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By Conné Spangenberg

Contents ?Introduction ?Metal accounting environment ?Problem statement ?Investigations & Achievements ?Metal Accounting ?Principles ?Standards ?Audits ?Questions

Jan 1, 2005

By Peter L. McSwiggen

The mineralogy of the Biwabik Iron Formation changes dramatically from west to east as the formation nears the basal contact of the Duluth Complex. This reflects a contact metamorphism that took place with the emplacement of the igneous Duluth Complex at tem¬peratures as high as 1200 °C. However, the mineralogy of the Biwabik Iron Formation also varies vertically through the stratigraphy of the unit. This variability in both the vertical and horizontal dimensions makes it difficult to predict exact horizons where specific minerals will occur. The iron-formation has been subdivided into four broad stratigraphic units (lower cherty, lower slaty, upper cherty, and upper slaty) and into four lateral mineralogical zones (1-4). Zone 1, the westernmost zone, is characterized by quartz, magnetite, hematite, carbonates, talc, chamosite, greenalite, minnesotaite, and stilpnomelane. The silicate mineralogy in Zone 2 of the Biwabik Iron Forma¬tion changes very little. However, the minerals begin to change dramatically in Zone 3. Most significantly, Zone 3 is characterized by the appearance of grunerite in both a tabular form and a fibrous form. In Zone 4, the original silicate minerals have completely reacted, and a new suite of minerals occupies the iron-formation. These include grunerite, hornblende, hedenbergite, ferrohypersthene (ferrosilite), and fayalite.

Jan 1, 2007

Upon cessation of mining activity open-cast mine pits typically fill with water, forming a æpit-lakeÆ. The water in these lakes, in some instances, contains high concentrations of ædeleteriousÆ material. Containment and/or dilution typically requires an understanding of how stratification in the pit-lake will develop over a long timescale (say 100 years). Vastly different transport rates can develop due to differing hydrogeochemistry, basin morphology and climate. Numerical (computer) modelling is the most likely approach for successful prediction over long times. While lake modelling tools are available, useful numerical modelling requires improved understanding of transport in such systems because they are different to natural lakes in a number of ways. Notwithstanding the effort required to improve our understanding, the modelling provide a means of testing approaches to active management of pit-lakes.

Jan 1, 2002

A Good Product Range - So What! While in terms of water, waste management and environment protectrion, the Gippsland Basin may appear to have a good product range, what does this really mean? What it means is that, like any product range, the virtues of the product range must be sold and accepted by a majority of the public. The social, economic and environmental benefits of any enterprise using these products must be sold and accepted by the regional population. Many a budding entrepreneur has failed because he assumed that the public would accept his product, so good did it appear to be! However, we know that such an assumption must be avoided and that a great deal of time and effort needs to be invested in promoting and gaining acceptance of a product to ensure a long term and viable market.

