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By M. Maldonado

This work details the application of a decentralized control strategy to a pilot flotation column working with a two-phase system (water-air). The process is represented by a multivariable system composed of three inputs and three outputs. The selected control variables are the froth depth, the air hold-up and the bias rate, whereas the corresponding manipulated variables are the set-points of the local flow controllers of tailings, air and wash water. All controlled variables are estimated using electrical conductivity based techniques. In particular, the results of a new method for estimating the bias rate, based on the measurement of the volumetric fraction of wash water under the interface, is presented. This method reduces the coupling problem associated to the bias estimation as a difference between feed and tailing water rates. Moreover, the nominal system transfer matrix can be represented by an upper triangular matrix, in such a way that the closed-loop system stability reduces to the stability of the independent control loops. The experimental results show that the closed-loop system performance, particularly that of the bias rate loop, is strongly dependent on the air flow rate, reaching in some cases the saturation point of the controller.

Jan 1, 2007

By Haruka Takeura, Tomoaki Murata, Kazunari Yoshida, Masato Adachi

"Pure magnesium is a material with high functionality, however, the cold drawing of this material is very difficult, that is why, until this day there are no optimal cold drawing conditions. Furthermore, cold drawing of pure magnesium wire shows a problem with internal defects that occurs under certain conditions. In this research, the aim is the suppression of internal defects, and final target is to create the optimal cold drawing conditions for pure magnesium wires. The first step is the investigation of the drawing limit by using 250°Cannealed wire. As a result, reduction of 10% per pass was chosen for stable wire drawing. However, in this case, it was found that internal defects occurred at total reduction of over 45% during drawing. Investigation of intermediate annealing conditions that can suppress internal defects, and influence on internal defect that the die half angle and reduction per pass. As a result, it was found that the drawing condition capable of suppressing internal defects most efficiently was 13% reduction drawing by using under 6°half angle die. Consequently, it’s possible to manufacture a cold fine drawn pure magnesium wire of 100µm, without defects in the center of the wire and hindering its mechanical properties.INTRODUCTIONMagnesium is a light and high functionality material that has high vibration absorbency, heat dissipation, electromagnetic wave-shielding and recycling efficiency (Conruy, 1989). However, proper cold wire drawing conditions haven’t been established, that is why warm or hot processing is commonly used (Oishi, Mori, &Kawabe, 2005). As a result, strength improvement of the wires is not possible, that is why the production of medical tools is disregarded. If it was possible to cold draw magnesium wires, the applications for material products would expand. Further, in wire drawing such difficult processing material, if appropriate processing conditions are not selected, defects will be generated inside the drawn wire."

Jan 1, 2017

By Harvey McLeod

M3 -Technology HOWEVER:In practice we have limitations ?Clients: aggressive or cost based; inexperienced ?Consultants: ?expanding market w/training limitations ?Prescriptive designs ?Lack of senior oversight ?Regulators: difficult to retain technical capacity ?Stakeholders: perceptions and expectations ?Physical settings: challenging terrain, climate, soils/rock Do M3?s Perform? YES?Generally M3?s since mid-1960 do perform ?BC Closed Mines: Afton, Highmont, Trojan, Bethlehem, Cheni, SNIP, NO?ARD/ML issues?e.g. Equity Silver, Samatosum; selenium, cadmium, sulphate

May 1, 2010

By W. H. Gross

To pollute means to make impure or unclean. We tend to forget that man defecates, urinates, sweats, expectorates and exhales and in himself is a beastly little pollutor-but then so is Mother Nature! The object of this paper is to try to put what man and nature do into perspective. The facts indicate that although man may sweat a little, Ms. Nature is by for the greatest pollutor of all.

