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By C. E. Wicks, F. E. Block, F. D. Stevenson

The vapor pressures of tungsten (VI ) chloride ( WC1 ) and hafnium ( IV ) iodide ( HFI ) were measured by a metal diaphragm technique . Vapor pressure values were obtained to permit calculation of the thermodynamic properties of the vaporization processes of the compounds . The vapor pressure data of WC16 are represented by the following equations for the liquid , B - solid , and a- solid over the temperature intervals indicated : - log P = 8.194 3,253 /T Liquid , 281.5 ° to 325 ° C : B - solid 230.0 ° to 281.5 ° C : log P a - solid 185.0 ° to 230.0 ° C : log Pam *** = 8.794 - 3,588 / T = 9.615 - 3,996 /T where T is the absolute temperature in degrees Kelvin . The heats of vaporization and sublimation are 14.9 , 16.4 , and 18.3 kcal / g mole , respectively . The entropy of vaporization at the normal boiling point , 330 ° C , was 24.3 eu . The fusion temperature , 281.5 ° C , and transition temperatures , 230.0 ° and 185 ° C , were found by thermal analysis .

Jan 1, 1964

By Forrest T. Moyer

In 1969, the number of fatal injuries in the coal mining industry was lower than in any previous year and the number of nonfatal injuries was lower than in any preceding year except 1968. Fatal injuries in 1969 totaled 203 with frequency rates of 0.85 per million man-hours of worktime and 0.36 per million tons of coal These rates were new annual lows. Nonfatal injuries totaled 9,917 with frequency rates of 41.76 per million man-hours and 17.42 per million tons. The severity rate for fatal and nonfatal injuries combined was 7,359 days lost or charged per million man-hours. The average severity was 173 days lost or charged per injury. These statistics represent the injury experience of an average of 133,302 employees per day working an average of 225 days in 5,955 coal mines for a total of 237-5 million man-hours worked and a coal output of 565 2 million tons

Jan 1, 1973

By R. A. Beall, S. L. Ausmus

The development of a completely water - free expendable graphite mold material , useful for reactive metal castings , has been detailed . Mixing and curing variables have been evaluated both by physical testing of the material itself and by castings of titanium , zirconium , and hafnium . The blend of powdered graphite , cornstarch , dextrin , cereal binder , linseed oil , and Carbowax -4000 is a successful mix when mulled in a carbon dioxide atmosphere , and properly cured and fired . The primary advantage of this material is its adaptability to standard foundry techniques ; i . e . , core blowing and hand ramming . Temperatures in the curing and firing cycles do not exceed 960 ° C , and no vacuum firing is required .

Jan 1, 1964

By W. H. Oppelt

The continuous gasification of lignite in an externally heated alloy-steel re-tort was investigated by the Bureau of Mines, Grand Forks, N. Dak., from 1945 to 1951. The main objective of the long-term experimental program was to obtain data on the mechanical performance of this type of gasification retort, particularly the alloy-steel heat-transfer surface of the retort, when operated on large pilot-plant scale. At the same time, extensive experimental data were obtained concerning the effect of process variables and the effect of a limited number of design modifications on gasifier performance. In the period covered by this progress report 4 pilot-plant runs totaling 2,879 hours of operation were completed with the rolled-plate, 310-alloy reaction tube. Over 30 million cubic feet of gas, having H2-CO ratios from 2.1 to 4.4, was made by the partial gasification of 636 tons of 1-1/2-by 3/8-inch natural lignite. Rates of gas generation were from 8,200 to 14,300 cubic feet per hour. Three of the four runs were carried out with the lowered gas offtake or continuous-annulus design modification of the gasification retort. In the final run of the series, gasification of lignite from seven different mines in North Dakota and Saskatchewan, Canada, was investigated at similar combustion-space temperatures and lignite and steam feed rates.

Jan 1, 1955

By S. S. M. Chan

The Bureau of Mines has investigated the structural aspects of shafts and support systems using the finite-element technique. In situ field measurements in deep, vein-type metal mines show that rock stresses are often higher in the horizontal direction than the vertical, and unequal in the horizontal plane. These data and laboratory and field-determined physical properties were used as input to analytical studies. Various design and construction parameters were investigated to deter-mine the effect on shaft stability. Rectangular shafts were studied in detail to determine the effects of applied stress ratio, shaft orientation and dimension, influence of interbedded quartzite and argillite, and rock fracturing. Various support systems were analyzed, including concrete lining, timber, and steel sets. Circular configurations were investigated to evaluate yield zones and liner thickness. Elliptical shafts and time effects were briefly evaluated to illustrate shape and time effects and demonstrate the methodology. It is shown that the magnitude, direction, and ratio of applied stress and rock mass anisotropy are keys to determining shaft stability. A realistic conceptual framework was developed with which to examine the rock and support interaction in deep mine shafts. Structural analysis techniques overcome some of the historical difficulties with shaft de-sign by defining the field data requirements and structural sensitivity of various design and construction parameters.