Jan 1, 1992

By T. K. Perkins, L. R. Kern, R. E. Wyant

Many factors influence the results of hydraulic fracturing to stimulate well productivity. Most of these factors have been studied and their effects discussed in the literature. However, the movement of sand through the crack during fracturing has received little consideration. Exactly where the sand goes in the fracture, how it gets there, and how this might influence results have not been studied, judging from published reports. To get an answer to some of these questions we have studied sand movement through a simulated crack segment in the laboratory. Although the work is preliminary, we have answered some questions about sand movement in a semiquantitative sense. We are reporting our results at this time in the hope of stimulating interest and further study in this important aspect of fracturing. LABORATORY EXPERIMENTS Fig. 1 is a schematic diagram of equipment used in this study. A segment of a vertical crack 0.25-in. wide was formed between two Plexiglas plates, and movement of sand in fluid through the crack was observed under various conditions. Sand and fluid were injected into the crack at constant rates. The top and bottom of the crack were closed so that the fluid flowed horizontally. Because of gravity most of the sand settled to the bottom before moving very far through the crack. If the fluid velocity exceeded a certain critical value, then all the sand injected was washed on through the crack even though it had settled to the bottom. When the fluid velocity was less than this value when sand injection was started, most of the sand which settled in the crack remained in place until enough of the area open to fluid flow was blocked by the settled sand to increase the fluid velocity to the critical value.. At this point all injected sand moved on through the crack even though it settled to the lower portion of the moving fluid section. All sand previously settled remained in place. When fluid velocity was increased at this paint by increasing fluid injection rate (without also increasing sand injection rate), some of the previously settled sand was washed out until enough area was open to flow that the velocity dropped to the critical value. Conversely, when the fluid velocity was decreased by decreasing the fluid injection rate (without changing the rate of sand injection), additional sand would settle until the critical velocity was again attained. In short, the critical velocity is an equilibrium value which the system will automatically seek, if possible. The equilibrium (or critical) velocity was measured under several conditions. The results of these measurements are shown in Pig. 2 where the equilibrium velocity is shown as a function of the amount of sand injected per minute. The points falling in the shaded band shown in Fig. 2 were obtained with water. The higher viscosities were obtained by adding CMC (carboxymethylcellu-lose). Data indicate that the equilibrium velocity is not very sensitive to sand size or transport fluid viscosity, or to sand injection rate (except at very low rates). Points connected by the solid CUrve in Fig. 2 were obtained with water and 20- to 40-mesh steel shot. The equilibrium velocity is apparently fairly sensitive to difference in density between particle and fluid. Only one run was made with a gelled fluid and that was gelled water at zero sand injection rate as shown in Fig. 2. (Measurements of equilibrium velocity at zero sand injection rate were made by filling the crack

By Peter L. McSwiggen

The mineralogy of the Biwabik Iron Formation changes dramatically from west to east as the formation nears the basal contact of the Duluth Complex. This reflects a contact metamorphism that took place with the emplacement of the igneous Duluth Complex at temperatures as high as 1200 °C. However, the mineralogy of the Biwabik Iron Formation also varies vertically through the stratigraphy of the unit. This variability in both the vertical and horizontal dimensions makes it difficult to predict exact horizons where specific minerals will occur. The iron-formation has been subdivided into four broad stratigraphic units (lower cherty, lower slaty, upper cherty, and upper slaty) and into four lateral mineralogical zones (1-4). Zone 1, the westernmost zone, is characterized by quartz, magnetite, hematite, carbonates, talc, chamosite, greenalite, minnesotaite, and stilpnomelane. The silicate mineralogy in Zone 2 of the Biwabik Iron Formation changes very little. However, the minerals begin to change dramatically in Zone 3. Most significantly, Zone 3 is characterized by the appearance of grunerite in both a tabular form and a fibrous form. In Zone 4, the original silicate minerals have completely reacted, and a new suite of minerals occupies the iron-formation. These include grunerite, hornblende, hedenbergite, ferrohypersthene (ferrosilite), and fayalite. © 2007 Elsevier Inc. All rights reserved. Keywords: Biwabik Iron Formation; Duluth Complex; Mineralogy

Jan 1, 2007

By R. A. Wood, R. I. Jaffee, H. R. Ogden, D. N. Williams

Strain-induced porosity has been found to occur in titanium and other materials at tensile strains greater than the uniform elongation of the material. Porosity in titanium increases with increasing strain and temperature, being most severe at 300° to 800°F. Strain-induced porosity is believed to be a normal part of the mechanism of deformation in ductile materials. DURING the past few years there have been numerous references to the occurrence of voids in laboratory test specimens of metals subjected to strain.l-7 These voids have been referred to as intercrystalline cracking, strain-induced porosity, intergranular cav-itation, voids, and porosity. They appear to occur at grain boundaries or interfaces, and are generally associated with large amounts of strain and have been found mostly in creep specimens and to a lesser extent in tensile specimens. Because the phenomenon does not occur unless the material has been strained,

Jan 1, 1960

By James A. Schneider

Selection of resistance factors within Load and Resistance Factor Design (LRFD) requires accurate assessment of uncertainty and bias in load and resistance. To date, many studies have focused predominantly on the assessment of uncertainty, while the potential for bias appears to be the dominant factor in design for consistent levels of reliability under a variety of situations. Bias comes from factors which have been ignored in design method development but significantly influence resistance when extrapolating from conditions typical of databases to those at a given site. Uncertainty and bias can be quantified as the coefficient of variation and mean (or median) of a data set, respectively, for statistical assessment of load and resistance factors. This paper first presents an overview of statistical assessment of resistance factors, and then discusses factors that influence uncertainty and bias when extrapolating to situations outside of conventional databases of driven pile axial capacity.

