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By Jonas Addai-Mensah

Despite the fact that nickel (Ni) laterites accounts for about 60 % of the world?s nickel mineralization, commercial processing of complex, low grade Ni laterite ores by conventional beneficiation (e.g. magnetic, electrostatic and flotation separation) still presents intractable challenges, particularly in heap leaching. Invariably, low grade laterite ores require aggressive hydrometallurgical techniques (e.g., highly acidic lixiviant leaching at ambient or elevated temperatures) for Ni and cobalt (Co) extraction. As a precursor to heap leaching, agglomeration of the multi-mineral phase feed particles into robust and porous granules of 4-10 m permeable bed, is essential. In the present work, several basic and applied studies of the agglomeration behavior of real Ni laterite ores and selected oxides and clay minerals (hematite, quartz smectite and kaolinite) which constitute the predominant host gangue phases of typical laterite ores are performed. Isothermal, batch agglomeration tests involving sulphuric acid solution as a binder were carried out to produce coarse, narrow-sized (5 ? 40 mm) granules which were well characterized. The influential role of feed ore characteristics (e.g., mineralogy/chemistry and primary particle size distribution) and binder composition (30 vs. 44% w/w H2SO4) and dosage (15-25 wt.%) in agglomeration behavior and granule properties were examined through several characterization techniques including granule size, compressive strength, bed percolation and re-wetting stability and 3-dimensional micro-structure analyses. Links between feed mineralogy/chemistry and size, binder formulation, agglomeration behavior, curing conditions and final granule properties and structural characteristics are established. The implications of the findings to Ni laterite plant agglomeration for enhanced heap leaching are discussed. Keywords: nickel laterite, complex low-grade ores, agglomeration, heap leaching, micro-structure

Sep 1, 2012

By S. L. Zheng

The compound material of Nano-TiO2 Supported on the diatomite was prepared by the hydrolytic method with purified diatomite and TiCl4. The compound material was characterized by SEM, XRD, TEM, EDX, XPS, and the application test of the compound material was studied. The characterization test results showed that the Nano-TiO2 was coated on the surface of diatomite, the crystal of TiO2 is anatase, and the average crystal size is 12 nm. The pore diameter was reduced, but pore volume and surface area of the compound material are increased after Nano-TiO2 Supported on the diatomite. The application test results for treating coking waste water and formaldehyde gas show that the compound material of Nano-TiO2 / diatomite has adsorption and photo-catalytic function and strong degradation performance for phenol and formaldehyde.

Jan 1, 2014

By Irena Grigorova, Tashka Ignatova, Ivan Nishkov, Andrian Valchev

"Feldspars used by ceramic and glass industries as fluxing agents are mainly obtained from high quality feldspar deposits. The demand for feldspar as raw material for industrial applications especially in ceramic manufactures is continuously increasing. However, due to the depletion of those deposits, the research activities related to the recovery of feldspar from the lower grade feldspar deposits and feldspar bearing rocks such as pegmatite, granite, arkosic sandstone and syenite have been intensified in the last two decade. In Bulgaria, the main deposit of arkosic sandstone is located in the area of Shumen town, NE Bulgaria. In Srednya deposit arkosic sandstones are found in Upper Cretaceous sediments (Santonian). In this formation, there are two major industrial minerals - feldspar and quartz. They may be of economic value and possibly suitable for commercial uses. The main purpose of the present study was to investigate the beneficiation and upgrading processes of Srednya deposit arkosic sandstones. In a laboratory scale it was studied the possibility to obtain the feldspar concentrate and quartz sand from arkosic sandstones. Particle size distribution, chemical and mineralogical compositions of quartz-feldspar sands were determined. The bench-scale tests using the KOALIN AD laboratory experimental facilities were conducted. Many processing techniques were tested: disintegration, washing, sizing, carbonate flotation and feldspar flotation. The experimental results show that there are possibilities to obtain the silica sand with low content of Fe2O3 - below 0.02 % and potassium feldspar with content of K2O > 14 %. A new technology for recovery of feldspar and silica sand from arkosic sandstone was developed."

