Search Documents

By Charles W. Bauer

Most of the aluminum produced in the United States today is derived from foreign bauxite deposits. Earth Sciences, Inc. initiated a program to evaluate domestic non-bauxite sources for alumina in the 1960's. In the initial evaluation of alunite, domestic resources were not sufficient to support development. An exploration program led to the discovery of large deposits of alunite in Utah and several other western states. Identification of alunite is difficult as both its physical and chemical characteristics are similar to the minerals with which it is associated. Most of the significant alunite deposits in the western United States are replacement type deposits. These deposits have formed as a result of hydrothermal alteration of volcanic, sub-volcanic, and igneous rocks. Typical alunite deposits contain between 30% and 50% alunite between 50% and 70% quartz with minor amounts of other minerals. Four mineralogical zones are common in these systems. They include a siliceous zone, a quartz-alunite zone, a kaolinite zone and a chlorite-montmorillonite zone. Total U.S. reserves of alunite were estimated at 20 million metric tons (at 30% alunite) by the U.S. Bureau of Mines in 1941. Here recent work by the U.S. Geological Survey estimates reserves of 252 million metric tons and potential resources at 1.4 billion metric tons. Reserves and resources estimated for 23 properties on which field work has been done by ESI are considerably higher. Most of these properties have reserves and potential resources of several hundred million metric tons. The combined demonstrated reserves at these properties are estimated to be about 650 million metric tons. Inferred reserves are estimated at 2.5 billion metric tons and potential resources at 8 billion metric tons. It appears that the U.S. has sufficient reserves and resources for alunite to be considered as a potential non-bauxite source of alumina.

Jan 1, 1980

By Karim El-Ouassiti, Marc Minville, Stéphane Chabot, Claude Bazin, Valérie Ouellet

"Alumina is the main source of aluminium and it is extracted almost exclusively from bauxite ores found in the Southern hemisphere. Clays are abundant minerals that contain from 15 to 40% w/w of alumina from which it can be extracted by various processes. This paper reviews the processes used for the extraction of alumina from clays and discusses results obtained with a clay sample from the Murdochville area in the Quebec Province. The application of a conventional process to this clay did not yield an acceptable recovery although smelter grade alumina was produced. A modification to the process allows increasing alumina recovery from 85% to more than 92%. The application of the improved flow sheet to other alumina carriers failed to yield comparable recovery, showing that an optimum processing path for the recovery of alumina should be found for individual clay materials.INTRODUCTIONMost of the aluminium smelters are fed with alumina extracted from bauxite found in the Southern hemisphere. Bauxite is processed by the Bayer process that uses a caustic leach of the ore. In the middle of the century, the US Bureau of mines, motivated by the fear of an alumina delivery disruption, conducted several research projects aiming at producing alumina from non bauxitic ores. These projects led to the development of various acid leaching processes (Habashi, 1993). The sulphuric and hydrochloric acid leaching processes were brought to pilot plant evaluation (Bengtson, 1979), while nitric and other leach liquors were tested in the laboratory (Phillips and Wills, 1982; Habashi, 1983). Although clays are abundant and inexpensive minerals, the studied processes remained uncompetitive with the alumina extraction from bauxite (Hudson, 1987 page 42; Peters et al., 1962) for which reserves are estimated to support alumina production for the next 50 years (Oye et al., 1999). On the other hand, the local extraction of alumina from clays could significantly reduce the transportation costs of alumina to smelters and provide an alternative source of alumina supply from the Southern hemisphere countries. Also, the extraction of secondary products for some types of clay (Nasyrov et al., 1999) containing significant amounts of potassium and sodium could provide an additional return that may improve the economics of alumina production from clays."

