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By V. V. Zakopaylo, M. V. Lukyantseva, V. A. Ignatkina, V. A. Bocharov, L. C. Khachatryan, D. M. Altynamanov, A. A. Kayumov, R. H. Sharipov

"This research was aimed to explain the reasons of low floatability of tennantite from refractory pyrite ores of non-ferrous metals and to create a reagent regime for selective increasing a recovery of copper sulfide minerals from arsenic-containing copper pyrite ore. ?opper-zinc ore of the Uzelga deposit has 89% of pyrite, some part as melnikovite; copper is assayed as 3.58% of tennantite and 0.25% of chalcopyrite; there is 2.19% sphalerite. Sulfide minerals are very finely disseminated. Tennantite is genetically related to primary copper sulfides. Graphene was identified on the surface of tennantite by a transmission electron microscopy (TEM) method. The recovery of tennantite was rose up by using the collector M-TF. M-TF is the mixture of diisobutylditiophosphate (DTF) and O-isopropyl-N-methyl (ethyl) (TC) in the certain ratio. M-TF change up a kinetic of copper sulfide flotation in a slightly alkaline medium, but pyrite has slowly floatability at this moment. A depressing effect of thiosulfate ions in a liquid phase of pulp flotation tennantite from pyrite ore has been established. A copper recovery up 14.2% (from 67.7 to 82.0%) into a copper concentrate level off copper grade of 18.65% (butkx) and 18.68% (M-TF) has been increased by the new technology with M-TF compared to a standard technology with butkx. A main copper recovery up to 50 % in an inter-cycle copper concentrate assaying 19-21% Cu in case of using M-TF was gotten. A zinc concentrate with recovery of 50% and a zinc assay of 41.76% by a standard flow sheet with butyl xanthate was obtained. A zinc recovery of 70.3% with a zinc grade of 44.17% by the M-TF technology was achieved.INTRODUCTION The pyrite copper-zinc ores of the Urals region are considered refractory. The distinctive features of these ores include a high content of pyrite (90-95%), the presence of arsenopyrite and arsenical pyrite, and the simultaneous presence of chalcopyrite, bornite, tennantite with the predominance of the latter (Andreasen et al.,2008;.Dobrotsvetov, 2009; Chanturiya et al. 2016). The flotation properties of tennantite differ from those of chalcopyrite (Xumeng Chen, Yongjun Peng, Dee Bradshaw. 2014), which is the reason why a comprehensive study was under taken of the flotation activity of tennantite and a process for its recovery was developed. The proposed agent treatment and flotation process make it possible to produce salable copper and zinc concentrates."

Jan 1, 2018

By P. Holtzhausen, L. Auret, B. Lindner, A. Haasbroek

"Spiral concentrators offer a cost effective way to separate valuable minerals from gangue by displacing lighter materials to the outside, and heavier materials to the inside of the spiral. The separation can be seen as visible concentrate bands and splitters are set at the bottom of the spiral to effectively split the ore into various densities. As there are typically many spirals in a concentrator plant, it becomes ineffective to continually adjust the splitter positions manually. Vermaak et al. (2008) proposed to use image recognition to detect the concentrate bands, thereafter, creating a model predicting the positions under certain input conditions. This model could then be used for optimisation and/or control of splitter position or band position. In contrast an online concentrate band detection system would provide real time concentrate band positions without losing accuracy due to model generalisation. These systems are usually expensive and time consuming to develop, due to a lot of centralised features required (image capturing, image processing and/or feedback to a controller). This study took advantage of the recently developed Raspberry Pi minicomputer to perform rapid prototyping of an online image processing sensor. The Raspberry Pi, and accompanying camera module, offers a portable Linux environment which can natively run the required image processing algorithms. Furthermore, extensive use of OpenCV was made to reduce development time, by relying on existing and proven algorithms to detect the concentrate bands. The Raspberry Pi also incorporates generic input/output ports which can be used in future work to provide the signal to a controller. In conclusion, the Raspberry Pi was successfully used to perform real time concentrate band position detection on a spiral concentrator. This solution is more general than an experimentally identified input-output model and may be used for control or optimisation studies in a wide array of spiral concentrators."

