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By A. L. Murray, D. Harrington

From 1870 to the end of 1929 the coal production of Utah has been some- what less than 110,000,000 tons. During this period at least three major disasters have occurred with fatalities totaling about 380, establishing a decidedly bad record of approximately 3.5 persons killed by major mine explo- sions per million tons of coal produced. Even during the period when there have been no disasters, such as the years 1914 to 1920, inclusive, the fatalities in ordinary working were about 5.4 per million tons produced, against 3.7 per million tons for the whole United States for the same years. The 5-year period following the World War, 1918 to 1922, inclusive, had 4.7 fatalities per million tons; hence, the fatality record in the coal mines of Utah has uniformly been in excess of the average of the coal mines of the entire country. Notwithstanding this poor record, Utah has given to the coal-mining world many excellent safety methods and practices, and Utah coal mines in general take greater measures toward safe mining than do the coal mines of any other State; if practices and methods allowed and pursued in coal mines of other States were tried in Utah coal mines, there would be a succession of disasters.

Nov 1, 1931

By E. D. Regad, W. E. Wallace, V. Vallythan, V. Castranova, P. Hathaway, F. H. Y. Green, M. J. Keane

"Abstract—Inhaled particle contact with pulmonary surfactant in the hypophase lining pulmonary alveoli was modelled in vitro by exposing two respirable sized dusts, kaolin and silica quartz, to lecithin, a major component of pulmonary surfactant, emulsified in physiological saline. Lecithin adsorbs to the dusts upon incubation at 3TC and suppresses their cytotoxicity as measured by pulmonary macrophage and erythrocyte assays, suggesting that pulmonary surfactant provides a defence system against prompt cell membrane lysis by inhaled dusts. Subsequent pulmonary macrophage phagocytosis and lysosomal enzyme digestion of the coated dusts was modelled in vitro by incubation with phospholipase A2 for one hour. With increasing lipase activity, silica haemolytic potential was restored to native silica levels. Kaolin was retoxified to levels far in excess of native kaolin haemolytic potential. Elution, thin layer chromatography and phosphate assay of treated dusts indicate that most lecithin on silica is digested to lysolecithin and desorbed, silica retoxification being due to surface and adherent lysolecithin effects. Most lecithin on kaolin is not digested in the same time; that which is. results in adherent lysolecithin which is responsible for the kaolin retoxification. Digestion with phospholipases A2 and C together produces only weakly retoxified kaolin. Results suggest that surface adsorption properties which control the adherence of prophylactic surfactant distinguish the pathogenic potentials of quartz, kaolin and mixed dust.INTRODUCTIONERYTHROCYTE HAEMOLYSIS and pulmonary macrophage enzyme release assays show quantitatively comparable high cytotoxicities for both silica quartz and kaolin respirable sized dusts (BROWN, et al., 1980; DANIEL and LE BOUFFANT, 1980.) This contrasts with the strong potential for respirable quartz dust to induce pulmonary fibrosis and the much more limited potential of kaolin dust to do the same (MORGAN and SEATON, 1975).In an attempt to understand this anomalous situation, assays were performed on quartz and kaolin dusts incubated with dipalmitoyl lecithin emulsified in physiological saline, to simulate the initial contact of a respired dust with the pulmonary alveolar hypophase. The ability of kaolin dust to adsorb dipalmitoyl lecithin from physiological saline has been quantified (WALLACE, et al., 1975). Such lecithin treatment suppresses the cytotoxicity of both silica and kaolin to background levels (WALLACE, et a1.,1984).Surfactant coated detoxified dusts should then be phagocytised by pulmonary macrophages, incorporated into a macrophage secondary lysosome and exposed to hydrolytic lysosomal enzymes. Among these is phospholipase A2, which hydrolyses diacyl lecithin to lysolecithin. This was modelled by incubating lecithin treated dusts with phospholipase A2 in vitro to determine if the enzyme can digest the dust-adsorbed lecithin, and if the retoxification differs between the two dusts in a manner which might distinguish their pathogenicity."

