Search Documents

By Trevor R. Ellis

"The valuation of mineral properties in the U.S. is only partially regulated. The regulations which have jurisdiction or impact appear to have such mainly as a consequence of unintended fallout, since the regulations were designed for other purposes. Court case history can also be important. The combined results are a mixture of bad and good, with important lessons to be learned.Since 1981, the Securities and Exchange Commission has prohibited U.S. listed companies from reporting quantitative estimates of mineralization and the value of mineralization, other than proven and probable reserves. This results in the minerals appraiser (valuator) working with a shortage of data in his everyday work, both on the subject property and in sales analysis.Between 1989 and 1995, all 50 states and essentially all Federal agencies adopted the Uniform Standards of Professional Appraisal Practice (USPAP) for real property appraisals (valuations). The major national appraisal societies also require their members to abide by USPAP. A significant portion of minerals appraisals must now follow these standards. This paper will discuss the content of USPAP. It provides a very good framework for the valuation of a minerals property or a mine, both as real property and as a business. However, the credentialing standards for real property appraisers are now prohibitive for minerals appraisers."

Jan 1, 2003

By Harry Siewert, Tom Milner, Jack Stickney

"LocationThe Gibraltar mine is located in central British Columbia (NTS 93B/9W), 362 km north of Vancouver. Access is provided by 20 km of paved road from McLeese Lake, which lies 45 km north of Williams Lake on Highway 97. Latitude and longitude of the mine are 52° 30' and 122° 16', respectively.The total area of the McLeese Lake site is approximately 1700 ha (4200 acres). This includes the orebodies, dumps, surface drainage collection system, plant site, roads and tailings ponds.Brief Description of OperationOre is mined by open pit methods and is concentrated using conventional crushing, grinding and flotation processes. Copper and molybdenum flotation occurs at an average rate of 40 000 tons per day. Tailing is discharged to an impoundment area and the water recycled as process water. Additional copper is extracted from the waste dumps using sulphuric acid as a leach solution followed by solvent extraction and electrowinning.HistoryExploration by Gibraltar began in 1964, continuing until late 1970, at which time it was announced that the property would go into production. Construction started in early 1971, with initial production in March 1972. Target capacity of 30 000 tons per day was achieved by the end of March and is currently at 40 000 tons per day.Ore reserves as of January 1, 1998 were 184 384 000 tons grading 0.31% Cu and 0.010% MoS2."

Jan 1, 2000

Building off the enthusiasm generated by Credit Suisse First Boston on the potential benefits of an industry-wide effort to market gold jewellery, a group of gold producers, led by Randall Oliphant, CEO of Barrick Gold, decides to investigate the long -term impact of launching a significant marketing initiative to stimulate demand for gold jewellery. The group establishes an international Steering Committee representing producers of differing sizes, members and non-members of the World Gold Council. This Committee comprises representatives from AngloGold, Barrick, Gympie Gold, Kinross, Randgold, and Sons of Gwalia and is supported by the Australian Gold Council, the Gold and Silver Institute, and CSFB. The Steering Committee hires McKinsey to assist it by conducting an independent review of whether investment in a large-scale marketing initiative for gold jewellery would be effective in increasing demand for gold, and ultimately of significant economic benefit of the gold industry. Based on McKinsey?s review* and its own discussions with key stakeholders across the industry, the Steering Committee strongly believes the case for marketing is compelling and sufficiently proven to persuade the industry to undertake a major initiative over the next few years. The Steering Committee, supported by McKinsey, conducts briefings with a range of gold producers to share its findings and to understand producers? perspectives on an industry-funded marketing campaign. The Steering Committee is asking for your support to bring this industry-funded marketing campaign to life.

