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By W. N. Marchant

The Bureau of Mines performed chemical research to elaborate details of sulfur chemistry pertaining to the citrate flue gas desulfurization process in which sulfur dioxide (SO2), absorbed (as bisulfite ion) in a buffered sodium citrate solution, is reduced by hydrogen sulfide (H2S) according to the overall reaction 2H2S + HSO3 + H+ ? 3S + 3H20. The rate-limiting step in the process was shown to be the reduction by H2S of thiosulfate (S2031-) that is formed as an intermediate. Pseudo first-order kinetic measurements were made at room temperature to retard the reaction sufficiently that adequate analysis was possible. These measurements showed the rates of the following net processes to be -d [S02]/dt (pH 4.5) = (0.409±0.050)min-1 [S02]; d [S2032-]/dt (pH 4.5) = (0.199±0.017)min-1 [S02]; -d [S2032-]/dt (pH 4.0) = (0.0437±0.0265)min-1 [S2032-]~1; -dH2S/dt (pH 3.9) = (21.6±3.0) mmoles/min-atm [H2S]g1.4, where [H2S]g is the partial pressure of H2S in the gas phase, in atmospheres, and the rate describes the consumption of H2S, in millimoles per minute; d[S]/dt (pH 4.0) = (38.0±3.4)min-1 [H2S]1, where [H2S] is the concentration of H2S in solution. Hydrogen ion consumption during the slow phase of regeneration was shown to occur at (2.1±0.5) times he rate of thiosulfate consumption, which is interpreted as evidence for the following as the rate-limiting reaction: 2H2S + S2032- + 2H+ ? 4S + 3H20 A scheme consisting of five sequential general reactions is proposed to account for sulfur formation.

Jan 1, 1981

By R. H. Dickson

This paper, which describes the milling practice of the Verde Central Mines, Inc., is one of a series on milling methods and costs being prepared by the United States Bureau of Mines. GENERAL DESCRIPTION The Verde Central concentrator is located in Walnut Gulch, about 1 mile west of Jerome, Ariz., and on the Jerome-Prescott highway. It is about 1,000 feet distant from the main shaft of the Verde Central mine and treats ore from this mine only. The mill is connected with the main shaft of the mine by a 24-inch gave railway, over which the ore is hauled in 5-cubic yard capacity, rocker, side-dump cars, by a 3-ton Brookville gasoline locomotive.

Jan 1, 1931

By M. J. Ankeny, J. J. Forbes

"One of the main functions of the U. S. Bureau of Mines, as authorized by Congress, is to investigate safety and health conditions, to disseminate information regarding safe and unsafe practices in mining, and to aid in improving safety and health conditions of mining communities and in promoting the welfare of the miner. Among several methods of reaching the miner and interesting him in safety work, perhaps the most effective is through the 11 mine safety stations and 11 railroad cars known as mine rescue, or more correctly, mine safety cars.Frequently, the Bureau of Mines receives requests for information regarding the purpose, equipment, personnel, and construction of its safety cars used in the field service. It is the intention of this circular to present to the mining public in particular, and to the public in general, some definite information regarding these safety cars and their functions.The cars are operated throughout the mining fields of the United States and are headquartered as follows (see fig. 1): Car 1, Reno, Nev.; Car 2, Raton, N. M.; Car 3, Pittsburgh, Pa.; Car 4, Terre Haute, Ind.; Car 5, Pineville, Ky.; Car 6, Pittsburg, Kans.; Car 7, Huntington, W. Va.; Car 8, Duluth, Minn.; Car 9, Butte, Mont.; Car 10, Des Moines, Iowa; Car 11, Anchorage, Alaska.One of the most important purposes of the U. S. Bureau of Mines safety cars is to render service at mine fires and explosions where human life is endangered. State mine inspectors and other interested persons are supplied with itineraries of the car operating in their districts from time to time, so that they may know at all times where the car can be found in case of emergency. When these disasters occur the car may be reached direct or through its field headquarters, and upon receiving word of a mine disaster, or request for assistance, it immediately proceeds to the scene of trouble. Frequently a special locomotive is supplied by the railroads and in many instances the movement of the car is given the right of way over all other railway traffic. Upon reaching the destination, the facilities and personnel of the car are immediately available for rescue and recovery operations.Following most mine disasters a thorough investigation is made by engineers of the Bureau of Mines, and a confidential report is submitted to the operator. The information gained in this manner from a large number of mine fires and explosions, together with the knowledge gained from the experimental work carried on at the Experimental mine of the bureau at Bruceton, Pa., serves as a basis upon which the bureau is able to recommend preventive measures whereby similar occurrences may be averted. The bureau car is often used as headquarters for the investigating engineer when such an examination is being made."