Jan 1, 1988

By R. R. Sayers

carbon monoxide mav occur in many places and inhalation of that insidious s is a. frequent and .videly distributed cause of poisoning, ranging in severity from headache and. inefficiency to unconsciousness and death. People are continual­ly being affected by carbon monoxide 1n the home, in garages, around gas and gasoline engines and blast-furnaces, in fighting fires, after blasting in mines and quarries, and after mine fires and explosions; in fact, everywhere there is the possibility of an exposure to the products of combustion of carbonaceous fuels or products, On the other hand, there are arzy' cases reported wherP. ill effects and acci:ients are wro:1gly .ttributed to carbon monoxide. Thus it is essential indeed for doctors, coroners, safety engineers, a.n1 !irst-aid men to be able to recognize this poisoning, not only as reeards giving proper treatment, but to ensure just decisions on claims and to eliminate false illusions and complaints of ·11orkrr.en.

May 1, 1922

By Noel N. Moebs

The Bureau of Mines conducted five reconnaissance magnetometer traverses across a small abandoned chromite mine in the State Line district of Pennsylvania and Maryland to determine the geophysical response of the area. The results indicate that more extensive geophysical surveys of the region might establish some worthwhile guidelines for chromite exploration. While chromite only rarely can be detected directly by magnetic methods, there is a possibility that geophysical signatures in the adjacent host rock could provide some guidelines for further exploration. Prior to 1875, all the chromite produced in the United States came from the State Line district, and the potential for discovering additional podiform deposits could be significant. Virtually no state-of-the-art geuphysical or geochemical studies have been conducted in this district since World War II and sizable areas remain undeveloped and suitable for exploration. While the results reported in this paper are not supported by drilling, it may encourage others to investigate the area more fully for improved methods of detecting subsurface podiform chromite deposits. New theories on the emplacement of ophiolites also could contribute to an assessment of the chromite potential of the serpentinite belt.

Jan 1, 1991

By James A. Powell

The theory of electromagnetic fields indicates such fields could be used to detect and locate trapped miners. To be useful, the hardware of the system must meet a number of requirements, including small size, intrinsic safety, and rugged construction. Such hardware has been built, and the system has been tested by the Bureau of Mines and its contractors. These tests indicate that the electromagnetic method provides a practical means to locate miners in emergencies.

Jan 1, 1976

By O. C. Blade, E. L. Garton

Louisiana is one of the major oil-producing States of the country. Commercial production of crude oil in the State began in 1902 and has increased to an estimated output of 157,409,000 barrels in 1945, which is the maximum production up to this time and places the State fourth in the nation. The cumulative production for Louisiana through 1944 is 1,544,481,000 barrels, and, adding the output for 1945, the total to January 1, 1946, is 1,681,890,000 barrels. Data on annual production of crude oil in Louisiana and tentative statistics for 1945 are given in table 1. The large production of crude oil in Louisiana and the present trend to utilize petroleum in accordance with its general characteristics make it increasingly important to present analytical data for crude oils. This report is the fifth of a series presenting such data obtained on crude oils from Louisiana according to the procedure used by the Bureau of Mines. Individual analyses are given for 82 samples from 64 fields; many of the samples are from recently discovered fields, and some are from new producing formations.

Dec 1, 1946

By Seymour Wasserman

To develop noise control designs for secondary crushers in Taconite plants. Taken into consideration: 1. Acoustical criteria 2. Day-to-day operational considerations and maintenance accessibility 3. Materials of construction 4. Adaptability of design to other Taconite plants having crushers 5. Cost of noise control treatment.

Jan 1, 1977

By Robert F. Chaiken, Thomas H. Dubaniewicz, Gregory M. Green, Kenneth L. Cashdollar

Optical technologies have progressed rapidly in the past 15 years. One application of laser technology in underground coal mines currently under evaluation is the remote measurement of explosive methane gas. Federal regulations require that atmospheric monitoring systems used in gassy underground mines where permissible equipment is required shall be intrinsically safe. Mine Safety and Health Administration criteria for the evaluation and testing of intrinsically safe apparatus and associated apparatus contain no specific guidance for optoelectronic components such as diode lasers. The National Institute for Occupational Safety and Health is conducting a study to help provide a scientific basis for developing appropriate safety guidelines for optical equipment in under- ground coal mines. Results of experiments involving ignition of methane-air mixtures by collections of small heated particles of Pittsburgh seam coal and black iron oxide are reported. The inert but more strongly absorbing iron oxide targets consistently ignited methane-air mixtures at lower powers than the coal targets. Minimum observed igniting powers for laser energy delivered by 200, 400 and 800 pm core fiber optic cables and directed onto iron oxide targets in methane-air atmospheres were 0.6, 1.1, and 2.2 W, respectively. Comparisons with the results of other researchers are made. A thermal layer theoretical approach to describing the process is included as an appendix.

