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By Sabri Ergun

This report gives the result of investigations of coals of different rank, coal com¬ponents, chemically and thermally treated and irradiated coals, and sedimented organic matter. In most studies the arbitrary parameters obtained from the usual quantitative profile analyses are not given largely because they lack physical meaning. Instead comp interpretations are offered. X-ray patterns of high-volatile bituminous and lower rank coals are not self¬-sufficient for structural interpretation by the methods of analysis developed to date. The patterns of hydrogenated and dehydrogenated coals indicate that the basic change in the structure of bituminous coals with increase in rank is the conversion of alicyclic structures into aromatic layers. In low-rank anthracites the aromatic layers are about 10 A in size. The increase in rank is the result of coalescence of layers. High-rank anthracites have layer sizes of 25 to 40 A and exhibit the development of three-dimensional (hkl) reflections of graphite, indicating ordering of adjacent layers. In meta-anthracites the layers are > 1000 A and the basic structure is that of defective crystalline graphite. The well-known petrographic components in low-rank coals have different structures; the differences dissappear in low-volatile bituminous and higher rank coals. The patterns of sedimented organic matter, except impsonites, differ from those of coal hydrogen contents are high, and their X-ray patterns are consistent with those of structures. In contrast to normal coals, the patterns of uranium-bearing coals show increased diffuseness with decrease in hydrogen content. The diffuseness is accompanied by increase in the uranium content of the coal. It is very likely that high uranium-bearing coals have predominantly tetrahedral structures.

Jan 1, 1968

By Ralph Husack

The Bureau of Mines investigated the effect of gamma radiation on reactions between Pennsylvania anthracite and fluorine and chlorine. In the tests with fluorine about 90 percent of the coal reacted at 350° C to form volatile products whether or not irradiation was employed. Up to 0.8 ml of liquid products per gram of anthracite was collected. Among the 25 com-pounds indicated by gas chromatography, fluoroform and l,l-difluoroethylene were tentatively identified from their relative retention times and perfluoro-cyclopentane from its infrared spectrum. In addition, a clear, hard, wax, probably a fluorocarbon, was formed at 45° C in both the presence and absence of radiation. With chlorine there was no significant difference due to radiation, and preliminary tests indicated that the chlorine reacted more with the organic matter of anthracite at 200° C than with inorganic matter. At 400° C the results were inconclusive because of excessive corrosion in the reaction vessel.

Jan 1, 1966

By John S. Ball

Aniline points have been used to some extent for more than 20 years. to indicate the types of structures in hydrocarbons and thus to analyze mixtures of hydrocarbons . This type of analysis has been applied - principally to the low -boiling hydrocarbons found in the gasoline range . Although there is some disagreement as to their merits , both aniline point and diesel index (aniline point in degrees Fahrenheit times A.P.I. gravity at 60 ° F. divided by 100) are used rather extensively for evaluating ignition qualities of diesel fuels . In recent years aniline points have been employed in the study of lubricating - oil fractions . They also have been used to predict : the tendency of different oils to cause swelling of synthetic rubbers.5/ Recent standardization of the aniline - point determination by the American Society for Testing Materials has encouraged wider use of this test . Considerable data concerning , aniline points and critical solution temperatures in aniline have been accumulated in the course of a study of related subjects . Thesc data , together with some original results , are presented here in the hope that they will prove useful to other worker's in this field ...

Oct 1, 1943

By D. J. Stoops, H. Kato, M. D. Carver

The effects of impurity elements silicon , aluminum, copper , nitrogen , and manganese , at 50 to 300 ppm, on properties of the zirconium alloy Zircaloy 2 were investigated . Variations in microstructure , mechanical properties , and corrosion behavior in some inorganic acid and salt solutions were observed with variations in level of impurity element . Corrodents were solutions of sulfuric acid , phosphoric acid , copper chloride , and iron chloride . Silicon was found to modify annealed microstructures by spheroidizing and dispersion of secondphase material throughout grains . Silicon or manganese improved ultimate and yield strength of the alloy without loss in ductility . All five elements affected corrosion rates of the alloy , the effect being generally different for each element .

Jan 1, 1964

By James R. Boyle

The value of Alabama's nonfuel mineral production in 1985 was $405.9 million, a slight decrease from the record high of 1984. With the exception of clays, output of most nonfuel minerals increased over that of 1984. Alabama was second in the Nation in production of crushed marble and bauxite; third in firre clay; fourth in masonry cement and kaolin; fifth in portland cement and lime; and sixth in ferroalloys and recovered sulfur, Alabama ranked 20th in the Nation in value of nonfuel minerals produced, but ranked 13th in value of industrial minerals. Valuewise, Alabama produced 2.4% of the Nation's industrial minerals.

