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By R. E. Peterson

Scrap iron is partially oxidized at elevated temperatures in the selective oxidation process to produce iron oxide and a dense residual metal of high purity. Investigation of the process was confined to converting automobile hulks into useful products. In one test series, compressed, sheared automobile scrap was processed at 1,000° C in a 36-foot-long rotary kiln at feed rates ranging from 300 to 1,200 lb/hr. Less fuel was required to maintain the temperature at the higher feed rates because of the heat generated from the burning of the combustibles and the oxidation of the iron. The bulk density of the residual metal exceeded 75 pounds per cubic foot. In an attempt to lower the quantity of contaminants in the residual metal, another test was designed using automobile hulks which had been prepared by ripping, a low-cost method of scrap fragmentation. Before oxidizing the ripped scrap approximately 62 percent of the total copper was removed in a tumbling, screening, magnetic separation and hand-sorting system. Cast iron made from the residual metal obtained by selective oxidation contained 0.15 percent copper; iron oxide scale obtained from the kiln averaged 0.13 percent copper. Pellets made from the scale demonstrated compressive strengths necessary for blast furnace reduction; lead and zinc were removed by volatilization when the induration was performed in a reducing atmosphere.

Jan 1, 1972

By Y. Miron

Previous studies at the Bureau of Mines outlined the hazards of ammonium nitrate-fuel oil (AN-FO) mixtures in the presence of pyrite-bearing ores. The recent trend in the mining industry to strengthen AN-FO by the addition of aluminum metal raised the question regarding the effect of aluminum in AN-FO in the presence of pyrite-bearing ore. Laboratory work, similar to that done previously, demonstrated that the temperature of a self-sustaining reaction in the presence of AN-FO ore-aluminum is not lower than that for a comparable AN-FO-ore mixture. However, as might be expected from known thermochemical data, once initiated, the resulting reactions between AN-FO, aluminum, and pyrite are much more vigorous than those observed for AN-FO and pyrites alone. The temperature required to produce a self-sustained reaction for the combinations tested in this study is 250°±20° F while in the previous Bureau study, reactions were noted, in some instances, at 150° F. The different pyritic ores may be the cause of this variation.

Jan 1, 1976

By L. C. IlsLey, E. J. Gleim, F. CRAVEN

Electrical apparatus and circuits began to be used in mines about 50 years ago. A search of the literature on mining reveals that in 1882, umping was being done by electricity in some aines of England. One account tells of a small electric locomotive being used in 1882 "to drive eight corves loaded with coal" in a mine near Dresden. In an account of his visit to some English mines, en American in 1892 mentions that he saw underground electric signals, lights, pumps, hoists, and one revolving- cutter-bar 19wall mining machine,. Among the carl electrical installa- tions in the United States was an electric locomotive in the Lykens Valley Coal Co. mine at Lykens Valley, Pa., in 1887. In 1889 the Sperry electric coal digger was being tried out. Tarce mining machines were placed in the Prospect mine, East Palestine, Ohio, in 1890. An electrical pumping plant was put in oneration during 1892 in the Woodward mine of the Delaware, Lacka- rahma & Western Railroad Co. Thus we Almost coincident with the proposed use of this new servant in under- ground workings, came the thought of making it safe in gassy mines. find an account of a design for a protected stationary electric mine lamp proposed by Edison in 1831. Enclosed-type motors rere developed in the United States and shiped to English collieries about 1903. From those early beginnings there has been continuous progress until to-day one finds hundreds of pieces of specially designed electrical apparatus distributed in American coal mines and in mines of nearly all important coal-producing countries. Along with introduction of this equipment grew the idea of the necessi- ty of government aid, in standardization. In most coal-mining countries to- day the governments either directly or indirectly have a considerable in- fluence in guiding the design of electrical equipment intended for use in Pasay mine