Jan 1, 2014

By A. F. Usov

The paper is concerned with an analysis of the experience gained in development of special electro-technical installations applied in electric-pulse destruction of materials. A principle scheme of an electric electric-pulse installation is given, and electric circuit variants of its blocks made on various element bases are discussed. Also assessed are some ideas to further improve the technical and economic characteristics of the equipment.

Jan 1, 2014

By N. Naudé

The theory on particles displacement subjected to upwards and settling movements in water, using a water pulse, is described in literature, but very little experimental data is available to verify these theoretical ideas. The aim of this research work was to visualize the displacement of solid particles in a mixture of water and solid particles created with the aid of water pulses in the Mineral Density Separator. From the literature it is known that lighter particles are subjected to higher levels of displacement than heavier particles, and when the particles then settled down, layers of material are formed ac-cording to the densities of the material. By removing the individual material layers, the materials can then be separated according to their densities. During this study the individual material layers were investigated regarding the density and size distribution in that specific density layer. It is important for this project to have a statistical prediction of the ?real? flow of the particles with different density and size distribution, inside the Mineral Density Separator. The information gathered during this study will be used to show the correlation between a two dimensional model of the particle flow and that of the real three dimensional flow inside the Mineral Density Separator.

Jan 1, 2014

By X. W. Lv

The intelligent recognizing and processing system for sinter ore mineragraphy make a great convenience of recognition and measurement. Specially, it?s critical important for a successful intelligent system to extract the minerals? feature accurately and sufficiently. Reflection index, as the crucial feature of mineral, is calculated by the theoretical calculating model of index based on the principle of imaging color models. In gray histogram of minerals? micrograph, the peaks? positions represent the information about mineral categories and contents. The relationships of different minerals? peak-positions in curve of gray histogram were got by using the peak-find model of gray histogram and calculating model of reflection index. These two models which can be regard as the method of feature extraction for minerals? photomicrograph also lay a good foundation for the artificial intelligent system of recognition and processing in sinter ore.

Jan 1, 2014

By Marzio Piller, Girolamo Belardi, Jure Mencinger, Paolo Bozano, Gianni Schena

"The hydrodynamics of the Tri-Flo™, a two stage cylindrical cyclone used in dense media separation, is studied using Computational Fluid Dynamics. The flow field is simulated with an Euler-Euler Volume of Fluid two-phase approach and the Reynolds stress turbulence model.A unique feature of the device is that the separation medium suspension is pumped and introduced tangentially into the two cylindrical compartments while the raw feed is conveyed to the feed hopper and fed at the axial inlet. This feature allows to use less pumping energy and limits the unavoidable production of fines. The Tri-Flo™ complex flow pattern is little known but central to the efficiency of the separation.The velocity field is computed within the two compartments of the separator. The interface of the air-core that forms in the inner axial part of the cylindrical sections is identified and visualized. The numerical results for a reduced-size 100 mm ID Tri-Flo™ are compared against laser Doppler measurements on a transparent acrylic model (Chinè, 1995) operated with water. The robustness of the model and its prediction capability are verified.The possibility to accurately predict the velocity profiles within the vessel and their dependence on the main Tri-Flo™ operating and geometrical variables paves the way to a better understanding of the functioning of the separator, its design improvements and scale-up."

Jan 1, 2014

By Jacek Kolacz

A new sensor based sorting system related to complex image analysis has been developed at Comex AS - Norway. It makes it possible to separate different mineral particles regarding their color, shape, texture, size, density and indirectly their composition. The sorting system has been successfully tested and applied for sorting minerals providing high separation efficiency in the range of 95-99.9 %. The main advantage of this system is connected with its universality where many material parameters are analyzed in the same processing unit by a single passage.

