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By Gertrude N. Greenspoon

Legislation and Government Programs.-The Occupational Safety and Health Administration (OSHA) held public hearings in early 1975 on proposed standards for exposure to inorganic arsenic. The findings obtained at the hearings will be considered to promulgate emission standards. Domestic Production.-Arsenic trioxide (As203) was produced domestically only at the Tacoma, Wash. copper smelter of ASARCO Incorporated. Production data cannot be published. Output rose 9% over that of 1974, shipments were less than half those of 1974, and stocks rose 31 %. Production of arsenic metal, begun by ASARCO in August 1974, continued in 1975.

Jan 1, 1977

By J. W. Montoya

The chemical, mineralogical, and physical properties of berylliferous tuff from Spor Mountain, Utah, were determined in laboratory research conducted by the Bureau of Mines. Two beryllium-bearing minerals--a hydrated form of bertrandite and a berylliferous saponite--were found to be present in the tuff. Each of the beryllium mineral forms predominated in samples from certain areas of the district. The possibility of practicably separating the beryllium minerals from the tuff by physical methods appears remote because of the complexity and nature of the mineral associations. Beryllium mineralization in the region occurs in a rhyolitic tuff usually overlaid by unaltered rhyolite. The beryllium is distributed erratically throughout the tuff in individual mineralized bodies. Many samples of mineralized tuff were examined and found to contain from 0.2 to 1.8 percent BeO. All samples contained a hydrated form of bertrandite that was nearly cryptocrystalline, whereas samples from one area also contained a berylliferous saponite of variable beryllium content. Neither mineral has been previously reported, although related bertrandite-like minerals have been found in the U.S.S.R. and berylliferous minerals of the montmorillonite group have been synthesized. Most of the minerals of the tuff are finely crystalline, intergrown, and have similar densities. The complexity and intimacy of the mineral associations, the difficulty of achieving effective mineral liberation, and the highly friable nature are characteristics that lead to the conviction that tuff of the type examined cannot be effectively concentrated by gravity, magnetic, electrostatic, attrition, washing, sizing, or flotation methods.

Jan 1, 1962

Provide better ventilation for mines by reducing air leakage around stoppings. Approach Most stoppings are constructed of concrete blocks and trowelled-on mortar and are not very airtight. Bureau of Mines research has shown that brushing on modified mortar containing fiberglass and/or other additives, that enhance strength and adhesion, minimizes air leakage around and through the stoppings. Airtightness is an important factor in building stoppings since an airtight stopping will provide for more efficient ventilation airflow and more cost-efficient use of the mine's ventilation system. How the New Technique Works After broken floor and rib material is removed, the stop-ping faces are covered with one or two coats of modified

Jan 1, 1982

By R. D. Leitch

Tests have recently been conducted by the Bureau of wines on the ignition hazard of exposing heated filaments of electric mine lam bulbs in an explosive mixture of methane and air. This investigation was undertaken in order to settle a question that had arisen in connection with the safety of miners? electric lamps. For several years, in view of former studies made by the Bureau and reported in Bulletin 524, the fact that the heated filaments of even low voltage, lour candlepower bulbs constitute a danger was generally accepted by the Bureau's engineers. These early tests, as well as subsequent tests, were conducted with Pittsburgh natural was as the testing medium.

Jan 1, 1925

By C. C. Clark, R. R. Backer, J. D. Vickery

This report presents the results of tests conducted by the U.S. Bureau of Mines to determine the transport characteristics of highly concentrated paste backfill mixes made from dewatered total mine tailings. The slurry concentrations of the mixes were all above 78 pct by weight with slumps ranging from 6.4 to 16.5 cm (2.5 to 6.5in). Laboratory material property tests and full-scale pumping tests were conducted using pipe diameters of 102,128, and 154 mm (4, 5, and 6 in) and a positive-displacement pump. The results indicated that the tested backfill mixes can be successfully transported as a stiff paste and identified the influence of and the interaction among the various mix and system variables.

Jan 1, 1995

By L. J. Douglas, A. G. Kim

Methane and other hydrocarbon gases, byproducts of coalification, are emitted from coal at widely varying rates and often present ventilation problems during mining. The air in some coal mines apparently contains no methane. To determine if coals from mines which had no history of detectable gas emission contained adsorbed methane, samples of coal at the shaft bottom and at an active face were obtained and placed in sealed metal cylinders. The atmosphere around the coal was sampled and analysed by gas chromatography. Methane, ethane, ethylene, propane, propylene, and butane were found to have been desorbed from these coals. Hydrogen and helium were also detected. An estimate of the amount of residual gas per ton of coal indicated that coal samples from the active face generally contained more adsorbed gas than coal samples obtained from the shaft bottom, although in both instances the total amount of gas was relatively small.