Jan 1, 2014

By F. Karakas

In this investigation, one of the most energy consuming stage of the cement manufacturing process, grinding stage, was studied. The aim of the study is to reduce the energy consumption. Optimum operating parameters were determined. Experimental studies were performed at three differ-ent stages. Grinding of limestone, clay and marl which are the main components of the cement, to approximately below 90 microns, was the first stage of the cement grinding. At this stage, effect of feed size and ball charge were investigated. At the second stage, the Bond work index of clinker and additives (slag, trass, limestone and gypsum) was found separately. After forming composite cement with clinker and additives, the Bond work index of this mixture was also determined, thus the results of separate grinding and grinding of mixture were compared. The Bond work index of mixture was found as 13.59 kWh/t, while the arithmetic mean of the Bond work index values of components was 14.90 kWh/t. Finally, clinker and additives (slag, trass, limestone and gypsum) were ground under the same conditions. At this stage, laboratory type of ball mill was used in order to understand grinding characteristics of the cement components. As a result of the experiments, it was found that energy consumption for the grinding will be lowered if the mills with 38 % ~ 40 % ball charge are used in the cement grinding. Moreover, grinding with mixture of clinker and additives gave better results than separate grinding of these components in terms of energy consumption.

Jan 1, 2014

By B. K. Mohapatra

Small manganese ore bodies in south Odisha, India occurs both as stratiform and stratabound ore bodies. These two ore bodies show contrasting mineralogical, petrographical and chemical characteristics. Stratiform type of Mn-ores consists of manganese, iron and silicate- phases in approximately same proportion. In contrast, stratabound ore bodies contain a high proportion of manganese oxides, silicates and phosphorus phases. Phosphorus is found within apatite in the stratabound ore bodies while in the stratiform ore it occurs as an adsorbed state with iron phase (goethite). Both ore bodies are low-grade (17-23% Mn) therefore do not have a market value. However, the stratabound ores are enriched in phosphorus (P2O5: >1%) compared to the stratiform ores. Both the ore types were processed through gravity, magnetic and roast reduction followed by magnetic separation techniques. The strata bound ore could be upgraded to 33% Mn from a feed of 23% by combination of dry and wet magnetic separation methods. But the phosphorus content also suits up (P2O5: 1.2%) in the processed product making it unsuitable for further use. The stratiform ores do not respond to either gravity or magnetic separation because of close association of manganese with iron phases. However, this could be beneficiated through roast reduction followed by magnetic separation. An ore with 17% Mn content could be upgraded to 40% Mn with a 42% yield and 78% recovery. The goethite, having phosphorus, converts to magnetite and is retained within the magnetic fraction, thereby reducing the concentration of phosphorus in the non-magnetic fraction, which becomes the product. This report demonstrates the influence of ore petrology in determining the up-gradational potential of manganese ore in the southern Odisha, India. Keywords: manganese ore, physical beneficiation, phosphorus rich ore

Sep 1, 2012

By S. Kelebek, A. Khan, J. Caceres, Beckett. D.

"Pyrrhotite in nickel-copper sulphide ores is nickeliferrous and intimately associated with pentlandite. Due to its low nickel content, pyrrhotite rejection is an important step in processing of these ores. In our laboratory, various reagents were investigated for their effect on pyrrhotite depression. Among these, a combined use of triethylenetetramine and sodium metabisulphite was found highly promising.The work described in this paper has two parts. The firs part is a summary of results obtained on process samples from the pyrrhotite rejection circuit at Falconbridge’s Strathcona Mill. The second part involves simulation of the circuit performance based on the reagent conditions used in the experimental work and the concept of split factors.Two sets of reagent conditions were evaluated. The first one involved baseline conditions, simulating the current reagent performance. The second one simulated the impact these new reagents can have on the circuit performance.The simulation results obtained under baseline conditions indicated a good agreement with the current circuit performance. The simulation results suggest that at practically the same pentlandite recovery and tailing grades, the circuit concentrate nickel grade can be doubled through effective pyrrhotite rejection by these new reagents."