Jan 1, 1933

By R. H. Grau, A. Sainato, S. J. Schatzel, T. M. Kohler, A. T. Iannacchione

This Bureau of Mines research study found gas emission rates from an advancing face, and flows and pressure of gas from an exploration drill hole were dependent upon the geology of salt encountered in a domal salt mine. Normal production-grade "pure" salt adjacent to an anomalous' zone was found to have a methane emission rate of less than 5 ft3/ ton (0.1 m3/t) of mined salt from a room advanced by a continuous miner. Extremely low gas flows [less the 4 ft3/h (0.1 m3/h)] and lack of pressure buildup were also observed from this normal salt in a 154-ft (47-m) exploration drill hole. These data indicate that methane emissions should not be a problem when mining in this type of salt. In the adjacent anomalous zone, methane emission rates ranged from 15 to 70 ft3/ton (0.4 to 1.8 m3/t) of mined salt from an advancing face. Gas flows of approximately 42 ft3/h (1.2 m3/h), and pressures in excess of 900 psig (6,200 kPa) were observed in an exploration drill hole when the anomalous zone was encountered. This information suggests a greater methane emission hazard from the anomalous zone than from the associated normal salt. If this trend of increasing emissions problems associated with anomalous zones of salt is common with similar anomalous zones encountered or observed in other domal salt mines, then special control strategies should be employed to minimize this potential mining hazard.

Jan 1, 1984

By Arnold P. Pipilen

In a study of the principal factors affecting the transport of coal-water mixtures through a centrifugal pump and a pipeline, the interrelation between solids concentration, velocity, and pressure drop was established for a bituminous lump coal (minus 2 inch) in concentrations up to 48 weight-percent. An optimum concentration was found to exist for maximum capacity of a given pipe-line, and for minimum energy requirements per ton of coal. Coal size degradation by particle fracture took place in the pump; abrasion and attrition to form fines took place in both pump and line. A novel system of studying flow of solid-liquid mixtures in pipelines by the determination of relative sound intensities was developed.

Jan 1, 1966

By P. L. Woolf

Three trials with oxygen-enriched unheated blast air are described. The trials were conducted in the Bureau of Mines experimental blast furnace located in Bruceton, PA. The first trial utilized moisture addition to the oxygenated blast. The second and third trial were conducted with natural gas injection. The test was basically a feasibility study and in that regard the practice was demonstrated to be feasible and also have possible advantages over hot blast operation. The testwork was conducted in 1964 and 1965 as part of a continuing study of iron making technology in cooperation with several North American Steel Companies.

Jan 1, 1985

By David K. Ingram

Research performed by the U.S. insurance industry has determined that mine subsidence is uninsurable. Consequently, the insurance industry has decided not to voluntarily offer mine subsidence insurance. The U.S. Department of the Interior has long been investigating the effects of mine subsidence. These investigations have resulted in Federal regulations and controls of mine subsidence. This U.S. Bureau of Mines report generally describes mine subsidence, the development of mine subsidence insurance programs, and the eight current mine subsidence insurance programs in the United States. The States that have these subsidence programs include Colorado, Illinois, Indiana, Kentucky, Ohio, Pennsylvania, West Virginia, and Wyoming. Major aspects of the programs include history, administrative and operational procedures, insurable structures, recognition of mine subsidence, major exclusions, claims, insurance premiums, and the economic health of each program. Addresses of agencies involved with mine subsidence insurance are also given. Information within this report can be useful for residential and commercial property owners and mine operators. States that are considering starting or have an existing mine subsidence insurance program can also use this report as a model for initiating or modifying their programs.

Jan 1, 1993

By H. G. Iverson

Solid state reactions of manganese with silica were investigated in high-temperature tests. Reactions of 0.5 to 4.0 moles manganese (Mn) with 1 mole silica (SiO2) at 1,100° C and of 2.0 Mn:SiO2 mole-ratio mixtures at 1,000° to 1,150° C yielded products consisting of a slag phase and a metallic phase. At 1,100° C, the slag phase from reactions of the low Mn:SiO2 mole-ratio mixtures was composed of SiO2 and rhodonite (MnSiO3), and the slag phase from the high Mn:SiO2 mixtures was composed of MnSiOs and tephroite (Mn2SiO4). The metallic phase from the corresponding low Mn:SiO2 mole-ratio reactants consisted of two manganese silicides, Mn5Si3 and Mn3Si; from the high Mn:SiOg mixtures, it was Mn and the manganese silicide (Mn5Si). For the higher mole ratios of MnSiO2 the manganese content in the metallic phase increased, while the manganese and silica contents of the slag phase remained nearly constant. The slags did not contain free or uncombined manganese oxide (MuO). For the 2.5 to 4.0 Mn:SiO2 mole-ratio mixtures reacted at 1,100° C, the maximum quantities of silica reduced and of the manganese in the slag appeared to become asymptotical at about 41 and 48 percent, respectively. A brominating procedure was developed that was highly selective in removing the metallic constituents from the reaction product, leaving the slag phase as residue. X-ray diffraction patterns were obtained on prepared silicides Mn5Si, Mn3Si, and MnSi.