Jan 1, 1973

By D. K. Ingram, G. L. Mowrey, T. R. Rehak

Problem: Blasting is a hazardous component of surface mining. Serious injuries and fatalities result from improper judgement or practice during rock blasting. This paper describes several fatal injury case studies, analyzes causative factors, and emphasizes preventive measures. Method: This study examines publications by MSHA, USGS, and other authors. The primary source of information was MSHA’s injury-related publications. Results: During the 21-yearperiod from 1978 to 1998, the mean yearly explosive-related injuries (fatal and nonfatal) for surface coal mines was 8.86 (95% CI: 6.38 -11.33), and for surface metal/nonmetal mines 10.76(95% CI: 8.39 - 13.14). Flyrock and lack of blast area security accounted for 68.2% of these injuries. This paper reviews several case studies of fatal injuries. Case studies indicate that the causative factors for fatal injuries are primarily personal and task-related and to some extent environmental. A reduction in the annual injuries in surface coal mines was observed during the ten-year period of 1989 - 1998 [5.80 (95% CI: 2.71 - 8.89) compared to the previous ten-year period of 1979 - 1988 [10.90 (95% CI: 7.77 - 14.14)]. However, such reduction was not noticed in the metal/nonmetal sector, i.e., 9.30 (95% CI: 6.84 - 11.76) for the period 1989-1998compared with 11.00 (95% CI: 7.11 - 14.89) for the period 1979-1988. Discussion: A multifaceted injury prevention approach consisting of behavioral/educational, administrative/regulatory, and engineering interventions merits consideration. Impact on industry: The mining community, especially the blasters, will find useful information on causative factors and preventive measures to mitigate injuries due to flyrock and lack of blast area security in surface blasting. Discussion of case studies during safety meetings will help to mitigate fatal injuries and derive important payoffs in terms of lower risks and costs of injuries.

By E. G. Davis

The flash reduction of fine iron ore in a dilute-phase system was investigated at 500° to 900° C within a heated stainless steel tubular coil. Alabama brown iron ore and Mesabi semitaconite ore were fed into the coil concurrently with reducing gases of hydrogen and reformed natural gas, so that the velocity of the gas at the reaction temperature was sufficient to entrain and pneumatically transport the solids through the coil. Reduction is very rapid with retention time of the ore in the coil varying from 4 to 15 seconds. Variables affecting reduction are temperature, ore feed rate, and gas flow or velocity. Results of the studies show that a partially reduced product (10-to 25-percent reduction) can be made which, on subsequent magnetic concentration, yields a concentrate containing 64 to 70 percent iron with a 90-to 94-percent iron recovery. Maximum reduction of 77 percent was obtained when hydrogen was used in a four-stage reduction test to yield a product containing 61 percent metallic iron.

Jan 1, 1972

By Michael S. Wieland

The work-principle method was developed for theoretically resolving toxic fumes from non-ideal charge formulations. The whole description of a wanted process refers to macroscopic changes resulting from removing and imposing constraints that work one at a time to chronologically render trajectory terminal (key) states. The trajectory resolution utilizes a thermodynamic quasi-potential or negative work function, and numeric results require some appropriate standard thermodynamic (equilibrium) reaction code TDRC. The underlying method is unable to restrict reactions, tailor the work output or resolve states within the trajectory transitions, so the trajectory terminology is used somewhat figuratively. The work-principle model has the working fluid (reaction material) interacting with a tremendous reservoir (chamber air and walls), while forecasting the work performed upon a mechanical agent. Within the underground test chamber, the widening fume zone undergoes a decline in temperature, a reduction in reaction rates, resulting in out-of- equilibrium circumstances at the Q*-point, representing the measurement state. Rather than coping with the hard issues of non-equilibrium, the toxic fumes are resolved numerically for the Z-point, rendered by a zero-net- interaction energy constraint. Though other techniques require complex equation-of-state EOS for the whole trajectory, the work-principle formulation eludes the issue, requiring an EOS that works just for the terminal-state. Under the circumstances, the Z-state is reconcilable with the ideal-gas domain, and relevant TDRC results yield the restricted state in a numerical way for different charge formulations. The work principle makes it hard to remedy or to tamper with the resulting Z-point fumes: non-macroscopic trajectory readjustment is forsaken, terminal states are results rather than stipulations, and resetting the EOS formula constants would be ineffectual. Though the non-equilibrium portion remains unresolved, it is noteworthy that the work principle rigidly fixes the Z-state, thereby reducing the uncertainty for rendering reaction-rate models characterizing the non-equilibrium Z-Q* transition. Though more refinements are needed, some Z-point fume results are included to illustrate the threshold (minimum) resolving capacity of the work- principle formulation.