Jan 1, 1987

By L. B. Berger

Studies showing the effect of mixing hot exhaust gases with the intake air of a four-stroke-cycle Diesel engine are described. The results indicate a marked increase in carbon monoxide in tip exhaust gases, a decrease in oxides of nitrogen, and no significant effect on aldehydes. The increase in carbon monoxide was greater at higher fuel-air ratios and was caused partly by the increase in fuel-air ratio end partly by the decrease in oxygen concentration resulting when exhaust has was added. The application of these results to the use of Diesel engines underground is considered.

Jan 1, 1940

By Henry H. Ginsberg

The effectiveness of 0.01 pct. molybdenum, as ammonium molybdate impregnated on coal, on the hydrogenation of a high-volatile bituminous C coal at 8,000 p.s.i.g. and 460° to 480° C. has been studied in a pilot plant by the Federal Bureau of Mines. Under these conditions, the Bureau obtained 98 to 99 pct. conversion5/ of coal to liquids and gases at throughputs of 29 to 101 lb. of m.a.f. coal per cubic foot of reaction space per hour. At 460° C. the indicated yield of oil ranged from 63 pct. (based on m.a.f. coal) at a throughput of 35 lb./c.f.h. (pounds per cubic foot per hour) to 68.5 pct. at a throughput of 58 lb./c.f.h., and the yield of gaseous hydro-carbons ranged from 25.5 to 19 pct. at the same throughputs. The maximum measured yield of oil boiling under 325° C. was 47 pct.

Jan 1, 1960

By R. A. Friedel, J. L. Shultz, A. G. Sharkey

The purpose of this investigation was to study the primary materials associated with the coal structure . Mass spectrometric techniques can be useful in studying the chemical structure of coal and various high- molecularweight materials derived from coal . Investigations of pyrolysis products and extracts of coal , and also whole coal , showed : 1. Aromatic hydrocarbons obtained by the vacuum pyrolysis of coal below 300 ° C possibly were sorbed material rather than decomposition products . 2 . 2 . Thirteen structural types having molecular weights from 78 to 400 were identified in pyridine extracts constituting one - quarter or more of the coal by weight . 3. Material extracted at room temperature with a methanol - benzene solvent and a vacuum pyrolysis condensate obtained at 450 ° C contain similar components . The extract and the condensate have approximately the same average molecular weights ( 200-300 ) . 4. Material extracted from coal at room temperature is altered even by mild thermal treatment . 5. Changes in various alkyl series occurring in thermally treated coal extracts can be followed quantitatively . 6. Similarities in the spectra of coal and graphite were indicated in an investigation using a mass spectrometer equipped with a spark source . Determinations on a coal - ash sample by this technique showed good agreement with data obtained by emission spectroscopy .

Jan 1, 1963

By M. A. Elliott, F. W. Brown

"INTRODUCTION During the recent war the Bureau of Mines, at the request of one of the armed services, investigated the hazards that night be encountered 5n handling perchloric acid, particularly if spilled on certain materials. The hazardous nature of perchloric acid when mixed with reducing agents had been known qualitatively, but it was desired to obtain quantitative data on the explosion hazards of such materials. Accordingly, tests were made to determine the sensitivity of mixtures of perchloric acid and oxidizable materials to initiation by heat, impact, sparks, flame, and explosive impulses. This report summarizes the results of those tests.PROPERTIES OF PERCELORIC ACIDAnhydrous perchloric acid is a colorless,hygroscopic, volatile, mobile liquid that fumes in the air. The anhydrous acid is unstable at ordinary temperatures, and therefore the commercial acid is a water solution containing either 60 percent or 70 percent by weight of the anhydrous acid. The commercial acid is widely used in chemical analysis, frequently to oxidize organic material. If proper precautions are not observed, such an oxidixation may become exceedingly rapid and result in an explosion. Several such explosions involving the acid are mentioned in the literature. 4, 5, 6/"

Jan 1, 1948

By G. W. Birge, D. E. Wolfson, J. G. Walters

An investigation was conducted to determine the relationship between ASTM and Micum tumbler data and to develop equations that would enable the conversion of data from one test method for comparison with those determined by the other , and thereby facilitate the international exchange of data . Relative strengths of 18 commercially produced cokes were determined by ASTM and Micum tumblers and ASTM shatter test . Two of the samples were coke produced for foundry use , and two were produced in beehive ovens . The remaining 14 samples were produced for blast furnace consumption and had ASTM tumbler stabilities of 36 to 58. Statistical procedures were used to relate the three test methods and also to evaluate the effect of charge weights , top sizes of coke , and types of screens specified by the two standard tumbler procedures , square - hole wire mesh for the ASTM tumbler and punched round - hole for the Micum . A significant result was that the data obtained with like screens have a higher degree of correlation with a smaller standard deviation than data from the screens specified for each tumbler .