Jan 1, 1979

By O. Mejia

"As study was undertaken to investigate the relationship between mill liner wear and grinding energy efficiency and to assess the opportunity to control mill speed to improve energy performance as mill liner wears. The study involved analysis of plant operating data and liner wear profiles over time. The operating work index was found to be an effective tool to identify the decrease of grinding efficiency along the liner service. The plant data show that the mill grinding efficiency as determined by monitoring the operating work index, and throughput decreases as liner wears. However, efficiency and throughput can be maintained by either changing the liner more frequently or by increasing the mill speed. Two scenarios for increasing mill throughput were analyzed. The first one involves changing the liner before the efficiency drops and the second one requires increasing the mill speed from 75% to 79%. Both scenarios show financial benefits that can be used in mill operations.INTRODUCTION The analysis of the mill power draw is used in this study as a key parameter for comparing mill liner profile and its effect on mill performance. Current technology and simulation software used in the mining industry do not factor in the impact of liner wear profiles in grinding efficiency and mill throughput (Toor, 2013). To address this gap, this study provides an analysis of key factors affecting mill throughput and grinding efficiency: mill speed, ball loading, and liner profiles. Several years of plant mill operating data, published research papers, and MillTraj® simulation results are used to demonstrate that face angles impact grinding efficiency and throughput and that mill speed can be used to overcome this problem. Moreover, the liner profile wear analyses clarify a mismatch between actual and estimated power draw calculations."

Jan 1, 2019

By R. Bainbridge

"IntroductionTHE LEAD SMELTING Department of The Consolidated Mining •and Smelting Company of Canada, Limited (Cominco), at Trail, B.C. treats materials from numerous sources for the recovery of lead, •and, of secondary importance, for the .recovery of sulphur as S02• The Department's sintering section has a .capacity of 1,500 tons daily. This section is being replaced by •a new charge-•handling and sintering plant with a daily capacity of 2,000 tons of finished sinter. Materials handled in the sintering section comprise concentrates, ores, and fluxes from Company mines and from 'custom' (independent) producers, together with intermediate products from various plants of Cominco'•s Metallurgical Division, all of which must be treated to, make up a chemically balanced charge of a predetermined lead content for the sintering plant.As received, 80 •per .cent of these materials are finer than 200 mesh, and one-quarter of the tonnage (dry basis) is a slurry .at 30 to 40 per cent moisture. This slurry, a -residue from the electrolytic zinc operation, was, for many years, partially dried before being mixed with other dry materials to make up the sinterplant charge.Some experimental work carried out in 1937 indicated that the metallurgy of the sintering operation could be improved by adopting a technique of 'wet-mixing' followed by controlled drying and nodulizing."

