Search Documents

By C. Heckman, M. S. Moats, A. Luyima, W. Cui

"Nucleation and growth of copper on 316L stainless steel from synthetic acidified copper sulfate was studied in the absence and presence of chloride ions and/or organic additives (HydroStar® 4208, DXG®-F7, Cyquest® N-900) using a potentiostatic technique. The current-time data obtained at 0.16V vs. SHE was analyzed using nucleation and growth models. Scanning electron microscope (SEM) images of deposits produced at 300 A m-2 show that the addition of 20 mg/L chloride ions increased the size and reduced the number of copper nuclei. Potentiostatic current-time data from the electrolyte without organic additives indicate progressive nucleation with two-dimensional (2-D) growth under diffusion control. SEM images obtained confirmed progressive nucleation with 2-D growth. 20 mg/L Cl- and 2.5 mg/L organic additives did not change the nucleation and growth mechanism, however the additives increased the number and reduced the size of copper nuclei leading to more uniform coverage of the stainless steel substrate.INTRODUCTION Electrowinning of copper is an important process in the manufacture of high purity copper metal. It is approximated that 20% of the world’s refined copper is produced from acidified copper sulfate solutions by electrowinning (Schlesinger, Sole, and Davenport, 2011). In many plants, copper is electrodeposited on AISI 316L stainless steel substrates for a period of 6-7 days, after which the copper is stripped from the blanks. Even though the deposition time for a commercial copper electrowinning circuit is around one week, it is critically important to control the nucleation, growth, and nature of the initial deposit (Sun and O'Keefe, 1992). Deposit morphology and structure are influenced by the real current density at the electrode surface. The real current density across the cathode surface is made uniform by proper design of the electrowinning cell and electrodes and careful operational practice. Even with good design and control, some current maldistribution occurs. The outcome of severe current maldistribution is poor deposits that affect product quality and/or increase energy consumption. To combat current maldistribution and create a larger operating window in terms of current density, temperature, and copper concentration, small amounts of organic smoothing agents (traditionally guar products) are added to copper electrowinning electrolytes. Moreover, these additives inhibit the growth of copper dendrites, which leads to improved deposit quality by producing bright, smooth, and dense cathodes."

Jan 1, 2015

By C. H. Bucknam

Metallurgical processing of gold ores in positive water balance environments has been facing decreasing discharge concentrations in permits and additional requirements to pass acute toxicity testing before discharges will be allowed to native fisheries. In response to the challenge to meet 0.005 mg/L free cyanide guidance for discharges to fresh water fisheries, the American Society of Testing and Materials (ASTM) International Cyanide Task Group has undertaken an interlaboratory study for the free cyanide method in the metallurgical processing cyanide detoxified reverse osmosis effluent to determine if the quantitation limit for the method could be lowered from the current 0.009 mg/L free cyanide (1) to less than the 0.005 mg/L guidance concentration. Results of the testing are presented below.

Jan 1, 2012

By W. Petruk, D. B. Sikka

Lithium-bearing lepidolites from three deposits in the province of Goias, Brazil, were investigated to determine whether there is a correlution between the lithium content of the mineral and the color of lepidolite and associated tourmaline. Such a correlation can be a useful guide to field geologists for outlining high-grade lithium ore zones. It was found that mauve-pink lepidolite associated with pink tour-maline, and brownish lepidolite associated with black tourmaline have high lithium contents, but that the color of lepidolite is not due to lithium. The pink color of lepidolite and tourmaline is likely due to Mn3+, and the brownish tint of lepidolite and black color of tourmaline to Fe3+. Lepidolites appear to be lithium- rich when the lepidolite and associated tourmaline contain relatively high amounts of Mn3+ and/or Fe3+.

Jan 1, 1988

By G. Righettini, P. Mousset-Jones

Diesel powered vehicles have made underground mines more efficient, but with the advent of DPM regulations, in most cases, extra ventilation and/or engine emissions control technology will be required. Using fuel cell powered vehicles will not need these measures to be taken. Nine US underground mines of varying production rates and mining methods were studied to determine possible ventilation reductions if their diesel fleets were replaced with identical fuel cell powered vehicles. Factors that might limit ventilation reductions, such as heat and the effects on other pollutants were determined for each mine. The ventilation cost savings and other benefits of fuel cell vehicles show that when they become commercially available they have the potential of being viable alternatives to diesel vehicles.

