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By C. H. Lee, K. Adham, D. Lemieux, J. P. Mai, A. M. S. Hussein, S. Francey

Copper concentrates contain an increasing amount of arsenic, as the older sources of cleaner ores are depleted. At the same time, the market-determined price penalties on arsenic rich concentrates are rising due to limited arsenic treatment capacity at smelters and increasingly stringent environmental emissions limits, necessitating arsenic removal from the copper concentrates. Heating the concentrate to about 700°C can remove significant amounts of arsenic (as elemental and/or sulfide); however, it is important to achieve that removal economically and with due consideration to post-roasting arsenic (toxic waste) treatment. A comparison is made among different roasting options (kilns, multi-hearths and fluid beds) to qualify their potential application to arsenic roasting of copper concentrates. Both direct and indirect methods of heating as well as inert, air and oxygen atmosphere options are considered. Technology comparisons are made with respect to the roaster’s operation, its off-gas treatment and arsenic stabilization. INTRODUCTION In the last twenty years, the arsenic content in globally produced copper concentrates have risen steadily due to the depletion of cleaner ores and the increase in complex concentrate production. Smelter contracts typically limit arsenic to less than 0.5wt%, with a penalty paid per unit of additional arsenic and other contaminants such as antimony. While penalties can vary, they can be on the order of $70/dry metric tonne of concentrate per 1% of arsenic. Strategies used by miners to avoid the price penalties have been to blend clean and complex concentrates, and to remove arsenic from complex concentrates to achieve smelter limits. Arsenic can be removed from copper concentrates by the heat-induced decomposition of the predominant enargite mineral (Cu3AsS4) at ~700°C. Roasting at such elevated temperature is a commercially proven option, but still suffers from process, cost and environmental challenges. After roasting, the released arsenic sulfide fumes can be separated from most of the entrained concentrate dust in cyclones. Then, the As2S3 laden off-gas can be oxidized to generate a still volatile oxide (As2O3), which can be further separated from the residual concentrate dust in a hot electrostatic separator. Next, the off-gas can be cooled with air or water, to either deposit the arsenic oxide in a dry or dissolved state. Dissolved arsenic acid can be oxidized to As(V) and reacted with iron to yield a stabilized ferrihydrite precipitate or scorodite that can be safely disposed. In the case of dry arsenic trioxide, it can be mixed with reactants (e.g. iron) and fluxes before thermal stabilization in a glass matrix, thus eliminating the need for costly oxidation.

Jan 1, 2019

By Marianne Snedeker

In September 1985 we published a questionnaire asking about the content of MINING ENGINEERING and about your interests. By Dec. 10, our cutoff date, we had 430 responses, representing about 1.5% of the 28,238 people who received the September issue of ME. In the data that follow the tabulation and percentages are based on the number of individuals who responded to the particular question. About ME Through responses to the questionnaire, we were hoping to learn more about you, your interests, and how the magazine could better serve you. Those of you who responded told us something positive - you look at or read the magazine. Of the 430 respondents, 428 or 99.5% indicated that they had read or looked through the July and/or August issues. Those of you who refer to the magazine once are 207 or 48.5%. Those of you who refer to the magazine two or three times are 193 or 45.2%. Those of you who refer to the magazine four or more times are 27 or 6.3%. How much time do you spend reading the magazine? Of those responding to this question: 64 spent up to 1/2 hr 15.0% 224 spent up to 1 hr 52.6% 115 spent up to 1-2 hr 27.0% 23 spent more than 2 hr 5.4% In an informal survey among our staff, we determined that most people spend 1/2 to 1 hr reading magazines to which they subscribe at home. Does that match your experience? Many of you, 335 or 79%, clip your magazine for further reference. Also, many of you, 313 or 73.6%, do not pass your copy on to another reader, indicating that you are clipping it or receiving the magazine at home. Those magazines that are passed on reach: 1 person 3 0.7% 2 people 64 15.1% 3-5 people 34 8.0% 5 or more 11 2.6% Answers to what portions of the magazine you find useful indicated that the top three were Industry Newswatch, feature articles and Technical Papers; see Table 1. The "other" category included advertising - display, classified, Employment, and Professional Services - Washington Survey, New Products, Free Literature, book reviews, technology news, and Coming Events and Short Courses. We asked your appraisal of the technical level of the magazine. Of those responding, 39 or 9.1% indicated that it is too technical, 55 or 12.8% indicated it is not technical enough, and 335 or 78.1% judged it to have the correct technical level. In response to the question about whether you like to read an occasional feature that is not technically oriented, 21 or 5.1% said no, but an overwhelming 94.9% (393) said yes. Of the specific

