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By M. Ng

As part of a long-term study of titanium minerals processing being undertaken by the Julius Kruttschnitt Mineral Research Centre, techniques have been developed to measure the resistivity of ilmenite, rutile, zircon and other associated minerals. The techniques have proven reproducible and have allowed the measurement of resistivity under conditions of varying temperature, surface condition and surface moisture adsorption. The measured values can be linked to the separability of the minerals in the dry plant, and hence are useful as a diagnostic test for existing plants when performance deteriorates, or for greenfield sites to investigate potential problems. One of the major problems in electrical separation of titanium minerals is surface coating on the mineral grains. Coatings can make normally conductive minerals such as ilmenite and leucoxene behave much more like non-conductors. Electrical separation of surface contaminated ilmenite from non-conductors then becomes extremely difficult unless the surface contaminant is first removed. The resistivity measurement technique was used to evaluate the effect of surface cleaning on the resistivity of ilmenite and zircon from a Western Australian deposit which will shortly be in production. Ten different attritioning methods were evaluated, ranging from simple rinsing inwater to chemical attritioning in sulphuric acid combined with ultrasonic leaching. A roasting and quenching step was also investigated. As would be expected, the gentler treatments, such as rinsing in water or Calgon, had only amoderate effect on the ilmenite surface coatings. Ilmenite resistivity decreased by about 1 order of magnitude from 5.6 x108?m to between 2.5 and 4.4 x107?m. More intense treatments had a much more pronounced effect. The most effective, reduced ilmenite resistivity to 6.5 x105?m or three orders of magnitude. Zircon was relatively unaffected by any of the attritioning methods, with only a small increase in resistivity observed from 8.0 x1012?m to 2 x1013 ?m. The results show that measurement of mineral resistivity allows the effect of surface treatments to be easily quantified in a way that has benefits for greenfield site development where only small samples are available for testing. The effect of surface moisture has also been investigated using resistivity measurements. Measurements were made on zircon in an environmental chamber in which both humidity and temperature could be closely controlled. Zircon resistivity at 60 deg C decreased from 6 x1011?m at 5% relative humidity to 8 x108?m at 95% humidity. Moisture content and moisture re-adsorption from dry of zircon and number of other minerals were measured using a Mettler moisture analyser. Zircon adsorbed the least amount of surface moisture (0.05–0.09%) but re-adsorbed moisture from dry the fastest, reaching 98% of the original level in 10 minutes. Leucoxene adsorbed the most moisture (0.67%), but was much slower re-adsorbing this moisture from the dry state, reaching only 63% of the original level in 10 minutes. The difference was attributed to the surface characteristics of the grains, the leucoxene being much more porous than the zircon examined. The resistivities and differing rates of moisture adsorption can be used to quantify the effects of changes in atmospheric conditions of the performance of electrical separation in dry plants.

Jan 1, 2003

By Kerry Gee, Gary Colgan, James Fricke

Introduction Elevated zinc concentrations are observed in groundwater within alluvium adjacent to Silver Creek east of Park City, Utah. The study area is located in a small valley one and one-half miles northeast of Park City, Utah in Summit County, Utah (Figure 1). Although surface water concentrations in Silver Creek are typically less than 1 mg/l, groundwater concentrations have been measured as high as 85 mg/l in a near neutral pH environment. The elevated zinc concentrations in groundwater result from several factors including: (1) dissolution of zinc from tailings exposed at the surface and within the alluvium, (2) oxidizing conditions created by surface/ground-water exchange, and (3) ideal geochemical conditions for the dissolution of zinc-containing minerals. These ideal conditions include readily soluble minerals, available anions for complexation, and lack of available surface adsorption sites.