To suppress the natural bacterial action in acid mine drainage (AMD), the major contributor to acid formation. Approach Recycle partially-treated affluent back to the source of AMD within a mine, or to the coal or coal-waste stockpile. This effectively eliminates any further biologically-promoted AMD by inhibiting catalyzed weathering or oxidation by acid-forming bacteria. How it Works AMO-type effluents can be largely reduced by "recycling" the acidic outflow back to the source of AMD within a mine or to the Input side of a waste pile to percolate through the reactive pyrite and bacteria mixture. The bacteria in the cell thrive on the oxidation of ferrous to ferric iron through the electron transfer, Fe2 +[=]Fe3 + + e. Its reaction product [s, therefore, essentially ferric iron. While small quantities of Fe3 + will not interfere with the exponential multiplication of the bacteria

Jan 1, 1982

Capture airborne coal dust generated by a continuous mining machine to reduce workers? dust exposure and to improve face visibility. Approach Develop a low-profile dust collector system which can be mounted on the boom of a continuous miner. How It Works When coal is mined with a milling head continuous miner, a substantial amount of coal dust (respirable and non-respirable) escapes the dust suppression sprays at the cutter head. This can cause poor visibility around the cutting head and can expose the workers to high levels of respirable dust. A practical means of removing this dust is with a scrubber mounted directly on the mining machine. Under a Bureau of Mines contract, a low-profile, machine-mounted dust collector (MMDC) was developed to avoid adding extra height to the continuous

Jan 1, 1983

By M. J. Sapko

The Bureau of Mines conducted laboratory-scale flammability experiments to investigate the possible use of water spray systems for inerting or quenching mine-gas ignitions, such as those encountered at the working face of a coal mine. The inerting results for premixed methane-air-water mixtures indicated that water droplets of less than 10 µm tend to be as effective as the vapor. Water requirements for inerting such mixtures were much smaller than those for quenching the sustained flame propagation by the application of water sprays. The minimum water mass concentration for quenching methane-air flames increased linearly with increasing droplet diameter (surface weighted mean) and decreased with increasing spray temperature, whereas the droplet surface area required per unit volume was essentially constant for a given gas mixture composition. Data extrapolations indicated that a quenching system may be feasible for the longwall mining application.

Jan 1, 1977

By L. B. Pankratz

Low-temperature heat capacities, high-temperature enthalpy increments, and the enthalpy of formation at 298° K were determined calorimetrically for vanadium subnitride (VN0.465). The low-temperature investigation gave S°298.15 = 6.379 ±0.005 cal/deg mole, and a combustion calorimeter investiga¬tion provided ?Hf°298.15 = -31.80 ±0.60 kcal/mole. The two quantities were combined with the high-temperature data to give standard values of enthalpies of formation and free energies of formation above 298° K. These and related thermodynamic functions were tabulated to 1,800° K. Similar data are included in the range of 298° to 1,600° K for the mononitride, VN.

Jan 1, 1971

Provide reasonably priced, reliable fire protection for large walking draglines. Approach Fire hazards on large draglines were analyzed, then appropriate automatic fire sensing and suppression systems developed and in-mine tested. How It Works Five fire hazard areas identified for special attention are: electrical control room, high voltage transformer enclosures, circuit breaker rooms, collector ring/roller path area, and the automatic lubrication rooms. Automatic fire sensing and suppression systems were separately designed for each area. The design of each system was tailored to the hazards and equipment protected. Spot thermal sensing and Halon 1301 suppression were specified for the electrical

Jan 1, 1981

By S. P. Sandoval, A. E. Clark, S. W. Yopps, J. S. Gomer

The U.S. Bureau of Mines conducted Cu exchange tests for six common clays under simulated in situ leaching conditions. Regression equations were obtained from the data expressing the Cu exchange capacity as a function of Cu concentration, pH, and temperature. Using these equations, an analysis was made of the impact each clay could have on overall Cu recovery. The results suggest that Ca and Na montmorillonite clays could have a major impact on Cu recovery and that attapulgite and illite clays could have a smaller, but still significant, impact. Kaolinite and ripidolite clays pose little threat to loss of Cu from in situ leaching solutions.