Jan 1, 2009

By Leo J. Neill, O&apos

Abrasives are essential to the manufacture of munitions - airplanes, gas, shells, tanks, and in fact every product that involves metal forming or finishing. An indication of the importance of abrasives in the national defense and aid-to-Britain programs is the close peace-time correlation between demand for abrasives and automobile production, which in recent years has consumed more than 35 percent of the total output of abrasives. Unprecedented demands on the abrasives industry are forecast by the rapid expansion in airplane output, tie increased mechanization of all armed forces, and the consequent speeding up not only of the factories where finished munitions are made but also of the steel mills and other factories were additional large quantities of abrasives are needed for snagging or rough-grinding semifinished products before they can be used by the fabricators. A recent survey by the artificial abrasives manufacturers indicates that they can readily increase their output 75 percent compared with the previous peak of 1937 without building new plants. By overhauling production schedules, their maximum production possible could be increased to 182 percent of the 1937 output, and the nature of the industry is such that plant capacity could be increased rapidly if need therefor should arise. No figures on the estimated requirements for abrasives in 1941 or 1942 have as yet been compiled, but the industry feels that it can meet demands as they develop.

Jan 1, 1941

By F. Petkovich, M. P. Sudbury

Development of a new method of treating flotation concentrates for the preparation of feed suitable for direct charging to blast furnaces or converters is described. The method takes advantage of the fact that pyrrhotite contained in the concentrates can be made to undergo exothermic reactions which, under properly controlled conditions, result information of oxidation products that serve to cement the concentrate particles together. Thus green concentrates either in the form of pellets or briquettes containing 5 to 8 pct moisture not only were hardened, but also completely dried autogenously by continuous countercu,vrent shaft treatment with air. The process was developed through pilot plant operations ranging from 35 1b per hr to 2.5 tph, culminating in products evaluation tests on a railway-car scale. Falconbridge Nickel Mines Ltd., Falconbridge, Ont., have practised sintering, on a travelling grate machine, for many years to prepare a pyr-rhotite-bearing Cu-Ni sulfide flotation concentrate for blast furnace smelting. In recent years the development of new mines, and the construction of concentration plants some 40 miles from the smelter has increased the quantity of concentrate shipped, and encouraged the search for a method of producing dry, hard pellets or briquettes suitable for direct charging to a blast furnace or converter, and capable of withstanding considerable handling. The cementing properties of pyrrhotite oxidation products were discovered during a search for a suitable agglomeration method for sulfide concentrates, and were exploited in a process subsequently developed for autogenously drying and hardening pellets and briquettes of pyrrhotite-bearing Cu-Ni sulfide flotation concentrate. EARLY TEST WORK The production of hard, dry pellets of concentrate filter cake was attempted in the drying plant of one of the new concentrators. While soft pellets were produced containing 5 pct moisture, attempts at further drying resulted in disintegration of the pellets and intolerable dusting. The plant therefore was controlled to produce a concentrate containing about 6 pct moisture. The partially dried concentrate, which was shipped to Falconbridge for sintering, tended to heat spontaneously in transit. An at- tempt to briquette the moist concentrate at Falconbridge, in a plant incorporating a muller, a 20-in. roll briquetting press, and a steam-heated travelling grate oven, was more successful, although the equipment corroded rapidly due to the acid nature of the concentrate after spontaneous heating had occurred. LABORATORY STUDIES OF SPONTANEOUS HEATING OF CONCENTRATE The spontaneous heating of partially dried concentrate was studied in the laboratory. Moist concen-