Jan 1, 2005

By Ann G. Kim

Studies on the initiation and propagation of mine fires have dealt almost exclusively with coal. It has been assumed that the self-heating potential of carbonaceous shales and coal wastes is relatively low. However, in abandoned coal mines and waste banks, initiation and propagation of fires may be strongly dependent on the self-heating tendency of these materials. The purpose of this study was to compare the self-heating probability of carbonaceous shales and coal wastes to that of coals. This study utilized a modified differential thermal analysis method, in which the combustion furnace temperature was the reference to which the sample temperature was compared. Based on the distribution of the maximum temperature differential and the sample heating rate, a self-heating probability value (SHPV) was calculated that corresponded to observed self-heating behavior. In this study, several of the carbonaceous shales and one coal waste had relatively high SHPV. The SHPV did not correspond directly to heating values or to differences in sulfur concentration.

Jan 1, 2010

By B Prasad, M P. Roy, P K. Singh, C Drebenstedt

Blasting operations play a pivotal role in the overall economics of opencast mines. The blasting subsystem affects all the other associated subsystems, ie loading, transport, crushing and milling operations. Fragmentation control through effective blast design and its effect on productivity is a challenging job for the practicing blasting engineer due to inadequate knowledge of actual explosive energy released in the borehole, effect of varying initiation practice in blast design and its effect on explosive energy release characteristic. This paper describes the result of a systematic study on the impact of blast design parameters on rock fragmentation at two mines in India. Both the mines use draglines and shovel-dumper combination for removal of overburden. Despite its pivotal role in controlling the overall economics of a mining operation, the expected blasting performance is often judged almost exclusively on the basis of poorly defined parameters such as powder factor and is often qualitative, which results in a very subjective assessment of blasting performance. Such an approach is a very poor substitute for accurate assessment of explosive and blasting performance. Forty-seven blasts were conducted with varying blast designs and charging patterns and their impact on the rock fragmentation are documented. A high-speed camera was deployed to record the detonation sequences of the blasts. The efficiency of the loading machines was also correlated with the mean fragment size obtained from the fragmentation analyses.CITATION:Singh, P K, Roy, M P, Drebenstedt, C and Prasad, B, 2015. Blast design parameters and their impact on rock fragmentation, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 755–762 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By W. R. Hardwick

This paper describing the mining methods of the Inspiration Consolidated Copper Co. is one of a series being prepared by the Bureau of Mines on mining methods and costs in various mining districts of the United States. The story of mining at Inspiration is of particular interest because, after 127,812,000 tons of low-grade copper ore were successfully mined, the mining method was changed from block caving to open-pit. As the open pit became deeper, many features of the former block-caving operation that were exposed elucidated concepts of the mechanics of caving that previously had been assumed but not observed. The conversion to open-pit mining was accomplished by unique combinations of equipment and the introduction of ingenious engineering and operating practices that have extended the expected life of the mine for many years.

Jan 1, 1963

By S. Mafi

The Broken Aro project is associated with a 1910 abandoned underground mine complex that has been discharging aeid mine drainage from entries, seeps and springs. The Ohio Department of Natural Resources(ODNR), R&F Coal Company (R&F) and American Electric Power (AEP) are involved with this unique project that will remine the abandoned underground complex and install a mine seal constructed of fixated flue gas desulfurization (FGD) material. The goal of the project is to eliminate or reduce the acid mine drainage that is discharging into the watershed. This paper discusses remining, installation of the FGD mine seal, government financed reclamation projects and future application to active and abandoned mining sites.

Jan 1, 1998

By J. B. Zadra

Much has been published by various investigators on the use of activated carbon for adsorbing precious metals from cyanide solution and pulp. For the benefit of the reader, a list of these earlier publications appears at the end of this report. The present paper deals only with a process for extracting gold from gold-laden carbon and re-use of the de-adsorbed carbon. At the Getchell mine, Redhouse, Nev., experiments have been in progress for several years concerning the use of activated carbon to adsorb gold from their slime circuit pulp. The experimental work has been successful. Their practice has been to ship the gold-laden carbon to a smelter for treatment, which meant the total loss of the carbon in addition to smelter and freight, charges, all of which proved costly and wasteful.