Jan 1, 1953

By Joël P. T. Kapusta

Back in 1995, Air Liquide and Union Minière presented a joint paper at the Copper 95 – Cobre 95 Conference in Santiago, Chile, describing the first full scale plant trials of shrouded sonic injection in a Hoboken converter at the Hoboken smelter in Belgium. Almost a quarter of a century later, the technology known as ALSI, or Air Liquide Shrouded Injection, has been tested or commercially implemented in several copper and nickel smelters. Despite these successes, the copper industry did not adopt it widely in the same manner the steel industry adopted the Savard-Lee tuyere in the 1970s and beyond, not even in the way the lead industry adopted it with the Queneau-Schuhmann-Lurgi, or QSL, process. The development and implementation of bottom-blowing smelting and converting technologies in China in the last ten years, however, changed the industry’s perception that high- and ultra-high oxygen injection in copper smelting and converting was indeed possible under specific process conditions. In this paper, I retrace the key learnings of my journey with sonic injection over the twenty five years from my humble beginnings in my early years with Air Liquide, through plant trials and technology implementation in the late 1990s and into the first decade of the new millennium, and ultimately, to the most conclusive proof that the sonic injection design methodology I established is valid, and the calculation tools I developed are accurate. I conclude by sharing my thoughts about whether the deployment of the Savard and Lee legacy within the nonferrous industry was just a pipe dream or whether it will become a reality. INTRODUCTION In the context of lower quality ores and changing economic markets, copper smelters need to continuously innovate and improve to remain competitive and respect their corporate social responsibility engagements. One avenue towards this business, social, and environmental goal is to increase process intensity while lowering fossil fuel consumption to lower greenhouse gas emissions and reducing process off-gas volumes to better capture As and SO2–laden emissions. I believe high oxygen sonic injection for submerged tuyere copper bath smelting and converting is one technology that can help smelters achieve that goal of higher business, social, and environmental performance. Twenty five years ago, when I discovered that the Savard-Lee tuyere had revolutionized the steel industry (Savard & Lee, 1966; Knuppel, Brotzmann, Fassbieder, Savard, & Lee, 1972), I had a dream — or was it a vision? — that within the first decade of the new millennium, modern copper smelters operating submerged tuyere bath smelting and converting vessels will have implemented high oxygen sonic injection and will be reaping the financial and environmental benefits that the steel industry enjoyed in the 1970s. As we approach the end of the second decade of the new millennium, I have to admit that my dream has been all but shattered as the majority of copper bath smelting and converting vessels today continue to operate under bubbling regime conditions. This mode of operation is archaic, still requires tuyere punching and blows at inherently low enrichment levels, particularly in converting, producing large volumes of process off-gases. Under such operating conditions, regulations and emission quotas for As, SO2, and particulate matter oblige smelters to use not just primary or secondary hoods, but sometimes even tertiary hoods. I vividly recall being told, fifteen or twenty years ago when visiting smelters to promote the application of the Savard-Lee tuyere in nonferrous processes, that implementing sonic injection was not economically viable due to the high cost of compressing air and oxygen. Some of the smelters I visited back then have since mandated their engineering partners to design and build secondary or even tertiary hoods. I cannot fathom how secondary and particularly tertiary hoods, with all of their auxiliary equipment and added ducting, could be more economically viable than purchasing and installing a few compressors, expanding the pipeline network for compressed air and oxygen, and installing a new control valve train to feed sonic tuyeres. Besides, adding hoods does not address the problem of As and SO2-laden fugitive emissions at its source but merely provides a costly mitigation for it by capturing larger volumes of process off-gases rather than reducing these large volumes in the first place. Moreover, hooding does not reduce energy consumption nor does it increase process intensity, two aspects that I believe are critical for smelters to remain competitive and sustainable in a deeply changing market environment.

Jan 1, 2019

By N. Manopulo, J. Maier, L. Tong, C. Becker, P. Hora

The contribution presents a new finite element approach in which the common updated Lagrangian formulation is replaced by a spatial flow formulation applying a special arbitrary Lagrangian-Eulerian for-mulation (ALE). The description separates spatially the process in a die inside zone and in a profile zone. For the description of the inside zone, where the filling process occurs, a special Euler time independent mesh is applied. By this formulation the mesh has to be generated only once, which simplifies the generation of spatially optimized meshes. For mapping of the material flow during the filling process the method uses a flow surface traction method as applied in casting simulations. A further strength of the new method is the computational efficiency which allows the modelling of extrusion process with the highest complexity with a response time of 12 hours, which is important for the industrial optimization process.

Jan 1, 2015

By M. M. C Jiménez, J. A. S Ténorio

For the recovery of valuable materials and for the protection of environment, recycling process of printed circuit board is an important subject of study. Moreover, the popularization of the computers and its technological evolution has generated a large number of waste electrical and electronic equipment. This paper presents a study of synergistic solvent extraction of copper, nickel and zinc from a sulfuric leaching liquor of printed circuit boards (PCB’s). The percent extraction of copper, nickel and zinc from dilute aqueous sulfate media besides synergistic effect of mixture of the .extractants Cyanex 272 and D2EHPA have been studied. Furthermore, different conditions such as temperature, pH of the feed solution have been examined. The results suggest that the synergistic effect of the .extractants mixture enhance the extraction efficiency of nickel.

