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By H. H. Hughes, J. G. Dunn, P. G. Fernandez, H. G. Linge

Dissolved Arsenic (As) is stabilised primarily as As(III) and As(V) and enters ground water streams from sources such as the increasing metallurgical processing of As - containing ores [1]. As(III) is more toxic than As(V) and is less effectively removed from solution by oxide precipitation. Even for dilute As(III) solutions, skin contact or ingestion can cause dermatitis or cancer and there are stringent effluent control standards in place for As containing effluent from mining operations [2]. Chemtronics (Perth, Australia) has manufactured a compact digital voltamme­ter, based on anodic stripping voltammetry (ASV) and suitable for use in the laboratory or field. In this paper we demonstrate the utility of this equipment for measuring As(III) concentration with a detection limit of ca. 10 ppb.

Jan 1, 1995

By John D. Batty

With the emergence ofbiooxidation as a viable process for the pre treatment of refractory gold ores, so have the number of publica­tions on this topic increased dramatically. To a novice in the field of biooxidation, the infonnation presented is often confusing and sometimes even incorrect. Infonnation has also been published that is misleading in that it highlights a particular feature of a process that is either totally irrelevant or of no consequence to the ultimate goal viz. achieving the maximum economical gold recovery. To assist a potential user of biooxidation in evaluating the available published infonnation some guidelines or considera­tions for some of the more important aspects are given, as well as some extracts from publications that demonstrate the manner in which information has been presented.

Jan 1, 1996

By John W. Greene

ennec?tt's Bameys Canyon Mine personnel developed an mnovahve process to extract gold from a small (1.8 million tons) sulfide ore zone in an oxidized ore body located at the Bameys Canyon Mine. This approach consists of extracting the sulfides from the ore via flotation, shipping the concentrate to Kennecott's new smelter, and mixing the flotation tailings with the oxide ore, agglomerating the mixture, and stacking the resultin tailings/oxide ore combination on the heaps. Conventional heap leaching technology is utilized to recover the gold from the mixed materials. Overall, the total gold recovery from the sulfide ore is esti­mated to be 90%. This approximation is based on a smelter gold recovery of 98% from the concentrate and an 88% recovery from the tailings during heap leaching

Jan 1, 1996

By H. G. Linge

The Australian gold industry currently contributes some $4bpa to the national economy [l]. Some 40% of the total gold is produced in the region centred on Kalgoorlie known as the Eastern Goldfields of Western Australia. This region is the largest single centre of production with an output of some 100 tpa of gold [2]. In the Eastern Goldfields, refractory arseno­pyritic gold ore is an increasingly significant source of gold, feeding several operations utilizing bio-oxidation as the pre­carbon in pulp/leach (CIP/L) treatment process [1]. This paper desribes an alternative pre-CIP/L treatment option for use in the Eastern Goldfields based on the chlorination of arsenopyrite by chlor-alkali technology [3] using the salt resources available from saline water present in abundance in the region.

Jan 1, 1995

The feasibility of exploiting a mineral deposit by developing a surface mine is closely related to the environmental protection and land reclamation costs. This issue has utmost importance for West Macedonia Lignite Centre (WMLC) of Greece, where there is still a lot of interest for opening of new mines and for further development of the existing open-pits. The decision-making process in these cases can be based on a decision tree that takes into consideration the various cost components of environmental management, the alternative solutions, the environmental permits and the cost reports of environmental management actions carried out so far. Moreover, the mine planning procedure is affected indirectly by numerous uncertain environmental and socioeconomic parameters, such as the delays caused by the bureaucratic procedures and the settlement of arguments in the Court.

Jan 1, 2006

By Didem Maral

Olivine is a name of a mineral group that has a chemical formula of: (Mg, Fe), SiO4. The most important rock for the olivine group minerals is dunite, which can contain olivine up to 95-99%. Dunite can be obtained from chrome enrichment as a by-product. As a result of alteration of the olivine group minerals, several kinds of different minerals can occur. Main consumption areas of olivine are steel and iron industry. Also olivine is used in not only casting and refractory industries but also production of radiator, ballast material and abrasive. North of Bursa-Orhaneli has got more than 5 billion tons reserves in ultrabasic massifs. M.T.A found that olivine has got high quality of using in refractory and casting industry.

Jan 1, 2005

By Fathi Habashi

THE MOST important arsenic minerals are shown in Table 6-1. The recovery of arsenic from arsenic sulfides is treated in Chapter Four. Arsenical ores may be either leached directly, or first smelted to volatilize as much arsenic and sulfur as possible, and the resulting product, called speiss, is then leached. A speiss is mainly a complex mixture of metal arsenides, but its [Table 6-1. Arsenic minerals. Arsenides Niccolite NiS Smaltite CoAs2 Skutterudite CoAs3 Sulfarsenides Cobaltite CoAsS Enargite CuaAsS4 Arsenopyrite FeAsS Arsenic sulfides Realgar As4S4 Orpiment As2S3] composition varies widely, depending on the type of ore treated. A speiss usually contains 15-35% arsenic. Methods of leaching are describedd in the following paragraphs.