Jan 1, 2003

By A. V. Bogdanovich

In diamond ores processing, final waste tailings size, rejected to dump, is one of the most important parameters. On one side, it is necessary to minimize losses of diamonds, whose size exceeds 1 mm, on the other side ? to provide for the plant high throughput and sufficiently low capital and energy costs, which is in greater part connected with disintegration process. Extensive laboratory, pilot-scale and commercial-scale dressability studies of different types of diamond ores have been performed at JSC ?Mekhanobr Engineering? in recent years. With that, special consideration was given to determination of the required ores? disintegration size that would provide for a high recovery of diamonds. In diamond ores processing, in order to exclude breaking of large diamonds, stage disintegration is used with regrinding of light fractions and heavy fraction X-ray fluorescent separation tailings. On account of rather weak bonds of diamonds with enclosing minerals, in crushing and grinding of diamond ores, selective disintegration takes place, with aggregates? breakup along plane surfaces of least bonding, which facilitates liberation of diamonds and their transition to free state. Heavy components losses with different sizes of final dump tailings were studied in processing of large samples. It was established, that in order to almost completely exclude losses of heavy components over 1 mm size, light fractions had to be ground to 2.5-3 mm size, while X-ray fluorescent separation heavy tailings of -15+3 mm size do not contain diamonds larger 1 mm in aggregates, and their regrinding does not increase total recovery of diamonds. On the basis of the conducted studies, relationships regarding heavy components and diamonds losses with respect to diamond ores final disintegration size were obtained, providing for more rational organization of the ores disintegration and processing flow sheet. Keywords: diamond, waste tailings size, disintegration process, recovery of diamonds

Sep 1, 2012

By Zofia Swierczek

This paper reports the results of a detailed mineralogical study of typical, low-grade Australian nickel laterite run-of-mine ores. Successful development of an effective beneficiation process for upgrading such low grade laterite ores relies on good knowledge of the laterite mineralogy and the value metal(s)? distribution characteristics. Both QEMSCAN and quantitative X-ray diffraction techniques were used to conduct the mineralogical analysis of three types of laterite ores, and the results were compared with those obtained by chemical analysis. Some of the major challenges faced included accounting for the mismatch between the nickel values measured by QEMSCAN and those recorded by chemical analysis. This was primarily due to the relatively low concentration of nickel in the ores and its wide dissemination among several major host minerals in complex association. Careful analysis showed that the limit of nickel detection in iron oxide host mineral grains under normal operating conditions was around 4%. Keywords: nickel laterites, mineralogy, characterisation, QXRD, QEMSCAN

Sep 1, 2012

By Johannes Käppeler, Alexander Weh, Harald Giese, Klaas van der Wielen

"High voltage breakage is a novel comminution technology that shows considerable potential for various applications in mineral processing and recycling. It relies on highly energetic electrical pulses to induce electrical explosions in rocks, causing the formation of plasma channels and powerful shockwaves that result in fracturing and fragmentation of particles. There has been considerable interest in this technology for its ability to weaken rocks and preferentially liberate target minerals, as previously demonstrated by other authors. Weakening has the potential to significantly reduce energy consumption during comminution, or alternatively, increase throughput of a circuit. Better liberation may yield an improved concentrate grade and/or recovery, reduce fines losses to tailings or increase the grind size required for liberation, thereby also reducing energy requirements. This review aims to increase general awareness of this technology, and promote further research into it by providing a general summary of the theory underlying high voltage breakage, as well as the envisaged applications of this novel technology. A brief history of the technology is presented before progressing onto the physics underlying the electrical and geomechanical aspects of high voltage breakage. Key results regarding weakening and liberation are discussed, and some mention is made of current challenges and planned developments to increase the throughput of high voltage breakage units to the level where it can be integrated into new and existing processing circuits."