Jan 1, 2014

By Yongjie Bu, Wei Sun, Zhiyong Gao, Yuehua Hu, Hongbiao Tao, Runqing Liu, Central South University

"The flotation behavior of O-isopropyl-N-ethyl thionocarbamate (IPETC) and pH for chalcopyrite and galena was studied through pure mineral test, adsorption quantity determination, solution chemistry calculation and Materials Studio simulation. The results show that the recovery differential value of chalcopyrite and galena is about 20% when pH of the pulp 9.5 and IPETC is 7×10-4 mol/L, the flotability differences of the two minerals is significant. There is competitive adsorption between OH? and IPETC on mineral surfaces, it lead to galena flotability is lower than chalcopyrite flotability. IPETC can remove the hydration layer on mineral surface and adsorb on active sites for collector adsorption, minerals have a better hydrophobicity.INTRODUCTIONCopper and lead are two of the most widely used metals in industrial and living, their applications include building construction, various metal alloys, heat and electricity, machine manufacturing (Zhang et al., 2014). Chalcopyrite and galena are the major source of copper and lead, normally they associated with each other. With the growing use of these resources, high grade and dissemination large particle sizes minerals are less and less, the use of low grade and complex dissemination minerals have to be paid more attention (Chen, Ye, & Li, 2010; Liu, Sun, Hu, & Wang, 2009). As the special properties and complex composition of copper-lead sulfide ore, flotation separation of chalcopyrite from galena effective is a research emphasis and difficulty point in mineral processing (Bruckard, Sparrow, & Woodcock, 2011).In the separation process of chalcopyrite and galena, it is rather important to choose effective collector (Huang, Wang, & Liu, 2014). Enlarging and using the two mineral flotability will be a good basis and start in flotation (Reyes-Bozo et al., 2014). Qin et al. (2013) made a great deal of research on flotation separation of copper/lead concentrate, collector O-isopropyl-N-ethyl thionocarbamate (IPETC), butyl xanthate (BX) and ammonium dibutyl dithiophosphate (ADTP) were investigated, BX and ADTP floated both chalcopyrite and galena well, specific adsorption appeared in the surface of mineral, the problem was the collectors were not selective enough, however IPETC showed better selective."

Jan 1, 2016

By M. Dupuis, V. Bojarevics

It is well known that horizontal current density in the metal pad contributes greatly to the generation of MHD driven bath-metal interface wave. It is possible to compute very accurately the metal pad current density using a very detailed finite element model [1], but a MHD model must be compatible to this level of mesh refinement and to recalculate the current distribution at each time step, including the full busbar supply system. The accuracy of the instability prediction of the cell depends on the accuracy of the metal pad current density calculation. This study presents the comparison of the metal pad current density calculation of the detailed finite element model and the MHD-Valdis model for different metal pad heights and ledge thickness. It also presents the corresponding cell MHD stability predictions.

Jan 1, 2006

By Mike Robotham

Drum hoists in the 21st century have the same fundamental objective as their earliest 19th century counterpart. And yet a lot has changed in the design of the hoist from those early days of underground mining. These changes are driven by the need for greater productivity and reliability at ever increasing depths without compromising the all important safety demanded by the industry today. This paper reflects on how these changes have influenced design of a modern hoist Director of Engineering, Mike Robotham is a chartered engineer and has been with DavyMarkham for over 30 years. Having completed a craft apprenticeship he later joined the engineering department as a junior engineer. He has a wealth of experience of working on medium to large engineering projects in the field of mechanical, electrical and hydraulic equipment

May 1, 2013

By R. B. Nourse, S. F. Gwynn-Jones, S. Nikolic, M. L. Bakker, I. McDougall, H. Joubert