Jan 1, 1985

This is the second of a series of reports on properties of commercial motor fuels made pursuant to a cooperative agreement between the Cooperative Fuel Research (C.F.R.) Committee and the Bureau of Mines of the Department of the Interior. The first report gave data on motor gasolines sold during the winter of 1935-36.3/ These gasoline surveys report results of inspections, in oil-company laboratories, of samples of gasoline obtained by representatives of oil companies from service-station pumps in marketing areas throughout the country. In the present survey are presented inspection data on 239 samples of regular-price gasoline, 166 samples of premium-price gasoline, and 157 samples of third-grade gasoline, a total of 562 samples collected during the summer of 1936.

Jan 1, 1937

This is the second of a series of reports on properties of commercial motor fuels made pursuant to a cooperative agreement between the Cooperative Fuel Research (C.F.R.) Committee and the Bureau of Mines of the Department of the Interior. The first report gave data oil motor gasolines sold during the minter of 1935-36.3/ These gasoline surveys report results of inspections, in oil-company laboratories, of samples of gasoline obtained by representatives of oil companies from service-station pumps in marketing areas throughout the country. In the present survey are presented inspection data on 239 samples of regular- price gasoline, 166 samples of premium-price gasoline, and 157 samples of third-grade gasoline, a total of 562 samples collected during the summer of 1936.

Jan 1, 1937

By D. Harrington

The record of fatalities from mine explosions during the past 2 fiscal years has been anything but encouraging; more men were killed by explosions (379) than were killed from the ante cause during to' preceding 6 years combined (368). The reason for the large increase in the number of explosion fatalities during the past 2 years as compared with the previous 6 years is not entirely clear. In some instances, there has been laxity in the enforcement of State mining laws; in others, both workers and operating officials is have failed to observe recognized precautionary measures to prevent explosions. In many of the explosions that lave occurred within the asst few years in mechanized mines it has been evident that speed of operation and a demand for maximum tonnage at minimum cost resulted in neglect of ordinary safety measures.

Jan 1, 1942

By H. S. Kalman

A table of factors for rapid, accurate calculation of the volume of pure helium in cylindrical steel containers, at base conditions of 14.7 psia and 70° F, is presented. The table covers a pressure range from 10 to 10,000 psin in 10-psi increments and a temperature range of 0° to 120° F in 2° increments. The volume of helium is calculated from the observed pressure and temperature of the helium, expressed as a factor from the table, and the known internal volume of the container. The calculation requires a single multiplication. A discussion and evaluation of the accuracy obtainable and a derivation of the formula used (which takes into account compressibility of helium, thermal expansion of steel containers, and the stretch of steel due to internal pressure) are presented. An example showing how the table can be used is given also.

Jan 1, 1968

By David Schlain

The galvanic corrosion properties of titanium in contact with commercially pure aluminum, copper, or type 302 stainless steel in some of the common organic acids were investigated. Acids used in these experiments were 10 percent formic, acetic, lactic, citric; 1 percent oxalic and tartaric; and 9 percent oxalic. Electrode-potential measurements and several types of galvanic couple experiments were carried out. Solutions were aerated by three methods: Flow of air, flow of helium, and natural aeration. Work was done at 35° C. with couples consisting of equal areas of the 2 metals. Titanium was resistant to corrosion in most of the organic acids studied, whether alone or in contact with a dissimilar metal. However, titanium coupled with aluminum did corrode in 1- and 9-percent oxalic acid solutions. Contact with titanium usually caused aluminum to corrode by galvanic action. Copper was subject to galvanic attack in 10-percent acetic acid with a flow of air. Contact with aluminum to some solutions in which titanium is ordinarily inert and noble with respect to aluminum caused titanium to corrode