Sep 1, 2012

By X. L. Song

A large amount of tailings in concentrators bring a series of problems to the environment and society. It is significant to reclaim the huge tailings and reuse them in industries in order to utilize mineral resources adequately. Primarily Lead-Zinc tailings with a certain quality of clay and feldspar were used to produce ceramic tiles by sintering method under specific technical conditions. By testing the properties of the ceramic tiles, it was shown that the amount of Lead-Zinc tailing used in the tiles was 60%~70%, and the mechanics properties were good. The optimum proportion parameters were Lead-Zinc tailing 60%, clay 35%, feldspar 5%, and the maximum flexural strength of tiles was up to 38.2MPa when it was sintered at 1090? for 30min. Its flexural strength, water absorption and thermal shock resistance reached the State Standard of GB/T4100.4. The product is suitable to be used in pavements and paths of parks.

Jan 1, 2014

By P. Gao, J. W. Yu

"Pre-concentration is a necessary step for upgrading low-grade iron ores, and its aim is to remove gangue minerals for improving efficiency of downstream separation process. The most important pre-concentration technique for iron ores, including hematite, siderite and limonite, is magnetic separation based on the appreciable differences between the desired iron minerals and gangue minerals in magnetic susceptibility. In this paper, the separation efficiency of one-stage low-intensity magnetic roughing combined with two-stage high-gradient magnetic scavenging for the pre-concentration of a low-grade hematite from Donganshan was investigated. It is a BIF type of ore containing hematite, magnetite and a bit of siderite, and an average content of Fe is about 34.6%. The effects of grinding fineness and magnetic field intensity for scavenging I and II were studied and optimized. The results showed that a magnetic preconcentrate assaying 42.7% with a recovery of 95.4% was obtained under the conditions of ore grinding fineness of -74 µm 70%, magnetic field intensity of 300 mT and 800 mT for scavenging I and II, respectively. Over 20% of the feed was rejected as the final tailings assaying 6.4% Fe. Meanwhile, the XRD, iron chemical phase and SEM analyses of different stage products revealed that hematite, magnetite and siderite could be recovered successfully by magnetic separation. However, some ultra-fine hematite particles (-10 µm) were difficult to be captured by magnet, and lost in the final tailing, resulting in lower iron recovery.INTRODUCTION Donganshan iron ore belongs to sedimentary-metamorphic iron formation called banded iron formation (BIF), which is formed in the Precambrian with a layered structure composed of ore bodies (Shen, 2012). Such type of iron deposit contains various iron-bearing minerals like hematite, magnetite, and siderite, suggesting it may be amenable to pre-concentration with magnetic separation. The pre-concentration process is effectively applied in recovering hematite, magnetite and siderite from iron ore, due to its benefits of further upgrading iron ore and improving separation efficiency. The most important pre-concentration technique for iron ore is magnetic separation, including low-intensity magnetic separation and high-gradient magnetic separation, based on the fact that there are appreciable differences between the desired hematite, magnetite or siderite and the gangue minerals in magnetic susceptibility."

Jan 1, 2018

By W. Z. Zu

In proved reserves of vanadium-containing titanomagnetite in Panxi, China, iron grades of ores were 50% ~ 15%. China?s metallurgical industry departments defined the iron ores containing 50% ~ 20% TFe as exploitable resources and the extreme lean iron ores containing 20% ~ 15% TFe as temporary unexploitable resources, the extreme lean ores were as waste rejected into waste dump in mining process. This paper researched process mineralogy of the extreme lean ores, adopted mineral processing technology responded to the properties of the ores to treat the ores and obtained quality vanadium-iron concentrate, titanium concentrate and sulfur concentrate, therefore successfully utilized the extreme lean ores, changed the ores from waste resources to exploitable resources.

Jan 1, 2014

By P. K. Arya

Huge quantity of copper is lost in Crown, Sill, Rib Pillars, hanging wall, foot wall and unexploited ore bodies in several closed underground copper mines and old worked out stopes of Hindustan Copper Limited at Mosaboni and other places. These mines might have been uneconomical to work with conventional mining methods. However, huge quantity of mineral reserves is lost due to their closure. Chemical and in-situ bio-wash leaching, if tried can provide an answer to facilitate the recovery of metallic values economically. Encouraging results were obtained during an experiment at North Badia Mines at Mosabani in the past. Though the experiments were not completed but whatever results obtained were very encouraging and can be successfully tried to make it viable. The results of the experiments are discussed here and a plan is suggested to recover copper from such mines.