By David A. Monaghan, Kenneth R. Maser, Adi R. Gurdar, D. Randolph Berry

4. Preliminary Study - Remote Seal Checker 4.1 Introduction Determination of the completeness of each individual seal at the time of its emplacement is essential for an effective remote sealing system. A satisfactory seal checking technique should provide a signal which: (1) indicates percentage completion as the seal is emplaced (2) provides a definite indication of a complete seal (3) indicates the size of the unsealed area if a complete seal is not feasible This information is required to establish the need for additional seal material, the need for additional seals, and the risk likely involved in entering the mine., In many situations it is as important to know the quality of a seal as it is to build an effective one. It is likely that with repeated use the remote sealing technique developed by Foster-Miller Associates will be sufficiently reliable and predictable to preclude the seal checking requirement. It is recommended, however, that each seal be checked during construction to insure its completeness and increase the level of confidence so necessary in reopening the mine. 4.2 Description of General Problem Several characteristics of remote mine seals are important in considering techniques for evaluating the effectiveness of these seals. These include:

Jan 1, 1973

By G. A. Brady

Seven samples of Pennsylvania anthracite from the Bottom Ross bed were analyzed and tested to obtain data on cleaning characteristics, proximate and ultimate analyses, specific gravity, grindability, heating value, and ash softening temperature. Ash content of the samples varied irregularly from 9.0 to 34.4 percent, the range being narrowed to an upper limit of 14.8 percent ash by removing impurities dense enough to sink in a medium with a specific gravity of 1.90. Ash content of the sink material with specific gravity greater than 1.90 ranged from 56.4 to 80.4 percent; corresponding specific gravities were 2.095 to 2.534. Volatile matter contents were indicated to be higher for the ash-forming minerals than for the pure coal substance in the various specific gravity fractions of a given sample. Specific gravities of anthracites with compa¬rable ash contents but from different locations in the bed varied as much as 0.06. The grindability index increased significantly with increasing ash con¬tent of specific gravity fractions from all the samples.

Jan 1, 1968

By James J. Olson

The Bureau of Mines used micro fracture density analysis of quartz grains in thin sections and diametric pulse velocity measurements along preblast and postblast cores to determine the nature and extent of rock damage produced by small (0.25-,0.50-,1.0-, and 2.0-kg) charges of high intensity explosive (C-4) in granite. Pulse velocities from the postblast cores were significantly lower than velocities from the preblast cores and, with the core logs, provided clear identification of the upper and sometimes the lower limits of most severe damage. These zones ranged from about 1.68 ft for the 0.25-kg blast to 4.16 ft for the 2.0-kg blast. Microfracture densities from postblast cores were significantly higher and more variable than densities measured from preblast cores. The microfracture density measurements showed that microscopic damage was present far past the zones of most severe damage as delineated by the pulse velocity logs and core logs. An exponential relation-ship was observed between the micro fracture density levels and the charge weight.