Jan 1, 2014

By Y. B. Zhu

Soil reconstruction and improvement trials and vegetation experiment is carried out at Shuilong-shan acid rock waste dumps at Dexing Copper Mine in China. pH value, Cu2+, Pb2+, Zn2+, etc. concentration in acid rock drainage (ARD) is also monitored every month since 2005. The results of experiment show that: Lime and topsoil stripped from open-pit is appropriated soil improvement material. Full cover soil improvement method is suitable for flat area, contour soil improvement method and hole soil improvement method is appropriate for slope area. The optimal plant species is ligustrum lucidum Ait,Lespedeza bicolor, Paspalum notatum, Veti-veria zizanioides, Eragrostis pilos and Neyraudia reynaudian. It is the best for Arbor, shrub and grass to be arranged in pairs or groups in order to remold optimal landscape. Pilot sites, covering 3ha, is established. Vegetation coverage reaches 90% in platform area, 40% in slope area. pH value in ARD increased slightly, Cu2+, Pb2+ concentration in ARD decreased, Zn2+ concentration in ARD decreased and varied slightly.

Jan 1, 2014

By Chenyang Zhang, Zhigang Yin, Wei Sun, Jingxiang Zou, Jianyong He, Yuehua Hu, Zhijie Xu

"In this work, a novel compound 4-Amino-5-mercapto-1,2,4-triazole was first synthesized and its selective adsorption mechanism on the surface of chalcopyrite was comprehensively investigated using UV-vis spectra, zeta potential, Fourier Transform Infrared Spectroscopy(FTIR), X-ray Photoelectron Spectrscpy Measurements(XPS), and Time of Flight Secondary Ion Mass Spectrometry (ToF-SIMS) and first principle calculations. The experimental and computational results consistently demonstrated that AMT would chemisorb onto the chalcopyrite surface by the formation of a five-membered chelate ring. The first principle periodic calculations further indicated that AMT would prefer to adsorb onto Cu rather than Fe due to the more negative adsorption energy of AMT on Cu on the chalcopyrite (001) surface, which was further confirmed by the coordination bonding energies of AMT-Cu and AMT-Fe based on the simplified cluster models at a higher accuracy level (UB3LYP/Def2TZVP). The bench scale results indicated that the selective index improved significantly when using AMT as a potential chalcopyrite depressant in Cu-Mo flotation separation.INTRODUCTIONFroth flotation is one of the most important processes to separate valuable minerals from gangue by taking advantage of differences in the physical chemistry of their surface properties(Laitinen et al., 2014), particularly in their surface hydrophobicity. Hydrophobicity differences between valuable and gangue minerals could be regulated by adding different chemical additives (surfactants)(Kor, Korczyk, Addai-Mensah, Krasowska, & Beattie, 2014), such as collector and depressant. It could be conducted economically to selectively separate and enrich the complicated and/or poor ores, by adopting appropriate surfactants. For example, the beneficiation of molybdenite usually relies on a two-stage process to realize flotation separation of molybdenite from other unwanted sulphide ores(Wie & Fuerstenau, 1974). In the first step, a bulk molybdenite concentrate is produced by utilizing kerosene/ diesel oil and pine oil/alcohols as collector and frother, respectively. Second, sodium hydrosulphide, sodium cyanide, ammonium sulphide, or Nokes reagent are adopted as depressants in the separation stage. However, these depressants are usually toxicant and cannot meet the requirements of environmental protection. A large number of efforts have been taken to develop alternative environmentally-friendly depressants (Ansari & Pawlik, 2007; J. H. Chen, Lan, & Liao, 2013; Li et al., 2015; Yin, Sun, Hu, Zhai, & Guan, 2017; Yin, Sun, Hu, Zhang, Guan, Liu, et al., 2017; Yin et al., 2016). Although some novel and environmental-friendly depressants have been reported to achieve good performance in Cu-Mo flotation separation at a laboratory scale, there are still some challenging problems, including toxicity, high price or poor performance in practice, which severely limit their practical applications in Cu-Mo flotation separation on a commercial scale."