May 1, 2002

Automation Defined ?Using self-operating equipment to reduce human exposure to the mining environment and routine or repetitive work.?-Atlas Copco Terminology: ?Manual Operation ?A vehicle being operated by a person ?in the cab?. ?Radio Remote Control (RRC) ?A vehicle being physically operated by a person through a Line Of Sight (LOS) or Video-Remote equipment. ?Tele-Remote Control ?A vehicle being physically operated by a person at an operator station which is not necessarily located near the vehicle?s working area. ?Autonomous Operation ?A vehicle under self control with the possibility of human supervision and override.

Oct 1, 2010

By Thomas. Lisa, Mark Coleman

Schenck Process is an established customer-driven solutions provider, utilising its knowledge, expertise and technologies to transform production processes. Operating across several industries Schenck Process have developed quality solutions from their range of equipment to solve problems and fill holes in other people’s processes. In the non-ferrous metals industries Schenck Process have been using their Clyde Brand solutions in Pneumatic Transport to solve problems on smelter sites for a number of years, handling of concentrates, additives and metallurgical dusts. Working alongside clients around the world they have developed a number of dust handling systems for flash furnaces from New Boliden, through Codelco to PASAR. Solving handling issues in dust collection has proved to suit Schenck Process range of equipment well and now a series of solutions are available. Solutions have been developed to handle materials up to 600°C and can convey over 1 km. Conveying to remote location for disposal, injecting directly into a furnace through lances, return to furnace burner feed, or deliver and dose into leaching reactors, Schenck Process are ready to ‘make processes work’. Historic solutions at New Boliden and Codelco demonstrate a range of material application and the long term performance of the equipment. Recent installations at Pasar utilise the Schenck new ProPhaseTM equipment and handle the Waste Heat Boiler and ESP dusts directly and simplify the dust train. The paper will seek to show how this equipment can bring benefit in handling high temperature materials directly and eliminate several traditional steps that are often unreliable. The systems can be paired with Schenck Process new PHASiQTM and STREAMiQTM control systems which are complete PC, HMI, PLC, Interface system with full SCADA, Data Storage and IoT ready remote interrogation and support available. Installed in this challenging environment the systems are ready for smelter use. The systems can be also joined to our new E-nizingTM web portal. A perfect partnership to deliver the trend in ‘Big Data’ while providing visibility and off site support. The paper will show how these systems can deliver reliable equipment and remote support for these often isolated sites as well as delivering rapid return on investment. This paper discusses a step change in simplifying Flash Furnace Dust handling which Schenck believes shows the truth of Schenck Process Solutions claim that ‘we make processes work’.

Jan 1, 2019

By S. W. Marcuson

In the late 1960's concerns about the natural environment reached high levels within North America and provided activists with suitable platforms for exerting influence over the general public and politicians. In response a host of regulatory mechanisms were developed, statutes, voluntary measures, land grants, codes of practices etc. Emerging environmental awareness from the era provided impetus for rapid technological change that encompassed all industries, especially the base metal business. The resulting clean up impacted all aspects of copper production, dealing with issues such as waste disposal, water and air quality with specific impact on emissions of sulfur dioxide and particulate. This paper provides a perspective of these changes reviewing the macro-economic impact of environmental movement in mining with its specific implications to the copper smelting industry. The fundamental challenges that were faced by the old, but capital-intensive North American plants and the approaches taken to deal with the changing times are reviewed with special emphasis on the conceptual approach to smelter S02 abatement and different paths taken in the USA and Canada. The role of economics, sustainable R&D and presence of technical infrastructure that facilitated the change process is elucidated, and speculations are made about the future state of pyrometallurgy and the natural environment. Cu2007 -