Jan 1, 1964

By Roger L. Williams

The Bureau of Mines investigated northern New Jersey as a potential future source of yttrium and the rare-earth elements. The studies, consisting of geophysical surveying, sampling, and exploratory drilling, began in the spring of 1959. A total of three and one-half months were spent in the field collecting data. Thirty-three deposits were investigated, of which five demonstrated some potential resources of yttrium and rare-earth minerals. Results indicate that the deposits examined do not contain quantities of yttrium and the rare-earth elements recoverable under present economic conditions. Detailed studies conducted at the Scrub Oaks mine, near Dover, N. J., delineated a yttrium and rare-earth-bearing zone within the magnetite-hematite ore body that represents a potential low-grade deposit. Beneficiation studies on this deposit indicate that a final product, averaging 31.3 percent rare-earth oxides including yttrium, could be produced through amine and fatty acid flotation procedures with 77 percent recovery. Two hundred and eighty-five feet of diamond drill core was obtained from exploration studies conducted at the Bemco prospect in Sussex County. The deposit averages 2.30 percent rare-earth oxides (including yttrium), 0.45 percent uranium and 0.24 percent thorium. Low-grade deposits were identified at the Canfield phosphat2 mine and the Tanners Brook Monazite placers in Morris County, and the Marble Mountain prospect in Warren County.

Jan 1, 1967

By Paul R. Thimas, Edward H. Boyle

"The Bureau of Mines evaluated the long-term cost and availability of primary gold production from 135 mines and deposits worldwide. Collectively, the evaluated countries represent 93 pct of world gold production. Total recoverable gold available (as of January 1984) from a subset of 111 significant producing mines and developing deposits in 13 market economy countries (MEC's) is estimated at 810 million tr oz. The Republic of South Africa is estimated to account for 87 pct of total recoverable gold. The United States and Canada account for 4 and 4.5 pct of the total, respectively. Eighty-three percent of total recoverable gold is available at a constant 1984 break-even price of $400/tr oz, and 70 pct is available at $300/tr oz. South Africa accounts for 90 pct of the gold available at $400/tr oz or less.Major conclusions are that (1) South Africa should remain the largest world producer through the year 2000, (2) annual MEC output in 2000 should not be significantly different than current output given constant 1984 gold prices of more than $300/tr oz, and (3) there may be a significant decline in production after 2010 in the absence of major new discoveries and continued development of new mines to offset the depletion of the South African mines. INTRODUCTIONSince the late 1970's the world gold mining industry has been characterized by dynamic growth in production and volatility in price. World production in 1983 was almost 15 pct greater than in 1980, and the short-term trend continues upward. Annual dollar-based price changes since the early 1970's have been unprecedented in both magnitude and volatility. This commodity, which sold for $35/tr oz3 for over a third of a century, reached an annual average $612/tr oz in 1980. Until 1980, the future price of gold seemed set on an upward trend. Since that year, however, world gold prices have fallen by over 50 pct to slightly over $300/tr oz at the end of 1984.Against this background, this study was undertaken to determine (1) the level of world demonstrated gold resources, (2) total and annual availability of gold mine production, (3) long-run production costs per operation and by national aggregates, (4) the economic and technical factors that impact upon cost and availability, and (5) probable future mine production and cost trends."

Jan 1, 1985

By William Catron

This paper is one of a series being prepared by the United States Bureau of Mines on mining methods, practices, and cuts in the various reining districts of the United States. The mining methods described are those used in the mines of the Cananea Consolidated Copper Co., a Mexico corporation whose holding company in the United States is the Greene Cananea Copper Co. The mines are at Cananea, Sonora, Mexico, 25 miles directly south of the international boundary, approximately in 31° nor to latitude and 110 to 130° west longitude. Cananea is connected with the boundary towns of Naco and Nogales, Ariz., by a standard-gage railroad.