Jan 1, 2018

By Bruce Mathema, Steven Huynh, Terry Cheng, Gerry Gomez

"The use of PM40N, a specialty precious metals promoter in conjunction with a standard Xanthate based collector was extensively investigated in the flotation of a complex, silver-bearing, lead-zinc ore containing naturally occurring graphitic gangue. The ore, considered difficult to treat with conventional reagents, was tested at plant scale to determine the impact of the promoter on silver recovery, lead grade and also on the amount of zinc misplaced to the final lead concentrate.Initial laboratory-scale rougher flotation testing implied significant improvements in the recovery of silver and lead with a marginal amount of zinc displaced. Subsequent mini pilot flotation tests further revealed that a gain in selectivity and recovery could be achieved by adjusting PM40N promoter dosage and incorporating a cleaner flotation step, further improving rejection of sphalerite. Plant trials resulted in an improvement of 3% in Silver recovery coupled with a 2% increase in recovered lead whilst maintaining lead grade in the lead circuit.To date, the use of PM40N as a promoter has enabled the processing operation to significantly increase its plant economics. The partial replacement of the standard Xanthate based collector has also reduced the overall quantity of Xanthate required in the standard circuit by approximately 10% - which is a positive impact on the environment. It is envisaged that further optimization of plant parameters will favor stable operation and continue to boost revenues generated by subsequent improvements in silver metallurgy."

Jan 1, 2014

By Leonardo Soto, Fernando Villanueva

"Antofagasta Minerals S.A. (AMSA), for its Centinela District Project, is currently developing, at a first stage, a new 90 ktpd Concentrator Plant incorporating Esperanza Sur (ESP Sur) and Encuentro (ENC) ores. In order to dimension properly main equipment, specifically for grinding circuit, a final decision has been taken using geological and metallurgical (comminution) data from both body ores. Data was analyzed internally within AMSA and its consultants to get a final proposed circuit for further engineering studies. Specific Energy Consumption (SEC) parameter is one of the main key factors for proper dimensioning. To get an accurate value different tests have been made and modelled to ESP Sur and ENC ores. Also, operational data from Esperanza operation has been taken into account due to its similar ore characteristics to ESP Sur ore and incorporated as input data for design. Depending on data, quality and amount, it is possible to estimate accuracy for project investment and risk level, hence investment decision can be taken under good and reliable information."

Jan 1, 2014

By Andrzej Wieniewski, Cezary Regula, Bozena Skorupska, Krystian Cichy

"In this paper, experiences from Polish non-ferrous metals ores enrichment plants in the copper and blende concentrates quality improvement are discussed. The blende concentrate being produced in ZGH Boleslaw S.A., with Zn content of about 54,5% is characterized by the relatively high magnesium content reaching a level of 1% resulting from the dolomite presence, while for the zinc production by electrowinning a concentrate in which magnesium content should not exceed 0,3% is required. The implemented new technology for the quality improvement of blende concentrate is based on the leaching of zinc concentrate with sulfuric acid aimed at dissolving of the contained dolomite, and then flotation of the leached concentrate. It allows to obtain a concentrate with magnesium content below 0,1% at the simultaneously increased zinc content to about 57,5%. In the paper, laboratory tests results on the development of optimal flotation flowsheet for the gypsum removal and the industrial tests results concerning the process optimization of this flotation are discussed. In turn, the copper concentrate being produced in Polish copper ore enrichment plants KGHM PM S.A., is characterized by the increased organic carbon content - above 8%. It creates problems with the smelting of this concentrate because of difficulties with the heat removal derived from the combustion of organic carbon in the flash smelting process. The implementation of segregating flotation to the industrial practice allows the effective production of two concentrates with the differentiated chemical compositions - a concentrate with increased copper content and reduced organic carbon content for the flash smelting process, and a concentrate with lower copper content and increased organic carbon content for the shaft smelting process. In the paper, conditions of the segregating flotation and the achieved results are described."