"Tenova Pyromet’s core furnace knowhow and expertise has been built within the ferroalloy and nickel/platinum group metal (PGM) industries with the supply of electric furnaces for a number of nickel/PGM operators, including Eastplats, Lonmin, and Anglo-Platinum in South Africa, Mineraçào Serra Da Fortaleza in Brazil, and Norilsk Nickel in Russia. Tenova Pyromet has also supplied the electrode columns and associated electrode equipment – the heart of the electric furnace technology – for cobalt recovery in furnaces in Zambia and the Democratic Republic of the Congo. The quantity and size of projects undertaken by Tenova Pyromet has provided the opportunity to continuously improve furnace designs and the scope of supply, culminating in the most recent nickel/PGM project currently under construction at Northam Platinum. Through this innovative culture, the Tenova Pyromet Base Metals Initiative was formed in 2015 to develop the Novasmelt™ Furnace; a next generation optimised Top Submerged Lance (TSL) furnace design. The combination of Tenova Pyromet’s advanced Novasmelt™ product with our industry leading electric furnace technology are discussed with reference to applications for nickel and cobalt production. Flowsheet arrangements are compared summarising potential capital savings, operating requirements and achievement of downstream product quality.INTRODUCTION Tenova Pyromet is a leading player in the field of smelting technology development and equipment supply. Tenova Pyromet is the result of the union of three furnace suppliers under the Tenova banner: Techint Technologies (Tagliaferri), Core Furnace Systems Corp (Lectromelt) and Pyromet Technologies. The furnace experience of the combined groups dates back over a century with the earliest Lectromelt going into production in the early 1900s. Throughout the modern era, Tenova Pyromet has developed a reputation for providing dependable innovative smelting technology, high quality equipment and sound project execution to a worldwide client base with customer plants operating in Europe, Southern Africa, North America, South America, Russia, Kazakhstan, the Middle East, South Korea, and India. Tenova Pyromet’s core knowledge and expertise was developed in the South African ferroalloy, base metals, and platinum group metals (PGM) smelting industries. Tenova Pyromet has spent considerable effort on development and has contributed significantly to improve the state of the smelting industry. Tenova Pyromet’s electrode columns have become widely renowned and are now providing significant benefits, especially in increased furnace availability, to many smelting furnace operators. The electrode column is the heart of the furnace as it delivers a controlled amount of electrical energy, at an optimum depth in the burden/bath, to the smelting process. Every furnace is custom designed to the specific operating range and optimal operating point of that furnace and process"

Jan 1, 2017

By Kaiwen Xia, Bibhu Mohanty, Per Svedensten, Sheng Huang

"The mechanics of crushing and grinding operations in mining and excavation processes has been investigated in a laboratory simulation study. It employs a multi-particle bedded rock target, which is subjected to multiple impacts. The impact set-up consists of a Hopkinson pressure bar and a Piston-holder system. The apparatus, employing a 38 mm diameter pressure bar, was used to apply varying but calibrated dynamic loading force on the rock particles. The energy consumed by the sample during fragmentation was determined by considering the energy carried by the incident wave and the reflected wave. The Pistonholder system is used to hold rock samples and to recycle fragments after each test for particle size analysis, for single as well as multiple impacts. The feed size selected was in the range of 9.5 to 12.7 mm for all rock samples, and the impact velocity was set at 14 m/s. Two strong granitic rocks and a relatively weak limestone were the target rocks. The resulting particle size distribution after each set of impacts, ranging from single to 10 consecutive impacts, were analyzed, and various size distribution functions (i.e. Rosin- Rammler, Swebrec, Grady and Gilvarry functions) were fitted to compare their suitability in predicting the fragment size distribution for each rock type. INTRODUCTIONCrushers are widely used in the mining industry all over the world. Understanding fragmentation behaviour of rock under crushing process is fundamental to improved productivity and efficiency in mining operations. This is particularly so as all subsequent size reduction processes such as crushing and grinding are far more energy intensive than the initial blasting process employed in breaking of in situ rock. A considerable body of experimental studies exists on the behaviour of rock crushers for specific rock types in order to aid in the design of various types of crushers. However, these studies are mainly site specific, that is, the results are largely empirical, and the fundamentals of fracture process that lead to size reduction have not been dealt with adequately. Most such studies have attempted to link the input parameters, such as feed size and crusher parameters, with output particle size, and global energy expended in the process. However the physical mechanism of crushing process is still not well understood. First of all, the energy consumed by the rock sample is hard to calculate during standard crushing or grinding tests; secondly, multi-particle test is hard to perform in the laboratory due to irregular shape of the subject rock sample. In This paper, describes a laboratory crushing apparatus for multi-particle rock samples, with sufficient control of the energy expended in the process, with a view to relate creation of new fracture surfaces in the size reduction process."