Jan 1, 2007

By Beaumier. M., J. -P. Lalonde

"Les réultats obtenus dans les sols sur quatorze aires d'essai et six cheminements régionaux dans I'A bitibi-Témiscamingue indiquent clairement qu'il existe des variations régionales importantes dans les teneurs en éléments traces de l'horizon A1 formé sur l’épais recouvrement glacio-lacustre de cette région. Les anomalies obtenues correspondent à celles qui ont été décelées lors de précédents levés des eaux souterraines et du till de base.Selon les critères d'évaluation utilisés, treize des quatorze aires d'essai ressortent comme anomales dans Ie contexte abitibien; dix de celles-ci sont tres anomales. Ceci suggère fortement qu'un levé régional de sols, fondé sur une approche multi-éléments, identifierait entre 70 et 90 % des cibles géochimiques reconnues par des échantillonnages en profondeur. Les résultats d'un échantillonnage systématique effectué sur une région de 1000km2 viennent aussi appuyer cette hypothèse. Conséquemment, les sols formes sur les sédiments glacio-lacustres sont un médium très utile pour inventorier de grandes regions recouvertes par ce typ e de sédiments.L 'horizon A1 est Ie plus utile pour ce type de levé parce qu'i1 est facil e d échantillonner, qu 'it assure une plus grande constance du typ e de matériel échantillonne et qu'il contient des teneurs accrues.De multiples mécanismes de dispersion géochimique ont joué des rôles d 'importance variable pendant et après la mise en place des sédiments glacio-Iacustres. Les plus importants sont la pression hydrostatique, la diffusion chimique et électrochimique ainsi que la bio-accumulation. Si on veut progresser dans la connaissance de ce milieu complexe, on devra adopter une approche plus systemique tenant compte de I'interaction des mécanismes agissant dans l'environnement global avant, durant et apres Ie depôt du mort-terrain."

Jan 1, 1984

By M. Vallée, J. -P. Charette, D. P. Gold

"The Oka Carbonatite and Alkaline Complex is a Lower Cretaceous intrusive body of the Monteregian petrographic province. Carbonate rocks of various types, and associated alkaline rocks of the ijolite and okaite suites, are distributed in a double ring-dyke structure 4 Yi miles long by 1 1/2 miles across. Alnoite and alrioite breccia pipes intrude all rocks of the Complex and indicate, from inclusions, that a cover of Palaeozoic rocks existed at the time of emplacement.The results of radiometric, magnetic and gravity surveys of the Complex are compiled and discussed both with respect to the regional pattern and, locally, the bed-rock geology. The Complex is characterized by high-intensity anomalies.Exploration activities started during 1953, and mining operations began in 1961 on the property of St. Lawrence Columbium and Metals Corporation, at one time the world's largest producer of niobium concentrates. Because of the boudinaged and fractured nature of many of the rocks and the variability in grade of the ore minerals, the role of the mining geologist is both demanding and exacting. Rock types are varied and their mutual relation-ships ambiguous, the minerals are rare and complex, and close geological control of the ore is needed in the mine and in the mill. Closely spaced diamond drill holes are needed for mining control, and the ore-waste contact is defined mainly by assay results.In the exploration for 'carbonatites' in Eastern Canada, aeromagnetic surveys are judged to be the best exploration tool, followed in decreasing order by the search for circular structures on aerial photographs, regional gravity surveys and radiometric surveys."

Jan 1, 1967

By T. Skinner, M. Sahebkar

"In recent years, the mining industry has been inundated with new technologies and software systems to aid in productivity improvement. Accompanying this increased level of technology and computer systems has been the exponential growth in data sources and sinks for all aspects of a mining operation. This rapid growth in data and technology has evolved through vendor “push” approaches and user “pull” scenarios, the result of which has been that currently, no standards exist defining how data from new technology should be accessed and transferred from surface mining equipment and systems. Consequently, many incremental benefits of the systems have not been realized. This paper will present a discussion of this important issue and introduce a new committee formed to address standards to assist the industry in making effective use of current and future technology. Potential benefits accruing from the development of these standards will be illustrated through the use of a case study at Fording Coal Limited. IntroductionThe mining industry is currently faced with a rapid evolution in the computing-based systems capabilities of mobile production equipment. At the same time, there is a trend toward the introduction of even larger machines, with novel designs or incorporation of new technologies within existing designs. Computing and control technology will be required to operate and acquire knowledge about equipment operation, utilization, and performance. Such knowledge has the potential to lead to enhanced equipment design, more appropriate equipment selection, and optimized equipment performance. The equipment systems will be required to be integrated with mine production monitoring systems, maintenance management software, and a wealth of other information systems to provide a complete understanding of the effects of various factors such as maintenance, equipment design and production on economics (Roman and Daneshmend, 2001). This will lead to a better understanding and implementation of the opportunities to enhance the performance of the mine through interaction of the mine operations."