Jan 1, 1930

By Richard V. Ageton, Harry E. Tufft, E. A. Holbrook

When an underground excavation is made, the rock surrounding the sides and top of the opening is deprived of its natural support and tends to fall. Whenever caving takes place, the time and extent of the caving depend on the character and condition of the rock. In strong homogenous rock, such as solid granite, even a large chamber may stand indefinitely, whereas a soft material, such as clay or a loose material like unconsolidated sand, falls immediately if not supported. Weaknesses in the rocks induced by structural features, such as joints, :fissures, bedding and cleavage planes, and fractures produced by blasting, will cause the falling of insecure blocks or slabs unless means are provided to support these in place. In an unsupported mine opening, as a tunnel, the first slight settling or adjusting movement of the rocks (the "initial creep" or "set") is caused by the great weight of overlying material pressing down the rock masses above and around the roof and sides of the opening until they key together in roughly the form of an arch. The rock, after it has adjusted itself to this shape, becomes. selfsupporting. Timbering is necessa.ry in all mining only to support, therefore, those comparatively small blocks or pieces of rock which tend to loosen from the top and sides of the opening during or after the formation 'of the natural rock arch, and which lie between this natural rock arch and the opening. This statement, of course, has its limitations. For example; a layer of strong rock, like limestone, may act as a beam; then only the material under the limestone will need support. Timbering is not, as is commonly supposed by the layman, used to supp!ort the huge mass of rock between the back (roof) of an underground opening and the surface. It would be impossible to place enough timbers in a:ny underground opening to support such a mass. This fact is not'·perceived by all miners.

Jan 1, 1923

By Leo A. Schrider

This report analyzes the successful low-pressure gas drive in the Keener sand of the Bonds Creek oilfield, Pleasants and Ritchie Counties, W. Va.) and predicts its future performance. Core analysis from two wells and electrical and radioactivity logs were used to evaluate the reservoir characteristics. Production records over a 37-year period indicate that over 240,000 barrels of oil have been produced from the Keener sand by low-pressure gas injection. Decline-curve analysis shows that 165,000 additional barrels should be recovered from 108 acres of productive sand by continuing this secondary-recovery method.

Jan 1, 1966

By William W. Adams

A general increase in employment prevailed in the stone-quarrying industry of the United States during 1941 compared with 1940. Likewise, more accidents occurred to men working in and about the quarries, with the result that the accident-frequency rate for the industry as a whole was higher in 1941 than in the previous year. Reports from operating companies to the Bureau of Mines, covering open and underground quarries, as well as rock-crushing and rock-dressing plants, cement mills, and limekilns at or near the quarries, showed a total of 86,123 men employed and a total of more than 22 million man-days of labor performed during 1941. The total working time of the industry averaged 260 days per man. Measured in man-hours, the volume of work equaled 173 million, an average of 2,011 man-hours per employee.

Jan 1, 1943

In 2007, a total of 278 metal mining operations reported employment to the Mine Safety and Health Administration (MSHA).1 Metal mines were the smallest mining commodity sector, comprising 1.9% of all mining operations. ? Gold mines comprised 44.6% (n=124) of all metal mining operations. Other common types of metal mines were iron ore (n=36; 12.9%) and copper ore (n=35; 12.6%). ? Nevada had the largest number of metal mines (n=45; 16.2%), followed by Alaska (n=28; 10.1%).

Aug 1, 2009

By R. Havens

During investigations of the occurrence of manganese in the western United States in the early 1940?s, examining engineers of the Bureau of Mines collected samples from seven claims and mines in southern Arizona. For convenience in reporting the results, the work on the properties is grouped in three districts. As the ores were too low grade to be acceptable to producers of ferromanganese, beneficiation studies were made to determine the amenability of the ores to concentration. The San Fernando group is about 10.5 miles south of Patagonia in the Harshaw mining district. G. T. Humphries and D. Alonso held an option on the property, which was owned by H. Bender. Two samples were taken; 1 was a picked sample and the other a representative sample of ore as exposed in the mine.

Jan 1, 1954

By R. W. Dalzell

The performance characteristics, efficiency, and operating pressure of jute line-brattice systems were studied under varying underground conditions; various fabric grades and installation methods were used. The test results indicate that line-brattice system efficiency is dependent upon the method of ventilation the method of installation, porosity of fabric, and size of tight rib area.

Jan 1, 1966

By A. T. Tye

This paper describing the concentrator practice of the Cananea Consolidated Copper Co. at Cananea, Sonora, Mexico, is one of a series of articles on milling methods and costs being prepared by the U. S. Bureau of Mines. The Cananea concentrator treats 2,400 tons of copper ore per day by preferential flotation, whereby the copper sulphides are floated and the iron pyrite depressed. During the first half of the year 1929 the heads to the concentrator averaged 3.29 per cent of copper, the recovery was 95.74 per cent of the total copper, and the concentrates produced contained 21.44 per cent of copper.

Jan 1, 1930