Jan 1, 2015

By H. Kudelka

Copper electrowinning at Duisburger Kupferhuette was introduced in March 1975. The electrowinning plant has a capacity of 10,000 mT of copper cathodes a year. The cuprous oxide feed material is an intermediate product of the treatment of the leach solutions, originating from chloridizing roasting of pyrite cinders. This material is characterized not only by a wide spectrum of accompanying impurities, but also by an unusually high level of precious metals. As the priority set was the production of high-purity cathodes. there was a need for developing a process which would be suited to treat complex leach liquors . The process adopted consist s of an oxidizing leach in spent electrolyte, followed by two- stage purification, By this means. a low- acid pregnant copper electrolyte is obtained free of elements detrimental to copper quality. Electrowinning is carried out at a current density of 200 A / m2 in the presence of 10 g/l zinc. The electrowon copper has a conductivity of at least 101.4% lACS and a softening temperature not exceeding 200°C, which makes it a suitable product for continuous casting and dip ?forming.

Jan 1, 1977

By V. G. Papangelakis, S. Peters

Pressure oxidation of refractory gold ores can be conducted on ores with high carbonate content using just water or water with alkaline reagents to promote fast kinetics, and suppress the formation of elemental sulphur and CO2. In this work, a fundamental study was conducted to explore the silica-pyrite interaction in the presence of calcium and sodium carbonate. It was found that an alkaline environment increases the pyrite decomposition kinetics on one hand, but on the other dissolves silica, which encapsulates the dissolving pyrite thus hindering ultimately its complete decomposition.

Jan 1, 2011

By The Hollinger Mill Staff

MR. E. L. Longmore (l), in presenting this paper at the Annual General Meeting, suggested that it was neither desirable nor necessary to read any but the briefest portion of the paper. He wished to emphasize that the scale of the milling operations at the Hollinger not only provided several units in continuous operation to ensure that the test work was being carried on under normal conditions, but also provided a large and competent staff to supervise such an extensive experiment and to criticize intelligently the recorded results. He wished to acknowledge the enthusiastic co-operation of the group of assistants whose excellent work was responsible for the confidence with which the conclusions could be presented. The following data were given as a supplement to the published paper. Following conclusion of the test work described in the paper, the size of the balls fed to the mill was changed from 3-in. diameter to 2Yz-in. Within a short time, a gradual rise in the tonnage rate took place and, as no other condition had been changed, the increased tonnage was credited to the changed character of the ball load. At present, the average daily tonnage for the mill with low discharge is 1,507 tons, an increase of 77 tons over the 1,430 tons ground when feeding a 3-in. ball. A similar increase in tonnage should be credited to the high-discharge test, if the 2;Y2-in. ball had been used at that time. This would raise the 1,117 tons ground at that time to a new figure of 1,177 tons. From a study made to determine those factors influencing the rate of pulp flow through the low-discharge mill, it became evident that the ball screen used on the high-discharge mill must have been restricting the flow through the mill, although this was not recognized at the time. Accord-ingly, it was decided to repeat the high-discharge run. Additional length was added to the 21-in. ring grizzly originally used, and the length of the reverse spiral was increased. The end of the grizzly was left open so that, if necessary, excess pulp might flow out. A coarse mesh 3 ft. by 3 ft. flat screen was provided to catch stray balls.