Jan 1, 2003

By Pierre Sauvé, Alex Makila

"The Camflo stock of porphyritic quartz syenite is an irregular pipe-like body 200 metres in diameter injected along the axial plane of an E-W trending F2 fold, near the contact between the. Kewagama and Malartic groups. The stock plunges 55° to the NE, almost parallel to the fold axis. The stock, exhibiting pervasive, weak cataclasis with numerous, locally auriferous quartz veinlets, is cut by minor faults striking WNW and dipping about 45°NE.Two types of gold ore are distinguished at Camflo: ""porphyry"" ore and ""fault zone"" ore. ""Porphyry"" ore, accounting for 90% of the gold produced, forms wide zones within the stock. The zones are irregular in shape but tend to be oriented E-W in plan view (on a horizontal plane) and are elongated paraliel to the plunge of the stock. These zones are more abundant in the northern part of the stock. Differences between ore and barren porphyry are not obvious. ""Fault zone"" ore occurs outside the stock along minor faults, particularly in differentiated sills offer rodiorite and felsic granophyre. Gold grade is roughly proportional to the pyrite content which in turns depends in part on the original magnetite content of the host rock. Although both types of ore show some correlation between Au and S, the Au/S ratio is considerably higher in porphyry ore.The bulk of the gold is in quartz syenite and in felsic granophyre, the most brittle lithologies at the mine. Presumably, the vertically continuous, pipe-like stock, made up of shattered rock, provided the main channelway for the ascending mineralizing solutions."

Jan 1, 1990

By C. H. Hopper

THE gold orebodies of the Matachewan Consolidated mine are of particular interest geologically because of their odd shapes, their apparent lack of connection one with another, and the fact that they occur in a number of different formations. All of the orebodies exhibit a similar fracture pattern and the areas of fracturing appear related to the local folding. However, the lack of either horizontal or vertical continuity suggests additional controls not yet discovered. The question of origin, so ably discussed by H. C. Cooke in 1919, will be reviewed in the light of the additional evidence uncovered since his examination of surface trenches twenty-four years ago. The Matachewan Consolidated mine, with its neighbour, the Young-Davidson mine, is in Powell township, 25 miles by road northwest from Elk Lake, 30 miles west of Kirkland Lake, and 45 miles southeast of Porcupine. It may be considered as being on the westerly extension of the Kirk-land Lake sedimentary belt, where the rock column is markedly similar. There is no similarity in structure, however, for great ore-bearing shears and faults simply do not occur at Matachewan. Rather may it be said that the region, under stress, failed in isolated brecciated patches, some of which make up today's orebodies. The mine currently treats 1,000 tons a day of porphyry ore averaging 0.10 oz. gold per ton. It started operations in 1934 on greenstone ore, and the mill then treated 150 tons a day of ore averaging 0.23 oz. gold per ton. Total production to the end of 1941 has been 929,484 .tons averaging 0.160 oz. gold per ton.

Jan 1, 1942

By J. A. Finch

"Gas dispersion in flotation defines the efficiency of the process once the chemistry has been established. There are three measurements, superficial gas velocity, gas holdup, and bubble size, which along with the derived quantity bubble surface area flux, are used to define “gas dispersion.” Sensors for measuring gas dispersion in industrial machines have been developed. This communication describes the working principle of the techniques and illustrates their potential to detect problems and to improve the operation of individual cells, banks and circuits. IntroductionFlotation is the most widely used process to separate minerals and is finding increasing application in other chemical and environmental fields. The process exploits natural and induced hydrophobicity to collect selected particles on the surface of a bubble. Once the process chemistry to control hydrophobicity has been established, the efficiency depends on dispersion of air to generate the necessary bubble surface area. Bubble surface area flux, Sb, the interfacial area generated per unit time and unit area of the machine, is emerging as one of the most useful variables to quantify gas dispersion (Gorain et al., 1997, 1998) although not without its critics (Heiskenan et al., 2001).For a bubble population of mean size db at a superficial gas velocity (or rate) Jg, the bubble surface area flux can be derived from geometric considerations (Finch et al., 1999):"