Jan 1, 1961

A poured slag bottom is universally considered to be the best type bottom for copper reverberatory furnaces. It is impervious to molten matte and ready for immediate use.When molten slag is not available a monolithic silica bottom is the second best; such a bottom has been adopted at Mount Morgan. The laying of such a bottom is a phase of smelter construction on which so little real information is obtainable that a day to day record of such a recent example as Mt. Morgan's 19 ft. x 40 ft. reverberatory may be of interest. The work was done under the direction of E. Pesout, of McGill Smelter, Nevada. PREPARATION OF THE BOTTOMA 26-inch bed of closely packed firebrick with sand-filled joints was first laid on the clean, dry concrete foundation and the whole dried out by small fires maintained on the brickwork for several days. Ninety tons of silica sand was meantime thoroughly dried and stored in clean drums. This sand must be low in FeO and CaO and contain about 95% Si02 , the majority of which should be present as tridymite. This form of silica shows little expansion at high temperatures, for it is the form stable between 870° and 1470° C.Its presence thus minimises disturbance to the bottom by the expansion which, during the burning in, would mark the transformation of quartz to tridymite.

Jan 1, 1939

By Frank E. Chase, John L. Ellenberger, Christopher Mark

The nature of competition in the coal market tends to deplete the most favorable coal reserves first, and forces subsequent development of mines in more extreme ground conditions such as those associated with multiple-seam mining. In fact, 70% of the United States coal reserves are in multiple-seam situations. The National Institute for Occupational Safety and Health (NIOSH) is conducting research to develop mine design algorithms that will result in safer multiple seam mines. This paper presents an overview of multiple seam issues in the central Appalachian coalfields. To date, more than 50 case histories have been analyzed from 20 operating mines in Eastern KY, Western VA, and Southern WV. Each case history is classified according to the degree of multiple-seam interaction, ranging from no apparent interaction to severe interaction with direct impacts on mine safety and resource recovery. The case histories are also examined with regard to amount and geologic characteristics of interburden and overburden, and design stability factors. The sequence of mining has also been found to be critical when the lower seam is fully-extracted. This paper compares current case histories to traditional rules of thumb. In addition two situations were modeled using LaModel software. LaModel has been upgraded to import pillar grids and topographic data from AutoCAD files. The cases presented demonstrate vertical stress capabilities of LaModel.

Up to 19 chemical parameters were studied in flotation pulps in six Australian lead-zinc concentrators with the aim of obtaining a better understanding of the nature of, and changes in, the chemical environment. This paperdiscusses collector residuals, metal concentrations in solution, and other parameters.Collectors used in the plants studied were various xanthates, Z-200, and Aerofloats. Xanthate residuals varied in different ways in most plants. However the general trend was for residuals to be at the O· 5-2 p.p.m. level in lead flotation and O· 5 p.p.m. or less in zinc flotation.Aerofloat residuals were also variable but in the plant concerned were at a much higher level (8-10 p.p.m.) than xanthate residuals. Z-200 residuals were in the 10-20 p.p.m. range and it was found that the Z-200 added to zinc flotation was reporting in dam return water and entering lead flotation.Copper concentrations in solution were negligibly low in those plants where cyanide was not used. When cyanide was used, copper was at the 5-20 p.p.m. level and appeared to be present as Cu(CN)-2. However the hiocyanatepresent may be important. Xanthate was also present in these solutions.Zinc concentrations ranged from 0·1 to 800 p.p.m. in different plants. The general trend was for the zinc level to be highest in the grinding circuit and to drop during flotation. However there was always an increase in zinc concentration when copper sulphate was added, even tho.ugh this incre.ase was not permanent, and the increase was greater with higher copper sulphate additions.The manganese concentration also increased appreciably during copper-activation of marmatite. In some plants lead concentrations increased from 0·1 to 1 p.p.m. during activation of marmatite.Calcium concentrations (20-1200 p.p.m.) and magnesium concentrations (10-600 p.p.m.) tended to be fairly stable in each circuit.

Jan 1, 1970

By John F. Spence

Ever since opening, the M25 motorway to the west of London has carried a rapidly increasing volume of traffic. The section of M25 between the junctions with the M3 and M4 motorways, which is in the near vicinity of Heathrow airport, is the most heavily trafficked section. Piling and ground treatment was required for motorway widening works over this route, which is 7 miles long. The foundation works were undertaken next to the live motorway and beneath the flightpath for aircraft landing and taking off at the airport. The paper describes the foundation construction techniques used, and the how the methods were affected by the live motorway and the height restrictions imposed by the airport. A unique method of piled retaining wall construction is also described.