Mar 1, 1931

By Graham W. Marks

This report is the fourth of a series concerning the development of spectrochemical methods for the analysis of ore samples and related Metallurgical materials by the total-energy method. In this report, the application of this method to the determination of thallium is discussed. This element lies in group III of the periodic tale; one other Clement of this group; indium, has already been investigated.

Jan 1, 1949

By J. E. Chilton

Underground miners may be exposed to hazardous quantities of toxic gases, such as carbon monoxide (CO), generated from mine fires or explosions. Every underground miner is required to carry a filter self-rescuer (FSR), which when operated will remove CO from the miner's breathing air. In addition, every underground miner must have a self-contained self-rescuer (SCSR) near the worksite that will supply breathing oxygen. In many situations, miners do not know when to don either rescuer since they do not know if there is a fire in the mine, nor do they carry instrumentation necessary for the detection of the toxic, colorless, and odorless fire product CO. If each miner carried a personal CO alarm, which would respond to high concentrations of CO, the miner would then be alerted when to don either the FSR or SCSR and exit the mine. A prototype personal miner's CO alarm called PEMCOAL was developed by the U.S. Bureau of Mines. The PEMCOAL unit is small enough to be carried on a miner's belt, has a flash lamp visual alarm, requires no calibration for use, and uses a chemical sensor that changes color by reaction with trace quantities of CO. The chemical sensor was tested at concentrations of CO from 10 to 1,000 ppm, at temperatures from 5° to 40° C, and with several potential mine gas interferents. The PEMCOAL alarm times were sufficiently fast to warn miners before they are exposed to hazardous quantities of CO.

Jan 1, 1989

By A. D. Garman

This digest of Brazilian mining law is based upon Decree 4265 of January 15 , 1921 , and its regulation , Decree 15,211 of December 28 , 1921. Unless otherwise stated , the references are to the latter exclusively , since it includes practically everything contained in the law itself . It should be borne in mind that these regulations do not necessarily apply to mines other than those on private and national land . Each State of the Union is free , in respect to State land , to regulate or interpret the national mining law , which is very general in its terms , as it sees fit . Whether such local regulations are anywhere in force with respect to the law of 1921 the bureau has not been informed . Article 64 of the Constitution indicates that only such portions of territory as are required for the defense of the frontiers , for fortifications , military constructions , and federal railways belong to the Union . Lessees of such lands , unless in debt to the Treasury , have preferential prospecting rights for one year ( art . 28 ) . This carries with it the right to work any mines discovered (Law , art . 12 ) .

Jul 1, 1930

By K. P. V. Lei

An electrochemical process was developed for the preparation of vanadium from vanadium carbide. Commercially available vanadium carbide (V2C) was used as the starting material. Vanadium was obtained by electrolysis of the V2C in a BaCl2-KCl-NaCI-VCl2 electrolyte at 670° C using a helium-atmosphere, molten-salt electrolytic cell. Vanadium products were recovered with purities high as 99.6 percent. Current efficiencies of 87 percent and vanadium recoveries of 84 percent were attained. The cathode products were amenable to electrorefining to high-purity vanadium of 99.96-percent purity.