Jan 1, 1937

By Andre Panteleyev, Charels S. Ney, John M. Anderson

"Sam Goosly prospect, 22 miles southeast of Houston, B.C., was discovered in 1967 through geochemical reconnaissance. Soil sampling interpreted with respect to an east-to-west ice movement led to drilling targets.Mineralization is in a window of rocks thought to be Hazelton Group surrounded by Tertiary volcanic rocks and intruded by two stocks separated by about one mile. A westerly quartz monzonite stock is dated 61.1 m.y. and an easterly gabbro-monzonite complex is dated 52.5 m.y. The Tertiary volcanics are trachyandesites shown by the B.C. Department of Mines and Petroleum Resources to be in part extrusive equivalents of the gabbro, and they overlie Hazelton rocks uncomformably. Copper-molybdenum mineralization is sparsely developed in the westerly stock. Silver-copper mineralization forms an elongate west-dipping slab between the stocks in Hazelton rocks, which are continuously pyritized. The gabbro stock is not mineralized, but some dikes related to it are slightly so. Tertiary rocks are pyritized, but are not known to carry copper-silver mineralization. Hazelton rocks are divided into a lower conglomerate, an intermediate pyroclastic unit and an upper mainly sedimentary unit. They form a west-facing homocline. Coppersilver mineralization resides in the pyroclastic unit, mainly in a massive dust tuff through which are lenticular units of lapilli tuff. Well-mineralized rock is typically a breccia of light fragments in a dark chlorite-sulphide matrix. Sulphides are pyrite, chakopyrite and locally pyrrhotite, with very minor tetrahedrite, s phalerite and other sulphosalts. Rock alteration is predominantly a pervasive pyrite-sericite type, with widespread tourmaline, scorzalite, gypsum, ankerite and traces of fluorite. The most evident control of the copper-silver mineralization is the gross parallelism, over a strike length of 1.5 miles, to Hazelton strata, particularly a massive dust .tuff unit. In detail, mineralization crosscuts bedding and there is no appreciable banding within sulphides . A strictly syngenetic origin is untenable, but some initial concentration in a volcanogenic environment with subsequent modification by thermal processes seems likely."

Jan 1, 1972

By V. G. Papangelakis, G. A. Moldoveanu

"Rare earths adsorbed on clay minerals are easily recovered via ion exchange during leaching with inorganic monovalent salt solutions. The leaching efficiency of various salts at 0.5M and 25°C was investigated as a function of cation type and salt system (sulphates vs. chlorides). (NH4)2SO4 was identified as the lixiviant of choice and a procedure was established to investigate the influence of lixiviant concentration, temperature, pH and agitation on desorption kinetics and REE extraction levels. It was determined that the kinetics were fast and the optimum leaching conditions (for >80% total REE extraction) required pH below 5 and moderate temperatures (<50°C). INTRODUCTIONRare earth elements (REE) are at the core of numerous advanced applications due to their various uses in high strength permanent magnets, lasers, automotive catalytic converters, fiber optics/superconductors, and electronic devices (as phosphors in TVs and display screens for computers and cell phones). Because of the ongoing development of new technologies, there is an increased demand for REE in the international market, with emphasis on identifying new resources to insure an adequate supply for present and future use. World production of rare earths is dominated by China, the United States and Australia; however, in terms of resources, China dominates the world potential with reserves estimated to be over 90% of the total (Chen, 2011).The main commercially significant REE sources, as reviewed by O’Driscoll (1991) are bastnasite (carbonate) and monazite (phosphate) minerals, containing up to 70% wt. rare earth oxides (REO). In spite of being high grade, these ores are associated with elevated recovery costs due to difficulty in mining, separation and beneficiation. Moreover, aggressive conditions are required to solubilize the REE from the mineral, such as leaching with hot, concentrated acids or baking in 70% NaOH (Gupta & Krishnamurti, 2005)."

Jan 1, 2012

By S. Khoshkhooei

In this research, the effects of rare earth elements addition on thermal fatigue behaviors of AZ91 alloy were studied. Repeated heating and cooling cycles were applied on the samples at 170°C and 210 °C to develop thermal fatigue cracks, Crack growth mechanisms and microstructural influences were investigated by optical and scanning electron microscopy (SEM) as well as energy dispersive X-ray spectroscopy (EDS), Thermal fatigue behaviors were improved successively by addition of up to 2-wt% RE, This improvement is attributed to consummation of the aluminum of the melt by precipitation of the needle shape Al 11 RE3 phases, This process reduces the volume of Mg17Al12 phases and consequently decreases the brittle Mg/Mg17Al12 interfaces which are the main reason of weak thermal properties of the alloy at rather high temperatures, Further additions of RE, however, reduced the thermal shock resistance of samples by increasing in the mean length of the brittle needle shape phases.

Jan 1, 2005