Jan 1, 1956

By N. A. Eilertsen

The Aroostook manganese-bearing deposits lie within a rectangle 30 miles wide and 70 miles long. Over 40 different deposits have been discovered in this area, but they have not been mined because the ores are difficult to treat. In 1949, the Maple Mountain area was selected for detailed investigation by the Bureau of Mines, because study by the State of Maine and the Federal Geological Survey indicated that it was the most promising in Aroostook County for developing a large tonnage of reserves. Investigation by the Bureau of Mines disclosed that all of the reported deposits of the central district were located on the limbs of a syncline underlying a pear-shaped area of 283 acres between the crests of Maple Mountain and Hovey Mountain. The ore area has been outlined by trenching and drilling along three sides of the perimeter, while the remaining side is defined by a fault. The area has a length of 6,300 feet and a maximum width of 3,100 feet. Diamond-drill holes have intersected the deposit as deep as 1,550 feet below surface, but additional deep drilling would be required to determine the intensity of folding or warping at depth. The Maple Mountain-Hovey Mountain deposit lies in the slates of Ordovician age and is classified into three zones, of which the upper, averaging about 57 feet thick, is designated manganiferous purple and red slate. The central zone, also averaging about 57 feet thick and containing the highest manganese content, is manganiferous, banded hematite. The lower zone is manganiferous, interbedded hematitic and green slate with an average width of about 33 feet. Manganese minerals occur with hematite in all three units. Trenching on the northwestern slope of Hovey Mountain uncovered other disconnected deposits of manganiferous rocks of earlier age than the ore of the syncline. The general strike of these deposits, which range from 15 feet to 75 feet in thickness, is southwest a length of 5,000 feet. They dip steeply southeast. The ore of the syncline is predominantly deep, hematitic red, inclining to red-dish black, fine-grained, dense, and thinly laminated. It is hard and siliceous. Hematite has, in places, been altered to magnetite. Because of the fine-grained texture of the ore, the manganese-mineral constituents are difficult to determine. Of the manganese silicates present, braunite is the most readily identified. Manganese carbonates and oxides are found also.

Jan 1, 1952

By Frank C. Townsend

Waste disposal schemes using spent shale in embankments require a thorough knowledge of its geotechnical engineering properties for environ-mentally safe disposal. In this context, the objective of this laboratory investigation was to determine the physical properties, geotechnical properties, and composition of spent oil shale retorted by the PARAHO and TOSCO processes. Physical properties consisted of mechanical analyses, Atterberg limits, and specific gravity determinations. Geotechnical engineering properties were determined by compaction, maximum-minimum density, unconfined compression, triaxial compression, permeability, direct shear, Ko, cyclic tri-axial, resonant column, and Los Angeles Abrasion tests. Petrographic, chemical, and scanning electron microscopy analyses were used to determine compositional features. Unprocessed shale is hard and durable and more properly described as a carbonate rock instead of shale. PARAHO is classified as a GP, while TOSCO classifies as an SM. PARAHO requires no moisture for compaction to maximum densities; however, TOSCO does. Retorting causes a loss in durability but creates self-cementing characteristics, which for PARAHO a 3-to 8-fold strength increase was observed, while for TOSCO the increase was 1.5 to 3 folds. The shear strength, compressibility, and dynamic properties of compacted PARAHO are comparable to those for sandy gravels. Compacted PARAHO is semipervious, while compacted TOSCO can be semipervious to impermeable.

Jan 1, 1979

By J. H. Holden, C. C. Shale, G. R. Strimbeck, W. S. Bowie

Electrical characteristics are presented for air in a 2 - inch pipe - type electrostatic precipitator operating under dynamic conditions at temperatures of 600 ° to 1,500 ° F and pressures of 0 to 80 psig using a negative discharge electrode . Results of this one - geometry study show that current - voltage relationships are a function of air pressure and temperature and indicate that precipitators can be used at any temperature through about 1,350 ° F over the full range of pressure . Corona starting voltage and sparkover voltage vary directly with pressure and inversely with temperature . At temperatures above 1,350 ° F use of precipitators may be limited to operations at pressures somewhat above atmospheric pressure . Theoretical derivations are presented that relate the effect of gas density on corona starting voltage and the effect of ion mobility on corona current . Deviation from the theory is noted at high current levels . Theoretical discussion is presented to explain the apparent electrical limitations for use of precipitators at high temperature , low gas density , and high corona currents , conditions at which calculated ionic velocities are extremely high . Experimental results are interpreted in terms of the theory presented . 1,500 ° F thermal ionization does not appear to be a critical factor .

Jan 1, 1963

By P. L. Swanson, A. T. Iannacchione, W. J. Gale

This paper outlines the concepts used to correlate rock failure with microseismic events and presents examples of microseismic monitoring together with associated computer modelling of the rock failure. This study is motivated by the need to develop improved ways to reduce ground control hazards in underground mining. Toward this end we present and compare results from numerical modelling and micro- seismic monitoring studies conducted at several different mine sites. Emphasis is on integrating results obtained with these tools to characterize, and thus increase our understanding of, important mine deformation processes. The ultimate goal is to use this knowledge to design mine structures, and develop mitigation measures, that minimize specific ground control hazards.