Jan 1, 1971

By Paul W. McGann

THE MINERAL INDUSTRIES had a near-record year in 1950, as rising industrial activity in general, greatly accentuated by the outbreak of hostilities in Korea in midyear, called forth increasing supplies of mineral fuels and raw materials. The aggregate value of mineral production was second only to that in 1948, and the aggregate physical volume was exceeded only in 1948 and 1947. Lower coal production accounted for the failure to surpass these earlier years. Growth of production was fairly constant throughout the year, especially for crude petroleum; its physical output for the year as a whole exceeded that of 1949 by 7 percent. According to Federal Reserve Board indexes, other relative gains were 16 percent for coal, 9 percent for fuels in general, and 17 percent for metals. The increase for mining in general was of the order of 10 percent. This was not quite as large as the general increase in industrial production but clearly reflected the total-industrial trend (see fig. 1).

Jan 1, 1953

By Seymour Wasserman

To develop noise control designs for secondary crushers in Taconite plants. Taken into consideration: 1. Acoustical criteria 2. Day-to-day operational considerations and maintenance accessibility 3. Materials of construction 4. Adaptability of design to other Taconite plants having crushers 5. Cost of noise control treatment.

Jan 1, 1977

By M. O. Serbousek

The load-transfer mechanics of fully grouted roof bolts in coal mines have been investigated in laboratory and analytical studies. The purpose of this Bureau of Mines research is to increase understanding and better interpret data from routine field pull tests and to develop a numerical model of a grouted bolt that can be used in a global computer model of a mine roof. Analytical studies using closed-form solutions and finite-element techniques were compared to experimental results. Laboratory work includes variation of bolt length, hole diameter, and grouL type. Pull tests were pel'fol·med on 4-, 2-, and I-ft bolts in holes of 1-and I-3IB-in diameters. Both polyester resin and inorganic grouts were used as the anchorage medium. Strain gauges were installed on the bolts at several locations to observe the rate of load transfer from the bolt through the grout to the rock mass when a force was applied at the bolt end using standard jack pull testing procedures and equipment. The average anchorage length of 4-and 2-ft bolts was 22 in. Grout type and hole size variations did not produce a significant effect on the rate of load transfer from the bolt to the rock.

Jan 1, 1987

By Edward Thomas

In 1947 the Bureau of Mines, as an accident-prevention measure, decided to advocate the adoption of roof bolting (suspension roof supports) in coal mines where it appeared to be applicable. Subsequent experience has disclosed that the applicability of this support is more general than was first suspected; moreover, comparison of the accident records of mines before and after adoption of the roof-bolting method shows results that more than justify the effort and funds expended. The industry has responded enthusiastically, because roof bolting proved to be not only an accident-prevention measure but also one to increase productive efficiency. In some instances this increase in the productivity of men and machines has been almost incredible and has led many mining men to conclude that through some hocus-pocus they can now cast aside many or all of the time-proven rule of good mining practice. If this tendency is not counteracted, it could easily result in an increase of roof-fall accidents, which may outweigh the benefits of roof bolting and discredit an innovation in roof control that shows great promise of materially reducing our mining accidents. From an economic standpoint it may represent the margin between profit and loss in many mining operations. The purpose of this manuscript is not to propose an inflexible code or set of rules but to summarize the experience to date as a guide for those who have the responsibility for the installation and inspection of roof bolts. This experience consists of approximately 250 investigations of roof failure in which roof bolting was involved either directly or indirectly. It should be pointed out that many of these failures were controlled, occurring during experimental periods, and comparatively few of the accidental failures actually resulted in personal injury, yet a significant number represented potential hazards.