Jan 1, 1992

By Maria I. De Rosa

Table 10 and figure 4 show the number of fires and fire injuries occurring at the surface of underground coal mines by state during 199&1999. Table 10 also shows by state the risk rate, employees' working hours, and lost workdays. A total of 65 fires occurred in 10 states. Thirteen of those fires caused 12 injuries and 1 fatality (the yearly average was 6.5 fires and 1.2 injuries). Four fues and one fire injury involved con- tractors. The Ewhr value was 97 x l O6 hr (Irr = 0.025); the LWD value was 6,206. Pennsylvania had the most fues (20 fues and 5 injuries), followed by West Virginia (1 6 fires and 1 fatality) and Kentucky (1 5 fires and 3 injuries). Among these states, Pennsylvania had the highest injury risk rate value (Irr - 0.095). Table 1 1, partly illustrated in figure 5, shows by time period the number of fires, fire injuries, and fire fatalities; risk rates; employees' working hours; and lost workdays. The number of fires and fire injuries show a decrease followed by an increase during the five time periods, accompanied by a decline in employees' working hours throughout the periods (see table 11 and figure 5). The Irr values follow patterns similar to those shown by the injury values. Tables 12- 17 show the number of fires by ignition source, method of detection and suppression, equipment involved, location, and burning material by time period. Figure 6 shows the major variables during 199&1999. Table 18 shows the number of fire injuries per number of fires causing injuries and total fires by year, ignition source, equipment involved, and location.

Jan 1, 2004

By David S. Yantek

A-weighted sound levels around vibrating screens in coal preparation plants often exceed 90 dB(A). The National Institute for Occupational Safety and Health (NIOSH) is actively developing noise controls to reduce noise generated by horizontal vibrating screens. A 121-microphone, 3.5-meter-diameter array was used to perform beamforming to determine locations of significant noise radiation on the screen. Below about 1 kHz, the screen body was found to be the most significant noise source. The beamforming contour maps showed several key locations on the sides of the screen and the feedbox are the most significant contributors. Operating deflection shape (ODS) analysis was used to examine the screen behavior under actual operating conditions. This information is helpful in determining how to modify the screen body to reduce the noise radiated by the screen below 1 kHz. The analysis showed modal vibration patterns on the sides and feed box were the main contributors to noise. The results show several areas on the screen sides and feedbox that can be modified to reduce noise.

Jan 1, 2009

By James W. Townsend, William H. King

"INTRODUCTION As a byproduct of its mineral investigation program, the Bureau of Mines has developed a number of operating devices and techniques worthy of note. This paper, prepared under the direct supervision of Paul T. Alisman, chief, Salt Lake City Division, Mining Branch, and under the general supervision of Lowell B. Moon, chief, Mining Branch, reports upon ore such technique.The Wright borehole-surveying instrument developed at the Homestake mine, Lead, S. Dak., has been described in several publications. 3/ For the benefit of those to whom the publications are not available, the instrument is described here. However, this article will be concerned mainly with the technique developed by the Federal Bureau of Mines for using the instrument.In the use of the Wright borehole-surveying instrument, it was found advantageous to develop a standard practice of operation covering type of film, preparation and care of film, loading film in instrument, placing instrument in container, exposure time, unloading film from instrument, development of film, and determination of dip and strike from film impressions."

May 1, 1947

By M. B. Shirts

Bench-scale studies were made on a reductive hydrometallurgical procedure to convert chalcopyrite flotation concentrate to copper metal or a readily leachable sulfide. Reductive conversion of chalcopyrite and dissolution of iron and sulfur were accomplished in hydrochloric or sulfuric acid solution by the addition of metallic copper, iron, or lead. Use of metallic copper as the reductant enabled extraction of 95 and 46 percent of the iron and sulfur, respectively. The products were ferrous iron, hydrogen sulfide, and a copper sulfide. Use of metallic iron or lead as the reductant enabled extraction of 95 percent of both the iron and sulfur. The products obtained with metallic iron or lead were ferrous iron, hydrogen sulfide, and metallic copper.

Jan 1, 1974

By John Gross

The modern practice of grinding ores so that often 80 per cent or more of the product is finer than 200 mesh makes it desirable to supplement sieve sizing so as to extend considerably the range of sizing. Moreover, the fact that the material finer than sieve size represents the major part of the work done in grinding emphasizes thick need in can investigation of crushing efficiency. A method based on the settling rate of particles in grater appeared to be most practical for sizing; finely ground ores. There are two possible methods of utilizing this principle: one based on free settling or sedimentation; and the other on separation by means of a rising; current of water, or elutriation. In sedimentation, mechanical entanglement causes material at the start to settle in a mass, and this persists throughout. As this feature is largely eliminated by elutriation, which permits a comparatively clean separation of the various sizes, the elutriation method was adopted.

Jan 1, 1929