Jan 1, 2004

By Timms. Greg P., John W. Bennett

A field-based method for measuring the diffusive oxygen flux through covers placed on sulfidic waste rock dumps has been developed and applied at a number of mine sites. The technique provides a means of quantifying oxidation rates in dumps and can thus be used to assess the effectiveness of cover systems. Two instruments can be used. The first is portable and easy to set up, enabling a picture to be built up of the overall diffusive flux into a dump by making measurements at a sufficient number of locations. The second is installed beneath a cover and is preferred in situations where oxygen is consumed in the cover since it provides a direct measurement of the oxygen flux into the underlying waste rock.

Jan 1, 2000

By P. Richardson, B. Sceresini

The carbon-in-pulp and the carbon-in leach process for the recovery of gold and silver from cyanide leaching of ores is now widespread in the precious metals mining industry. However the presence of various base metals can have a detrimental effect on the efficiency and the economics of the process due to high cyani,:••? consumption and a reduction in leaching and adsorption rates resulting in poor recovery of the precious metals. Furthermore the presence of fast leaching and adsorbing metals such as copper can significantly reduce carbon loading capacity for the precious metais thereby necessitating a higher carbon inventory, more frequent stripping and poor bullion quality resulting in higher production costs. This paper describes the development and application of a process for the recovery of copper and and the recovery and re-use of the associated cyanide from the leach circuit at the Mt. Gibson Gold Project in the Murchison Goldfield in Western Australia. The process provides a means to counter-act the detrimental effects of the copper which occurs in the ore as various oxide and sulphide minerals including an extremely fine chalcopyrite powder. It has the added benefit of recovering the base metals in this instance copper, in a saleable form. The process is subject to a patent application by Reynolds Australia Metals, Forsayth N.L. and the author.

Jan 1, 1991

By Shailesh K. Patel, Shaaban Ben-Poorat

In order to ascertain the environmental fate of flotation reagents (fatty acids, fuel oils, and amines) associated with phosphate rock processing with confidence, it was necessary to first establish laboratory methodologies to identify and quantify flotation reagents. This approach was necessitated by the fact that the reagents used in the flotation process are either reclaimed or by-products of other industries and is dictated by their cost. Initially, several blind performance evaluation samples were prepared by spiking water samples with known amounts of either single reagents or reagent mixes and then analyzed. Reagent recovery for the blind performance evaluation samples was within acceptable limits for similar compounds established by the US Environmental Protection Agency. Averification process involving the use of standards and the refinement of analytical methods was utilized to develop standard operat- ing procedures (SOPS) and method detection limits (MDLs) specific to the identification and quantification of the flotation reagents used in the phosphate industry. These procedures and MDLs were critical to support the project's primary goal of assessing the fate of selected flotation reagents in the environment.

Jan 1, 1999

By Orville L. Lantto, Bruce K. Cantrell, Keith S. Olson

Approximately 10 to 20 pct of exhaust aerosol mass from diesel equipped vehicles operating without exhaust controls is attributable to particles in the 1.0-10 µm size range. Recent in-mine measurements suggest that, in addition to reducing overall exhaust aerosol mass concentrations, the use of waterbath exhaust conditioners (water scrubbers) may significantly reduce the concentration of diesel exhaust particles larger than approximately 0.5 µm aerodynamic diameter. This implies that a measurement system that discriminates between diesel and mineral dust aerosols on the basis of aerosol size would have different accuracies depending on use of a water scrubber. To test this hypothesis, laboratory measurements were made by the Bureau of Mines to determine diesel exhaust aerosol penetration efficiency through a water scrubber as a function of size and engine operating conditions. Size distributions were determined using a Micro-Orifice, Uniform Deposit Impactor. Concentrations of CO, CO2, NO x, O2 and gas-phase hydrocarbon concentrations were also measured. No significant effect was found for these gases other than a slight decrease in NOx emissions. The water scrubber served as a moderate aerosol control with reductions in mass concentrations of about 29±9 pct under most conditions. This reduction occurred for particles less than 0.2 µm and greater than 0.6 µm aerodynamic diameter. Coal dust aerosols are mostly larger than 0.8 µm aerodynamic diameter. With use of a water scrubber, separating the aerosol into two parts, greater and less than about 0.8 µm aerodynamic diameter during sampling, results in collection of diesel and coal dust aerosol accurate to within 10 pct. Without a water scrubber in operation, such a sampling protocol would only be accurate to approximately 15 pct.

