Search Documents

By D. R. Forshey

The recent occurrence of fatal accidents in copper mines, presumably due to premature ignition of loaded holes by the heat from reacting ammonium nitrate-fuel oil (AN-FO) and pyrite-bearing ores, has led to an examination of this reaction. The reactivity of prilled AN-FO mixtures with pyrite-bearing ores and the effects of water, dilute sulfuric acid, and potential inhibitors on reactivity of the mixtures were evaluated. Initiation of an exothermic reaction was observed as low as 150° F with acid in the absence of inhibitors. Low concentrations of urea, calcium carbonate, zinc oxide, and magnesium oxide were effective in inhibiting the reactivity of the mixtures. The temperatures produced during the reaction of mixtures of AN-FO and pyrite-bearing ores, in the absence of inhibitors, always exceeded the temperature at which electric blasting caps are thermally initiated.

Jan 1, 1968

By E. Morrice

Gadolinium, dysprosium, and yttrium are difficult to electrowin as high-purity liquid metals because of their high melting points (>1,300° C). Samarium metal is difficult to prepare directly by electrolysis because the metal reacts with the electrolyte. In this Bureau of Mines study, the rare-earth metal was electrodeposited on a solid manganese, chromium, or iron cathode to form a low-melting alloy. The alloy was then vacuum distilled to separate the rare-earth metal from the ferrous metal. A typical samarium metal product, obtained as the distillate from vacuum distillation of a samarium-iron alloy, contained 150 ppm oxygen, 80 ppm carbon, and 50 ppm iron as impurities, Gadolinium metal, obtained as a residue from the distillation of a gadolinium-chromium alloy, contained 300 ppm oxygen, 200 ppm carbon, and 100 ppm chromium.

Jan 1, 1969

By Richard H. Singleton

Native asphalt was produced in 1980 by six companies in four States. Leading States were Texas and Utah. Output decreased 22% in 1980 to 1.25 million tons while value decreased 2% to $25.0 million. Bituminous limestone was produced by Whites Uvalde Mines and by Uvalde Rock Asphalt Co. in Uvalde County, Tex.; by Southern Stone Co. in Colbert, Ala.; and by Barton County Rock Asphalt Co. in Barton County, Mo. The product was used mainly in street and road repair. Gilsonite was produced by American Gilsonite Co. in Uinta County, Utah, and by Ziegler Chemical and Mineral Corp. in Weber County, Utah. This material was used for purposes other than road repair.

Jan 1, 1981

By G. W. Groove, E. E. Quenon

"INTRODUCTION Uncontrolled mine fires originating in exposed coal beds through the acts of careless or irresponsible persons present a serious threat to buildings, surface property, and the life and health of persons near the affected area. Apparently, the seriousness of such fires is not fully understood by property owners or those residing in the vicinity, as practically nothing has been done to alleviate conditions. In many instances, such fires have been active for several years before property owners or civic organizations have shown any interest toward having the fire extinguished. Recommendations by Bureau of Mines investigators in the interest of controlling such fires are seldom followed, as the Bureau cannot provide the funds for doing the work.Several uncontrolled and widespread fires are burning along the outcrop of coal beds and in underground abandoned mine workings within a 25-mile radius of Pittsburgh, Allegheny County, Pa. If these fires are permitted to continue to burn unabated, the ultimate results may be far-reaching. Most of the outcrop fires investigated are believed to have originated from burning rubbish, forest fires, or workmen, hunters, or others building fires near the outcrop of ,the coal beds. In other instances, smoke and fumes have suddenly appeared in the vicinity of abandoned coal-mine openings, indicating that a fire has either burned its way along the outcrop of the coal bed or has traveled through the abandoned mine from another location. An underground or outcrop coal-mine fire will be very likely to continue to burn as long as an oxygen supply is present.; and, so far as is known, such fires do not stop burning automatically until virtually all combustible matter is consumed."