Jan 1, 2007

By G. C. McKerrow

"Mr. G.C. McKerrow, Assistant Manager of Noranda Mines and formerly Smelter Superintendent attended the meeting to answer questions as to why smelters imposed penalties for too much zinc in a copper concentrate or too much copper in a zinc concentrate, etc.D.W. Bridges -Mattagami Lake MinesWhat limits do you set on zinc and lead in a copper concentrate?G.C. McKerrow - At Noranda, we allow 5% zinc free and charge 25 cents for every unit above that. For lead, it is 1% free and 25 cents per unit above that. Lead is a much more harmful impurity than zinc because it tends to recycle more in the smelter circuit and creates a greater health hazard in the plant.E. Thornton - Sullivan GroupWHat harm does fluorine do in the smelting process?G.C. McKerrow - Fluorine usually does not occur in harmful concentrations in non-ferrous smelters. Fluorides are present in exhaust gases in the aluminum and phosphate industries. If these fumes escape into the atmosphere, they may settle out on forage grasses in concentrations that are harmful to livestock.Thorton - Sullivan GroupI have asked this question other places and have been told that it is hard on brick linings and causes gold and silver to be lost up the stack.G.C. McKerrow - Almost any volatile constituent in a smelter charge will aid in carrying other metal values. To this extent it may be harmful.E. Thornton - Sullivan GroupMr. Tait mentioned before a smelter where they have a copper-tin ore and they pay for copper, tin, bismuth and silver but object strongly to indium in the concentrate. Why would this be?G.G. McKerrow - 1 can't see why indium would be a serious impurity. It does tend to concentrate in flu dusts and if you get enough of it you can recover it and sell it but I have never heard of anyone putting a penalty on it.Question - I once ran into a small copper mine in Peru that had cadmium in the copper concentrate but no zinc. The copper smelter charged a penalty for the cadmium. Why would this be?"

Jan 1, 1971

By Steve Chorley

Open-type, or main beam, tunnel boring machines (TBMs) can achieve impressive rates of production. This type of TBM typically outperforms other types of TBMs currently in use around the world. In good ground conditions, main beam machines have achieved production rates of more than 1 km/month (0.6 miles/month). However, installing effective ground support in poorer rock conditions on main beam machines can be a major cause of concern. The design of main beam machines is such that installation of ground support equipment, particularly at the front of the machine in what is commonly known as the L1 support zone, has traditionally been limited to rock drills and basic working platforms. Personnel working in the L1 zone have, until recently, been protected by roof supports and extended fingers, often with restricted access to working areas.

Jan 1, 2011

Laboratory induced polarization measurements were made on representative samples of concentrated sulphide ores from three environments in New South Wales Comparisons were made with the membrane polarization exhibited by an argillaceous sandstone. The sulphide samples showed a strong polarization effect, the magmtude of whIch depended directly on the conductivity of tlIe pore electrolyte.

Jan 1, 1969

By J. W. Hunter, J. H. Jacobs

"Approximately 355 tons of nodules from Chamberlain; S. D., ore were processed in the 1-ton-per-day electrolytic-manganese pilot plant of the Bureau of lanes at Boulder City, Nev., in a continuous 3-month operation. The ore, ground to minus 48-mesh, was found to be amenable to leaching with acid directly or after roasting under reducing conditions in a Skinner muffled multiple-hearth furnace.Unroasted ore gave an acid-leach extraction of 84 to 88 percent of the manganese, which after neutralization showed an over-all extraction of between 81 and 85 percent of the manganese. The amount of iron extracted varied, but it was always,enough to permit the use of ammonia for neutralization.Roasted ore showed an acid-leach extraction of 89 to 91 percent of the manganese. A large amount of iron went-into solution, so that it was not economical to neutralize it entirely with ammonia. By neutralizing with calcine to a pH of 5.0 and completing -neutralization with ammonia to a pH of a.5 an over-all manganese extraction of 84 to 86 percent was obtained. The slight increase in. extraction on roasted ore probably would not justify the cost of roasting.Acid consumption averaged 1.75 pounds per pound of manganese extracted. Settling rates of the residue in leach solution were to slow to permit clarification in thickeners, but a Moore vacuum leaf filter proved to be satisfactory. Purification of raw leach solution was .accomplished readily by hydrogen sulfide with a low gas consumption. Electrolysis was normal, without difficulty, and with -current efficiency ranging between 62 and 66 percent.The use of Chamberlain modules for the production of electrolytic manganese would result in an operating cost of 0.8316 cent per pound higher than the cost of producing electrolytic manganese from Three Wids ore."