Jan 1, 1967

By Jerry B. F. Champlin

NIOSHAn accelerated testing procedure developed by the Bureau of Mines for evaluating commercially available corrosion inhibitors is described. Ultra-sonic agitation of the corrodent solutions and the hot-finished mild steel test coupons was used to evaluate the effects of several variables on the effectiveness of two corrosion inhibitors. Small changes in the weight of the test coupons in both controlled and inhibited corrodents, before and after exposure, affected the precision and accuracy of the results. Minute amounts of oxygen in the systems were found to be causing the relatively large deviations in the corrosion developed in the controlled tests. Microscopic examination of the test coupons revealed that both surface preparation and internal strains resulting from fabrication methods materially affect corrosion behavior.

Jan 1, 1965

By John E. Husted

Quantities of kaolin in Georgia in-contiguous or single bodies had been established by previous work to be sufficient for an alumina industry. The need for characterization of this kaolin to determine its suitability as an ore of aluminum resulted in the studies described herein. It was determined in an area roughly 7 x 27 miles, known as the Wrens district that approximately 5.9 billion short tons of kaolin averaging 35.55 percent A1203 exist in an essentially continuous clay body. The Macon-Sandersville district consists of discontinuous kaolin bodies averaging 35.28 percent A1203 with an average thickness of 28 feet. Tonnages for this district are not available. One hundred and twenty core samples of kaolin were analyzed for K20, CaO, MgO, Al203, T102, Cr203, Fe203, Si02, P205, and F. The P205 and F were analyzed by wet chemistry methods and the others by electron microprobe. Seventy-nine of the samples were from the Wrens district forty from the Sandersville-Macon district and one from the Andersonville district. Emission spectroscopic analyses were also made to qualitatively determine all elements present for each core. X-ray diffraction studies were made of each core to determine mineral species present. Scanning and transmission electron microscope pictures also are given for each I' core sample. Elevations, overburden thickness, and kaolin thickness are given for each core site as well as map locations. Isopachs for over-burden and kaolin thickness are given for the Wrens district.

Jan 1, 1983

By Glen C. Ware

The Bureau of Mines determined the factors involved in the corrosion of starting sheets used in the production of electrolytic zinc with the ultimate purpose of adapting zinc starting sheets to commercial practice . Under present practice , zinc is electrodeposited on aluminum cathodes and subsequently stripped for melting . The use of zinc instead of aluminum would eliminate the need to strip the deposit , thereby reducing the cost of handling and melting it , but zinc has not been suitable because it was too vulnerable to the corrosive attack of the electrolyte . Serious attack was found to be limited to the areas of the cathodes situated immediately above the surface of the electrolyte and to re - entrant corners . It was possible to avoid solution - level corrosion by immersing the starting sheets completely , exposing only a relatively heavy suspension member to solution - level attack . Zinc starting sheets could be made as reliable as aluminum and could be continued in residence for periods up to 39 days . Periods as long as a week were feasible under conditions similar to those found in commercial practice . A test of zirconium as a starting - sheet material showed that it promoted corrosion of the deposit to a lesser extent than aluminum and that the deposit adhered less tenaciously . These two properties lend themselves to the development of ways to strip deposits mechanically from zirconium starting sheets . Titanium was unsuitable for use as a starting - sheet material .

Jan 1, 1963

By A. Gene Collins, Cynthia A. Pearson, Cathy J. Waters

The chemistry of selenium and tellurium is discussed , along with a method of preparing a synthetic oilfield brine , an oilfield brine sampling method , and methods for determining selenium and tellurium in complex oilfield brines . Selenium either can be reduced to the elemental form with sulfur dioxide and determined semiquantitatively by color comparison of the red amorphous form or can be converted to selenite and determined quantitatively by reacting it with 3,3 ' - diaminobenzidine and obtaining its spectral absorbance at 420 mu . Tellurium can be reduced to the elemental form with hypophosphorous acid , and the spectral absorbance of its red hydrosol can be measured at 400 mu . Less than 0.05 mg / 1 of selenium and 0.1 mg / 1 of tellurium can be determined by the described methods .