Jan 1, 1950

By Alex Chapman, Cam Thomas, Bryan Karney

"During the early summer of 1989, Ontario Hydro removed a concrete portion of the North Channel Dam at Crystal Falls Generating Station by blasting and excavating in marine conditions. Because of the severity of underwater blasting and because the site was in close proximity to the replacement dam, there was concern that hydraulic shock waves generated by the detonation could damage either the new dam or its control structures. This paper examines the data associated with the hydraulic shock waves generated by underwater blasting, and studies the effectiveness of an air curtain in reducing the peak pressures. In previous trials using the air curtain technique, a rule-of-thumb factor was used to estimate that only 10% of the original pressure pulse would propagate across the air curtain. However, this value had little basis in theory. A theoretical formulation of the problem by Karney in 1989 indicated a provisional value of 0.18 for this factor, but was heavily dependent on confirmation from in-field testing. Data provided by Ontario Hydro from an actual blasting procedure indicate that a more conservative value of 0.32 may be more appropriate. Thus.although the air curtain did provide considerable reduction of peak pressures, the data at Crystal Falls indicates its performance was below the anticipated level. However, due to problems with the instrumentation and some inconsistencies in the resulting data. it is recommended that this value be further refined as additional data become available."

Jan 1, 1992

By Gerke Gilian, Pretz Thomas, Pehlken Alexandra

"The evaluation of health hazards within the treatment of mineral and waste materials is gaining more and more importance in industrial countries. The need to control occupational safety has been recognised, and regulations which describe general protective measurements for personnel provide a tool to protect their health. It is the aim of the paper to give an outlook for practical approaches to risk assessment and to present measures for exposure reduction in accordance with the state of the art in Germany.Both the treatment of minerals and of waste materials are described in relation to the risk assessment. The method of evaluating health hazards in the two industries is similar and therefore both examples are presented next to each other.The example presented in the paper is the German “Biostoffverordnung” (the regulation for biological materials) which is important for the waste treatment industry. All kinds of waste treatment facilities (like composting facilities, waste dumps, sorting facilities for packaging materials) are obliged to carry out an assessment of health hazards for a variety of working areas and working places. The possible safety requirements deriving from this regulation are presented and discussed under the aspect of biological hazards.All over the world each country has different guidelines and regulations but all have one target in common – to protect the employees. This can be achieved through a good management system of occupational health and safety. Therefore the health hazards have to be known and assessed.Principles of the assessment of health hazards are described through:Data collection on siteData evaluationAssessment of health hazardsDocumentation"

Jan 1, 2003

By Keith A. Heasley

The LaModel program has been used successfully in the United States for many years to design pillars to ensure global stability of pillar recovery operations. However, the recent Crandall Canyon Mine collapse showed that further research was required to improve the design of pillar recovery under deep cover. Toward this end, a new calibration procedure was implemented in LaModel. This calibration procedure prescribes techniques for calibrating the critical LaModel input parameters based on empirical abutment loading and pillar strength, as utilized in the time-tested ALPS and ARMPS programs. The calibration procedure is intended to help guide a novice modeler in choosing calibrated input parameters that produce a standard model that fits within the verification database. However, the rigid parameter specification incorporated in the calibration procedure also removes most of the flexibility in LaModel for specific calibration to the unique conditions at a given mine site. In this paper, a number of the LaModel input parameters are varied outside the bounds of the suggested calibration and the effects on the model results are analyzed. Ultimately, it is shown how the LaModel user might vary certain input parameters to adjust the model to site-specific conditions, while still maintaining the general accuracy and philosophy of the recommended calibration.

Jan 1, 2012

By G. Azimi, K. K. Varanasi1, A. T. Paxson, R. Dhiman, H. -M. Kwon

Hydrophobic materials that are robust to harsh environments are needed in a broad range of applications. Although durable materials such as metals and ceramics, which are generally hydrophilic, can be rendered hydrophobic by polymeric modifiers, these materials deteriorate in harsh environments. Here it is shown that a class of ceramics comprising the entire lanthanide oxide series, ranging from ceria to lutecia, is intrinsically hydrophobic. Their hydrophobicity is attributed to their unique electronic structure, which inhibits hydrogen bonding with interfacial water molecules. In addition, this work demonstrates that these ceramics sustain hydrophobicity even after exposure to high-temperature environment (1000 °C for 2 h in air). It is envisioned that this class of robust hydrophobic materials will have far-reaching technological potential in various industrial applications, where water repellency and dropwise condensation are desirable.

