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By G. P. Demopoulos

"The recovery and separation of platinum-group metals (PGM) from primary and secondary materials currently attracts a lot of interest due to the high value of the metals and their increasing demand for high-tech applications. Thus, the traditional refining processes are gradually replaced by newer more efficient separation techniques such as solvent extraction and ion exchange. In this paper the classical and modern refining techniques are reviewed and the pertinent solution chemistry dictating proper processing strategies in each case is discussed. The technological advantages of the modern separation methods are emphasized and reference to the recovery of PGM from primary as well as secondary materials is given. INTRODUCTIONDue to their outstanding physicochemical properties, such as catalytic activity, conductivity and corrosion/oxidation resistance, precious metals now find extensive usage outside of the traditional jewellery and investment industries. The increasing use of precious metals in such areas as electronics and catalysis, as well as their increasing high value, has led to a growing interest in their recovery and separation from primary and secondary materials.Quantitatively the demand of platinum metals in the western world by area of application is described in Table I. Platinum and palladium represent 90% of the total demand, Rh and Ru 8% and the remaining is taken by Ir and Os. In terms of value the following were the average prices (US$/oz) of the metals in the second half of 1986: 500 Pt, 125 Pd, 1200 Rh, 650 Os, 400 Ir and 80 Ru. Due to these prices, exploration, mining, reclamation and refining activity were very high in South Africa, the biggest producer of Pt metals in the world, as well as in other areas: United States (Stilwater deposit), Canada (Sudbury, Marathon and Lac des Isles, Ontario; Kenly Lake, Quebec, etc.), Australia, Europe and elsewhere"

Jan 1, 1989

By James H. Savory

"In recent years, there has become a growing interest toward a better understanding of balance rope behaviour. With this in mind, the auth or will present a comprehensive summary of field experience, as well as conclusions. In presenting this overview, it is the intent to stimulate further interest as well as provide a framework from which further in-depth investigation can be initiated.Topics which will be covered include rope cores, lubrication practices, loop dividers, rope failures, etc.IntroductionThe first friction hoist was designed in Belgium in J862 by Lemielle. However, it was not until 1877 when Carl Frederich Koepe installed a friction winder sheave at the Hanover Colliery in Germany, that the design was given serious consideration. The winder consisted of a motor-powered sheave over which a single rope was installed, and the end s attached to two conveyance s. Beneath the conveyances a rope was connected, designed to reduce the chance of slip. This was the first balance rope.This earl y mod el is a far cry from the modern tower or ground mounted Koepe winders employed throughout the mining industry today. There have been vast improvements in all aspects of the Koepe winders. One such improvement is in the balance ropes used. This particular area will be concentrated on, with emphasis on selection, maintenance and field experience.SelectionThe sale purpose o f a balance rope is to counter the head rope weight. Obviously then, in selection o f balance ropes, weight is of primary concern. Usually the head and balance ropes are equal in weight. However, sometimes balance ropes which are 5 to 10070 heavier than the head ropes are employed. These reduce horsepower demands during peak acceleration periods, and assist in overcoming inertia during retardation periods. As well, it is sometimes preferred to reduce the balance rope weight, in order to compensate for the eventual weight buildup of lubricant, dirt and debris."