Jan 1, 1986

By Stephen R. Iverson, Bill M. Stewart, Michael J. Beus

The U.S. Mine Safety and Health Administration (MSHA) has identified ore pass hazards as a significant safety problem in underground metal mines in the United States injury and fatality data show that many injuries are related to pulling or freeing ore pass chutes and structural failures of control gates and ore pass walls. Researchers at the Spokane Research Laboratory of the National Institute for Occupational Safety and Health are investigating these hazards and developing methods to improve safety during transport of ore and waste. Particle flow analysis methods were used to simulate chute and control gate response to various material loading scenarios. Results from computer models indicate that dynamic impacts from ore and waste rock might be considerably greater than theory predicts. Static and dynamic loads were measured in a laboratory setting using scaled ore (sass mock-ups. Field tests were initiated in an active ore pass to determine actual static and dynamic loads. Field data were compared to computer results and indicated that impact and total static loads were substantially less than the computer model results suggested. Damping factors, normal and shear stiffness, and mass frictional characteristics have a significant effect on particle flow and resulting impact loads.

By Sam Bang Jr, Rodney Burke

As mining progresses in the West, the depth of material has increased, making highwall stability a major factor in safety and production. The Jim Bridger Coal Mine’has made highwall stability a priority, concentrating on safety as well as increasing and improving production. Overburden depths are increasing dramatically; the geological environment consists of medium to sot? material, faulting, water, and current pit alignment not favorable to joint planes. Angle drilling the presplit at 20 degrees became necessaryas vertical presplit drilling produced wall failures.

Jan 1, 1998

The title of this address was selected before I had an opportunity to consider in detail the matters that I would like to discuss. Accordingly, I chose a very broad subject-so broad indeed that it would be foolhardy for me to attempt to deal with more than a few aspects of it. I do not propose to touch. at all on the developments to date of our mining and metallurgical enterprises, beyond paying a sincere tribute'to the skill and enterprise of those who have established an international reputation for Australian mining and metallurgy. I would rather look ahead and discuss certain factors that will play a decisive part in the future development of our mineral resources. I do this in no dogmatic spirit, and I hope that my remarks may lead to discussions which will stimulate action where it is needed.In recent years my colleagues and I have been forced by circumstances to give consideration to problems in the fields of mining and geology, and in process metallurgy, which lie outside the scope of our own research work. People come to us with metallurgical problems because they know of no more appropriate place to go, and it is distressing to have to inform them that it is nobody's job to offer them advice and assistance. I want to suggest to your Institute that it should press strongly for the provision of properresearch facilities for the mining and metallurgical industries, such as aready exist in most enlightened countries. In such countries, those connected with the development of mineral resources are able to obtain information and advice from Geological Surveys, Mines Departments or Bureaux of Mines, which offer far more comprehensive services than are available in this country.Before discussing specific technical problems of the mining and minerals industries, I shall enunciate certain general principles that I believe should be followed in respect to the technical side of the development of all Australian industries. The problem can, I suggest, be considered in three parts-technical education production, and research. I shall confine my remarks mostly to the research aspect, for it is with this that I am most familiar.For the efficient development of any industry in Australia, it is essential firstly that We should learn what is going on abroad, and secondly that we should simultaneously conduct independent research. In the latter sphere the Governmeht'departments and the private companies' or groups of companies should have complementary functions, the former concentrating on problems common to a number of companies or industries, and the latter on their oWn individual problems. It is essential to the continued existence of Australian industry that both company and govern...