Jan 1, 1951

By B. R. Eichbaum

To develop technology to assure an ample supply of zinc and to reduce environmental pollution, the U.S. Bureau of Mines investigated alternatives to the roast-leach process for treating complex sulfide concentrates. Previous studies proved that low-grade zinc sulfide (ZnS) concentrates could be leached using chlorine-oxygen to produce zinc chloride (ZnCI2). The process involves high energy requirements for evaporating the pregnant solution to produce anhydrous ZnCl2 needed for electrolytic cell feed. An efficient hydrometallurgical process would facilitate treatment of lower grade ores than can be used in conventional processing and would render roasting unnecessary. An alternative method was devised for recovering ZnCl2 from solution. Zinc diammine chloride [Zn(NH3)2CI2] was precipitated from solution by adding ammonium chloride (NH4CI) and sparging with ammonia (NH3) to a pH of 6 to 7.5. The spent solution was treated with calcium hydroxide [Ca(OH)21 at 60° to 80° C for 1 to 4 h to remove remaining zinc and NH3. The Zn(NH3)2CI2 was heated to 300° to 400° C to remove NH3 and produce anhydrous ZnCI2. A possible flowsheet was devised and is included.

Jan 1, 1991

By G. S. Rice, H. P. Greenwald, H. C. Howarth

"Stoppings in coal mines serve, important and. vital functions, such as coursing the ventilating current, sealing off abandoned or dangerous workings, sealing fire areas, and separating mines at boundaries. Stoppings may hold back water, but normally that is not their function; their design is, or should be very different from that of a hydraulic dap which is designed to a definite load, often a very heavy one, from one direction over an indefinitely long period. Hence, a dam usually requires an arched structure to resist hydraulic pressure, and it must be massive to meet vertical stresses due to heavy ground pressure.Stoppings are designed primarily to resist a pressure applied laterally through air or gases. Their strength cannot be stated without specifying the direction of applied load. A stopping may be placed in stress by proof pressure subsequent to erection, through extraction of pillars in the vicinity which may act direct, or by squeezing the ribs or heaving the floor. These forces act more or less parallel to the faces of the stopping and may be very great but measures must be taken suitable to each case, and it is impossible to allow for these in general specifications other than to call for normally good construction. A stopping is principally designed to resist the action of forces at right angles to its face, such as the shocks of blasting, the pressure of gas from instantaneous violent out bursts such as have occurred in certain British Columbia coal mines, sudden compression of the air by great falls of roof in closed spaces, and at time pressures that accompany an explosion of either fire damp or coal dust or both. This paper deals with the tests of pressures of explosions only."

Sep 1, 1930

By H. H. Schrenk

The Bureau of Mines midget impinger dust-sampling apparatus was described first in 1937.4/ Two supplementary reports5/6 were published in 1938. These reports are now out of print. The material published previously is combined in this paper to make information on this device available for distribution. The impinger was developed by the Bureau of Mines in cooperation with the United States Public Health Service in 1922. The underlying principle of this instruments is based on impingement land wetting, of the dust particles by drawing air through a nozzle at high velocity onto a smooth surface under a bubbling column of liquid. The dust particles are retained in the liquid. The apparatus has been used widely and permissible limits of dustiness have teen established in the United States on the basis of results obtained with this device in correlation with medical studies. However, it has been criticized for its bulk, weight, and power requirements.

Jan 1, 1939

By J. D. McLenegan

The purpose of this investigation was to prepare a market survey of the refractories industry in California and Nevada (referred to in subsequent paragraphs as the region), and to determine the degree of self-sufficiency and the potential capacity for anticipated growth. The report includes estimates of the total annual refractories consumption, the quantity of refractories imported into the region, the tonnage of raw materials required for their manufacture, and the resources of fire clay and high-alumina minerals in the region.