Jan 1, 2002

By Marcel Vallee, Fernand Dubuc

"The St-Honoré carbonatite complex, located 8 miles north of Chicoutimi, Quebec, was discovered in September 1967 as abnormal radioactivity was detected in the course of SOQUEM's aerial surveys. The complex, covered by a shallow layer of Trenton limestone, has been explored by aeromagnetic, ground gravimetric and magnetic surveys, and 12,013 feet of diamond drilling. Its age, from potassium-argon dating, is 650 million years. The carbonatite is approximately kidney-shaped and has a surface area of 6 square miles, 20 per cent of which is explored. It shows a central core of coarse-grained massive dolomitic carbonatite and an outer ring of foliated dolomitic carbonatite.The exploration work to date has resulted in the discovery, in the foliated carbonatite, of an incompletely drilled niobium (columbium) zone of pyrochlore-bearing carbonatite, at least 1,000 by 800 feet in size. This zone contains 5,000 tons per vertical foot grading 0.86 per cent Nb205 or at least 15,000 tons per vertical foot grading 0.66 per cent Nb205 or 45,000 tons grading 0.48 per cent Nb20s. The pyrochlore contains an average of 64 per cent Nb,Os. The central core contains a zone of rare-earth-bearing carbonatite (as monazite), grading up to 4.5 per cent rare-earth oxide, 3,500 ppm zinc and 290 ppm molybdenum. Stocks of nepheline syenite and magnetite diorite accompany the carbonatite. The total analysis and trace-element contents of typical rocks are presented."

Jan 1, 1970

By I. R. Muirhead, S. Frimpong

"The mechanization of mining operations in underground coal mines has led to faster cutting rates of coalfaces with increased levels of emission of gaseous and particulate contaminants in the workings. Consequently, the fresh air streams from the main ventilation systems reaching distant workings are often insufficient, ineffective or inadequate and have to be supplemented by auxiliary ventilation systems to create and maintain the required working environments underground. The efficiencies of auxiliary ventilation systems are largely affected by drivers of the system such as the type and capacity of the fan; the type, length, diameter and condition of the ventilation ducting and the distance from the discharge end of the intake ducting to the face. Traditionally, single point measurements of methane gas concentrations using either flame safety lamps or hand-held measuring instruments have been used to assess how safe underground coal workings were. Unfortunately, such occasional measurements of methane gas concentrations do not give an accurate picture of the real gas concentration in the working as they are often taken from the easily accessible locations in working. Continuous monitoring of the methane gas concentration in development headings enables a better assessment of the environmental conditions prevailing there. All variations in the methane concentrations are more easily captured on a continuous monitoring basis than by instantaneous single point measurements. The approach adopted in this work was to continuously monitor the concentration of methane very close to the face and about 60 m outbye in development headings, observe the types of auxiliary ventilation equipment and their sizes being used in the working as well as noting the lengths from the discharge ends of the forcing and exhaust ductings to the face.In this paper, empirical methods are used to calculate the mean efficiencies of the auxiliary ventilation systems in selected development headings in coal mines in North America. This enables the assessment of the effectiveness of the auxiliary ventilation systems and the identification of the system drivers in them. The results show that the efficiencies of the forcing systems ranged from 17.02% to 96.81% while the efficiencies of the overall systems varied from 6.04% to 54.16%. The distance from the discharge end of the intake ducting to the face appeared to be the strongest driver in the performance of the auxiliary ventilation systems studied. It was also noted that when the discharge end of the intake ducting to the face does not exceed 7 m, there were faster purging rates of methane at the face and the efficiencies of the overall auxiliary ventilation system were greater than 50%. These findings are very important in underground coal mining in North America as they will assist to avert calamities, such as the Westray coal mine disaster in 1992 which resulted from the explosion of methane gas, by identifying which components of the ventilation system need special attention to create safe working conditions underground."