Jan 1, 1944

By Maurice Bottiau

"Abstract When addressing the performance of deep foundations, many parameters play a role, from adequate soil investigation to performance monitoring and testing. The correct understanding of pile construction, though, remains crucial. After a long period of empirical design and regulations, the last decades have been the ones of theoretical considerations and extensive codes writing. The interaction between technology and design, however, still plays a determinant role. The introduction of hydraulics and the exponential increase in available power on one hand, the miniaturization and the introduction of electronics in control and monitoring systems on the other hand have exerted a major influence on new foundation systems or the evolution and control of existing systems. It appears important to try to take execution related parameters and their control during execution more deeply into account when assessing the final result of the deep foundations and the achieved level of safety and reliability. In this contribution, we will try to analyze how systems, equipment and pile production monitoring and testing can influence the pile performance, and if/how this influence could/should be translated in adapted safety or installation factors. This analysis will run through different categories of piles: driven, augercast and displacement auger piles and bored piles. INTRODUCTIONThe global performance of a deep foundation depends on different aspects (Poulos, 2003):1. Ground investigation2. Design and analysis3. Construction4. Testing5. Performance monitoring6. Remediation and performance enhancementThis paper intends to address the importance of pile construction and the control of it on the final performance of the pile-group of piles. There has been an increasing interest for theoretical analysis over the last 20 years, followed by an increasing impact of regulation and codes. Without denying the importance of the latter, the author wants to point out how installation procedure and project specific parameters can largely influence the reliability of the deep foundation. In this context, detailed and prescriptive standards can miss their objective of intended improvement of accuracy and reliability, but even worse they can adversely impact engineering judgment. In today’s construction world, it is possible to gather installation information which can be of outmost importance for the final deep foundations performance. Therefore, the increase or decrease of installation reliability through adequate pile testing and performance monitoring should be emphasized and should be taken into account in the codes. This is the case already in most advanced codes, but in a limited and insufficiently refined way. After reviewing how codes deal with this issue today, we will show some recent examples of unexpected results due to pile installation. We will try to put these examples into a broader perspective by highlighting some reference and/or recent literature considerations. Finally we will try to summarize how pile testing and installation documentation can increase reliability and attempt to open the debate on how codes could/should allow for more engineering judgment."

Jan 1, 2014

By K. Sugawara, H. -S. Jeong, Y. Ishiguro, J. Otani, Y. Obara, A. Hirata

A series of measurements of induced stress by the Compact Conical-ended Borehole Overcoring (CCBO) technique was performed within rock mass around a tunnel excavated in a region that an underground powerhouse is constructed under high initial rock stress. In the measurements, a phenomenon of core disking was observed during overcoring. The selecting method of strain data uninfluenced by the core disking was proposed, using X-ray CT scanner. Then, the state of induced stress determined from the selected strain data was discussed, comparing with the state of initial stress. Eine Serie von Messungen von induzierter Belastung mit kompaktem konisch-beendetem Überbohrverfahren (CCBO) wurde in Felsmassen um einen Tunnel ausgeführt, der in einer Region gebohrt wurde wo ein unterirdisches Kraftwert unter hoher anfänglicher Felsbelastung gebaut wird. Bei den Messungen wurde beim Überbohrverfahren ein Phänomen des Core Disking beobachtet. Die gewählte Methode der Belastungsdaten, unbeeinflusst durch Core Disking wurde vorgeschlagen, unter Verwendung von Röntgen-CT-Scanner. Dann wurde der Zustand der induzierten Belastung aus den gewählten Belastungsdaten diskutiert, unter Vergleich mit der ursprünglichen Belastung. Une série de mesures de contrainte induite effectuée avec la technique de forage de sur-carottage compacte à embout conique a été exécutée dans la masse rocheuse autour d'un tunnel excavé dans une région de construction d'une centrale électrique souterraine sous haute contrainte de roche initiale. Au cours des mesures, un phénomène de discage de carotte a été observé pendant le sur-carottage. La méthode de sélection des données de contrainte non influencée par le discage de carotte a été proposée, en utilisant un scanneur de tomographie calculée aux rayons X. Il s'ensuit que l'état de contrainte induite provoquée et déterminé à partir des données de la contrainte sélectionnées a été traitée, en effectuant une comparaison avec l'état de contrainte initiale.

Jan 1, 2003

By Albert L. Toenges

The production of bituminous coal by stripping methods has become an important factor in some areas, especially in the Central and South Central States. In the latter, production at strip mines exceeds that at deep mines. Table 1 shows the tonnage produced at strip mines and the percentage of the total production for 1924 to 1935, inclusive, for the States in which the mines described in this circular are situated.4/ Following are references to earlier Bureau of Mines publications on strip mining of bituminous coal: Cash, F. E., and von Bernewitz, M. W., Methods, Costs, and. Safety in, Stripping and Mining Coal, Copper Ore, Iron Ore, Bauxite, and Pebble Phosphate: Bull. 298, Bureau of Mines, 1929, 275 pp. Kiessling, O. E., Tryon, F. G., and Mann, L., The Economics of Strip-Coal Mining: Econ. Paper 11, Bureau of Mines, 1931, 32 pp. Turner, Scott, and Bureau of Mines Staff; Mining Bituminous Coal by Stripping Methods: Inf. Circ. 6383, Bureau of Mines, 1930, 23, pp.