Jan 1, 2005

By H. H. Murray

Abstract. World reserves of bauxite are abundant. Domestic reserves are limited and as a consequence the United States must rely on foreign suppliers for over 90 percent of its bauxite. Nationalization of many bauxite mining operations, levying of higher taxes, increased production and transportation costs, and attempts to create a uniform market price combined to place the United States in a vulnerable position. Alumina from kaolin, alunite, anorthosite, and oil shale have-been-or are being evaluated. World bauxite reserves are increasing and attempts to establish a uniform price have failed; therefore, it may be many years before domestic non-bauxite sources of alumina can compete with imported foreign bauxite.

Jan 1, 1980

By John Ward Smith

Dawsonite bearing oil shale of Colorado's Green River Formation offers a unique and vast (6.5 billion tons of Al2O3) resource of easily extractable alumina. The processing methods required by the thermal reactions dawsonite and its oil shale carrier also require production of shale oil, soda ash, and nahcolite as marketable coproducts. These production methods are presented. The alumina production process is contrasted with the Bayer process to describe technical advantages of extraction of alumina from oil shale which may offset the problems associated with processing a relatively lean ore. While alumina production from oil shale requires development of new technology, the technical problems appear solvable. Only the political problems arising from the now onerous and completely unnecessary Federal oil-shale withdrawal appear less solvable.

Jan 1, 1980

By John Ward Smith

Dawsonite-bearing oil shale of Colorado's Green River formation offers a unique and vast (more than 5.9 Gt of A120 j) resource of easily extractable alumina. The processing methods required by the thermal reactions of dawsonite and its oil-shale carrier also require production of shale oil, soda ash, and nahcolite as marketable coproducts. These production methods are presented. The alumina production process is contrasted with the Bayer process to describe technical advantages of extraction of alumina from oil shale which may offset the problems associated with processing a relatively lean ore. While alumina production from oil shale requires development of new technology, the technical problems appear solvable. Only the political problems arising from the now onerous and completely unnecessary federal oil-shale withdrawal appear less solvable.

Jan 1, 1982

By Errol D. Sehnke

This U.S. Bureau of Mines report provides detailed information on worldwide alumina production capacity by plant and country. The information was compiled from a variety of domestic and international sources and was based on information available to the Bureau through December 31, 1993. Capacity data represent announced installed and planned capacities and do not necessarily reflect a Bureau of Mines judgment of actual plant operating levels or timing of planned expansions, The year-end capacity is the ?nameplate" capacity or estimated production capacity, whichever is larger.

Jan 1, 1993

By N Murthy

Alumina is a major impurity in Australian iron ores and as the higher grade ores become depleted there will be a stronger focus on treating lower grade haematite/goethite ores and developing suitable beneficiation techniques to reduce the alumina content. High alumina in iron ore is deleterious in that it can:• produce slags with lower desulfurising capacity,• reduce sinter/pellet strength and quality, and• produce higher slag volume and increase slag viscosity.Meeting iron ore quality specifications for alumina by blending ore from different sources will eventually be insufficient. Hence, innovative flow sheets based on new and commercially available technologies will be required. Their advantages and disadvantages, the testing methodologies and the challenges and diffi culties involved in reducing the alumina content of iron ores are presented and discussed.

Jul 11, 2011

By Marcos Aurélio S. Costa, Nilton F. Nagem, Andreia B. Henriques, Herman S. Mansur, Alexandra A. P. Mansur, Antonio E. C. Peres, Valeria G. Silva

The superfine material generated in the Bayer process was used in one innovatively way as a precursor to geopolymerization techniques because of the presence of Gibbsite. Gibbsite can play a role in system adjustment because of the SiO2/Al2O3 ratio. Furthermore in the geopolymeric system it was studied the influenceof the additives such as kaolin, metakaolin and sodium trisilicate in an alkaline media. Others conditions to form the geopolymer were also evaluated such as solid/liquid ratio, SiO2/Al2O3 ratio and total alkaline. The raw materials and geopolymeric products were characterized by several techniques e.g. XRD, DSC, FTIR and SEM. Through the FTIR technique it was observed an increase in intensity and bandwidth in the region centered at 1010 cm-1, which is related to the asymmetric vibration Si(Al)-O, this is an indicating of the possible geopolymer formation This broadening of the band promotes a relative disappearance (overlapping) peaks at 965 and 935 cm-1 associated with raw material (ESPDust).