Jan 1, 1991

By Murat Budakoglu

Albite (NaA1Si308) is one of the important raw materials for the rapidly developing Turkish ceramic and glass industry. Prior to 1980, development of the ceramic industry in terms of raw material was dependent upon small-scale mining operations; in the last decade, these efforts have increased substantially. The aim of this study is to investigate the geochemical properties and distribution of albite occurrences in the Kocayayla district, which is about 12 km northeast of the town of Milas, about 50 km west of the city of Mugla in southwestern Anatolia. Kocayayla is also well known for its famous ancient city, Labranda. The field area is located in the Menderes Massif, which was formed by major tectonic events during the Late Proterozoic and subsequent periods. The target area was studied to prepare a detailed geological map (scale, 1:10,000), and to determine the formation of albite-mica-schist-quartzite borders in the host rock gneiss. To do this, systematic sampling of albite was done in the two main areas, the Sarikaya and Yumruta? regions. In the study area, albite zones are scattered within an area of about 20 km2, and they extend in a northeast-southwest direction; mica-schists and quartzite veins accompany these units. Mineralogical observations show that quartz is the main mineral associated with albite. In the ceramic industry, the albite + quartz assemblage is well known and is classified as "standard" or "super type," depending upon the content of TiO2 and Fe203. In this study, the Sarikaya albites (profile I) exhibit remarkably lower TiO2 (0.15% on the average) values contrasted to that of Yumruta? (profile 11; 0.24% on the average), whereas Fe203 values vary slightly from 0.076% to 0.085% in both regions.

Jan 1, 1999

By Barry A. Hillman

The rapid evolution of computer and field sensor technology is now providing the ability to integrate mine and office opera­tions. Digital maps and mine plans as well as CAD and GIS can be transferred to ruggcdized field computers for development of real-time mine surveys and real-time GPS machine navigation and monitoring. Surveyors can insure that their surveys arc accu­rate before returning to the office. Engineers and surveyors are also able to upload field computer-based surveys to mine plan­ning software and directly to mine equipment including shovels, drills, and dozers providing the operator of the equipment with a real-time view of their work space. Production information can be transmitted through dispatch and/or centralized mine servers to update mine plans with mining progress and production data. Static mine models then become a dynamic element of opera­tions, providing greater use of information that emphasizes the spatial aspects of the mine by providing real-time maps, produc­tivity charts, and graphs. This information can be disseminated through various mine communication systems to provide opera­tors and management with real-time feedback as well as daily and weekly reports. Integrated systems now being used in exten­sive trials arc reporting productivity increases of 4 - 7% or more thereby providing rapid payback to the mine.

Jan 1, 1998

By Zbigniew Hladysz

INTRODUCTION In the Polish coal mining industry, the Upper Silesian coal basin has an important position. It contributes over 98% of the total coal production of Poland which reached 193 mt in the year 1979. In view of the significant urbanized area in this region as well as the industrial potential, it is important to protect the surface by stowing the mined out underground workings. Approximately 18% of the total production is mined from longwall faces with stowing. However, caved longwall faces are most popular. In the upper Silesian coalfield, approximately 337 highly mechanized longwall faces are in operation. Out of these 337 faces, 301 longwall faces are caved. One of the main requirements for effective and safe coal extraction is a suitable method for strata control. We can divide the complex process of strata control into four steps: 1. Strata investigations 2. Selection of supports for roadways 3. Selection of supports for longwall 4. Rock bursts and other hazards protection STRATA INVESTIGATIONS Estimation of the structure and physico-mechanical properties of the rock mass surrounding the workings is an important constituent of strata control. These factors definitely influence the rock stability, support load, working conditions as well as the mining technology. Complex methods of strata investigations involve a set of indicators enabling the estimation of the stability of the roof rock, strength of the coal seam and load bearing capacity of the floor. The basis for the evaluation of roof stability for a coal seam is the classification according to the resistance to bed separation (1). The bed separation resistance is equal to the strength of the rock in tension perpendicular to the bedding plane. In order to properly classify a rock, it is indispensable to make continuous profiles of the bed separation resistance from the immediate roof up to a distance of three times the thickness of the coal seam. The profiles are developed by utilizing mine roof investigations with the hydraulic borehole penetrometer. (Fig. 1) The penetration resistance is determined by the critical pressure required to cause crushing of the rock by the penetrometer indentor (2). The classification of roof rocks and their ability to cave spontaneously during longwall mining is shown in [Fig. 2]. The measurement of the critical pressure also allows for the determination of the compressive strength of the rock, the index of workability and roof fissuration.