Jan 1, 1937

As far as is known at the present time, important ore occurrences at Mount Isa are restricted to the Urquhart Shale. These occur at Mount Isa itself, and some 13 miles north along strike at the Northern Leases.The primary silver-lead-zinc and copper orebodies occur as adjacent but discretc entities in lithologieally distinct host rocks. The copper orebodies occur in an envelope of "Silica Dolomite", whereas the silver-lead zinc orebodies occur in shale typical of the Urquhart Shale in general.At both Mount Isa and the Northern Leases, secondary lead orebodies occur at thc surface representing primary stratiform silver-lead-zinc sulphide accumulations in the fresh rocks at depth.Secondary copper orebodies are known only at Mount Isa, where they have formed in favourable environments, but unlike the secondary lead orebodies, not in the positions of the former primary mineralization that gave rise to them. The secondary copper is localized in shale remote from the point where the copper was released into solution by weathering. It was derived from very low grade fracture fillings and disseminations of chalcopyrite in the outcropping or suboutcropping crest of the "Silica Dolomite".Primary silver-lead-zinc orebodies arc oxidized without significant transport or secondary enrichment, but secondary copper orebodies arc characterized by considerable transport and extreme secondary enrichment.The original water table stood at approximately 1,150 ft (mine datum) and for the majority of the mine area controlled the base of complete oxidation fairly closely.An oxidized zone approximately 175 ft deep is general in the Urquhart Shale.Structures affecting ground conditions have influenced oxidation and leaching of the silver-lcad-zinc orebodies, and have had effects vital to the formation of secondary copper orebodies.

Jan 1, 1966

By P. C. Fletcher, E. Kaya

The Bond grindability testing procedure has been standardized to measure the same grindability values, i.e. Bond work index (BWi), for the same ore when tests are performed in different laboratories or by different operators. This is accomplished by the standardization of mill dimensions, tumbling speed, grinding ball charge weight and distribution, sample ore charge weight in the mill and operating practice. The results of this investigation reveal that the Bond work index grindability values may differ substantially with different standard Bond ball mills. This paper will review the results.

Jan 1, 2002

By Henry P. Chandler

[Diamond, because of its extreme hardness and abrasion resistance, has an important function in precision engineering and automation. With the increasing; requirements of modern production for fine tolerances, interchange-ability, and speed, it has become even more important. In spite of the supply of other abrasive and hard materials and of ultrasonic, electrospark rued other substitute grinding, methods, world industry seams likely to absorb large quantities of diamond for industrial purposes. An increasing part of the world's needs will be supplied by manufactured diamond, which was introduced commercially by General Electric Co. in 1957. Use of diamond for glass cutting roes bark several centuries, mid diamond drilling of rock became important to the mining industry M the 1870's. Today, diamond drilling is the most extensively used method of exploring the world's ore reserves; diamond drills two also used to determined the nature of bedrock below the foundations of buildings, dams, and bridges. Diamond drill bits are now used extensively in the petroleum industry, and replacement or steel rock bits with diamond drill bits in hard rock formations has affected substantial savings.]

Jan 1, 1964

By Henry P. Chandler

[Diamond, because of its extreme hardness and abrasion resistance, has an important function in precision engineering and automation. With the increasing; requirements of modern production for fine tolerances, interchangeability, and speed, it has become even hors, important in spite of the supply of other abrasive and hard materials and of ultrasonic, electrospspark rued other substitute grinding methods world industry seems likely to absorb large quantities of diamond for industrial purposes. An increasing part of the world's needs will be supplied by manufactured diamond, which was introduced commercially by General Electric Co. in 1957. Use of diamond for glass cutting goes bark several centuries, mid diamond drilling of rock became important to the mining industry M the 1870's. Today, diamond drilling is the most extensively used method of exploring the world's ore reserves; diamond drills two also used to determine the nature of bedrock below the foundations of buildings, dams, and bridges. Diamond drill bits are now used extensively in the petroleum industry, and replacement or steel rock bits with diamond drill bits in hard rock formations has effected substantial savings.]

