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By J. F. Shultz

The Bureau of Mines investigated the hydrogenation of carbon monoxide and carbon dioxide over Raney nickel catalyst and nitrided fused-iron catalyst using both a single-pass and a recycle system. Activation energy over Raney nickel catalyst is 29 to 32 kcal/mole for synthesis from either CO or CO2, Pressure dependence of the gas conversion is to the 0.3 power for synthesis from CO and to the 0.5 power for synthesis from CO2. Nitrided fused-iron catalysts were tested using high recycle rates and 3H2+lCO, 2H2+lCO, and 1H2+lCO feed gas at 21.4 atmospheres absolute pressure. The relative usage of hydrogen (moles H2 consumed per moles Ha+CO consumed) was larger than in corresponding single-pass tests, and the relative usage of hydrogen approached the feed gas ratio monotonically as conversion increased. Activation energy was found to be 12 or 13 kcal/mole fresh feed gases of 3H2+lCO or 2H2+lCO. For single-pass operation the activation energy under the same conditions was 19 to 21 kcal/mole.

Jan 1, 1967

By H. H. Schrenk

[A colorimetric method5/ for the determination of benzene in amounts as low as 0.001 mg has been developed recently at the U.S. Bureau of Mines Pittsburgh Experiment Station by the authors, with the assistance of chemical personnel fro a the Allegheny County (Pa.) Relief Works Division. The method is based on the direct nitration of either liquid - or gas - phase benzene, followed by neutralization, extraction with butanone, and final treatment with sodium hydroxide which produces a violet color. The color is matched with color standards of known values. Although the method is adaptable to many conditions the primary objective was a procedure that would be suitable for hygienic investigations. The development worth included a study of possible interference by chemicals that be present in those situations in which the method. would be employed. In this study it was found that a specimen of hexane prepared by the Gulf Research Laboratory, Pittsburgh, by fractionation of West Virginia natural gas gave positive result for benzene, whereas a specimen of pentane prepared in the same manner showed only a trace, and specimens of n -heptane and octane (2,2,4 trimethylpentane) supplied by Eastman Kodak Co. save a negative result. According to information obtained from the Eastman Kodak Co. the latter two compounds were highly purified, the n-heptene being prepared from line and the octane synthesized in the laboratory. On nitration of a larger amount of tae natural hexane a visible quantity, of needlelike crystals which resembled those of m-dinitrobenzene was obtained. The hexane from this nitration was recovered by distillation and again nitrated, but no crystals or colorimetric indication of benzene was obtained. This imitated that the specimen of natural hexane contained a substance which at least had the chemical behavior of benzene.]

Jan 1, 1935

By D. A. Paice, A. B. Shimp

A test program was conducted to determine the adequacy of molded case circuit breakers for dc electrical systems in coal mines. Mine electrical system parameters and the most severe operating conditions to be expected were determined. Tests of the interrupting capabilities of several molded case breakers were made under the worst conditions to be expected. Continuous and pulsed current carrying capability of the breakers was also investigated. Breakers from two different manufacturers passed all tests successfully. Based on the results of these tests, a set of guidelines for applying molded case breakers to dc systems has been prepared.

Jan 1, 1975

By Ralph L. Rinehart, Wils L. Cooley

This paper summarizes recent experiments with grounding systems. Problems and potential hazards related to in-mine grounding systems are discussed. The monitoring of trailing cable ground conductors and testing of commercially available ground monitors are discussed.

Jan 1, 1975

By William H. Schiffbauer, William D. Mayercheck, August J. Kwitowski

This report summarizes work sponsored by the Bureau of Mines in the development of a remote operating system (ROS) for controllng a thin-seam continuous miner (TSCM) 500 feet or more distant from the extraction face. Detail s are provided on ROS subsystems including the continuous miner, video equipment, controls and displays, the electronic control system, and the operator station.

By James P. Rider, Jay F. Colinet

The National Institute for Occupational Safety and Health (NIOSH) has conducted benchmarking surveys at longwall operations across the country to identify current operating practices and the types of controls being used. Gravimetric and instantaneous dust sampling was completed to quantify dust generation from major sources and determine the relative effectiveness of the different control technologies. Results from the underground dust surveys will be presented as an update on longwall dust control technology and operating practices.