Jan 1, 2015

By T. Kumaresan

The Bayer process used for refining bauxite to smelting grade Alumina serves as the linchpin of the Aluminum production industry worldwide. Even though the process is well established, the presence of impurities in the liquor affects the quality of product and imposes a major economic cost on the industry. This review article focuses on the issues pertaining to Gibbsitic (Al2O3.3H2O) precipitation circuit. The comprehensive review provides a basic understanding of the aluminum trihydrate precipitation and agglomeration phenomena. Crystal growth rate and agglomeration play a significant role in determining the output PSD of agglomerates. Hence, the effect of certain thermodynamic and hydrodynamic parameters along with the impact of impurities (oxalates, aldols, acids etc.) and additives on hydrate growth has been reviewed.

Sep 1, 2012

By I. Lackey

In 2004, Zinifex Budel Zink commenced testing with the objective to increase the precipitation of aluminium in the iron purification stage of its hydrometallurgical zinc circuit, without the use of expensive reagents. Findings from the literature applied to the leach circuit at Zinifex Budel Zink demonstrated that aluminium removal from the leach circuit could be increased by lowering the ferric concentration and acidity in the vessels where jarosite precipitation occurs. An associated increase in copper precipitation was mitigated by limiting the extent to which the ferric concentration was lowered in the vessels where jarosite forms and lowering the ratio of copper to aluminium in the solutions entering these vessels.

Jan 1, 2006

The Hall-Hoult process is likely to be the dominant method of aluminium production for the remainder of the century. The characteristics of the operation of a modern smelter are described and attention drawn to their disabilities which are due chiefly to the small production capacity of individual cells.The principal components of the Hall-H6roult cell - the electrolyte, the anode and the cathode - are discussed in order to identify the problems of scale-up. The factors influencing current efficiency and energy consumption are analysed and lead to the conclusion that the greatest potential for energy saving lies in reducing the anode to cathode distance (ACD).The most promising direction for major change is in the application of a new titanium diboride - carbon composite for coating of the surface of the cathode carbon. It improves the wetting of the carbon by aluminium and should permit the use of sloping cathodes and anodes. The deep metal pad would thereby be eliminated and, in the absence of magnetic perturbations, the ACD could be substantially decreased.The construction and testing of a full-size "Low Energy Cell" is scheduled for early 1986 and is expected to reduce energy consumption in aluminium production by about 15%.

Jan 1, 1985

By F H. S dosSantos, R L. C Santos

The main objective of this work was to develop, at a laboratory scale, a process for treating residues from the settling stage of water treatment so as to remove and recover the aluminium as sulphate. The chemical analysis of residues from different water treatment plants indicated that the aluminium content varied from 15 to 20 per cent w/w. By using the appropriate experimental conditions, it was found to be possible to leach most of the aluminium content. The pH value of the recovered water was suitable for it to be recycled to the water treatment process and the residue appears to be suitable as raw material for bricks. The process developed contributes to the sustainability of the water treatment process.

Jan 1, 2002

By B. M. Currell, M. J. Neate, P. W. Bowden

Historically the hydrogen fluoride laden fume emitted from the electrolytic cells in the aluminium reduction process is further treated in pulse jet dust collectors. These dust collectors act as dry scrubbers performing two duties: adsorbing the gaseous fluoride emitted from the cells onto alumina dust; and collecting the alumina dust minimising particulate and fluoride emissions to the environment.Patented StarBag (TM) technology has been used in aluminium smelters in Australia as a means of increasing the dust collection and fluoride scrubbing capacity of existing collectors. This technology provides an alternative to major capital equipment upgrade where increased capacity is required, and potentially lowers the production cost per tonne of aluminium where capacity limitations are being realised and production expansion is required. This paper presents the findings of on-site pilot scale, and full production scale comparative tests, highlighting the operational and variable differences observed utilising the Star-Bag(TM) technology at Boyne Smelters Ltd in Australia. The results illustrate how this technology can be utilised to increase the hydrogen fluoride scrubbing efficiency and dust collection capacity of existing capital equipment.