Jan 1, 1964

By Ihsan Berk Tulu

In the Analysis of Retreat Mining Pillar Stability (ARMPS) program, the magnitude of the abutment loading adjacent to a gob area is calculated using an ?abutment angle? concept. The extent of the abutment loading is determined solely as a function of depth from an empirically derived equation. In the recommended calibration method for LaModel, it was believed that the empirical equations for calculating the magnitude and extent of the abutment load, as used in ARMPS, were the best available methods for determining these critical overburden loading values. Therefore, similar calculations were implemented in the LaModel calibration method. However, the latest in situ stress measurements of abutment loading performed in the United States and Australia have shown that there can be significant deviations in the measured abutment magnitude and extent as compared to the predicted values from the empirical formulas used in ARMPS and LaModel. It seems reasonable that the overburden geology, depth, extraction panel width, and mining height should have a significant effect on the extent and magnitude of the abutment load. However, the current empirical formulas do not incorporate many of these significant parameters into determining the abutment load on the pillars. In this paper, stress measurements from US and Australian mines were back-analyzed by using analytical and numerical methods to investigate the measured abutment extent and loading. Ultimately, it was determined that the original empirical abutment extent formula in conjunction with the original ALPS square-decay stress distribution function was supported by the case histories in this paper. Also, for depths less than 900 ft, the average 21° abutment angle was supported by the case histories; however, at depths greater than 900 ft, the abutment angle was found to be significantly less than 21° and should be calculated with a new proposed equation.

Jan 1, 2012

By P. Trueman

A project is underway to convert a validated methodology to a system that will permit the near real time interpretation of loading data from longwall powered supports, allowing rapid adaptation of mining strategies, maintenance scheduling and set pressures for optimal roof control. Such a system has the potential to significantly reduce roof control problems and is a pre-requisite to successfully fully automating a longwall face. The development depended upon a robust methodology for interpreting the pressure sensor data coming from the face in the context of support strata interaction using a novel characteristic load cycle analysis concept. New software was developed capable of handling the large quantity of data emanating from a modern longwall with the current level of signal corruption and loss, accurately delineating load cycles and extracting the critical load cycle features essential for interpreting how the support and strata are interacting. Existing software being used to access the pressure data were found either to be incapable of delineating load cycles at all or, where they could, the accuracy was low, making it impractical to use them in combination with the new advances in load cycle analysis. The software is currently being extended from ?off line? to ?on line? in order to provide a real time response to changing strata conditions.

Jan 1, 2006

By Bauduin C. Besix

The Eurocode 7 "Geotechnical Design" is based on "Limit State Design", tackling the uncertainties as much as possible at their source through: - selection of characteristic values of variables (loads, soil properties, pile resistance,...); - partial factors applied on the characteristic values; - model factors to account explicitly for uncertainties of the calculation rule if necessary. Eurocode 7 will propose three "design approaches". The selection of one of them will be by National Determination. For pile design, the approaches are: - approach 1 is a "material factoring approach" at load side and a "resistance factoring approach" at resistance side. The structural and geotechnical design are checked for both of two separate sets of partial factors. - approach 2 is a "load and resistance factoring approach" and is in several aspects close to a deterministic approach. The design is checked for one set of partial factors. - approach 3 is a material factoring approach, at load as well as at resistance side. The design is checked for one set of factors. The aim of this paper is to introduce to the design of pile foundations based on pile load tests and on ground test results (semi-empirical and analytical methods) in the frame-work of the three design approaches. Detailed attention is devoted to: - the selection of the characteristic value of the pile resistance, accounting for spatial variability and stiffness of the structure; - the reliability of the prediction of the pile resistance using analytical or semi-empirical methods which may be accounted for through a "model factor". The results of a large test campaign on screw piles in OC Clay and a calculation example illustrate the proposed procedure when calculation rules using CPT results are used.

Jan 1, 2002

By William D. Leech, Ronald E. Romley, Gary N. Sheppard

The Price Road Drainage Tunnel was constructed for the Arizona Department of Transportation (ADOT) in 1988 and 1989 to provide surface water drainage for the proposed outer Loop Highway (SR 117). The 5.4 km (3 mile) long, 6.6 m (22 ft) excavated diameter tunnel was driven through sand, gravel and cobbles utilizing an open face digger shield. Precast concrete segments were erected for initial ground support. A second-pass reinforced concrete final lining was placed, which was followed by contact grouting. This paper will consider the owner's representatives' view of the effectiveness of using precast concrete segments for this project. Topics discussed include segment design and erection, ground support, geotechnical instrumentation, segment erection verses contact grout interactions and tunnel production.