Jan 1, 2014

By A. Javadi

"Our recent studies revealed that the sulfide minerals in contact with water during grinding produced hydrogen peroxide (H2O2) where the amount of H2O2 production by the minerals found to be in the order of pyrite > chalcopyrite > sphalerite > galena. The H2O2 effect on the oxidation of pulp components and its influence on the concentrate grade and recovery in flotation have been studied and the results have been presented and discussed in this paper. Studies have also been carried out to build correlation between percentage of pyrite in the concentrate, grinding conditions and concentration of OH•/H2O2 in the pulp and as well of controlling the formation of these species through known chemical means for depressing the generation of the oxidant. Flotation tests using a complex sulfide ore with the same reagent scheme that is being used at Bama concentrator in Iran but with the addition i) Na2S reductant and ii) inorganic (EDTA) and organic (TETA) surface modifiers, during grinding stage have been performed to judge the beneficial or detrimental role of H2O2 on the selective flotation of sulfides. The results demonstrate that the selectivity of metal sulfides against pyrite increases with increasing generation of H2O2 in the pulp liquid.INTRODUCTIONOur recent studies have illustrated the formation of hydrogen peroxide (H2O2) by metal-sulphides during grinding in the presence and absence of oxygen (Javadi Nooshabadi & Hanumantha Rao, 2013a; Javadi Nooshabadi & Hanumantha Rao, 2013b; Javadi Nooshabadi & Hanumantha Rao, 2013c; Javadi Nooshabadi & Hanumantha Rao, 2014). In the absence of oxygen, it was found that pyrite surface is catalytically active and able to breakdown water molecules to form OH• free radical and thereby deriving oxygen in the formation of H2O2 from water molecules. The in-situ formation of H2O2 and its influence on sulphide flotation has not been addressed yet. The presence of strong H2O2 oxidant in the pulp liquid and its selective oxidation of pyrite would be beneficial in depressing pyrite flotation. Therefore, it is important to build correlation between percentage of pyrite in the concentrate, grinding conditions and concentration of OH•/H2O2 in the pulp as well as to study possible ways of flexibly controlling the formation of these species through known chemical means for depressing the generation of the oxidant."

Jan 1, 2018

By J. Yianatos

The regrinding stage is necessary to achieve the particle size (liberation) for the final upgrade in the cleaning flotation process. At present, vertical mills (Vertimill) are employed at industrial scale, using small steel balls as grinding media. The regrinding process characterization requires mixing regime knowledge along with the mean residence time of the liquid and solid phases. The residence time distribution (RTD) and the actual mean residence time estimations from theoretical relationships are complex due to the presence of three components (solid mineral, balls and water), mass transport characteristics and segregation affecting solid holdup. Therefore, the experimental RTD determination is suitable for industrial mills. In this work, RTD measurements were performed in two different industrial flotation plants. Both plants operate with Vertimills of 1000-1500 HP in the regrinding process with different circuit arrangements according to the plant treatment capacity. The RTD was measured using the radioactive tracer technique. This technique allows for non-invasive tracer detection where the procedure consists of selecting a liquid (Br82 in aqueous solution) or solid (irradiated solid) tracer for RTD data acquisition in real time. The RTD was modelled by the Large and Small Tanks in Series (LSTS) model, which allowed the characterization of the different mixing regimes for both liquid and solids in the regrinding mills. Effective mean residence times in the range 2-11 min were obtained with RTD shapes similar to those obtained in tumbling ball mills. It was found that residence times of liquid and fine particles were similar, which is consistent with results observed in other mixing systems, e.g. mechanical flotation cells. Also, the mean residence times estimated from the RTD allowed the mass balance adjustment to be validated from metallurgical sampling data. RTD estimations are useful for better understanding the Vertimill behaviour and to identify the actual breakage rates. Keywords: vertical mill, residence time distribution, particle size, modeling