Feb 1, 1948

By A. R. Taylor

Using solution calorimetry, the following heats of reaction were determined: (1) NaCN(c) + 1/Cu20(c) + 129H20(l) ? CuCN(c) + NaOH?128.5H2O ?H = -13.44±0.10 kcal/mole, (2) HCN(2) + NaOH?128.5H20 ? NaCN(c) + 129.5H20(l) ? = -2.52±0.02 kcal/mole. From these reactions, the heats of formation for CuCN(c) and HCN(2) were calculated to be 22.7±0.4 kcal/mole and 24.9±0.4 kcal/mole, respectively. Reaction 2 was made to check the consistency of literature values for heats of formation of HCN and NaCN. Adiabatic calorimetric measurements between 10° and 400° K showed the entropy and heat capacity of CuCN(c) to be 21.51±0.06 eu and 14.58±0.04 cal/mole deg, respectively, at 298° K. A broad anomaly in the heat capacity was found in the temperature range 285°-320° K. The heat of transition associated with this anomaly was less than 1 cal/mole, the sensitivity of the measurements.

Jan 1, 1971

By Robert F. Holub

The Bureau of Mines has made a study of the magnitude of the variations of radon daughter mixtures, with the objective of determining whether these variations reflect the existing physical conditions in uranium mine atmospheres or if they are merely random or systematic errors. To accomplish this, many data have been plotted using a triangular graphing technique which shows that plateout affects RaA more than RaB or RaC, and that it is impossible to find simple correlations between working level ratios, radon daughter mixtures, and age.

Jan 1, 1978

By Richard A. Thomas, Charles D. Litton, Kenneth E. Mura, Harry C. Verakis

Experiments were undertaken to evaluate the flammability of typical noise abatement materials used to line the cab interior of mobile mining equipment. The experiments were conducted using three different experimental configurations: 1. A ventilated tunnel test. 2. A full-size cab test where the interior surfaces were lined with the sample material and then ignited near the floor using a methane-air burner. 3. Standard ASTM E-162 tests using a radiant panel test apparatus. This paper describes the tests and presents the results obtained for 15 to 20 different materials of various chemical compositions and thickness. With one exception, materials that did not exhibit flame spread in the tunnel test also performed well in the full-scale cab test. All materials that had passed only a small-scale flammability test, such as SAE J369, failed dramatically in all three of the above test configurations. With one exception, all materials that performed well in the full-scale cab test had flame spread indices < 25, based upon the ASTM E-162 results. The lone exception had an ASTM E-162 flame spread index of 68. With regard to samples that failed the full-scale cab test, the carbon monoxide levels within the cab reached lethal concentrations in the range of 1.8% to 3.8% within 2 minutes from ignition of the sample—dramatically illustrating the severe fire environment that can result within the cab space.

By H. Robert Ensminger

As a result of the new mining law implemented in August 1985 and the programs conducted by the Institute Ecustoriano de Mineria (INEMIN), which was created by this legislation, there was considerably greater activity in the nonfuels mineral sector during 1986. Over the next 2 years, INEMIN will be developing a national mining plan that will guide Ecuadorean mineral development for the balance of this century. As stage one of INEMIN&apos;s mineral study, historical records were reviewed and 300 abandoned mines and 1,200 unexplored mineral deposits were available for further investigation. In 1986, INEMIN established 5 branch offices and negotiated 250 new mining contracts with foreign companies valued at $16 million. Despite all this activity, INEMIN officials estimate that 100,000 square kilometers remain available for claim staking. Technical assistance contracts were signed with Belgium, the Federal Republic of Germany, Italy, Spain, and the United Kingdom, to assist in a variety of assignments ranging from helping prepare the national minion plan to the development of industrial mineral deposits.

Jan 1, 1988

By W. H. Eddy

The Bureau of Mines conducted laboratory batch-and small-scale continuous flotation processing tests on waste granite fines from Georgia, to determine the feasibility of recovering usable feldspar and quartz products by flotation. Two flotation methods were utilized for the removal of biotite and other iron-bearing minerals: One was in an acid-cationic circuit, and the other in an alkaline-anionic-cationic circuit. Feldspar was recovered using an acid-cationic method. To produce commercial-grade feldspar and quartz products it was necessary to employ either two sequential froth flotation circuits or one froth flotation circuit supplemented by wet-magnetic separation techniques to remove iron contaminants. Continuous flotation processing yielded a commercial-grade feldspar concentrate containing, in percent, 3.8 Na20, 5.4 K20, and 1.10 CaO, with recoveries of 77.8, 70.3, and 64.4, respectively. The feldspar tailing was high-quality glass sand containing 98.2 percent SiO2 and 0.024 percent Fe2O3. About 42 percent of the quartz was recovered at glass sand specifications. An effective separation of, potash feldspar from the bulk feldspar concentrate was achieved by batch flotation in a mineral separation cell.