Jan 1, 2014

By W. S. Eu

Thermal treatment of mineral ores can initiate thermal phase transformations which can affect either their activation or deactivation, subsequently influencing their ability to dissolve in a leaching reagent. The formation of rutile and hematite from ilmenite minerals, for example, has been suggested to occur through a series of reduction and segregation reactions. This process has been used in beneficiating low-grade weathered ilmenite ores to higher grade rutile. Despite decades of re-search, the mechanism of this process is not well understood, because dissolved intermediates are poorly crystalline and are difficult to quantify, with the exception of the final rutile products. Previous studies have shown that disrupted intermediate phases, by thermal treatment, are most susceptible to reagent attack and can often demonstrate ?activation? effects. In this study, synchrotron based X-ray diffraction method was used to investigate in-situ and in real-time the transformation of ilmenite minerals to rutile and hematite during calcination. The rate of formation and disappearance of specific Bragg peaks during the reaction and thermal decomposition of the mineral were used to derive an understanding of the solid-state reactions. The effects of the mineral transformation were validated by laboratory based batch calcination and leaching in sulphuric acid. The results suggest that transformation of major mineral phases occurs within of specific window of operation and thermal treatment appears to influence the extent of activation and leachability of ilmenite minerals.

Jan 1, 2014

By J. A. Venter

Mineralogical studies indicate the Pt-Pd-Bi-Te class to react poorly on the flotation stimuli and indications are that these minerals are slow floaters. However, recent studies performed on a number of minerals from this class indicated strong interactions with potassium ethyl xanthate resulting in the formation of dixanthogen (only one of several xanthate species). The poor flotation response is not a result of poor interaction of xanthate with the surface. It is proposed that the oxidation products of sulfides in the process water interact with the PGM surface. To test this, the effect of thiosulfate (an important oxidation product of sulfides) was investigated by employing electrochemical measurements and FTIR spectroscopy. The electrochemical investigations indicate no strong effect of thiosulfate on the interaction of xanthate with the minerals surface as well as the reduction of oxygenthiosulfate is likely not responsible for the poor flotation response of these minerals in industrial plants.

Jan 1, 2014

By D. M. R. Sekhar

Certain types of rock phosphates of sedimentary origin are applied to acidic soils as fertilizer directly. Recent research in India showed that high grade rock phosphate in fine size when used as a mix with organic manure works as efficiently as di-ammonium phosphate (DAP) in alkaline soils. The rock phosphate from Jhamarkotra, India (sedimentary origin), Egypt (sedimentary origin) and South Africa (volcanic origin) showed good agronomic efficiency when used as Phosphate Rich Organic Manure (PROM). Further PROM shows equal residual effect. The results of efficiency of PROM made using two grades (+ 24% P2O5 and 34% P2O5) of rock phosphate mineral from Jordan show that low grade rock phosphate slimes are as effective as high grade phosphate concentrate when used in PROM. Also PROM is very effective in the saline soil of Eshidiya desert where DAP is not at all effective.