Jan 1, 2014

By William H. Lewis

Energy Research Corp., under contract to the Bureau of Mines, has developed a new miners' caplamp battery. The new battery is based on nickel-cadmium technology and offers significant improvements in performance with reduced size and weight when compared to the conventional lead-acid battery presently in use. This report describes the design and fabrication of the nickel-cadmium battery, which utilizes a roll-bonded electrode structure. The final battery design has a 15-A-h capacity in a 2-112-lb package, which is over 2 lb lighter than the present lead-acid caplamp battery.

Jan 1, 1983

By P. R. Jones

The Bureau of Mines has written a computer program for the design and cost of a shell and tube type heat exchanger, in which a change in phase occurs on the shell side. The total cost, which was minimized, includes the annual fixed charges and annual operating costs. The program was written to meet the following requirements: (1) Triangular pitch, (2) single or multiple pass, and (3) heating or cooling. Price optimum design was obtained for four standard tube diameters and pitch. Standard heat exchangers whose area equaled or exceeded the required area are also listed. The program was made adaptable to various fluids and to various tube dimensions by including many of the required data such as physical properties of the fluids, tube data, and standard shell data as input data.

Jan 1, 1969

By Robert A. Cummings

A rock mass classification system has been developed for support estimation in mines using caving methods. The developed system (MBR System) accepts readily-obtainable geotechnical properties, and mining geometry, to develop a rating that permits recommendations for drift support in block caving mines. The data base includes major active United States caving mines. The method is intended to be used for planning and estimating purposes and for preliminary support design. The Manual explains the organization and nature of the MBR System, its derivations, details of required input data, methods for assessing the data and for developing rock mass ratings, and techniques for selecting the most appropriate mine support recognizing mine requirements and desired stability. A worked example is provided.

Jan 1, 1984

This Information Circular describes the Bureau of Mines Minerals Availability System (MAS), presents the Resource Classification Manual used for information input to a computer file, and discusses the methods of collecting and assembling background material' basic to coding the data.

Jan 1, 1974

By Eric Konigsmann

"The Pogo project is located on the Goodpaster River, 38 miles north of Delta Junction in east central Alaska. Sumitomo Metal Mining and Teck Corporation are planning to develop a 2,500 ton per day underground mine and mill at Pogo. A preliminary resource of 5.5 million ounces of gold has been identified in two flat lying lenses. An underground adit has been developed to facilitate underground drilling of the deposit and to provide samples for bench and pilot scale metallurgical testwork.Flowsheet development included the evaluation of several processing options. The final flowsheet selected includes SAGhall mill grinding, gravity concentration with intensive cyanidation and direct electrowinning, sulfide flotation with ultrafine regrinding, and cyanide leaching and CIP gold recovery from the flotation concentrates. Flotation tailings will be filtered for placement in a dry stack storage facility or disposed of as paste backfill underground. All of the CIP tailings will be disposed of underground as paste backfill. A pilot plant was carried out to evaluate the proposed flowsheet described above and to confirm the gravity recovery predictions.Great care was taken in the development of the flowsheet and site layout concepts to mitigate the environmental impact of the proposed operation. An overview of the site water management concepts is presented and the impact of water issues on the process flowsheet is discussed."