Jan 1, 2003

By P. Curry, H. G. Stephenson, B. Van Den Bussche

"Three Sisters Resorts Inc. currently owns a2035 acre (824 ha) parcel of land, which previously belonged to Canmore Mines Ltd. Approximately 50% of these lands, that are slated for residential, resort and recreation development, have been undermined for coal in one or more seams.Norwest Mine Services has been contracted by the developer to assess and advise them on any past mining activity that may be potentially hazardous to their development and offer solutions to how these hazards may be mitigated or avoided.The following paper deals mainly with the procedures put in place and accepted by the approval authorities, and the Staged approach to the Investigative Procedure that Norwest follows in the mining assessment and mitigation work for Three Sisters."

Jan 1, 1996

By B. Samanta

Abstract - Ore reserve estimation, based on sparse drill hole data, was conducted for a placer gold property in Nome, Alaska. A problem with sparse data is that random subdivision of the data into modelling and evaluation subsets (as is commonly done) becomes a problem, as random selection may result in biased/skewed subsets. Therefore, a technique that combined data segmentation with genetic algorithms (GA) was applied to divide the samples into three equivalent subsets: training, validation and testing. Data segmentation was done on the basis of the distribution of gold values. Neural network and a variety of kriging techniques were used to estimate gold grades. A multi-layer feed forward neural network along with "early/quick stop" training was used for neural network modelling. A comparative evaluation of kriging and neural network methods was then performed. The results revealed that neural network was generally superior to the kriging techniques for gold grade estimation in the Nome deposit.

Jan 1, 2002

By R. H. Chambers, L. Alderman

"The paper is introduced by an examination of the factors which have led to the present world-wide interest in charging preheated coal to coke ovens. Various possible methods of preheating and charging the coal are considered and reasons are given for the adoption of the methods chosen. The design of the pilot preheating plant for the British Coke Research Association is discussed and its influence on the design of the commercial units for the South African Iron and Steel Corporation's plant at Pretoria and the British Steel Corporation's plant at Beighton are explained. Operating procedures on the pilot plant are described, particularly with regard to the charging of the preheated coal. Design features of the commercial installations, engineered by Simon-Carves Ltd., are explained with emphasis on the built-in safety of the control system of the preheating plant, and the particular problems associated with the erection of such plants on working coke oven batteries. Commissioning and operating procedures are described and the problems associated with the integration of the preheating plant into the normal pushing schedule of the plant are discussed. Preliminary operating results with regard to the effect of preheating on coal throughput on the commercial plants and on the properties of the coke produced are given."