By R. Blickensderfer

Several thin film absorber stacks with spectrally selective characteristics were developed by the Bureau of Mines. The stacks consisted of a silicon thick film or a zirconium compound thin film on a reflective thin film of silver. The zirconium absorber films, with the general formula ZrCxOyNz, were prepared by reactively sputtering zirconium or zirconium carbide in argon with small amounts of oxygen, nitrogen, or both, or by oxidizing zirconium films in air. A few similar types of films were prepared from titanium. The short-wave absorptance over the solar spectrum, a(s), and thermal emittance at 600 K, e(600 K), of the solar absorber stacks were calculated from room-temperature reflectance data. The values of a(s) ranged from 0.47 to 0.93, e(600 K) from 0.49 to 0.034, and the ratio a(s)/e(600 K) from 1.7 to 34. The specimen with the best combination of properties, a ZrNx-Ag stack, had a solar absorptance a(s) of 0.85 and a ratio, a(s)/e(600 K), of 24. The effect of film thickness and composition on spectral selectivity was determined. An emissometer for measuring normal total emittance up to 800 K and a method for determining a (s), e(T) (hemispherical), and a(s)/e(T) using simulated solar radiation are described. A calorimetric method for measuring a(s) and e(T) (hemispherical) at elevated temperature is also described. Measurements made on several specimens agreed favorably with calculated values.

Jan 1, 1976

By J. K. Whyatt

The U.S. Bureau of Mines has been conducting a series of rock mechanics investigations at the Lucky Friday Mine in the Coeur d'Alene Mining District of northern Idaho. In the present study, the energy release rate (ERR) index was used to evaluate three underhand stope backfill parameters-cement content, density, and placement gap-to determine their influence on rock bursts. This index provides a relative measure of the likelihood of rock bursting for a given rock mass. It is known that the elastic idealization of the rock mass inherent in this method causes underestimation of stope closure and hence underestimation of the influence of backfill on rock bursting. However, this evaluation still showed that (1) changing from present practice to one in which backfill was omitted altogether would increase the ERR by 42 pct and (2) perfect placement of backfill would reduce the ERR below present practice levels by 28 pct. The easiest step toward perfect placement would be elimination of the placement gap, which accounted for half of the difference in ERR between present practice and ideal placement conditions. There was no indication that increasing initial fill strength through increased cement content would affect the ERR.

Jan 1, 2010

By James L. Hendrix

A study was made of the United States Bureau of Mines' chlorine-oxygen leaching process for complex sulfide concentrates. The investigation sought to determine the kinetic order and IT mechanisms involved in the reactions betweens sphalerite, and galena with chlorine. The influence of copper on the extraction rates was also studied. It has been shown the rates of reaction of chlorine in aqueous solutions with sphalerite and galena are both zero order at 373K with the rate limiting step being the chemical reaction. Addition of cupric chloride increased the extractions of both lead and zinc.

Jan 1, 1980

Lower noise exposure levels for operators and cleanup personnel working in portable nonmetallic mineral crushing and screening plants.

Jan 1, 1983

By John E. Rourke, O&apos

A survey of existing and developing field permeability test methods was conducted in order to identify and specify capable methods to be used in feasibility investigations or performance monitoring for in situ leaching of ore deposits. Geologic settings of leachable deposits are discussed, as well as representative techniques used for the in situ leaching operation. Subsurface investigation techniques including drilling, core recovery, and down-hole inspection methods relevant to field permeability investigations are discussed. Field experience is examined and capable field permeability test methods are identified. Specifications for test borehole preparation, test performance. and methods of analysis are given. The test methods are comparatively rated in a matrix with respect to costs ease of use, and data effectiveness' for a broad range of conditions. Well Pump and Packer test methods receive high ratings. Recommendations are made for needed developments in field permeability test methods and a comprehensive bibliography is given.

Jan 1, 1977

By R. V. Lundquist

A method was developed by the Federal Bureau of Mines for evaluating viscosity data from slurries obtained in leaching sinters from the lime soda sinter process for extracting alumina from aluminous silicates. The logarithm of the viscosity was observed to be a linear function with time. The slope of the plotted line provides a means for evaluating viscosity behavior in a lime soda sinter blurry and also a means for comparing gelation characteristics directly with other variables in the lime soda sinter process. This report presents one aspect of a continuing study by the Bureau of Mines on methods for treating siliceous aluminum ores. It is one of the many programs of the Bureau concerned with conservation, development, and use of our domestic minerals resources. Previous investigations of lime soda processes, both by the Bureau4-7/ and industrial concerns, have demonstrated that sintered materials containing CaO, Na2O, A1203, and S102 in various combinations exhibit a tendency to gel or set when mixed with water or other extraction solutions. Gelling prevents satisfactory recovery of alumina and in extreme cases prevents operation of an extraction plant.

Jan 1, 1960

By H. O. McDonald

The Bureau of Mines has demonstrated a hydrometallurgical method to separate chromium from other metals in a variety of surface-finishing wastes by precipitation with benzoate ion. The resulting chromium salt may then be converted to the hydroxide, and the benzoate may be recycled. Chromium recoveries of 92 to 100 pct are obtained.

