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By E. D. Palmes

This report was prepared by New York University Medical Center, Institute of Environmental Medicine, 550 First Avenue, New York, New York under USBM Grant Number G0133066, Personal Samplers for CO, NO and NO2 in Air. The grant was initiated under the Coal Mine Health and Safety Program. It was administered under the technical direction of the Pittsburgh Mining and Safety Research Center with Dr. George H. Schnakenberg acting as the Technical Project Officer. Mr. L. Young was the contract administrator for the Bureau of Mines. This report is a summary of the work recently completed as part of this grant during the period 3/1/73 to 11/30/76. This report was submitted by the authors in March, 1977.

Jan 1, 1977

By Stephen Gerard Sawyer

This report presents a Fortran IV computer program for the structural analysis of space-frame protective canopies used in underground mines to protect equipment operators from falls of roof, face, or rib. This program entitled CANOPY permits rapid calculation of the elastic strength of a canopy for a variety of static loading conditions. Stresses in, and displacements of each structural member are computed and printed out. Additionally, identification of all members that have commenced yielding, weight of the canopy, total loads on the canopy, and maximum loads that the canopy can sustain elastically are output. Program description, input instructions, program listing, and two example problems are included.

Jan 1, 1972

By Eric E. Unger

Results are presented of a census of the machines used in surface coal mines in the United States. The numbers of each machine type and model reported to be in use are tabulated for large and small mines in the Eastern, Central, and Western regions. Also tabulated are the average daily usage times of the major machine categories and the numbers of machines that have acoustical and other cabs. Projections of the total numbers of primary production machines are given. It is found that heavy tracked dozers and wheeled front end loaders constitute the most prevalent machine types, and that generally a very few models of machines made by one or two manufacturers constitute a major fraction of the population in each machine category. About 70 percent of all machines are reported to have some kind of cab, and about half of these are reported to be acoustical gabs; it is noted that acoustical cabs generally came into significant use since about the early 1970's. It is observed that the percentage-wise mixes of equipment types used in the various categories of mines differ significantly for only a few types of machines, notably for heavy dozers and loaders, and for haulers, highway trucks, and internal-combustion engine-powered shovels and draglines.

Jan 1, 1977

By Paul M. Tyler

Magnesite is of importance primarily as a refractory material for lining steel furnaces , although substantial amounts are used in the production of flooring compositions and other building materials and for certain chemicals , notably epsom salts . Since consumption for all of these purposes is largely in the eastern United States and domestic deposits are situated in California and Washington , this country's magnesite mining industry , which was created largely by war- time conditions , has subsequently been sustained by tariff protection .

May 1, 1931

By B. Gillenwater

This report describes the results of investigations into four specific areas related to trolley wire power distribution systems in coal mines. These are: 1. Partially insulated (shielded) trolley wire 2. High-speed insulator fault detectors 3. Dual-wire trolley systems 4. Insulator failure indicators. Prototype devices or designs were developed in each area. In addition, a brief survey was made in an attempt to assess the Future of mine trolley systems, and data was collected and reviewed in an attempt to analyze the nature of trolley wire related accidents. Other options for decreasing the risks associated with trolley systems that arose .during the study are briefly described in appendices. These include insulating equipment and miners from return and/or energized conductors and use of a segmented trolley wire with local control of current delivering capability.

Jan 1, 1981

By Steven J. Schatzel

Large-scale methane releases in dual salt mines have resulted in ignitions and mine fatalities as recently as 1979. Several past studies have implied that hazardous methane occurrences in U.S. salt domes are distributed neither uniformly nor randomly, but are geologically controlled and potentially predictable. A first step by the Bureau of Mines in addressing the problem of methane in deal salt mines required development of a new test to determine volumes of gases in solid salt samples. This report considers the results achieved when 80 deal salt samples were tested for gas content by dissolution in a controlled atmosphere chamber. Criteria were organized to delineate salt types based on geological occurrence. Outburst samples range from 0.014 to 7.4 cm3 CH4/100 g NaCl, anomalous salt samples from 0.0027 to 2.6 cm3 CH4/100 g NaCl, and normal salts from less than 0.0003 to 0.31 cm3 CH4/100 g NaCl. The presence of higher hydrocarbons was most common in samples containing larger quan¬tities of methane. The presence of higher hydrocarbons appears to be useful in detecting methane hazards where some methane may be lost before gas content testing. An exploratory rotary and/or core drilling program, dissolution testing for gas content, and up-to-date geologic mine napping could allow a mine operator to assess methane hazards in dual salt.