Jan 1, 1972

By K. C. Sole, G. Robinson, M. S. Moats, W. G. Davenport, S. Sandoval

Global practice in hydrometallurgical production of copper cathode by electrowinning is reviewed, based on individual plant operating data for 2018. Data from 29 plants were collected, representing 38% of world cathode copper production. Similar surveys were carried out in 1997, 1999, 2003, 2007, and 2013. This survey includes analysis of historical and current data. Evolving trends in operating conditions and performance, as well as equipment design and process technology choices, are analysed and differences in operating practices with location are assessed. Examples of recent technology and operational choices to increase productivity, improve copper quality, and decrease electrical energy consumption are discussed. Significant project expansions, particularly in Africa, and the consolidation of numerous small Chinese operations are also presented. INTRODUCTION Global trends and operating practices in copper electrowinning (EW) in 2018 are reviewed and evaluated. Similar world and African surveys were carried out in 1997, 1999, 2001, 2002, 2003, 2007, and 2013 (Robinson, Davenport, & Jenkins, 1997; Jenkins, Davenport, Kennedy, & Robinson, 1999; Davenport, Jenkins, Robinson, & Karcas, 2001; Robinson, Garbutt, & Davenport, 2002; Robinson, Davenport, Jenkins, King, & Rasmussen, 2003; Robinson, Davenport, Moats, Karcas, & Demetrio, 2007; Robinson, Sole, Sandoval, Moats, Siegmund, & Davenport, 2013). Contributing operations included sites from the USA and Mexico (9), Chile and Peru (6), Laos (1), Kazakhstan (1), and Africa (9). Despite fewer contributions compared with past experience, this survey nevertheless represents 2018 copper EW cathode production of 1.76 Mt, or about 38% of world production of 4.64 Mt (International Copper Study Group, 2017). This drop in permission to contribute is attributed to the more competitive nature of the industry and unprecedented production pressures; furthermore, several operations in Australia have shut down, while large operations that are currently commissioning or ramping up to full production in Africa and Asia declined to participate. Of the Chinese operations, which represent an increasingly important proportion of global electrowon cathode copper, particularly in Africa, only Tenke Fungurume (Democratic Republic of Congo; DRC) participated in this survey.

Jan 1, 2019

By Ron Light, Doug Applett

"HistoryThe Nanisivik mine began operation in October 1976 as the world's most northerly metal mine and the first permanent industrial project in the Canadian High Arctic. Located 700 km north of the Arctic Circle on Baffin Island's Strathcona Sound, exploration by Texasgulf Inc. between 1957 and 1970 had outlined the ore deposit. In 1974, Nanisivik Mines Ltd. was formed with Mineral Resources International, the Government of Canada, Metallgesellschaft and Billiton being shareholders, and Strathcona Mineral Services Ltd. providing project management. In 1996, Breakwater Resources purchased the mine from Alberta Energy Corporation Limited which had recently acquired the assets of then owners Conwest Exploration Ltd.Ore DepositThe main ore deposit is very flat, approximately 80 m in width and varying in thickness from 3 m to 16 m. The length of the deposit is approximately 3000 m with satellite zones located on the perimeter of the main zone. The economic mineralization is sphalerite with minor galena and silver. The sphalerite and galena are coarse grained and associated with pyrite as the main gangue component with minor inclusions pf dolomite and calcite within the deposit. The deposit being hosted in a permafi·ost environment creates a number of challenges. Dry drilling is employed in room and pillar production drilling. The permafrost aids in the stability of both the pillars and the back."

Jan 1, 2000

By Manjeet Chowdhry, Qingxia Liu, Phillip Choi, Zhenghe Xu

Computational chemistry methods, such as density functional theory (DFT), are powerful tools to quantify reagent-mineral interactions encountered in sulphide mineral flotation. A quantitative relationship between theoretically calculated parameters based on chemical structure of collectors and their reactivity with different metals/minerals can provide valuable insights for design and development of more powerful and tailor-made reagents offering enhanced metal/mineral selectivity. DFT calculations at B3LYP/6-311++G(3df,3pd) level were employed to elucidate the reactivity of neutral sulphide collector reagents, including thionocarbamates (TC), thioureas (TU), xanthogen-formates (XF), dialkyldithiocarbamates (DTC) and dialkyltrithiocarbonates (TTC) with different heavy metal ions (Cu2+, Zn2+ and Pb2+) in solution. The extent of delocalization of lone pair electrons of heteroatoms (attached directly to C in C=S) over C=S group was found to be the dominant factor in determining the collector’s reactivity. Order of reactivity was established as: TU > TC > XF > DTC > TTC. All the collectors showed superior affinity towards copper followed by lead. Unidentate binding was observed through sulphur atom except for xanthogen-formate for which bidentate binding mode was observed. Effect of nature of substituent groups at N and/or O atom on reactivity of thionocarbamate and thiourea was also investigated. The results obtained through DFT calculations are consistent with the experimental data reported in literature.

Jan 1, 2015