Jan 1, 1982

By O. Guyot, T. Mulpeter

Sadiola Hill mine is located in the sub-Saharan part of Mali. In its first two years of operations, Sadiola Hill mine had already exceeded expectations with respect to profitability, plant capacity, metallurgical recovery, cash costs and social integration into the area. The advanced control system installed by the authors has been a major contributor in the substantial throughput of the mill over the design tonnage with no loss of recovery. The run-of-mine ore at Sadiola consists of soft clays with a varying percentage of grit, producing a high viscosity slurry. The percentage of grit fed to the plant varies on an hourly basis. This combination was expected to have a large impact on the milling circuit and determined that the early installation of an expert mill control system would be advantageous. Svedala Cisa OCS©, was selected as the most suitable support software. The operational rules and control philosophy are housed in the OCS© graphic-oriented fuzzy expert system while a model­based Soft Sensor has the remarkable ability to detect the variations in grit in the feed. Designed during the second half of 1996, commissioning of the system began in March 1997, the OCS was fully on-line by September. With the implementation of the optimising control strategy a throughput of 5.0 million tons relative to the target of 4.4 million tons was achieved for the 1998-operating year. The Sadiola project confirms that advanced process control techniques are among the most cost-and time-effective methods of improving metallurgical plant performance. The recipe that worked at Sadiola is a mix of metallurgical expertise, proper software selection, adequate design of control philosophy, and excellent plant support and follow­up. The early decision, design and installation of the mill control system has resulted in an enhanced Return on Investment.

Jan 1, 2000

By P. C. Cochrane, I. S. Clelland, S. H. E. Phillips

Geological and hydrological conditions in the strata overlying the Salado Formation vary considerably in the Carlsbad, NM, area. The first four shafts sunk at International Minerals and Chemical Corp. (IMC) property have been located in competent and essentially dry conditions, while other shafts on adjacent properties have had such adverse conditions that ground freezing has been chosen as the water and ground control technique for shaft sinking. At the location of the IMC No. 5 shaft there has been extensive erosion and salt dissolution in the Rustler Formation, leading to collapse of some zones of the strata. Both ground freezing and pregrouting were considered as alternative methods of stabilizing the extremely poor ground conditions and controlling the potentially very heavy water inflows. It was decided that pregrouting the shaft was feasible and would offer substantial cost and time saving over a ground freezing technique. This paper describes the pregrouting techniques used and illustrates the requirement for flexibility in a grouting program so that it can be modified to reflect any new or additional information obtained during the progress of the grouting.

Jan 1, 1987

By D. Yadon, P. Lee, W. Kelly, C. Stilwell

Rico is a small town in an old zinc mining district in a mountain valley of southeastern Colorado. Mine waste rock and mill “tailings” remained after over 100 years of mining in the area, leaving associated surface water and groundwater impacts. Atlantic Richfield Company is proposing an innovative approach, which uses lime precipitation and wetland ponds (semi-natural system, also called treatment lagoon in a wetland setting) to treat adit water in the Rico area. Besides using a non-conventional treatment approach, a non-conventional (non-Superfund) regulatory/administrative approach is being proposed. This paper will focus on the water treatment issues and solutions, as well as describing the innovative “watershed” regulatory process.

Jan 1, 2004

By Yoginder P. Chugh, K. V. K. Prasad, R. Missavage

This paper presents results of field monitoring and finite element studies to analyze and improve a room-and-pillar retreat mining system. Fie1 d instrumentation was utilized to monitor pi11ar load changes, roof to floor convergence and differential roof strata movement as retreat mining progressed and to determine in-situ horizontal stresses. A two-dimensional finite element model depicting strata behavior at this mine was developed and used to analyze existing and alternate improved mining geometries. The results showed excellent correlation between fie1 d observed and model predicted behavior. Some of the recommended changes in mining geometry based on the study were incorporated in the mining system.