Jan 1, 1974

By P. G. Barnard

Losses of alloying metals in furnace flue dusts, grinding swarfs, and mill scale produced during the manufacture of stainless steel are substantial. About 25 million lb Cr, 8.7 million lb Ni, and 150,000 lb Mo and other critical metals can be made available annually for recycling by a process developed by the Bureau of Mines. Stainless steel wastes pelletized with a portland cement binder were reduced in a small electric-arc furnace by a two-stage process to produce a recyclable alloy containing Cr, Ni, Mn, and Fe. The initial reduction was with carbon; the second, with ferrosilicon. Results are compared with previously reported laboratory induction melting tests. A 2,000-lb demonstration test of the process in a commercial electric-arc furnace is also described. Data are also presented on three 1,500-lb tests made using various slag conditions in the electric-arc furnace. Recoveries up to 99 pct of the Fe, Cr, and Ni contents of stainless steel wastes were obtained in using the process.

Jan 1, 1977

By H. M. Lawrence

The recovery of phosphate rack from the ores in the land-pebble district of Florida is a simple washing and screening operation. In the gashing plants coarse phosphate only is saved. Log-Washer overflows and screen-undersize products containing an appreciable content of fine phosphate are discarded. The phosphate grains in the material discharged to waste are generally finer in size than the mesh--14 to 20 mesh or 0.346 to 0.03 inch--of the finest screen in the washer. The operators state that the washers ordinarily recover from 50 to 60 per cent of the phosphate content of the matrix mined. Any increase that can be effected in the recovery of phosphate would be of advantage to the industry and would conserve the mineral resources of the country. In considering possible methods that might increase the recovery obtained in phosphate-washing plants the application of flotation, if it could be successfully developed, seemed to warrant investigation.

Jan 1, 1928

By S. P. Howell, M. W. Von Bernewitz

"Introduction. The first short—flame explosives were made in the United States during the year 1902, then the mount was 11,300 pounds. In 1902 they were designated ""permissible explosives"", and were required to meet specific tests. By 1912 the total consumption thereof had increased to 24,630,000 pounds, equal to 5 per cent of the total quantity of all kinds of explosives produced in this country; while in 1922 the total was 43,429,000 Pounds, or 10 per cent of the production, and 18 per cent of the explosives used for the mining of coal.Each year the Bureau compiles statistics of explosives, one important object of this being to show the extent to which permissible explosives are replacing other classes of explosives in coal—mining operations, and the influence of such replacement in reducing the number of accidents caused by explosives in this class of mines. The consumption of permissible since 1916 has considerably exceeded the quantity of high explosives (dynamites, etc.) used in coal mines. While the increase in use of permissible is good, the replacement of other explosives therewith is not nearly as good as with be, considering the known general efficacy and safety of permissibles."

Mar 1, 1924

By F. P. Haver

A procedure is described for recovering both lead and sulfur from galena flotation concentrate, comprising the following steps: (1) Aqueous oxidation of the concentrate, using ferric sulfate to convert lead sulfide to sulfate and to give elemental sulfur; (2) regeneration of the ferric sulfate by electrolysis in a diaphragm cell; (3) treatment of the leach residue with ammonium carbonate solution to change the lead to an acid-soluble form and to produce ammonium sulfate as a byproduct; (4) solution of the lead carbonate in hydro-fluosilicic acid followed by electrolysis to recover the lead as metal and regenerate the acid; and (5) extraction of the elemental sulfur from the final residue with an organic solvent. About 90 percent of the lead can be recovered by the above method as 99.9-percent-pure metal, together with two-thirds of the sulfur--half in the elemental form and half as ammonium sulfate.

Jan 1, 1970

By Lewis V. Wade

This Bureau of Mines work was performed to theoretically determine the effects of specimen radius and specimen boundary conditions on the stress state in the rock near the anchor for rock specimens used to investigate expansion anchor behavior. Finite element analyses were performed on mathematical models of varying radius and boundary conditions. A review of the results of these analyses revealed a definite convergence of all stress measures considered as the specimen radius increased. There was, however, a significant variation in all stress measures as the specimen diameter increased from 8 to 12 inches.