Jan 1, 1983

By Andrew L. Mular, Robert P. Edwards

"The operation of flotation circuits is often regarded as a combination of art and science. Expert systems offer a method by which the art may be captured and supervisory control of flotation circuits fully realized. Operating knowledge, the art, can be consistently employed to enhance regulatory control through the judicious application of an expert system. Using an expert system, a supervisory control routine was developed, and success- fully implemented, in the copper flotation circuit at Brenda Mines Ltd.The expert system ran in conjunction with regulatory PI controllers on a personal computer. The expert system received assays via an on-stream analyzer and adjusted regulatory loop set points as required in real-time. From its commissioning in November, 1989, to the end of the mine 's operation in June, 1990, it was enthusiastically embraced by the operators and attained operating levels superior to those achievable manually.IntroductionExpert system (ES) software springs from research into artificial intelligence and is currently making significant inroads into business and industry. ES proponents make many attractive claims; they are a means of capturing the knowledge of experts and they can be programmed by non-programmers. To date, most uses of this software in the process industry are in off-line applications, meaning that the applications are not tied directly to operating (on-line) environments. Moreover, in on-line environments, they are typically employed as advisors and only suggest changes. Human operators are required to close-the-loop to the process. Yet, an ES should be applicable to operating environments and, if the claims of the proponents are valid, should also be better than existing tools. As an intelligent controller an ES must use the knowledge of experienced operators, apply it directly to a process and do this without the intervention of human operators. On-line applications have been successfully employed in the closed loop control of SAG circuits (Herbst et al., 1989) and flotation circuits (Hales, 1989). Harris and Kosick (1988)detail an implementation for flotation control at the Polaris Mine."

Jan 1, 1992

By N. Kacira

"Canada's largest known chromite deposit occurs in a layered intrusion in the Bird River area of Manitoba. However, numerically most of the chromite occurrences are in the Appalachians. Few, apparently minor, occurrences are also known in the Cordillera.In the Appalachians, chromite occurs as lenses and pods in dunite; they are of ""podiform"" type. The individual concentrations vary in size from a few pounds to tens of thousands of tons. Locally, chromite concentrations form discontinuous zones extending several hundred feet along strike and presumably down dip, therefore resembling boudinaged layers. Chromite layering and lineation are commonly concordant to those of the host rocks.The Appalachian chromite occurrences are thought to have been formed by fractional crystallization and perhaps also by liquid immiscibility. Their present shape and distribution are largely the result of deformation mostly prior to complete solidification of their host rocks. Therefore, the attitude of layering, foliation, lineation and other features related to deformation provide valuable guides in predicting the probable distribution of chromite, and hence are helpful in exploration.Chromites fulfilling the requirements for metallurgical, refractory and chemical grades occur in the Appalachians. Although the Appalachian deposits are similar in size and grade to some of the chromite deposits being mined elsewhere, they are unlikely to be economic, at present, in the higher wage Canadian environment. However, in case of shortages in chromite ore supply which may result, among other reasons, from increasing tendency to further processing in the producing countries, the Appalachian occurrences may become sources of ore. Such eventual shortages combined with relative abundance of electricity in Canada and recent innovations in oxide ore reduction technology may hasten the time when ferrochrome manufacture based on local chromite sources becomes economically viable."

Jan 1, 1982

By Steve Forgeron, Brendan MacKenzie, Kevin MacPherson

"The geological composition of strata immediately adjacent to coal seams has a significant effect on the safe and efficient extraction of coal from underground mines of the Sydney coalfield. Geological features such as paleo-sandstone river channels, seam splits, floor rolls, paleo-soils and stone-filled rupture features can rapidly alter the competency of immediate roof and floor strata, significantly reduce the height of the coal seam, cause rapid variations in seam gradient and influence the in situ and run-of-mine quality of the coal.The impact of these features on the over-all mining operation can be significantly reduced if mine management can be for-warned of their impending occurrence. Using the information acquired from boreholes, geological mapping, x-ray diffraction analyses, microscopic studies, geophysical logs and seismic surveys, sedimentary models have been constructed which enable the mine geologist to predict, with increasing accuracy, the future occurrence of deleterious geological features ahead of the working face."