Jan 1, 1956

By V. E. Erwin, W. W. Adams

"Production of explosives for industrial use in,the United States during 1934 continued the upward trend begun in 1933 from the low-level output of 1932, and the output in 1934 was only slightly less than in 1931.Reports to the United Stated Bureau of Mines from companies engaged in the manufacture of industrial explosives showed that the quantity of explosives manufactured in the United States and sold during 1934 for use within the various States was 314,767,922 pounds - 23 percent more than in 1931.Production during 1934 included 39,207,845 pounds of permissible explosives 5 206,625,027 pounds of high explosives other than permissibles, and,68,935,050 pounds of black blasting powder of which 37,192,700 pounds were in granular form and 31,742,350 pounds in pellet form. These figures represent an increase over 1933 of 15.6 percent for permissible explosives, 30.9 percent for other high explosive, and 7.4 percent for black powder.Coal-mining operations were the chief consumers of permissible explosives; 99 percent of the total output in 1934 was used, in coal mines. The proportion used by bituminous mines was 59 percent and by anthracite mines 40 percent. Coal mining was likewise the principal consumer of black blasting powder, taking 88 percent of the total sales during 1934; of this proportion, bituminous mines received 78 percent and anthracite mines between 9 and 10 percent. Consumers of high explosives other than permissibles were more varied; the reports showed that 11 percent of the total quantity sold was for coal mining, 22 percent for metal mining, 17 percent for quarrying and nonmetallic-mineral mining, 46 percent for railway and other construction work, and 4 percent for all other purposes."

Oct 1, 1935

By J. P. McGee

As part of a joint U.S. Atomic Energy Commission-Federal Bureau of Mines program for using nuclear energy to supply process heat, a simulated nuclear loop has been constructed to test components. This loop has been operated for more than 1,800 hours at 100 p.s.i.g. Of this period, 23 hours were at 2,500° F. and higher; 540 at 2,000° to 2,500° F.; 840 at 1,500° to 2,000° F.; 200 at 1,000° to 1,500° F.; and 260 below 1,000° F. Leakage at flanges and welds was not a serious problem. A helium-recycle system with gas temperatures of 2,300° to 2,500° F. and a static pressure of 250 p.s.i.g. appears feasible. Difficulties were encountered with the recycle compressor due to thermal distortion of the impeller and shaft. The use of sealed bearings limits compressor operation to the life of the bearings.

Jan 1, 1960

By R. E. Peterson

A reduction roasting/magnetic separation/flotation process for beneficiating oxidized taconite from the western Mesabi iron range in Minnesota was evaluated in a Bureau of Mines research program to insure an adequate supply of raw materials for future ironmaking and steelmaking needs. The research was performed on a sample containing 35.4 pct iron and representing a deposit of approximately 2 billion tons of raw materials. An average of 1,419 lb of oxidized taconite and 37 lb of lignite reluctant per hour were fed to a 35 -foot rotary kiln in which the iron oxides were converted to artificial magnetite. The kiln was heated with pulverized lignite and natural gas. Most of the dust collected from the kiln exhaust gas was pelletized and recycled to the kiln. Magnetic separation and cationic flotation of the roasted material in a 900-lb/hr pilot plant produced a concentrate analyzing 67.9 pct iron and 4.9 pct silica and containing 69.2 pct of the iron in the kiln feed.

Jan 1, 1981

By A. L. Engel

In recent investigations of chloride Volatilization of gold at the Reno Station, it was found that the addition of small amounts of copper and NaCl to the charge brought about improved volatilization of the gold. The investigations described in this report were concerned with the recovery, in an aqueous medium, of fumes from chloride volatilization of gold. It was attempted to discover a suitable aqueous medium that would permit absorption, solution, or precipitation of all the volatilized gold immediately upon contact with the medium. A simple laboratory apparatus was employed to produce fumes by volatilization. To this furnace was attached an absorption train consisting of a series of chambers containing the aqueous medium, through which the fumes were drawn by suction. A satisfactory synthetic ore that contained metallic, gold in a quartz-matrix was made and utilized, enough. gold being present in a' small amount of material to permit an accurate, metallurgical balance of the volatized values' to be obtained in all the experiments.

Jan 1, 1949

By Allen L. Frank

A portable radon diffusion chamber has been tested with electrical collection of the radon daughter nuclei for enhancement of sensitivity. The detector size was small enough to be worn suspended from the belt. With a battery-supplied high voltage the sensitivity was found to be 1.43 tracks/cm2 per pCi-hr/l of ambient radon at Sot relative humidity. The track densities on the surfaces of the CR-39 plastic nuclear track detectors were found to be non-uniform, making difficult the determination of average densities with high accuracy. The fabrication of electrets for use in the detector was investigated in accordance with published techniques with negative results.

Jan 1, 1983