Jan 1, 1983

By C. W. Davis

This is the first of a series of papers being; prepared as the work progresses in a study of the hydrometallurgy of manganese. The investigation is being made in an endeavor to make possible the utilization of lour-grade domestic manganese ores. The value of a hydrometallurgical process for manganese depends on the present and future uses for manganese products.

Jan 1, 1930

By J. A. Eisele

The Bureau of Hines conducted a bench-scale investigation of a concentrated H2S04 reaction for recovering and separating rare-earth elements, barium, and strontium from a bastnasite ore and byproduct. Barium and strontium were dissolved in the concentrated acid and precipitated as a mixed product by water dilution. Separation of strontium from barium was effected by reaction with Na2C03 solution, followed by a dilute acid leach of the SrC03 formed. After removing the barium and strontium from bastnäsite are, the rare-earth elements were roasted to water-soluble sulfates. The rare-earth sulfate solution was subsequently processed by solvent extraction to produce rare-earth oxides low in lead and magnesium.

Jan 1, 1974

By C. F. Wingquist

As part of an ongoing study to determine how the wear of mining tools affects dust generation, the Bureau of Mines has measured bit tempera-ture rise during cutting of abrasive rock. Radial bit wear-flat tem-peratures generated by linear cutting in Berea Sandstone were measured as a function of cutting depth and speed. Depths of cut (DOC) were 1/8, 1/4, and 1/2 in, and cutting speeds were 10, 40, and 80 in/s, respectively. Temperature sensing was accomplished by emplacement of a miniature thermocouple into the center of the wear flat. Temperatures observed ranged from 2000 to 5000 C. Correlation between depth and temperature was weak. Temperature increased linearly with speed at 1/2-in DOC, but data taken at 1/8-and 1/4-in DOC produced inconclusive results. The results indicated that at least for deeper cuts (1/2 in), bit temperature, and therefore wear, can be reduced by lowering the cutting speed.

Jan 1, 1987

By Edward D. Thimons, Jay F. Colinet

Underground coal mining operations in the United States continue to increase productivity as mining equipment and practices are improved. Unfortunately, increased production also results in the potential for increased respirable dust generation and worker exposure. In response, US operations are applying basic controls at elevated levels and looking to emerging technologies in an effort to better control respirable dust levels. Ventilating air and water sprays remain the basis of dust control strategies for both longwall and continuous mining operations, and the level of application for these controls continues to increase. In addition, new technologies are emerging that have the potential to further reduce dust levels. The National Institute for Occupational Safety and Health (NIOSH) has been conducting research into methods to optimize existing control technologies and evaluate emerging control technologies. This paper will summarize control technologies routinely being used in underground coal mine operations, as well as provide a review of new controls that are being pursued.

By Fred N. Kissell

Methane concentration peaks were measured by the Bureau of Mines at coal mine working faces during entry development. The statistical distribution of peaks was found to be normal or log normal depending on how well the methane was being mixed into the ventilation airstream. A normal distribution indicated good mixing, whereas a log-normal distribution indicated that mixing was poor. In addition, the "highest" peaks over selected intervals were found to fit a type I extreme-value distribution, a result similar to that obtained while mining longwall faces.

Jan 1, 1974

By F. E. Brantley, D. M. Yergensen, D. A. Martin

Fluidized - bed roasting was investigated as a means of decomposing gypsum and gypsum mixtures to produce a gas rich in sulfur dioxide and a lime or portland cement residue . Ninety- eight percent desulfurization of gypsum in a 10 - inch fluidized- bed reactor took 1.5 hours at an operating temperature between 1,200 ° and 1,225 ° C. A cement- type residue was obtained but had to be refired at 1,450 ° C before mortar prepared from it met the physical specifications for cement .

Jan 1, 1963

By C. J. Chindgren, L. C. Bauerle, J. B. Rosenbaum

Modifications of the conventional method of preparing ductile vanadium metal by calcium reduction of V2 05 in a bomb were explored for clues to a more economical procedure . The modifications examined included ( 1 ) omitting the gas purge of the bomb ordinarily used for eliminating atmospheric nitrogen , (2 ) using low- grade vanadium feed materials , ( 3 ) using alternative reductants , such as aluminum , magnesium , and silicon , and reductant mixtures , and ( 4 ) bomb refining of aluminothermic metal produced in open- vessel reductions . The most promising modification appeared to be bomb refining , using calcium to purify vanadium metal -- of low aluminum but high oxygen content-- prepared by open- vessel aluminothermic reduction of vanadium pentoxide .

Jul 1, 1960