Jan 1, 2014

By V. Sovmen

The gold-ore Olympiada deposit is located within the Yenissei range (Krasnoyarsk Region, Russia). Primary sulphides ores are metasomatic changed rocks, mica-calcite-quartz structure with impurity amphiboles, chlorites, carbon, the rare thin grains of sulfides (up to 3%~5%) and native gold. The structures of ores are fine-grained, prevailing texture of ores - interspersed, vein-interspersed, band-interspersed, veinlet. The most important minerals in the deposit are: gold, arsenopyrite, pyrrhotite, antimonite, Sb-sulphosalt, quartz, muscovite, calcite, siderite, titanium minerals, chlorite and minor sulfides like chalcopyrite, galena, sphalerite, etc. A common problem in mineralogical studies applied to mineral processing (concentration, cyanidation, etc.) is the characterization of gold in ores and technological products. This paper discusses the behavior of minerals during technological process at operating factory in Olympiada Mine and gold distribution in the ores and products. For the mineralogical characterization of minerals ? combination of analytical techniques was used. Gold is encountered in the primary ores as free grains among rocks, growth with sulfides and nonmetallic minerals, inclusions in sulfides, sulphosalt, and nonmetallic minerals. The gold-sulphide ores of Olympiada deposit can be quite complicated for enrichment. With the purpose to increase the extraction of metal from concentrates by liberating the dispersed gold, forming inclusions in sul-fides, there is used technology of biooxidation of flotation concentrates in Olympiada Mine. Gold and the basic ore-forming minerals in the ores feed, sulphidic concentrates, biocakes, tailings of concentrates of flotation and products of hydrometallurgical leaching have been studied in the mineralogical research. During researches it is established that pyrrhotite was completely oxidized while arsenopyrite was oxidized almost completely in the bacterial oxidation process. Pyrite and antimony minerals behave similarly and were oxidized only partially. The main oxyhydroxides in the bacterial oxida-tion process are goethite, limonite and jarosite. The results of mineralogical researches showed reasons of losses of gold during hydrometallurgical enrichment.

Jan 1, 2014

By Sergey Romanenko, Tatyana Aleksandrova, Karen Arustamian

"Current status of question about grinding stage effect to electrochemistry parameters of operation preparation slurry before intermediate selective flotation was assessed in the present scientific work. Needs of more detail study chemical reactions in the slurry preparation and flotation processes were shown. The ores are polymetallic sulphide type and the one are most difficult for mineral processing. The methodology allows increase information base during floatation tests. Ionometric methods and elements of neural network have been used in the study of mineral processing questions.We have also identified the relationship between the received values of the electrochemical parameters and the technological results in selective flotation. The optimal values of the electrochemistry parameters in operation of the preparation slurry before selective flotation has been found. The main effect of using the proposed methodology is to obtain scientifically based solutions to improve the technology parameters of flotation polymetallic sulfide ores. Challenging issue of selectivity of sulphide-polymetallic ores will be considered using case study of sulphidepolymetallic ores. It was shown that several factors are formed in ore grinding: formation of hydroxyl oxides of iron compounds, copper cation leaching, metal-sulphide and metal-sulphite complexes formation. The chemistry was revealed for current processes in slurry preparation operation before selective flotation. Quantitative assessment of interrelations between electrochemical parameters of slurry and process performance was given with using electrochemical control methods. Neuron network-based model was estimated based on data array and was allowed to establish optimum electrochemical conditions of metal-sulphite complex formation to provide maximum efficiency of selective flotation.INTRODUCTIONPhysical and chemical processes that take place in ore grinding have a significant impact on flotation selectivity and can cause low selectivity of the flotation process. Today this issue is given much attention. In the paper [1] it is pointed out that sulphide oxidation products and slurry components, such as sulphide ions, metallic iron and its oxidation products, have effect on flotation performance. So, metallic iron has impact on metal-sulphite complex formation as a result of oxidation-reduction reactions as follows:"

Jan 1, 2018

By Xuliang Yang, Yuemin Zhao, Bo Zhang, Liang Dong, Cheng Sheng, Gongmin Li, Zhenfu Luo, Yaqun He, Chenlong Duan

Coal plays an important role in the primary energy consumption of all over the world. In 2012, coal reached the highest share (29.9%) of global primary energy consumption since 1970. Coal burning mainly contributes to the emission of SO2, NOX, Hg and other impurities that jeopardize the future of environment. . Beneficiation before coal utilization is the most economical and effective technology for removing the hazardous material and gangue. In this paper, a novel process of dry beneficiation based on gas-solid two-phase flow composed of the compound dry cleaning separator (FGX), the air dense medium fluidized bed separator (ADMFB) and the vibrated fluidized bed with autogenous medium (VFB) is proposed. The main equipment and the flowsheet of the united system are described in detail. Separating principle of the FGX, ADMFB and VFB devices are all based on gas-solid two-phase flow. In FGX, gassolid suspension is composed of continuous gas flow and coal powder in feed coal. Large size coal (+6- 80mm) can be pre-separated effectively, and large size gangue can be removed effectively. Moreover, - 6mm particles fed serve as autogenous medium in FGX. The probable E value is 0.13 for -80 mm raw coal. In ADMFB, magnetic powder with -0.3 + 0.045 mm size fraction and coal powder in feed coal are compound medium solids. The separation density can be adjusted and controlled according to properties of raw coal. -50 + 6 mm raw coal can be cleaned efficiently, the probable E value is 0.05. In VFB, -6 + 1 mm coal can be separated. Generally, -80 mm raw coal can be cleaned efficiently in the united system based on gas-solid two-phase flow.