Jan 1, 1991

Jan 1, 1962

By C Vuillier, A Roshdieh

Water is the main medium for removing impurities from iron ore during wet processing to achieve a higher quality product. However, there is a substantial increase in freshwater consumption due to an increase in demand from the following two factors: in the past 55 years the world population has doubled from 3 to 7.5 billion and crude steel production has increased five times from approximately 350 to 1662 Mt/a (IISI, 2008). Furthermore, social development in developing countries exacerbates water consumption making freshwater an increasingly valuable resource with an average distribution of 70 per cent for agriculture, 20 per cent for industry and only ten per cent for domestic consumption (Hourtolle, 2005; OECD, 2009). Rapidly changing regulations over the access and preservation of water across the world indicates the growing importance of this issue, so the mining industry must adapt to this continual change and must be committed to increasing the efficiency of water usage.Tailings dams receive most of the water used by the process plant. In arid regions where evaporation is high and availability of water low or non-existent, technical solutions other than the conventional tailings dam, such as thickened and/or filtered tailings, exist to optimise the recovery of water and reduce the need for external water consumption. However, these solutions present additional challenges, such as energy consumption and transportation from the process plant to the ultimate storage area.This paper considers a range of alternatives covering thickening and filtering, transportation and storage, water return, closure and rehabilitation. Mining projects in the future will be more affected by the rising cost in water and tighter regulations in accessing water and energy. Good tailings management can contribute significantly to reducing the dependence on these two key commodities (water and electricity), improving the resilience of iron ore projects especially in arid regions and areas with high competition for water.CITATION:Vuillier, C and A Roshdieh, A, 2017. Minimising the water loss associated with mine tailings disposal, in Proceedings Iron Ore 2017, pp 245–250 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 24, 2017

By Carlos G. C

Geological mapping in various parts of Australia is revealing a number of regional associations of mineralizations with particular persistent stratigraphic horizons. Such associations have been found in the Broken Hill district of New South Wales, in the Nairne district of South Australia, in the Mount Isa district of Queensland, and in the Cloncurry district of Queensland. The question has arisen as to whether such mineralizations are of sedimentary origin, syngenetic with the enclosing formation, or whether they are of epigenetic origin, and reflect the selective hydrothermal mineralization of favourable beds on a regional scale.The purpose of this investigation is to test the use of sulphur-selenium ratios as an objective method of distinguishing between suphide deposits or sedimentary or supergene origin, and sulphide deposits of hydrothermal origin, with particular application to the districts mentioned. At the same time much data has been accumulated as to the selenium content of Australian sulphide ores. The possible use of sulphur-selenium ratios for this purpose was first demonstrated by Goldschmidt and his coworkers (1933; 1935), and later by Carstens (1941). Goldschmidt and Strock (1935) found that pyrite of sedimentary origin had a sulphur : selenium ratio of the order of 200,000 or more, whereas pyrite of hydrothermal origin had a sulphur: selenium ratio of 10,000 to 20,000. Carstensfound that sedimentary pyrite deposits in Norway contained less than 1 g. Se per ton, whereas hydrothermal pyrite deposits contained 20 to 30 g. per ton.

Jan 1, 1954

In a previous paper the author showed that silver considerably delayed the recrystallisation of lead after cold work. The effect of antimony on the rate of recrystallisation of distorted lead was studied next, and the experiments performed, and the results obtained, are described in this paper. Electrolytic lead was used as a standard of comparison.It was also used to make the lead antimony alloys.This electrolytic lead contained 0.0005% total impurities.It was prepared from commercial lead by fire refining, followed by electrolysis and finally by vacuum casting. The process was described in the previous paper and the description need not be repeated here. PREPARATION OF LEAD - ANTIMONY ALLOYS.The steps taken to procure pure antimony are outlined in the appendix. To make the lead antimony alloys a mother alloy was prepared thus:-A quantity of the antimony (it was received in the powdered form) was placed in a pyrex glass tube, which was closed at one end. The antimony was washed with hot hydrochloric acid (1: 1), then with more dilute acid, then with distilled water, and finally with absolute alcohol; it was dried by warming and evacu,ating the tube. This should leave the antimony more nearly free from surface oxides.The amount of antimony was determined by weighing quickly; the appropriate amount of vacuum-cast electrolytic *Research Fellow, Dept. of Metallurgy, University of Melbourne.

Jan 1, 1936