Jan 1, 1984

By G. S. Scott

In the course of the Bureau of Mines investigation relative to the causes, behavior, and control f anthracite-mine fires, attention was directed toward the correlation between the temperature of oxidation and the gaseous oxidation products in the range of temperatures between 100° and 350°C4/ These tests, made on a high-grade anthracite to determine the amount of oxygen consumed and the amounts of carbon dioxide, carbon monoxide, hydrogen and methane evolved when air was passed through samples of the anthracite at various elevated temperatures, showed that the gases evolved and their relative proportions vary with temperature, constitute a means for determining the probable temperature of the anthracite, and thus permit detection of incipient heating before a dangerous fire hazard exists. As the relationships mentioned are affected somewhat by the amount of previous oxidation of the coal, it was deemed desirable to know to what extent they might vary owing to this cause. It was also considered desirable to have a means for estimating the extent of oxidation from the gas analysis, as this would permit a more accurate estimate of probable temperature. Finally, it seemed desirable to know how much the composition of coal might vary over an extended period of oxidation, since this was previously suggested5/ as a possible means for estimating the probable maximum oxidation temperature to which a sample of coal had been subjected.

Jan 1, 1940

By H. Kenworthy

"INTRODUCTION ..Although the occurrence of iron ore in Missouri was recognized by Marquette as early as 1673, the first known mining and smelting operation was conducted in 1815. This operation was near Arcadia, Iron County, the first of its kind west of the Mississippi-Ohio River system. Several small furnaces of short life were erected in Missouri in the ensuing 30 years. However, until the extensive deposits of Iron Mountain and Pilot Knob were opened between 1843 and 1850, the state remained a minor producer of iron. It was this district which was chiefly responsible for the prominent position Missouri held in the iron industry until the late 1880's. At this time the easily minable high-grade ores became exhausted and the discovery of the immense Lake Superior deposits depressed the raw-ore price to such an extent that any mines ceased to operate. 3/Small yearly production of iron ores continued in Missouri to the present. Owing to war demands for hard ore suitable for open-hearth steel, the M. A. Hanna Co., through its subsidiary, the Ozark Ore Co., reopened the Iron Mountain, deposits and installed new equipment in an old concentrator to handle the low-grade ores left from previous operations. At present, ore production is from open pits, but underground mining is contemplated in the future. About 2,000 tons a day of iron ore is treated by gravity concentration of material from the open pits in the immediate vicinity. The concentrate is shipped to the Birmingham, Ala., district and to Granite City, Ill., for smelting. The coarse tailing is sold for ballast and concrete aggregate. The iron requirements of the concentrate stipulated by the purchaser are not difficult to meet, but the phosphorus is frequently higher than desired. For 1946 the concentrates averaged 54.18 percent iron and 0.235 percent phosphorus with low sulfur. The Ozark Ore Co. concentrate, however, sometimes contains as much as 0.40 percent phosphorus. The phosphorus in ores from those portions of the deposits wherein the phosphorus occurs with siliceous gangue is readily rejected in the milling, but in much of the ore the phosphorus is associated with the iron and concentrated with the iron minerals. Selective mining is impossible owing to the spotty occurrence of the phosphorus mineral. Often within 5 feet the ore will change from low phosphorus to high phosphorus, and it would be expedient to find a method of rejecting enough phosphorus at the mill from the latter type of ore to meet the phosphorus specification."