Jan 1, 1986

By R. W. Hutson

One of the fundamental precepts of experimentation is the isolation of a single variable to quantify its individual effect. Unfortunately, the variability of natural rock joints has frustrated such isolation. This variability and the high cost of securing a large member of natural joints has lead to increasing experimental dependence on stage shearing, artificial tension fractures and/or model materials. The new apparatus described herein allows for the first time replication of real joints with field scale asperities. It employs a diamond band-saw blade with computer controlled feed table to cut joints with high precision. The feed system is capable of placement to tolerances similar to those of a high quality computer plotter. The accompanying software allows the table to cut any desired joint shape (repeating or non-repeating) within certain, over-all size limitations. Resulting joint surface dimensions and roughness as well as shear resistance indicates that the joint surfaces are reproduced with a precision similar to that possible for the control of other experimental variables such as normal and shear forces.

Jan 1, 1986

By S. Svoronos, B. Moudgil, R. Stana, A. El-Midany

Due to their similar surface properties, it is not always easy to separate carbonate minerals from other salt type minerals by froth flotation. A particular example is the difficulty of separating dolomite impunities from phosphate minerals. Such challenging fundamental and practical problems have inspired several research efforts in various laboratories around the globe to find methods for economically removing the dolomite. However, a universal and cost effective process is not in commercial use. In this paper, a new process for separation of carbonate minerals (dolomite or calate) from other associated minerals is presented. Differential solubility of carbonates in slightly acidic solution is utilized to generate micro GO, bubbles at the carbonate mineral/ water interface. Particle (e.g., dolomite)/ bubble aggregates float to the surface leaving phosphate concentrate with low MgO content. Interestingly, up to 6.0 mm particles can be floated by such micro bubble/particle aggregates. Different sutface-active agents were tested to stabilize the bubbles. Results of these tests are presented and the mechanisms involved are discussed.

Jan 1, 2005

By Kerby Glass, Glenn A. Gruber

Mr. C. A. Hollingsworth introduced commercial column flotation to the Florida Phosphate Industry in 1976, with a six feet diameter prototype cell at the Tenoroc Mine. More than two-dozen column cells have been installed in phosphate beneficiation plants since then. The increased interest in column cells for phosphate flotation, and their potential use in new plant construction, prompted the Florida Institute of Phosphate Research to fund programs to investigate various aspects of column flotation. This report describes a test program, conducted by JACOBS at CF Industries Hardee Complex II, as part of a comprehensive research program awarded to the University of Florida by the Florida Institute of Phosphate Research. The 1.5 feet diameter test column was operated with plant process water and plant reagentized flotation feed. Several variables considered for column cells design and operation were tested. Feed specific capacity, air superficial velocity, and the length to diameter ratio of the column were the variables that influenced phosphate recovery. Concentrate phosphate grade was influenced by concentrate superficial velocity and feed specific capacity.

Jan 1, 2002

By Peter Sullivan, Johan van Heerden

Increased use of continuous miners and roadheaders in the underground coal mining industry in South Africa has led to improved productivity and efficiency of operations. Of major concern, however, is the increased amount of airborne dust generated during mining. Dust is a health hazard in terms of respiratory diseases, can impede productivity and is the major contributor to the potential of underground explosions. The concern of the South African coal mining industry with regard to the underground dust problem has led to the establishment of a Dust Control Section in the Coal Mining Division of COMRO. In the field of dust suppression system evaluation and design, collaborative work has been undertaken by COMRO and FLOSEP. This paper gives a review of the application of Computational Fluid Dynamics (CFD) in evaluating and improving environmental conditions in continuous miner and roadheader sections. A brief history of the development of the CFD model as well as a discussion of a typical application is included.

Jan 1, 1993

By Bernie W. Martin, Paul MacLeod

The new St. Clair River International Tunnel Project presented unique challenges in planning, permitting and approval. The project straddles the border between the Province of Ontario and the State of Michigan necessitating the review of U.S. approval legislation that has not been used in 60 years. The preparation of an environmental impact report to satisfy the legislative requirements for the Federal laws of the U.S. and Canada as well as the Province of Ontario and the State of Michigan presented a daunting task. In all, over 200 external contacts were made in carrying out the environmental approvals and permitting work. The definition of the alternatives including the NULL option were documented along with the impacts and mitigation measures. A "Modified Delphi" technique, along with other methodologies, was used for alternative evaluation and selection. A formal and informal public consultation process was undertaken which involved over forty major presentations and external meetings. A unique alternative to the traditional design, tender, build contracting practice was adopted; The Negotiated Compressed Process (NCP).

Jan 1, 1993