By B. D. Sartwell

The formation of alloyed regions near the surface of metals using ion implantation is being investigated by the Bureau of Mines as a means of providing corrosion resistance using much smaller amounts of the strategic alloying metals. Two ion implantation systems that can implant low-energy chromium, nickel, or aluminum ions into low-cost substrate materials such as iron or carbon steel have been designed and constructed. The development of the ion source, ion beam acceleration stage, mass analysis system, and target chamber are described in detail. The ion-implanted alloys have been characterized using proton-induced x-ray emission to give the total number of atoms implanted and to determine the extent of any surface contamination introduced by the ion implantation process. Research conducted at other laboratories on metallurgical applications of ion implantation is given.

Jan 1, 1980

By J. Bruce Clemmer

[Gypsum is one of the mo .. t iJf.l)ortant nonmp.tal1.ic T!1inerals, as is indicat-? ed by the fact that tlle Uni ted states cO!1sUl:Ied p, roximn..tely 3,500,000 tons of natura.l and calcinecl e::,j;-psum in 1937. The b\.'.ilr:.in.; traces \"fe.ro the largest users and required 2,520,000 tons of calcine for the r-roductiop. of plaster,]

Jan 1, 1941

By John C. Hartley

Large areas of the anthracite beds in the Wilkes-Barre, Pa., region have been first-mined in such a manner that over half of the original coal has been left underground as pillars to support the overburden. To recover the maximum amount of this remaining coal, improved devices to support the roof while pillars are being extracted are needed. Also needed are suitable backfilling systems that will stabilize the strata during the mining and effectively limit the inevitable subsidence after pillars are removed. Accordingly, the Federal Bureau of Mines furnished 400 yielding steel props that had been purchased abroad, where this type of prop had been used successfully. The cooperating company arranged for concurrent tests with a mechanical stower designed and built by an American manufacturer. In the area in which the experiments were conducted, pillar removal, using conventional timbering, was most difficult because the roof fractured badly, the installation of timbers consumed a substantial part of the work effort, and some coal nearly always was lost. With the application of the yielding props, the time needed for securing the roof was reduced 33.9 percent; production per man-shift was in¬creased over 33 percent; coal recovery was improved more than 9 percent; and the convergence between roof and floor, during mining and backfilling, amounted to as much as 8.03 inches without any break in the roof. However, in September 1953 some roof rock fell in pillar 10 owing to insufficient props in a small area where the ends of three top holes drilled in the coal face extended up into the roof rock.

Jan 1, 1956

By J. A. Kost

A dust-control manual was prepared for use by mine operations personnel. The manual documents state-of-the-art control techniques, dust sampling, and use of personal protective devices. Content addresses advantages/disadvantages of control techniques, design and operating specifications, and implementation and maintenance guidelines. An indexed list of selected references is also included. In addition to the completed manual, this report documents work performed in the course of its preparation.

Jan 1, 1981

By J. P. Hansen

Wustite beds were reduced with carbon monoxide and mixtures of hydrogen and nitrogen in the temperature range 900° to 1,300° C to determine the effect of temperature, gas flow, and surface area on the rate of reduction to iron. The composition of the gas stream as it passed through the wustite bed was continuously measured with infrared absorption cells and heated-wire methods. The change in composition was used to calculate the reaction rates. Arrhenius plots of the data give heats of activation of 34 kcal for particles using CO, 27 kcal for particles using H2, 24 kcal for pellets using C8, and 6 kcal for pellets using H2. The velocity of reduction is dependent on the area of reacting interface and the driving potential of the gas (reducing gas concentration minus equilibrium concentration) as well as the exponential temperature effect. The reaction rate was independent of the gas velocity over the range of conditions studied.

Jan 1, 1965

By Scott W. Hazen

This report describes exploration for lead-zinc ores at the Madonna mine between 1945 and 1953 by the Utze Lode Co., the Bureau of Mines, and the company with Government financial aid under the Defense Production Act of 1950. The Madonna mine yielded silver, lead, and zinc with a net smelter value of over $5,000.000. from 1882 to 1924. The mine was inactive from 1924 to 1942 when the Utze Lode Co. acquired the property. Possibilities for finding ore in the mine, especially at depth, were considered favorable. The Utze Lode Co. began rehabilitating the Madonna mine in 1945. An exploration program, which consisted of winze sinking and drifting, failed to produce commercial are.

Jan 1, 1956