the ore, which on average grades around 0.23% Ni and 12% Cr2O3. The PCMZ ore contains excessive amounts of fibrous silicates which makes it a challenging float, with gangue control as the key element to success. Extensive laboratory testwork, which eventually led to a pilot plant campaign, was undertaken with the aim of developing a process route for treating the PCMZ ore. Several flotation circuit configurations were tested and results from the optimal circuit indicated that a nickel concentrate grading at 8.5% is achievable at a recovery of 78%, with substantial recoveries for the copper, cobalt and PGM co-products. The chromite concentrate, grading at 45%, was extracted from the flotation rougher tailings via a spiral plant. These promising results were incorporated into the plant design and are currently being evaluated in a bankable feasibility study, which will see the current 100ktpm MMZ concentrator being upgraded to a 250ktpm PCMZ concentrator as part of Nkomati?s Phase II expansion.

Jan 1, 2007

A Colloquium and General Meeting were held on 17th March 1971, the theme being 'Future trends in steel production'. Mr V. C. Robinson (President) was in the Chair. The Colloquium was attended by 121 delegates and was opened by the President at 10 a.m. OBITUARIES THE PRESIDENT: 'It is my sad duty to announce the death of the following: F. O. Read, Fellow, who joined the Institute in 1957 and passed away on 13th January, 1971. P. G. M. May, Member, who joined the Institute in 1969 and passed away on 10th August, 1970. R. J. J. Rademeyer, Life Fellow, who joined the Institute in 1942 and passed away on 23rd September, 1970. As a mark of respect to the memory of the deceased and in sympathy with the bereaved I would ask you all to rise and observe a few moments silence. CONFIRMATION OF MINUTES THE PRESIDENT: 'May we confirm the minutes of the monthly general meeting held on 21st October and 18th November, 1970, as published in the Journal'. Agreed. MEMBERSHIP THE PRESIDENT: 'I have much pleasure in announcing that the names of the undermentioned candidates, having been published in accordance with ByLaw 5.2.2, Council has elected them to membership of the Institute in the following grades: FELLOWS: Romain August Lathioor, Paolo Piga, Renato Ribacchi, Willem Frederick Jacobus Smith, Matthew Churchill, Thomas Anthony James Braithwaite, Hugh Patrick Hart, Eleanor Innocentius Muller, David Alton Smith. MEMBERS: Douglas Adendorff, Petrus Jacob du Plooy, James Valentine Grant Middleton, Karl Anders Ullerstam, Josephus Theodorus Johannes van Wyk, Frank Douglas Abbott. GRADUATES: David Mervyn Gilbart-Smith, John Philip Wilcocks Bennie, Hendrik Theunis Burger, Johann Wilhelm Coetzee, Johannes Stephanus StOols, Leon van Tonder, Brian George Harvey, John Kennedy McLean. ASSOCIATES Richard Cyril Lee Stoyell, Terrence Brian Gouws, Alister Rodney Frederick MacDonald. STUDENTS: Andries Groenewald, Christiaan Johannes Hattingh, William Hendrik Hofmeyr, Stanley Thomas Vincent. I welcome the new members to the Institute and congratulate them on their election. COLLOQUIUM The President welcomed everyone present and mentioned that this was the first of the Colloquia which are to replace the Institute's monthly meetings. He stressed that discussion at Colloquia would be completely informal and would not be recorded unless the contributor requested publication. In conclusion, he thanked the organising committee, the authors and the contributors, and introduced the author of the first paper. The following papers were presented:- 'The future development of the Iron and Steel Industry' by J. P. Coetzee (Published in the Journal March 1971). Among those who contributed to the paper were Dr Bleloch, Dr K. Gebhard, Dr Way and Professor Müller. The main point made by Dr Bleloch related to the reserves of coking coal and of coal for power generation this in country and he deduced that in South Africa we are critically short of coking coal. On the basis that 4 million tons per year of coking coal are consumed for our present steel production, over 16 million tons would be required to meet the anticipated expansion in steel output by A.D. 2000. This must be set against the grim forecast made by the Coal Advisory Board in 1967 that our national reserves of coking coal will be exhausted before A.D. 2000. This gives tremendous significance to the development work presently being carried out by Iscor on alternative methods for coke production. On the other hand the blast furnace may have to be replaced by an alternative process for the reduction of iron ores, e.g., the use of rotary kilns followed by electric arc smelting. Dr Bleloch also expressed grave forebodings about the reserves of bituminous coal, pointing out that with present methods of mining the recoverable coal in any given reserve is in general only 50 per cent of that reserve. He stated that in the past seventy years great quantities of coal have been forever placed beyond the reach of mining by being undermined by extraction of lower seams or lost by being burned. A final point made by Dr Bleloch was the fast rise in the capital investment in a fully integrated steel plant, the figure having risen in the past decade from just over R200 to R350 per ton of finished steel per annum. Dr Gebhard spoke of the direct reduction processes for iron making pointing out the difficulties of securing a high percentage of reduction and the relatively high cost of smelting in electric arc furnaces. As an alternative he suggested briquetting the high carbon sponge iron