Feb 1, 1948

By Beatrice Lukens, David Schlain, John D. Prater

"The electrolytic manganese process4/ developed by the Bureau of Mines involves the electrolysis of a solution of manganese sulfate and ammonium sulfate in a diaphragm-type cell. Metallic manganese is deposited on the cathodes, and sulfuric acid is produced at the anodes. The spent electrolyte contains, in addition to the sulfuric acid, approximately 40 percent of the manganese sulfate and most of the ammonium sulfate originally present in the feed solution. This spent solution is used to leach fresh ore that has previously been subjected to a reducing roast. The resulting leach liquor is purified and returned to the cell.Manganese of very high purity is produced by the electrolytic process. The properties of this metal are so different from those of the best grade of manganese that can be made by any other commercially feasible process that it is virtually a new material. Electrolytic manganese has been used in the preparation of new high-manganese alloys with valuable properties.3/ and further developments are to be expected. The electrolytic manganese process not only results in a product of superior qualities, but is applicable to large tonnages of domestic ores that are unsuitable for direct use in producing ferromanganese.The future industrial use of electrolytic manganese is of course, related to its cost. Decreases in the cost of production will lead to wider use of the metal; conversely, increases in the volume of production made possible by greater demand will bring further .decreases in cost."

May 1, 1946

By McHenry Mosier

The Bureau of Mines, United States Department of the Interior, has established a testing adit on the Government reservation at Mount Weather, Virginia, to facility to research on the fundamental tats of mining under actual metal-mining conditions. A number of sites in several Eastern States were investigated, out Mount Weather was selected because the rock seemed best suited for rock drilling and other mining tests and because the ground was already owned by the Federal Government, the site having been acquired in 1902 for use of the Weather Bureau. The testing edit has an advantage over en active metal mine for certain investigations because variable conditions affecting any particular research problem can be controlled and maintained in a fixed status, whereas in an operating mine this seldom is feasible. Operations were begin September 1935, with a crew of four laborers under a resident engineer. The laborers were recruited from, nearby farms, and. although they had no previous mining experience, they have developed into satisfactory miners.

Jan 1, 1939

By Oliver Bowles

Limestone, including dolomite, is the most widely used of all rocks - nearly 300 million tons annually in the United States alone. It occurs in some form in every State and is produced in thousands of localities. Because of its attractiveness, substantiality, and durability it is employed extensively as a building stone. In crushed and broken form it is used for concrete aggregate and railroad ballast and in highway construction, metallurgy, agriculture, and a host of chemical and industrial processes. This paper proposes to furnish general information on the origin and occurrence of limestone and dolomite, chief production centers, major uses, and methods of quarrying and preparing stone for market. Footnote references will guide the reader to sources of more complete information.

Jan 1, 1956

By G. R. Hopkins

For several years prior to about the middle of 1928 both the number and capacity of natural-gasoline plants showed a steady increase; this resulted from a material gain in the supply of casinghead has due to the discovery of a number of flush fields with relatively high gas-oil ratios. From 1928 to date some form of proration has been continually in force, with a consequent curtailment in the supply of wet gas. This decline in available gas and a severe decrease in prices, due largely to the increasing competition of light refinery products, has eliminated virtually all of the weaker units during the last 5 years, with the result that the number of plants declined from 1,155 on January 1, 1928 to 19035 on January 1, 1930, to 909 on January 1, 1932, and then to 859 on January 1, 1934, The struggle of the small high-cost producers to exist is illustrated further by the trend in the number of shut-down plants, which has increased from 36 on January 1, 1930 to 100 on January 1, 1932 and to 128 on January 1, 1934. The increase in the number of plants prior to 1929 resulted in a material gain in the total capacity, but the decline in number between 1929 and 1932 was not followed by a corresponding decrease in capacity, as gains resulting from the construction of a few very large plants overbalanced the loss due to the dismantling of a large number of small ones. However, the low prices of 1932 and 1933 supplied little incentive for new construction, and the total capacity declined in approximately the same ratio as the number. Thus the total capacity declined from 11,387,000 gallons daily on January 1, 1932 to 13,060,000 gallons daily on January 1, 1934, Of the latter 9,181,000 gallons (91 percent) represented the capacity of the operating plants and 679,000 gallons (9 percent) the capacity of the idle plants.