Jan 1, 2002

By Derek Ettie

"In the Hydrometallurgical processes, the presence of the so-called "crud" is a constant challenge in solvent extraction. Crud is a stable emulsion which forms along the interface between the aqueous and organic phase. The spread is influenced by the following parameters: first, wind blows the dust and impurities into the open sedimentation tanks. Second, the undissolved solids such as sand transported in the PLS causing problems in conjunction with incorrect agitator design.The crud fraction can decisively impact the efficiency of the hydrometallurgical extraction because the phase interface can constitute a large fraction and the sedimentation tanks cannot react flexibly to it. In the downstream process of the series-connected sedimentation tanks, they are thus all contaminated with crud. At the same time, the necessary mass transport is significantly impeded at the phase boundary between organic phase and aqueous phase due to the crud formation.The transfer of the organic phase into the electrolysis cell can result in a "burnout" of the cathode. The carryover of this electrolyte into the extraction can cause problems with the pH regulation. The carry-over of the organic components into the raffinate also leads to contamination of the leaching circuit. The continuous treatment of the crud with a 3-phase decanter centrifuge is extremely effective in combating this problem. This technology splits all three phases from each other and they are consequently continuously separated. All subsequent process steps exhibit a stable, uniform effectiveness. The main advantage for the customer is that fluctuations in the process are eliminated and the organic phase can be recirculated back to the extraction. The recycling of the solvent alone justifies the investment in less than 6 months as examples from South Africa and Chile show.To operate solvent recovery in daily operation fully automated online at the optimum limit, the decanter centrifuge is equipped with a concentration-dependent pond adjustment called DControl® by this means, we can guarantee our customers the maximum possible solvent recovery and minimize the solvent costs in this process step. This system is presented in detail in this paper."

Jan 1, 2014

By Gerald L. Finlinger

This Bureau of Mines publication reviews underground methane drainage programs being conducted in various coalbeds. Equipment used in drainage programs such as drills, underground pipelines, and methane monitoring systems is described.

Jan 1, 1980

By Jr. Raleigh

As part vi the development of the Coal Quality Expert (CQRN) --a computer program capable of predicting the impacts of coal quality on power plant performance, costs, and emissions control--several nationally important coals are being characterized to augment the coal quality database associated with the software. The project is sponsored by the U.S. Department of Energy and the Electric Power Research Institute (EPRI) under the Clean coal Technology Program. Since 1989, CQ Inc. (a subsidiary of EPRI) has characterized seven bituminous coals from Alabama, Illinois, Kentucky and Oklahoma and six sub-bituminous coals from the Powder River Basin (PRB) in Montana and Wyoming. Coals from the PRB region--being burned more frequently in Midwestern and southern power plants to reduce emissions of sulfur oxide compounds--can sometimes contain significant concentrations of potentially toxic elements. Although no limits were imposed on air toxics emissions from fossil-fuel fired utilities by the Clean Air Act Amendments of 1990, future regulations may be implemented at the conclusion of Federally-mandated emissions studies. One possible result is that any increased utilization of coals, including those from the PRB, may depend on the potential for removing toxic trace elements prior to combustion.

Jan 1, 1993

By Claude W. Sill

In the usual volumetric determination of uranium, the solution containing uranium is reduced in a Jones reductor, yielding a mixture of trivalent and tetravalent uranium; the trivalent uranium is oxidized to the tetravalent state by bubbling a stream of air through the solution. The resulting solution of. Tetravalent uranium is titrated with a standard oxidant, generally sulfatoceric acid, dichromate, or permanganate; It seemed likely that the, same general procedure could be used in determining semimicro quantities of uranium if the conditions affecting the variables involved were understood more clearly than at present. In the method described below, the use of ferric sulfate to oxidize tetravalent uranium allows the titration to be made at room temperature in an essentially colorless solution with sulfatoceric acid. The latter oxidant its turn permits the use of the very stable indicator, ferroin, with its sharp color.., change and exactly reproducible blanks. Solutions of uranyl sulfate were prepared by diluting a stock solution that had been standardized gravimetrically according to the method of Lundell and Knowles (8).3/ Solutions of sulfatoceric acid were prepared according to the directions of G. F. Smith (12) and were standardized against arsenic trioxide in the presence of osmic acid according to the directions of Gleu. The cerium solutions were stored in 18-liter carboys fitted with siphon arrangements so that the bottles did not need to be opened and protected from light in a dark cupboard. Under these conditions, even the 0.01 N solution changed by less than 1 part per thousand over a period of about 6 months.

Jan 1, 1952