Jan 1, 1970

Acid Mine Drainage (AMD) is the most serious environmental problem facing the Canadian Mineral Industry today. Acid Mine Drainage results from oxidation of sulphide minerals (e.g. pyrite or pyrrhotite) contained in mine waste or mine tailings. It is characterised by acid effluents rich in heavy metals that are released into the environment. A new acid remediation technology is presented in this paper by which metallurgical residues from the aluminium extraction industry are used to construct permeable reactive barriers (PRB) to treat acid mine effluents. It describes column tests performed to simulate a PRB using Bauxsol?, a chemically and physically treated bauxite refinery residue, as a reactive material. This experimentation shows promising results for the Bauxsol? PRB method in neutralizing pH and removing metals from acidic mine effluents.

Jan 1, 2006

By T. Yegulalp, K. S. Lackner

Zero emission coal plants capture their own CO2 emissions. Since they have no smoke stack, they emit no pollutants to the air. Zero emission plants circulate a gas stream, to which fresh fuel is added and from which spent fuel and impurities are removed as solids or liquids. Coal is gasified via hydrogenation, steam reforming or CO2 gasification (Boudouard reaction). The gas is oxidized in a fuel cell and the resultant water and CO2 are partially removed before returning the remaining gas to the gasifier. The high conversion efficiency of zero emission power plants, which exceeds 70% even in realistic designs, stems from combining fuel cells with careful heat management. The paper generalizes the concepts and outlines the thermodynamic basis of zero emission power plants.

Jan 1, 2004

By R. H. T. Garnett

Offshore mining of placer diamond deposits along the coast of South Africa and Namibia has become a multi-scale activity. It is a successful offshoot of a land-based mining industry that has operated along the coastline for more than 80 years. Onshore diamond deposits have been worked by several methods from the foreshore to some kilometers inland (Hodgen). These deposits are the foundation of an ongoing industry along the coastline. The offshore diamond industry began in the late 1950s and has now come of age. Diamonds are produced along 800 km (500 miles) of coastline in water 200 m (660 ft) deep. About half of the coastline is in Namibia, north of the Orange River that defines the border with South Africa. The other half is in South Africa.

Jan 1, 1995

By F. M. Doyle, Jiang Tao, Xu Shi, Chen Jin, E. Peters

Tafel curve technique and leaching tests have been applied to study the kinetics of gold leaching with thiosulfate. Results show that cupric ions and ammonia play the part of catalysts in the leaching of gold with thiosulfate. The activation energy of gold dissolution is calculated as 27.99 KJ/mol in the absence of both cupric ions and ammonia. However, the energy is reduced to 15.54 KJ/mol in a solution of 0.01 mol/L Cu (NH3)2 4* and 0. 5moVL total ammonia. The reaction order of Cu (NH,) g is one in the range of 0.001~0.1mol/L. These results support the electrochemical-catalytic mechanism pro- posed by the authors and explains the behavior of cupric ion and ammonia (Jiang Tao, et al., 1993)

Jan 1, 1993

By Wang Dianzuo, Luo Lin, Hu Yuehua, Qiu Guanzhou

This paper introduces a novel classification approach named the flotation classification approach which works by controlling interactions between particles. It differs considerably from the conventional classification processes operating on mechanical forces. In the present test, the micro-bubble flotation technology is grafted onto hydro-classification. Selective aggregation and dispersion of ultrafine particles are achieved through governing the interactions in the classification process. A series of laboratory classification tests for -44 pm kaolin have been conducted on a classification column. As a result, about 92 percent recovery for minus 2 pm size fraction Kaolin in the final product is obtained. In addition, two criteria for the classification are set up. Finally, a principle of classifying and controlling the interactions between particles is discussed in terms of surface thermodynamics and hydrodynamics.

Jan 1, 1995

By Kotaro Ohga, Gota DEGUCHI, Kiyoshi HGUCHI

The situation of Japanes coal mine is in the severe enviroment, because the policy on coal mining has changed. Every year one or two coal mines will be foced to close. To continue the production of coal, we have to reduce the cost of production. Therefore, the mining by longwall method which is more than 250m was attempted at Taiheiyou Coal Mine to reduce the cost and this mining method have had successful results. To get successful results by this mining method, the controlling and prediction of gas emission from the longwall panel will be most important things. In this paper, the comparison of the predicted gas emission from the mining panel based on the measured gas content by using new device with the observed results is described.