Jan 1, 1973

By D. N. Nilsen

The Bureau of Mines is developing a method to recover Ni, Co, and Cu from laterites containing less than 1.2 pct Ni and 0.25 pct Co. The method consists of the following basic unit operations: (1) reduction roasting, (2) leaching, (3) solvent extraction, and (4) electrowinning. The method reflects three Bureau of Mines objectives: (1) recovery of critical minerals that are domestically in short supply from low-grade domestic laterites, (2) lower processing energy requirements, and (3) solution recycling. This report deals with the extraction of cobalt and the preparation of a suitable cobalt electrolyte by solvent extraction from liquor produced by this method. Nickel and copper are coextracted with LIX64N from an ammoniacal ammonium sulfate leach liquor containing about 1.00 g/l Ni, 0.30 g/l Co, 0.03 g/l Cu, and 0.02 g/l Zn. Cobalt (III) in the nickel-copper barren raffinate is reduced to cobalt (II) with cobalt metal. Reduction of cobalt (III) to cobalt (II) greatly aids subsequent extraction. Commercially available XI-51 extracts about 94 pct of the cobalt from the treated raffinate in one stage in a laboratory mixer-settler continuous circuit. Ammonia loaded on the solvent is removed in two washing steps. About 94 pct of the cobalt then is stripped from the XI-51 in one stage with spent cobalt electrolyte containing about 77 g/l Co and 18 g/l sulfuric acid (H2S04), Electrolytes containing less H2S04 also may be used. Preliminary data indicate that coextracted zinc may be removed from pregnant cobalt eletrolyte containing 3 g/l or less H2S04 with di-(2 ethylhexyl) phosphoric acid (D2EHPA).

Jan 1, 1980

By R. Barany

The heats of formation of goethite, ferrous vanadate, and manganese molybdate at 298.15° K were determined by solution calorimetry. For formation from the elements, the heat values were -133.7 ±0.3 kcal/mole for goethite, -453.8 ±0.5 kcal/mole for ferrous vanadate, and -284.8 ±0.2 kcal/mole for manganese molybdate. For formation from the oxides, the heat values were -0.9 ±0.1 kca1/mole for goethite, -19.4 ±0.3 kca1/mole for ferrous vanadate, and -14.6 ±O.l kcal/mole for manganese molybdate.

Jan 1, 1965

By J. J. Demeter

A tube-wall reactor with a Raney nickel catalyst deposited on the outer wall of the tube by flame spraying is effective in the practically complete conversion of 3H2+1CO synthesis gas to a high-Btu gas (methane) at an hourly space velocity of 7,000 volumes of gas (NTP) per hour per volume of annular volume. Partially reacted synthesis gas containing an appreciable amount of methane can also be treated in this reactor to increase the heating value to over 900 Btu per cubic foot. Excellent heat removal through the metal wall to a coolant and temperature control were obtained. The heat transfer co-efficient from the catalyst to the coolant was about 275 Btu per hour per square foot per ° F. Synthesis tests were conducted with tubes 1.2 inches in ad by 6 inches long, and 1.3 inches in od by 36 inches long. When operating at a synthesis gas rate of 100 to 120 scfh per square foot of catalyst-coated tube, catalyst life was long enough to realize a catalyst cost for the raw Raney nickel alloy of about 0.3 cent per 1,000 cubic feet of pipeline gas (900 to 950 Btu per scf). Gas recycling at ratios of 1:1 to 3:1 was effective in increasing conversion and in extending the life of the catalyst to about 16 weeks. In cost and in operating characteristics the tube-wall reactor compares favorably with the fluidized-bed and hot-gas-recycle reactor systems for the synthesis of high-Btu gas from H2+CO.

Jan 1, 1967

By J. L. Ellenberger

The National Institute for Occupational Safety and Health (NIOSH) has continued the research role of the former US Bureau of Mines (USBM) to engineer techniques that will reduce the hazards in the mining workplace associated with coal bumps. Recent research focused on a longwall coal mine in Utah with overburden greater than 750 m (2,500 ft) containing several massive sandstone units. The primary field instrumentation at the site was three-dimensional, full waveform, autonomous microseismic arrays placed underground and on the surface in order to surround the active multi-panel longwall district. The purpose of these arrays was to help investigate the strata mechanics associated with the redistribution of stress and the associated gob formation of the longwall. Specifically, the seismic arrays were used to determine the timing and location of the failure in the strata surrounding the active mining. Overall 13,000 seismic events were detected and located with on-site processing during the five months the panel was being mined, including a magnitude (ML) 4.2 event. Of these, a smaller subset of 5,000 well-located events was selected during post-processing to form a consistent data set for analysis in this paper. From this data set, it was observed that the seismic events generally occurred in advance of the longwall face, both above and below the panel, consistent with failure of the strata in the forward stress abutment zone. Also, the occurrence of the ML 4.2 seismic event within 150-180 m (500-600 ft) of a deep cover longwall face with no associated bump caused a re-evaluation of the nature of the connection between seismic activity and coal bumps.