Jan 1, 1934

By Corate L. Brierley

Low-grade porphyry copper ores containing chalcopyrite as the primary mineral was leached by two strains of acidophilic, thermophilic microbes belonging to the genus Sulfolobus. Leach tests were conducted in glass columns heated to 60-70° C. Pinto Valley and San Manuel ores sized to -1/2 inch + 50 mesh were effectively leached by the thermophilic organisms, but pinto Valley and Cyprus Bagdad ores sized to -2 inch + 1/2 inch resisted leaching. Aeration did not contribute measurably to bacterial copper extraction, since two columns, one inoculated and one sterilized, having a rest/ leach cycle without recurrent aeration exhibited copper extraction patterns similar to those of the aerated columns. Distilled water can be substituted for 9K medium without diminishing copper extraction. Decreasing the pH of the leachate to about 1.8 enhanced the extraction of copper from pinto Valley ore with the thermophilic microbes. Thiobacillus ferrooxidans was found to be relatively ineffective at copper extraction from pinto Valley ore. Of eleven solvent extraction reagents tested, Adogen 364 and Warsol at concentrations of 0.1% and 0.012 were inhibitory to oxygen uptake by the two Sulfolobus strains. Di-2-ethyhexyl phosphoric acid at concentrations of 0.1%, 0.01% and 0.001% were totally inhibitory to the respiration of both organisms.

Jan 1, 1979

By R. A. Vik

The influence of thermal treatments on the grindability of low-grade hematitic iron ores from Michigan and Minnesota was examined in bench-scale tests. Treatment factors were roasting temperature, roasting atmosphere, and ore cooling conditions. Bond ball mill grindability and work indices were used as response indicators in evaluating the condition of the ore. Of the three treatment factors evaluated, roasting atmosphere, which brought about the con version of iron oxides to magnetite, had the most significant effect; roasting temperature had the next most important effect; and cooling condition had the least effect. Optimum grindability was obtained with reduced-quenched products of both ores at 650° C, near the alpha-beta phase transformation of quartz.

Jan 1, 1971

By R. Barany

This report contains the results of experimental work conducted by the Bureau of Mines to obtain the heats of formation at 298.15° K. of analcite, dehydrated analcite, lawsonite, anorthite, hexagonal anorthite, and leonhardite. Thermodynamic data for these minerals have applications in ceramics, extractive metallurgy, and particularly in geochemistry. Except for data on anorthite, no previous similar data existed. The present results will be a substantial aid in deriving the temperature-pressure-equilibrium relationships among these minerals. The heats of formation were determined by solution calorimetry, with hydrofluoric acid as the reaction medium. The results were expressed both in terms of the constituent oxides and in terms of the constituent elements. The heat of formation data were combined with related entropy values to obtain the free energies of formation at 298.15° K.

Jan 1, 1962

By D. Harrington

The mining industry of the United States has for many years possessed the dubious aistinction of having the poorest accident rate of all of the major lines of industrial endeavor in this country, and until recently there ras little or nothing to show that any material improvement might be expected. However, there are now numerous trends indicating that the corner has ceen turned at last, and it is strongly hoped that the mining industry is likely to follow the railroads, the cement and other industries in operating with occurrence of only a reasonable amount of loss of life and limb through accidents. The complete accident figures for metal and nonmetallic mineral mining for 1931 are not yet available, but fragmentary data shor that 1831 vill un- questionably have very low accident rates, probably the lowest in the history of our metal mines. One underground metal mine has produced over 14,000,000 tons of copper ore rithout a fatality; another metal mining company with an electric slovel operation has handled upwards of 75,000,000 tons of material, copper ore and waste, without the occurrence of a fatality; an iron-ore compan, which orns six mines (three underground, three open pit), has operated every one for a year or more without a lost-time accident with a con- siderable number of employees and a large production; and alot.er iron-ore producer with 30 mines and about 3,000 employees as an average of nearly 10 months of operation in 1931 without a lost-time accident. umerous other wonderful safety records of metal mines in 1931 indicate unmistaimbly tat the record of the noncoal mining industry of the United States as a role in 1931 will undoubtedly be found to be excellent. According to the latest relatively complete figures (those of 1930) available for the coal industry, fewer than 650,000 persons are employed in and around the coal mines of the United States, the figures indicating at a little over 493,000 people are engaged in bituminous mining and a little under 151,CCO in anthracite mining. Bureau of Mines complete figures suc that 2,053 persons were killed and 103,821 non-fatally injured in our coal