Jan 1, 1993

By Bok-youn Kim

Presently, mobile diesel equipments contributes a lot in improving the economical feasibility of underground mining and tunneling operations. Even in Korea, quite a large number of diesel equipments is being applied to the underground workings already. This paper introduced the production procedure, characteristics and evaluation technology on diesel particulate matter(DPM) that is known as a carcinogen For easy measurement of DPM using laser dust monitor, the conversion factor(K) to gravimetric concentration was acquired. The field measurement of DPM was conducted to make a comparison between locally manufactured on-road equipments and imported equipments specially designed for underground use. According to the Government regulation revised h 1996, it was learned that the critical pollutants among the diesel exhaust is DPM instead of NOx which have been considered as a critical pollutants.

Jan 1, 1997

By Ernest K. Yanful, Paul H. Simms

The lysimeter is a useful tool for evaluating the performance of mine waste covers or liners. A major problem with its application is the possibility for preferential flow into or away from the lysimeter, if the lysimeter soil is finer or coarser than the barrier soil or sub-base soil. Analysis of a field lysimeter using a two-dimensional unsaturated-saturated liquid flow model suggested that preferential flow would occur and little or no water would be collected; however, in the field, the lysimeters collected significant amounts of water. A similar discrepancy was found between the observed and predicted water balance of a simple laboratory test simulating the lysimeter design. Vapour flow and partial flow, two phenomena not generally simulated in conventional flow models, are possible explanations for the difference between field and laboratory observations.

Jan 1, 2000

By J. T. Ryan, Griffin. Wayne H.

This paper shows that if a drift has a brattice which is sufficiently leaky, changes in the operating point of the fan depend solely on the volumetric efficiency within the drift. Under this high leakage condition, an increase in the length of the drift causes very little shift in the fan operating point. For less leaky brattices, the operating point depends on both the fan characteristic curve and the volumetric efficiency. It is shown that for the fan curve and drift parameters used in this paper the fan operating point in a drift with a volumetric efficiency of 50% is essentially the same as a drift which has a zero efficiency. In this region of efficiency, an increase of 300% in the length of the drift causes only a 3% increase in fan operating pressure.

Jan 1, 1993

By Barry T. Kilbourn

Yttrium Oxide is versatile; it is essential for television phosphors, for microwave garnets, for laser crystals and for high-performance ceramics, to name but a few advanced applications. When produced commercially, the material must satisfy not only stringent specifications regarding chemical purity but, increasingly, also meet closely defined physical parameters. The techniques needed for its production range from solvent extraction to carefully controlled precipitation and calcination. The processing steps from mineral concentrate to pure oxide will be described and related to the final oxide. The simple word "material" has complex connotations; it means, to paraphrase "Alice", exactly what we want it to mean. Throw in the label "advanced" and the picture darkens further! Just what is an advanced material and how does it differ from a common-or-garden material?

Jan 1, 1990

By G. Atesok, M. Hancer, M. S. Celik, O. F. Emrullahoglu

Multivalent ions are shown to activate the flotation of colemanite in the presence of sodium dodecylsulfate (NaDDS). Floatation recoveries versus barium ion concentrations exhibit three distinct regions of floatability. Adsorption, zeta potential and solubility mesurements under comparable conditions reveal that Region I is characterized by the uptake of Me2+ ions followed by electrostatic attraction of sulfate ions onto the oppositely charged surface. The improvement observed in flotation recoveries in Regions II and III is ascribed to surface and bulk precipitation of metal dodecyl sulfate onto colemanite, respectively. While the most soluble BaDDS ions yield the highest activation, the least soluble MgDDS achieve the lowest activation. It is postulated that metal ions depending on their solubility products with DDS are capable of activating the boron minerals.

Jan 1, 1993

By Brij M. Moudgil

Lack of understanding the major process parameters and inadequate scale-up factors have led to the belief that fundamental knowledge is not important for successful flotation plant operations. Flotation of simple and easy to process ores may not require a strong fundamental knowledge base for day to day operations. However, as low grade complex ores are mined and process control is integrated into flotation schemes, it is imperative for a plant operator to acquire a strong background in the basics of the flotation process at hand and/or have access to such a knowledge base at short notice. In order to meet the challenges of unexpected changes in the feed, reagent quality, water chemistry, physical, mechanical and hydrodynamic conditions, the flotation plant superintendent/chief metallurgist must have a strong background in the flotation fundamentals.

Jan 1, 1993

By John A. Herbst

At the last Comminution Symposium a challenge (Meloy and Williams, 1992) was issued to "predict the typical straight-line, self similar" tumbling mill product size distributions using a population balance model (PBM). Implicit in this challenge is the assumption that the PBM is inadequate for predicting real world grinding performance. This response is presented in three parts: I. Theoretical analysis of the general PBM and its appropriateness for comminution system modeling. II. Examination of the accuracy of prediction of real world milling behavior using linear and nonlinear PBMs. III. Evidence from recent microscale comminution research. This paper concludes with recommendations concerning future research which will: 1. further elucidate mechanisms of particle destruction and creation as well as attrition and 2. increase the accuracy of model predictions in highly nonlinear situations

Jan 1, 1997