Jan 1, 2002

New Continuous Personal Dust Monitors (CPDM) submitted to NIOSH for approval to sample coal mine dust must accurately measure respirable coal mine dust in mine environments. There are two steps in the process which may be done in any order. The manufacturer is required to submit the results of a comparative underground coal mine dust sampling study, where the candidate CPDM is compared to an approved coal mine dust sampling device (currently the Coal Mine Dust Personal Sampling Unit (CMDPSU)). This testing shall follow the guidelines outlined below and shall demonstrate through weighted regression analysis that the mean coefficient of variation with bias correction is equal to or less than 12.8%. The other step involves laboratory testing to determine the electronic and environmental stability. This testing must be conducted by a private, commercial, academic or other laboratory approved by NIOSH.

Jan 1, 2009

By N. A. Gokcen

Equilibrium partial pressures of gaseous HCl and H2O over aqueous binary and ternary solutions of HCl and AICls were calculated or estimated in the range of 20° to 110° C, and up to saturation with AlC13?6H2O. The results were extended to solutions containing less than 10 wt-pct FeCl3 by assuming that FeCl3 and AIC13 are equivalent on the molar basis, since both salts have trivalent cations with a cammon anion. The ionic activity coefficient of HCl and the equilibrium constant for dissolution of gaseous HCl were also computed. This research is part of the effort by the Bureau of Mines, U.S. Department of the Interior, to provide thermodynamic data to expand the technology base relevant to the extraction of alumina from nonbauxitic domestic raw materials.

Jan 1, 1980

By John M. Gomes

Two methods for electrowinning tungsten from wolframite [(Fe,Mn)W04] were investigated. The first method, direct electrowinning from wolframite concentrate dissolved in molten salt mixtures composed essentially of various combinations of sodium phosphates, sodium borates, and sodium halides, yielded impure products. The second method was electrowinning from a halide-tungstate melt that was obtained from a high-temperature, two-phase extraction of tungstic oxide (W03) from wolframite. Electrolysis in electrolytes prepared from addition of sodium metaphosphate (NaPO3) and boric oxide (B2O3) to the halide-tungstate melt produced tungsten metal of 99.9 percent purity. Tungsten carbide (WC) was electrodeposited from the halide-tungstate melt when the melt was adjusted to contain 82 mole-percent NaCI and 6.0 mole-percent each of W03, sodium metaborate (Na2B204), and caustic soda (NaOH).

Jan 1, 1970

By G. M. Wilemon

The Bureau of Mines conducted preliminary investigations on the use of an acid-alcohol leaching technique for recovering phosphate values from phosphate matrices. H2S04 and methanol were used as the leaching agents. Starting-matrix particle size and acid-apatite ratio were found to significantly affect the efficiency of phosphate leaching. Phosphate extractions of more than 80 pct were obtained when minus 200-mesh ore was used and the acid-apatite ratio was 8:1 or more. The iron and aluminum oxide impurities (R203) present in the crude acid products were monitored, and R203-P205 ratios are reported. Phosphate extractions in excess of 80 pct also were obtained when phosphatic clay wastes were leached. Typically, leach slurries filtered using test leaf filters ex-hibited filtration rates of 100 lb/(h·ft2) or more.

Jan 1, 1987

By E. D. Gardner

About five minutes after 3 o'clock on Thanksgiving morning, November 24, 1927, smoke was discovered coming up No. 2 shaft of the Magma Copper Co.'s mine at Superior, Pinal County, Arizona. Of the 49 men in the mine at the time, 42 were able to make their way to the outside unassisted, but 7 perished. Six bodies were recovered, and the seventh, that of an Apache Indian cage-tender at No. 2 shaft, is thought to be in the caved section between the 1,600 and 2,250 foot levels A second and independent fire broke, out in No. 1 shift about 2 a.m., November 27, burning .out the shaft timbers from the surface to the 200-foot level and destroying the surface fan and structures. About 20 men were underground fighting the fire in No. 2 shaft, but all were safely withdrawn, aril the fire in No. 1 haft was quickly controlled.

Jan 1, 1928