Sep 1, 2012

By M. Blagojev, R. Tomanec

"Studies reported in this paper used polymetallic Pb-Zn-Sb-As-(Ag, Au) ore from Dražnja, Kosovo. The ore is comparatively rich in Zn (6.56%) and Pb (2.87%), but with high rates of Sb and As. Conventional lead and zinc concentration by flotation produced galena and sphalerite rich concentrate with high recovery, but with excessive As and Sb. After chemical analyses, which could not detect the reason for the excessive elements, ore minerals were identified under the ore microscope, their texture characterized, and degree of liberation of useful minerals was assessed. Microscopy of the mineral concentrates revealed complex intergrowths of galena and marmatite minerals mostly with sulphosalt minerals (boulangerite, jamesonite and bournonite) and also with arsenopyrite mainly responsible for the unsatisfactory quality of the concentrate. These complex sulphosalts, among other things have similar behaviour during the flotation concentration, and in spite of their interlocking with galena, therefore inadequate liberation, sulphosalts remain in the lead concentrate. Microscopic analyses indicated that a better galena concentration product is possible with a higher rate of mineral liberation, and then by selective floc flotation of some sulphosalt minerals. Purpose of this work was to show that only chemical analysis is not sufficient, according to that we solved the problem by precise mineral identification and time consuming mineral liberation measurements. INTRODUCTION The polymetallic Pb-Zn-Sb-As-(Ag, Au) ore body of Dražnja, Kosovo, fairly rich in Zn (6.56%) and Pb (2.87%) was repeatedly explored and once even worked. Mineralization at Draznja was primarily represented by sphalerite, galenite and marcasite/pirite. Some sections comprise massive sulphides, and others are lower grade zones of semi-massive sphalerite/galena or marcasite/pyrite dominant sulphides. The ore body II was formed in the southern gallery in the structure Çukë – Lajthishtë (with content of 3.16% Pb and 7.31% Zn). Pb-Zn ore with increased content of As, Sb sulphosalts is not rare phenomenon in the world. While previously treated as unprofitable, economical uninteresting ore, today with development processing and new reagents (organic, ecologic), are the topic of scientific papers. The examination of Pb-Zn ore with high content of sulphosalts we find in deposits as: The hydrothermal vein deposit of Harja in the Baia Mare area, contain a wide variety of sulphosalts [Cook, N. & Damian, G., 1997]; also the deposits Fankou Mine in Guangdong Province and the Dachang Mine in Guangxi Province, where the flotation concentration of galena and jamesonite takes place [Runqing Liu et al. 2015], [Zhang Ting, Qin Wen-Qing, 2015];. On a samples from Tibet in China flotation separation test of galena and jamesonite was conducted [Sun Wei, Han Haisheng, Tao Hongbiao, Liu Runqing, 2015]. According to history of investigation, the mineralized area of Dražnja has a long history of exploration and possible exploitation activities [Slowey, Galen, 2009]. Recent workings were carried out in three stages through the 20th century."

Jan 1, 2018

By S. M. Narbekova, L. V. Semushkina, Zh. A. Aldybayeva, A. A. Mukhanova, D. K. Turysbekov, N. K. Tussupbayev

More complex and heavy-concentrating oxidized and mixed sulphidic oxidized ores are involved in production because of increasing needs for non-ferrous metals. Extraction of the oxidized minerals of non-ferrous metals general in current technologies. The problem is solved to oxidized polymetallic ores the preliminary selective sulphidization is the oxidized surface of the components by means of hydrogen sulphide, sulphide and calcium polysulphide, and also element sulphur, etc. The task was to study details of flotation of the oxidized lead-bearing ore of the Zarechnoe deposit (Kazakhstan) with calcium polysulphide as sulphidation. According to chemical analysis initial samples of the ore contain, %: lead – 4.8; zinc – 0.1; general iron – 0.81. Phase structure lead is characterized by the oxidized form of 57.76-64.5 %; by sulphidic status of 25.5-32.64 %, and by plyumboyarosite of 19.0-23.02 %. Researches on flotation beneficiation of oxidized lead-bearing ore are conducted. Sulfidizator gave to grinding, on flotations there were used the collector (butyl xanthogenate of sodium) and frother (T-80). Experiments were conducted with a new sulphidizator – calcium polysulphide. The latter is obtained by interaction of CaO calcium oxide with sulfur and water at high temperature with component mass the following ratio S:CaO:H2O =10:5:85. Extent of mill initial ore was optimised (88.42 % of - 0.071 mm grade). For the optimum mill mode the studies on matching of an optimized consumption of sulphidizators are performed. On basic technology with application of sulphide of sodium as a sulphidizator at optimum mill, the lead concentrate with the content of lead 64.4 % at extraction of 86.6 % was received. The content of cerussite in a concentrate was about 14.9 % at extraction of 82.1 %. With application of calcium polysulphide as a sulphidizator the lead concentrate with the content of lead 68.0 % at extraction of 88.0 % was received. The content of cerussite has made 16.0 % at extraction of 85.0 %. Application of a new sulphidizator allows to increase extraction of lead in a concentrate from 64.4% to 68% and cerussite extraction – from 82.1 % to 85.0 %. The possibility of application of calcium polysulphide as a sulphidizator instead of conventional sulphurous sodium was established.