Jan 1, 2014

By Danilo Zim, Matheus Paschoalino, Denis Guimarães, Jasbir Gill

The shortage of water supply in some regions of the globe is particularly problematic and forces mining companies to adopt alternatives like pumping sea water from the ocean up to the mining sites. Although deaeration of sea water or the use of lined pipelines are known options to prevent corrosion during pumping, a recent development of a new corrosion inhibitor allowed the use of simple mild steel pipelines for this purpose. The objective of this study is to demonstrate the recent advances of this technology in protecting against not only general corrosion but localized corrosion, main cause of corrosion-related pipeline failures. Corrosion studies were carried out using electrochemical techniques, weight loss balance as well microscopy surface analysis in order to measure and therefore evaluate the treatment efficiency. The right dosage of corrosion inhibitors may vary depending on water composition and characteristics of each system. Differences were observed depending on the sea water source. Pretreatment of metallic surface impacts the observed corrosion rate which can be as low as 3.6 mpy. The absence of pitting or localized corrosion was achieved in aerated seawater.

Jan 1, 2014

The flotation efficiency of magnetic concentrate of the Anhui hematite ore, which includes a great quantity of iron-bearing silicates, has been studied through reverse flotation test with a new type of collector Fly-102. The results indicate that collector Fly-102 has a strong adaptability to the variation of temperature, when the flotation temperature is in the range of 10? to 35?, using collector Fly-102 can obtain good flotation indexes. Collector Fly-102 has a strong adaptability to the variation of the slime contents and grades of the flotation samples. When the content of slime and the grade of the flotation feeds are 30% and 55.63% respectively, under the condition that the temperature is 15?, the open circuit flotation test was carried out with collector Fly-102. After one-stage roughing, one-stage cleaning and two-stage scavenging, a better result is got, the grade of iron concentrate reaches 67.12%, and the recovery of iron concentrate comes up to 84.15%.

Sep 1, 2012

By Y. Rama Murthy

Around 90% of the chromite resources of India are concentrated in the Boula-Nuasahi Sukinda belt of Orissa state. In order to conserve these valuable ore resources strategically, several companies established chrome ore beneficiation plants in this region. The general beneficiation process in these plants consists of gravity unit operations such as Floatex density separator, spiral, wet shaking table etc. Most of these gravity circuits suffer huge losses of valuable minerals in the tailing. Any attempt towards decreasing these losses would not only increase the limited reserves in India but also make the economics of the operations more attractive. Apart from the liberation phenomena, in many of the operating plants considerable quantity of values are lost in the tailings, due to inconsistent feed quality, inappropriate selection of operating and design parameters. Mineral engineers in this regard have to play a proactive and continuous role to improve the performance of all separating units by modifying even small changes based on tests conducted in laboratory under controlled conditions followed by attempts to make necessary changes in the plant. For such improvements, accurate data collection and proper data interpretation followed by making necessary change which is implementable in an operating plant play a very critical role in performance of the circuit. Databank collected over a period of time under various conditions would also help in overcoming the future problems related to either variation in the feed characteristics or specific demand by metallurgical industries. The above concept was adopted in one of the operating chromite beneficiation plant at Sukinda. The approach adopted and practical problems encountered during the study were reported in this paper. The result of trial campaign has shown that, an overall product assaying 30.2% Cr2O3 from the feed (18% Cr2O3 ) can be produced to in single stage. The final discards of the process contain 12% Cr2O3. Keywords: chromite, chromite beneficiation, chromite losses, gravity concentration techniques, plant operating data bank

Sep 1, 2012