Mar 1, 1946

By Jan E. Nesset, James A. Finch, Frank Rosenblum, Rebecca Payant

"Under certain conditions of moisture and oxygen, sulphides can spontaneously heat, a phenomenon known as self-heating. In this paper, we test a hypothesis that galvanic interaction between some sulphides can promote self-heating. Galvanic interaction is controlled by restpotential difference between minerals and their surface area of contact (particle size). In order to decrease rest-potential, four sulphides were tested: pyrite, chalcopyrite, sphalerite and galena. Two series of samples consisting of mixtures of two sulphides, each representing a mass fraction of 50 %, were run in standard self-heating tests. The first series comprised five mixtures, two with low rest-potential difference (pyrite-chalcopyrite and chalcopyrite-sphalerite) and three with high rest-potential difference (pyrite-galena, chalcopyrite-galena and pyrite-sphalerite). The second series was performed on a pyrite-sphalerite mixture at four particle sizes (80 % passing 850 µm, 300 µm, 75 µm and 38 µm). The first series showed that the individual sulphides and the mixtures of low rest-potential difference did not self-heat but the mixtures of high rest-potential difference did self-heat. The second series showed that self-heating increased inversely with particle size (increased specific surface area) and revealed that it was the fineness of the pyrite (high rest-potential sulphide) that governed the self-heating effect, indicating the rate-limiting step is the reduction reaction on pyrite (cathodic mineral). The increase in self-heating with high rest-potential difference and increasing particle fineness supports the hypothesis that galvanic interaction contributes to sulphide self-heating. A possible mechanism based on the hydrogen sulphide hypothesis is proposed where the reduction reaction at the cathodic mineral surface is ferric to ferrous. The understanding gained will be of interest to those involved in storage, shipping and disposal of sulphide minerals.INTRODUCTIONSulphide mineral ores are the major source of most base metals such as copper, zinc, nickel and lead. Once the ore is extracted, the sulphide minerals are liberated by size reduction (crushing and grinding), concentrated by flotation, and the concentrates sent for further processing to extract the metal (smelting and refining). At the various stages from mining to concentrate shipment and tailings storage, the sulphides are exposed to a variety of environments, which under certain conditions of air (oxygen), humidity and temperature can cause them to heat. Since no external heat source is involved, this pyrophoric process is known as spontaneous heating or, more commonly, self-heating. The self-heating of sulphides is associated with oxidation reactions under moist conditions. If the heat generated is greater than the heat dissipated, the sulphides will self-heat and the material temperature will rise. This can make working conditions potentially dangerous as oxygen is consumed from the surrounding air and significant quantities of sulphur dioxide (SO2) can be released (Ninteman, 1978)."

Jan 1, 2011

IN previous discussions on the occurrence of gold in the Bendigo quartz reefs the opinion has been put forward that the gold shoots are primary concentrations in the quartz reefs during the period of vein-formation. The view has been based upon the constant features of the gold shoots in a large number of individual reefs, independent of their depth below the surface. These features include the mineral associations accompanying the gold, the appearance and association of the gold in the quartz, the similarity in all respects (excepting mineral content) between richly gold-bearing quartz and poor quartz, and the variations in mineral content in the reef apart from gold. The view has been supported by a relation of the gold shoots to faults, together with the dependence of the reefs on the existence of pre-mineral faulting. The secondary deposition of gold has only been observed in a few instances .associated with the younger monchiquite dykes, and is of no economic importance.

Jan 1, 1922