By Piotr M. Kapias

Keywords: extraction, lead refining, Pb-Tl solutions, PbCl2-TlCl solutions. The theoretical part of the paper presents an analysis of the conditions of Tl extraction from Pb using different extractants and determines the activity coefficients in liquid solutions of Pb-Tl and PbCl2-TlCl. The dependence of the solution activity coefficients upon the composition and temperature is presented in the form of Krupkowski and Krupkowski-Fitzner equations. An analysis and evaluation were made of the influence of the methods of PbCl2 introduction into a Pb-Tl solution upon the efficiency of the Tl extraction process under thermodynamic equilibrium conditions. The analysis made it possible to formulate relevant equations describing the dynamics of the process of Tl extraction from Pb under stirring conditions as well as under the extractant injection into the liquid Pb-Tl solution conditions. In the part concerning experimental work, results are given for tests on the Tl extraction process from Pb-Tl liquid solutions of initial Tl content of approximately 0.05% mass using PbCl2 or, alternatively, Cl2(g) conducted in laboratorial scale. The tests made it possible to establish the influence of time, temperature, mass and the method of introducing the extractants into the liquid upon the level of Tl extraction from a Pb-Tl solution. Labels used in the text. WT1m - TI content in metallic phase, % mass WT1s - TI content in chloride phase, % mass wpTlm - TI content in metallic phase in initial state, % mass W°Tlm - TI content in metallic phase in equilibrium conditions, % mass m°m - initial mass in metallic phase mm - mass in metallic phase mPbC12 - lead chloride mass fed to the system MPbC12-TIC1 - mass in chloride phase MPb - lead atomic mass, g/mole MT1 - thallium atomic mass, g/mole K - Nernst distribution coefficient Xi - mole friction of solution component X°PbC12 - mole friction of PbC12 in saturated solution X°T1C1 - mole friction of T1C1 in saturated solution T - temperature, K R - gas constant, J/(mole K) k - kinetic equation constant, 1/(%-min.) ?i - solution component activity coefficient e - extraction rate, %

Jan 1, 2008

By D. Mjonono, S. T. L. Harrison, N. Maliela, A. Kotsiopoulos

The improvement of coal waste management practices, through the co-disposal of waste rock with sulphur-lean fine waste tailings (<1 mm in size), can potentially mitigate acid rock drainage (ARD). On exposure to natural oxidants, the sulphide compounds present in mine discards generate acidity, creating a cyclical oxidation process intensified by iron and sulphur oxidising microorganisms. To inhibit the emergence of ARD, a stable mine dump may be constructed that is structurally stable and incompressible through the mixing of complementary waste fractions that reduce voids and access to acid generating surfaces. However, large voids manifest as scale increases, due to decreased particle interlock, enabling the unrestricted access of oxidants leading to the early onset of ARD. To avoid this phenomenon, enhanced packing approaches based on geochemical and geotechnical characterisation tests were employed to improve bed stability. These were assessed for long-term prevention using aggressive oxidative conditions typical of heap leaching applications. Favourable results were obtained for both blended and multi-layered systems. However, long-term success was most notable in beds with alternating layers of waste rock and fine waste tailings with co-mingled systems being more susceptible to failure. Deconstructed co-disposed beds provided valuable insight into post-leach structural transformations. Results indicated that relative changes in initial coarse discards to fine waste ratios were most notable in blended systems. Mass fractions of the comparatively more mobile fine wastes increased axially down these test columns that ultimately resulted in increased contact of oxidants with the acid generating waste discards. Conversely, more consistent ratios were observed in multi-layered configurations. In these systems, near impervious hardpans were created by the moisture retaining fine tailings, forming stable structures with neutralising barriers sustained at each alternating layer. Consistent with post-leach geotechnical characteristics, static acid-base accounting tests showed that the uppermost sections of blended systems were more susceptible to oxidation due to structural failure with fine particles migration, while the more stable multi-layered configuration evenly maintained neutralising capacity. Keywords: Acid rock drainage (ARD), bed structure, mobility of fine particles

Jan 1, 2020

Toxic gases, mostly carbon monoxide (CO) and nitrous oxides (NOx), are invariably generated by commercial explosives under practical conditions of usage because of oxygen unbalance and non-ideal chemical reaction. Permitted explosives are statutorily required to meet the criteria stipulated by regulatory authority for their toxic fume quality for their safe use in underground coalmines. Solid blasting using P5 explosives contribute around 60% production from Indian underground coal mines. Low pull and yield per blast in solid blasting has been identified as a reason for low production and productivity of Indian underground coal mines. In an effort to improve performance of solid blasting, it was envisaged to apply air decking between suitable P5 explosives using high density polyethylene (HDPE) spacers under a Ministry of Coal, Government of India funded project. A non-deflagrating slurry explosive composition having high air gap sensitivity was specially developed for this purpose, so that air decked cartridges get detonated sympathetically with single priming. However, statutory authority in India apprehended that the use of oxygen negative HDPE spacers can influence the generation of toxic gases. The effect of using HDPE spacers on the generation of toxic gases was studied under simulated laboratory conditions with newly developed as well as with three commercial P5 explosives. The results of studies presented in this paper revealed that the level of carbon monoxide increases linearly and there is no significant effect on the level of oxides of nitrogen due to the use of HDPE spacers with selected explosives. Studies also revealed that this newly developed slurry explosive can be used for air decking up to 15 cm using HDPE spacers of weight not more than 21 g without exceeding the permissible limits for toxic gases.

Jan 1, 2008