Jan 1, 1964

By J. P. Powell

This report provides information on the techniques and results obtained on representative waterflooding projects in Cowley County, Kans. Records show that waterflooding was begun as early as 1935, but not until 1948 was the method expanded. The greater depths to the oil-producing formations in this area compared to those in eastern Kansas undoubtedly delayed the widespread use of secondary-recovery methods. This report presents a discussion of four waterflooding projects in Cowley County, Kans. The locations of these projects are shown in figure 1. The projects have been in operation from 1 to 7 years and have produced more than 1 million barrels of additional oil by injecting 11.5 million barrels of water. The projects are designed to take advantage of elevation and height of the separator tank to collect by gravity flow the produced brine at the respective treating or storage tanks. The closed-type water system is used on three of the projects and an open-type water conditioning system on the fourth. On one of the projects, which was drilled along a narrow shoestring formation, alternate well, were converted to input wells. However, most of the input wells for flooding converted producing wells.

Jan 1, 1958

By Joseph F. Davies

To gain knowledge of the actual accident hazards present in Kentucky coal mines, reports of fatalities during 1931, 1932, and 1933 have been analyzed and the pertinent factors included in tables, accompanied by some discussion and recommendations for the reduction of accidents from particular causes. ACKNOWLEDGMENT This study was made possible through the cooperation of John F. Daniel, chief of the Kentucky Department of Mines, who made available department records, in addition to the monthly bulletine issued by his office reporting these fatalities.

Jan 1, 1934

By Michael Sokaski

A dense-medium cyclone pilot plant was built to clean 112-inch to 0 size coal. This pilot plant does not require the removal of the extremely fine material (usually minus 1/2-mm) from the feed, which is necessary in conventional dense-medium cyclone plants. The essential difference between conventional cyclone plants and the pilot plant is in the medium-recovery system. The latter uses a combination of sieve bend screens, classifying cones, and magnetic separators for medium recovery. Eight tests were run in the pilot plant at a feed rate of 5 tons per hour with four different raw coals and one crushed jig middling product. Sharp separations were obtained as indicated by an average error area of 27 and probable error of 0.047 for the 112-inch to 200-mesh size range. Magnetite loss averaged about 2.5 pounds per ton of feed. The influence of several factors on cleaning performance of the cyclone was investigated. The diameters of both the overflow and underflow orifices were found to be important for optimum cleaning performance, but these diameters could vary over a wide range without serious effect; however, if this range was exceeded, cleaning performance deteriorated. Better cleaning performance was obtained when the cyclone inlet pressure was increased from 9 psig to 13 psig. The size of the magnetite particles in the medium was found to have a substantial effect, and the best cleaning results were obtained with grade B magnetite. Demagnetizing the magnetite in an effort to decrease the effective particle size did not improve cyclone performance.

Jan 1, 1963

By Joel N. Van Sant

The rapidly expanding economy of the West, with its growth of heavy industry, and increased steel production, is primarily responsible for the refractory clay industry's concern over the adequacy of the clay supply in States of the Great Plains and Rocky Mountains. Hence, the investigation by the Federal Bureau of Mines of the occurrence and use of refractory clays in North Dakota, South Dakota, Nebraska, Wyoming, Colorado, Utah, New Mexico, and Arizona has been encouraged by the major consumers and producers of this commodity. The Wyoming investigation is a part of the national program devised to close gaps in the domestic supply of specific types of clays to determine their characteristics and properties and to provide information that will assist the refractory-clay industry. Forty-two locations of clay-bearing rock in 17 areas in Wyoming were examined (fig. 1). Location 3 was not examined during this survey. Its description was taken from an earlier report. Locations 20, 21, and 22 were previously reported but were, also, examined by the Bureau. No samples were collected from these locations because field examination indicated that the shales were not refractory grade. The Hulett, Aladdin, and Newcastle areas are discussed in the section on the Black Hills district; the other 14 areas are described separately.