Jan 1, 2006

By P. W. Edwards

"This paper summarises many experiments conducted, and how in North American industry the use of aluminium in treatment and prevention has been adopted widely. The Pottery Insurance Co., Ltd., made it possible for me to investigate conditions in Canada and the U.S.A., and I thank them for permitting me to submit this short paper- an abstract of my report to them."

Jan 1, 1947

By J. W. G. Hannon

FOLLOWING the experimental work of Denny, Robson, and Irwin, and the clinical investigation by Crombie and Blaisdell, an investigation of aluminium therapy was begun at Washington, Pa., which is situated in a very large industrial section of the State. Some of the men to be studied were from plants manufacturing silica brick, refractories used in steel and glass manufacturing, and semi-porcelain table-ware; others were workers in foundries, sand blasters, and men engaged in the quarrying of ganister rock. This group of workmen gave an opportunity to study the effects of aluminium on various types of silicosis which differed somewhat from that found in hard-rock miners. EXPOSURE In their occupations, the men studied were exposed to silica dust concentrations ranging from 17 to 97 per cent free silica. In the silica brick industries, the unfired product averages 96 per cent silica in the form of quartz, whereas the fired brick contains 50 to 62 per cent cristobalite plus 17 to 30 per cent tridymite, forms of silica that, on account of their higher solubility, are more toxic than quartz. The operational dust counts in the plants varied from 15 to 9,500 particles per c.c., and the median particle size from the aerial samples was 1.0 micron for the green product and 2.0 microns for the fired product. The length of exposure varied with the occupation as well as with the individual plant, but disabling silicosis could be produced in less than four years in certain exposures. The average time needed to produce radiological silicosis in those susceptible to this disease was eight years. Some of the men in our series of cases have been treated as long as fifteen years after exposure had ceased, and have improved under treatment.

Jan 1, 1944

By D. J. Allan, W. R. Wilson

For conventional aerospace aluminium alloys of the 2000 (copper) and 7000 (zinc, magnesium) series the recycling of process scrap from both metal suppliers and aircraft manufacturers is a well-established, worldwide industry. The recent introduction of a new family of alloys that incorporates lithium has posed a new challenge to the recycling industry owing to the high cost of lithium, its high reactivity to the atmosphere and to refractories and its absence from the specifications of all other registered alloys. Various process options for recycling have been identified, but vacuum distillation has been selected as the most cost-effective and technically feasible solution. Experimental work established that the separation of Li from AI-Li scrap is feasible and an industrial process has been designed. The economics of Li recovery are very sensitive to the AI-Li content of the feed material. Owing to the design of aerospace vehicle manufacturing plants it is expected that the swarf will be mixed with other alloys. A method of enriching this feed has been developed that is based on the control of swarf morphology by thermal and mechanical treatments as a precursor to eddy-current separation. After eddy-current separation and vacuum distillation small proportions of Li are retained in the AI residue. The effects of this on the properties of conventional AI-Si shape-casting alloys were investigated and safe threshold levels have been established.

Jan 4, 1993

By Albert G. Funk, Gary M. Thornley

The available energy of aluminized ANFO and aluminized slurry blasting agents has been measured by seismic methods, calculated theoretically, and compared. With aluminized ANFO it is concluded that aluminum concentrations should be restricted to less than 10 percent because of diminished energy yields at high aluminum concentrations. However, with aluminized slurry it is concluded that efficient use of aluminum can be made at aluminum concert"rations up to 18 percent. It is further concluded that the difference in efficiency of use of aluminum by these two classes of blasting agents results from a higher contribution to useful work from the condensed detonation products of the relatively higher density aluminized slurry blasting agent.