Dec 1, 1932

By Paul C. Hyndman

Three properties in the Tuolumne River RARE II area, the Eagle Bluff Mine (lode) and the Indian Creek Bar and Bossy Bar Prospects (placer), have identified subeconomic gold resources (table 1). Nineteen other properties have potential for gold resources. Adjacent to the study area, five properties have identified mineral resources, and nine others have potential for resources. Properties having high-grade zones (shoots), but licking enough tonnage to be classified as resources, are listed in table 2. Gold, in lode and placer deposits, is the principal mineral commodity in the Toluene River study area. Ten properties within the RARE II boundary have gold-rich zones or shoots; they range in size from 12 to 2,500 tons and in average grade from 0.09 to 0.97 oz gold per ton.

Jan 1, 1983

By Noel N. Moebs

The coal wants at the Westland Mine in southwestern Pennsylvania consist chiefly of elongated, sandstone-filled channels with slickensided basal contacts. Tentatively identified as washouts, these channels are about 1,000 feet long and 300 feet wide, are erratic in occurrence and trend, and are difficult to delineate from the customary core drilling pattern. Roof conditions are hazardous adjacent to the washout contact, but roof stability is generally unaffected greater than 30 feet away.

Jan 1, 1981

By S. P. Sandoval

Previous research by the U.S. Bureau of Mines demonstrated that nonionic surfactants increased the leaching rate of copper in the flask leaching of chalcopyrite with ferric sulfate if sufficient ferric sulfate was present. This research was continued by the Bureau in Part 2 to further explore the application of nonionic surfactants to the dump leaching of chalcopyrite. A polyoxyethylene lauryl ether was selected as the superior nonionic surfactant tested at 25° and 50° C. The addition of the surfactant increased copper leaching by 116 pct at 25° C and 1.0 pct solids and by 61 pct at 50° C and 0.5 pct solids at Fe 3+ concentrations greater than 1 g/L. At 0.1.0 g/L Fe 3+ and below, the addition of the surfactant produced as much as a 35 pct decrease in leaching. Each of the nonionic surfactants studied was found to be heavily adsorbed by a typical chalcopyrite ore, which poses a serious barrier to the application of nonionic surfactants in an actual chalcopyrite dump.

Jan 1, 2010

By S. M. Shelton, W. A. Calhoun, M. M. Fine, T. L. Johnston

"FOREWORDFerrograde manganese ore or its equivalent is essential to the manufacture of every ton of steel produced; although it is well known that there are large deposits of low-grade are in the United States, the production of substantial amounts of ferrograde material from domestic sources presents a problem that becomes more and more critical as the stockpiled ore depleted through inability to procure adequate supplies from foreign sources. Consequently, a program of laboratory,and pilot-plant investigation designed to solve the problem of obtaining a domestic supply of manganese has been undertaken by the Metallurgical Division, Bureau of Mines.This paper is one of a new series that include reports of results obtained in the various investigations conducted under the manganese program. The scope of the program and the organization that was set up to direct and supervise the were discussed in the foreword of the first paper of this series, Report of Investigations 3606 Manganese Investigations. 1. Concentration of Manganese Ores,from the Drum Mountain District, Utah, by S. R. J. D. Vincent, and C. R. Schack. Other reports will be published as the work progresses."

Mar 1, 1942