Jan 1, 1961

By D. P. Schlick

As of June 30, 1970, Federal regulations required the operator of each underground coal mine to maintain the average concentration of respirable dust below legislative standards. As of March 1, 1971, over 152,000 respirable dust samples have been processed by the Bureau of Mines. Approximately 75 percent of underground working sections are being sampled in accordance with Federal regulations. Results indicate that 72 percent of the sections which have completed at least one basic sampling cycle are below 3.0 mg/m3, the standard in effect under the Federal Coal Mine Health and Safety Act of 1969 (P.L. 91-173). Notices of Violation were issued on 1,670 underground mines for failure to begin a sampling program; Withdrawal Orders were issued in 64 of these instances. Notices of Violation were issued on 1,121 sections where applicable dust levels were exceeded; Withdrawal Orders were issued in seven of these instances. There are 381 mining sections currently operating on permit; from the interim Compliance Panel.

Jan 1, 1971

By K. L. Rubow

"IntroductionAir sampling for airborne contaminants requires a system for moving air, a collection method, and a procedure to determine the quantity of contaminant collected. Because occupational exposure limits and air quality standards frequently are expressed in terms of concentrations, a method of determining the volume of air sampled is also needed. The four principal components in a sampling train are shown in Figure 12-1. The inlet admits the air sample into the train; the collector(s) separates the gas, vapor, or particles from the air; the flowmeter measures the rate or total quantity of air sampled; and the pump (air mover) provides the suction required to draw an air sample through the train. Inlet sampling considerations are discussed in Chapter 21. Various types of collectors are described in subsequent chapters. Flowmeters are discussed in Chapter 7.This chapter will describe the air mover portion of the sampling train and air sampling systems that contain three or four components in a convenient package. The chapter consists of two parts. The first part contains a brief description of the different types of air movers and air sampling systems. The second part consists of tables and figures showing detailed information on a wide variety of commercially available air movers and sampling systems. ient size is filled with a liquid in which the suspected contaminant is insoluble. When the liquid is allowed to escape from the vessel, it is replaced by air from the atmosphere to be sampled. Such an air sample is an integrated sample rather than an instantaneous sample because the mass of fluid requires a finite time to empty. In fact, by employing a large vessel with controlled drainage, this method can be used to move air at low flow rates through a sample collector for extended intervals. Additional discussion of this method can be found in Chapter 17."

Dec 1, 1996

By Wallace W. Roepke

The Bureau of Mines studied the cutting characteristics of point-attack bits to reduce airborne respirable dust and energy during cutting. Linear cutting of two coal types using four bit types at three depths of cut with three space-depth ratios was performed with a modified horizontal milling machine using an optical particle-size monitor for respirable dust sampling. The cutting action of one bit on a rotary hardhead mining machine was mathematically analyzed and compared with the results of the linear cutting test. Airborne respirable dust per unit mass cut (specific dust) was found to be a monotonically increasing function of specific energy. Specific dust and energy decrease with increasing depth of cut. The amount of nonairborne respirable dust was 100 to 1,000 times greater than the airborne dust. The plumb-bob bit produced the most airborne respirable dust and the highest specific energy of the four bits tested. Rotary cutting was a greater dust producer and energy consumer than linear cutting because of the constantly changing depth of cut, space-depth ratio, and attack angle of the bit relative to the horizontal bedding planes. A new cutting technique is proposed to minimize the existing problems of the rotary cutting machines by providing greater production, reduced dust, and minimized methane ignition potential at the face.

Jan 1, 1976

By Maria I. De Rosa

The U.S. Bureau of Mines performed experiments to determine if primary gas toxicities that evolve during the early (~300° C) and later (~.400° C) combustion stages of polyvinyl chloride and chlorinated brattices could be predicted by a smoke particle characteristic, which could be used as a simple and inexpensive test parameter. The experiments were conducted in an approximately 20-L furnace at set furnace temperatures of 2500 and 1,0000 C, for 14 min duration, with an airflow through the furnace of 10 L/min. The variables studied, as a function of time, were the hydrogen chloride (HCl) and carbon monoxide (CO) concentrations, sample and furnace temperatures, the sample mass weight loss, the average smoke particle diameter (dg and number concentration (no), and the product of the average smoke particle diameter and concentration (dgno)' Results show that the inverse of the smoke particle diameter-concentration (l/dgno) correlates directly with the primary gas toxicities evolved during both stages of combustion.

Jan 1, 1989