Jan 1, 1981

By D S. Perera, P Wal, D C. Southam, J L. Lowe

The Cooperative Research Centre for Sustainable Resource Processing (CSRP) is undertaking a large research project involving partners from industry, universities and government, which aims to develop the necessary chemical and structural understanding of geopolymer materials made from waste products for them to be used to capture a significant market share of the concrete business for a given industrial region. We are investigating the suitability of a range of soluble silica-bearing waste streams for use as geopolymer concrete feedstocks. In order to utilise a variety of waste streams, either singly or blended, an understanding of the role of secondary metal ions (Fe, Ca, Mg, Ti, etc) in the geopolymerisation process is essential. A range of experimental and analytical techniques is therefore being used to better understand the structure-chemistry-property relationships of geopolymers. Currently, we are investigating geopolymers made from a variety of waste streams (fly ash, kaolinite, red mud, etc) available in the Kwinana Industrial Region, Western Australia. This paper will detail how the basic scientific research underpinning the project is vital if waste streams of varying composition are to be successfully used in a commercial concrete product and the regional synergies required to develop geopolymers from waste streams.

Jan 1, 2006

By M Zhu, G Tranell, N Simkhada, K Jakovljevic, M Wallin

Silicon is a vital element in many products today, such as electronic components, solar devices, high-quality alloys, and many others. The growing global demand highlights the need for the development of sustainable production methods to meet this demand as an alternative to the current carbothermic reduction, submerged arc furnace (SAF) based process. An alternative to this is the aluminothermic reduction of quartz in a CaO-SiO2 slag, which not only reduces direct carbon dioxide emissions but also promotes the utilisation of secondary raw materials such as quartz fines, aluminium dross and scrap as well as secondary alumina (SA) from dross recycling. In the current study, the effects of SA and CaF2 additions to slag on the resulting metal composition and metal yield were explored. Results were compared with thermodynamic simulations using FactSage™ 8.1. Experimental results show that, in agreement with thermodynamic simulations, the silicon content of the alloy is increased, while the Ca is decreased for starting slags where CaO-SiO2 is partly replaced by CaF2. Similarly, the addition of SA to the initial slag results in an alloy with a higher silicon content.

Jun 19, 2024

By Jr. Robison

"Aluminothermic (""thermite"") smelting became commercial with the development of tonnage aluminum, and prospered producing metals and alloys with higher cleanliness, consistency and elemental control than competing technologies. We explore the scope of thermite smelting, and metallothermic smelting in general; the thermochemistry of the process; and its advantages and limitations as applied to industrial production. We review currently-produced products of thermite smelting in several forms and a wide range of heat sizes. As these products serve several industries, we relate the demands of those industries to the requirements imposed on the thermite process, leading to process dynamics and mechanisms to control/alter those dynamics. We review ways to lower the process costs by altering process stoichiometry, using other energy sources and utilizing less costly materials while considering effects on product quality and customer requirements. Finally, we examine overall emissions control and waste disposal.IntroductionAluminothermic smelting is the reduction of various oxides by aluminum to produce metals or alloys with varying levels of residual aluminum. One of the earliest uses of the process was the production of liquid iron to weld railroad rails, later modified in ""thermite grenades"" used to ""spike"" artillery pieces in World War II. Then during the 50's, 60's and 70's the growth of jet aircraft created a demand for new superalloys and titanium alloys, both requiring master alloys for efficient production. Aluminothermic smelting grew with the aerospace industry and with the expansion of microalloyed steels. It is very much a niche industry, dependent on the specialized demands of the specialty steel, superalloy and titanium industries. In this paper we introduce the characteristics of aluminothermic smelting, the scope of smelting operations, the markets served, and the environmental aspects of the process, as seen through the eyes of a company using aluminothermic smelting for over fifty years"

Jan 1, 2012