Jan 1, 1973

By Ruth A. Holmes

A Bureau of Mines method for recovering nickel, cobalt, and copper from low-grade domestic laterites is described, which includes the unit operations of solvent extraction and electrowinning. Previous Bureau work indicated that addition of Na2S04 (sodium sulfate) to the nickel electrolyte improved current efficiency in nickel electrowinning. The present study determines the compatibility of Na2S04 with nickel strip-ping in the solvent extraction operation of the Bureau method. The effect of adding 100 g/l Na2S04 on nickel stripping, phase disengagement, and pH was determined in comparative laboratory-scale tests. In continuous-circuit testing, Na2S04 reduced stripping efficiency to the extent that five, instead of four, strip stages were required for complete stripping of nickel from the loaded solvent. In tests made in a phase-disengagement cell that had a variable settler area, the addition of Na2S04 did not significantly affect phase separation characteristics. The pH of the nickel electrolyte in the temperature range of 20° to 65° C was also unaffected by the addition of Na2S04. An economic evaluation showed that the energy saved by adding Na2S04 to the electrolyte would more than offset the cost of adding another stripping stage.

Jan 1, 1983

By Kenneth J. Miller

The Bureau of Mines conducted an investigation to improve the flotation response of coals that are difficult to wash by froth flotation. A literature survey and experimentation showed that, for the most part, refractory coals can be floated with oily collectors and frothers. Collector reagent consumption can be minimized and the selectivity of the flotation enhanced by assuring adequate, but not prolonged, reagent conditioning. Where flotation selectivity is especially poor, two-stage rougher-cleaner flotation is recommended. It was concluded that a major problem with refractory coals is predicting when they will appear in a flotation circuit so that supplementary flotation collectors can be added. Coal losses due to variation in the floatability of the feed might be reduced if a nonpolar collector such as kerosine or fuel oil is used along with a frother as general coal flotation practice.

Jan 1, 1977

Assure fail-safe stopping of a mining vehicle immediately following a loss of electric power. Approach A separate emergency brake system which actuates when electrical power is interrupted, was installed on several mining vehicles and tested in a long-term underground mining demonstration. How It Works Separate, spring-actuated brakes, which press against brake discs, are used to stop the vehicle following power failure. To allow norm al movement of the vehicle, hydraulic oil under pres? sure from the vehicle&apos;s hydraulic system is directed to a spring? loaded piston in each emergency brake housing. That pressure causes the piston to compress the spring and relieves the spring pressure against the puck, thereby allowing the brake disc to turn freely. See Figure 1 A. If the electrical power fails or if the machine is turned off, a valve in the hydraulic line to the emergency brakes opens. That valve, shown as ?Solenoid Valve (automatic)" in Figure 1, which is normally held closed by its electrical solenoid while the vehicle is electrically powered, is opened by the spring in the valve assembly. The pressure in the hydraulic line which is connected to the emergency brakes then drops to

Jan 1, 1978

Objective To develop and evaluate the effectiveness of safety training tools specific to the underground hard-rock mining industry. Background Scaling, the removal of loose rock from the roofs and walls of a mine by manual or mechanized means, may be necessary during any stage of mining. Manual scaling is very labor intensive, and mechanical methods can be too powerful and actually produce a less stable roof.

Jan 1, 2001

Generate less respirable dust during mining by reducing the clogging and downtime of the water sprays on mining machines, especially on continuous miners. Approach An improved filtering system, having commercially available components, has been designed and tested. How It Works The improved filtering system shown opposite is mounted on the mining machine, where It traps particles of coal and pipe scale which cause most clogging of the water sprays. Water entering the system first flows through a ?Y" strainer, which screens out particles larger than 1/8 inch diameter. Next, the water whirls through a small hydrocyclone. Most of the remaining smaller particles are removed and pass Into the accumulator compartment built into the hydrocyclone. The water also flows through a final filter. This filter catches particles that might pass the hydrocyclone, especially during water spray start-up and shut-down, when the speed of the water flow is not sufficient for

Jan 1, 1976

By J. W. Miller

An investigation was begun by the Bureau of Mines in 1948 to determine the preparation characteristics of American coals. Results of the investigation were planned to be reported on a county basis and from the data developed to determine: 1. Which coals either as mined or after beneficiation by conventional preparation are chemically suitable under present standards for producing metallurgical coke. 2. Which coals require special and more intensive treatment in preparation than is now practiced. 3. Which coals cannot be considered potential sources of metallurgical coke, regardless of preparation by present-day methods. This report is one in this county series that describes the preparation characteristics of the coals of Lee County, Va.

Jan 1, 1957