Jan 1, 2018

By A. Vidyadhar

Printed circuit boards (PCBs) constitute a majorpart of electrical and electronic equipment containing valuable metals such as Cu, Ni, Au, Ag, Pd, Fe, Sn, Pb, etc. The concentration of base and precious metals in PCBs is observed to be several times more than those in their respective ores. Therefore, the recycling of PCBs is necessary to recover the valuable materials. However, the ultrafine particles pose a big challenge. Removal of them is suggested prior to processing by flotation. Froth flotation is observed to be a promising technique for rejecting the plastics from the comminution product. In the present work, enrichment of ground 1.0 mm PCB powder was investigated through flotation route by varying the operating variables such as frother dosage, pulp density, air flow rate and rotational speed of the impeller. The liberation studies indicate that excellent liberation of metal values is achieved from the non-metallic constituents at -1.0 mm size and below. The particulate system is quite rich in metal value with about 23% total metal content. The non-metallic constituents such as plastics are observed to possess strong hydrophobicity while the metal particles in the pulverized mass are hydrophilic in nature. Froth flotation kinetics is studied in depth with a view to facilitate high rejection of plastics and identify optimum operating conditions for the same. A number of experiments are performed to establish the influence of the operating variables on flotation performance. The conditions for achieving higher yield of the metal-rich fraction with respect to a specified grade are discussed in the light of the experimental results. It is found that the requirement of reagents is negligible which could be a very important factor from the commercial stand point. Single-stage flotation increases the metal content from 23% to over 32% with a mass yield of around 75% and over 90% recovery of metal values. 32% of the materials in the feed could be effectively rejected in the float fraction losing less than 4% metal values. The dependence of kinetics on the process variables is also discussed. It was concluded that a high rotor speed helps in efficiently rejecting the plastics. Frother should be added to help stabilize the froth and enhance the kinetics. A moderate air flow is required while pulp density must be kept low for efficient pre-concentration. It is established that the entire -1.0 mm comminution product could be treated by flotation for generating a pre-concentrate. Keywords: printed circuit boards, recycling, froth flotation, kinetics, recovery

Sep 1, 2012

By Tiago de Souza, Caroline Gonçalves, Carlos Eduardo de Castro, Everton Dias

The Miraí plant from Votorantim Metais, has two screening stages to the bauxite classification after scrubbagem. The final product has hold the larger size of 0,84 millimeters (20 mesh). There are two sieves Haver & Boecker (model R-TE 3658 x 10972), which have four modules with cut size sieves of 10 mesh (1.70 millimeters) and ¼ inch (6.35 millimeters) on the primary screen, and 20 mesh (0.84 mm) on the secondary screen, all made of polyurethane. The actual configuration was established according to the empirical tests realized that aimed the increase material load on the secondary screening. However, having in mind the screening process improvement and use the fractions smaller than 0,84 mm, which have significant levels of Alumina and low reactive silica, was proposed a new test of change the sieves opening for 6 mesh in the primary screen and 28 mesh for the secondary sieve. The objective of this work was measure the ore alterations on the particle size distribution on the screening steps, increasing the plant weight and ratio recovery before and after the test.

Jan 1, 2014