Jan 1, 1986

By Henry Brehaut

"It is difficult to know how much environmental information is absorbed by those in a position to put it to use. The following information may seem like ""old stuff"" to those whose companies are taking steps to improve their environmental performance. This paper is directed in particular to those people who are interested in determining what further changes are required to make improvements as concerned environment citizens.IntroductionUntil recently, the author was comfortable with the fact that none of the operations for which he was responsible had any environmental charges against them. It was not until one of his operations was charged with non-compliance that the author discovered due diligence as a way to avoid a second charge, and when an unfortunate spill occurred at another operation, the meaning of risk prevention was learned. Knowledge was gained step by step to the point where finally environmental information is being heeded, rather than waiting to learn from sad experience. With the appreciation of what it takes to do a good environmental job, comes an understanding of the challenge that lies ahead, and the fact that there is a lot to learn.At a recent environmental gathering, comments from the participants varied considerably. Some just didn't understand why government was being so unreasonable, while at the other end of the spectrum one individual whose company was well along the path to becoming a good environmental citizen remarked that it was all very basic. What was immediately understandable to one went right over the heads of others, indicating the different stages that have been attained in the acceptance of environmental responsibilities."

Jan 1, 1991

By David Dreisinger

Arsenic occurs in nature in association with many valuable metals including copper, nickel, cobalt, gold and platinum group metals. The recovery of these valuable metals is of course complicated by the need to extract and stabilize arsenic in a form suitable for disposal. In this paper, a review of some recent developments related to hydrometallurgical treatment of arsenic bearing materials is provided. The key aspects of metal dissolution, arsenic stabilization and disposal are discussed.

Jan 1, 2014

By J. Peck, M. J. Scobie, M. D. Pollitt

"IntroductionOne aspect of current research in the Canadian Centre for Automation and Robotics in Mining (CCARM) involves the automatic identification of different rock types based on particular drill performance parameter responses. In this paper, the four drill performance parameters of torque, pulldown pressure, rotary speed and penetration rate, were measured from an instrumented rotary blasthole drill during field investigations undertaken at the Fording River Mine, Elkford, British Columbia. The variations in these parameters were subsequently correlated with the corresponding rock types using the results from gamma, neutron and core logs in the same or adjacent boreholes. Work to date has sought to understand the relationships between drilling performance parameter variation and rock properties. Using the results of these studies, the present research is aimed at developing techniques whereby classical statistical pattern recognition methods are applied to drill data to permit the discrimination of different rock units. A monitoring system incorporating such a capability would greatly enhance the quality and amount of geological information on a per borehole basis while drilling. This data in tum could be used economically and directly towards explosive loading, geological exploration and reserve estimation. Background and PhilosophyThis work is an extension of equipment monitoring studies at the Fording River Mine. At this site over a two-year period, 5180 m of data was acquired on an instrumented Bucyrus-Erie 60R drill during routine production blasthole drilling. Throughout these studies, a 311mm diameter S8M Security tungsten-carbide tricone bit was used. The mine, located in southeast British Columbia, is a large-scale, open pit coal operation. The means of excavation revolves around a drill-blast-muck cycle and employs a standard shovel-truck system of transport. Four main rock types are present: sandstone, siltstone, mudstone and coal, with average compressive strengths ranging from 10 MPa to 150MPa respectively (peck 1989). However, based on the field studies, very few differences in terms of strength and compositional properties were seen between the sandstones and siltstones at the site. Therefore, they are referred to as sandstone/siltstone in all further discussions."

Jan 1, 1991

By Martin Wacker

Cameco Corporation, on behalf of a joint venture, is preparing surface and underground facilities at their northern Saskatchewan property in preparation for the future operation of a high-grade uranium mine. The Cigar Lake orebody is situated about 430 metres below surface at the unconformity between metamorphic basement rocks and flat lying sandstone. Major technical factors influencing the mining method selection include ground stability, control of ground water, radiation exposure and ore handling and storage. A decade-long test mine program resulted in the selection and validation of ?jet boring? a non-entry mining method. Cigar Lake?s jet boring mining method involves several major steps; artificial ground freezing of the orebody and surrounding rock, TBM (tunnel boring) type development of access crosscuts below the orebody, installation of cased pilot holes upwards through the ore, and ore extraction using a rotating high pressure water jet within the pilot holes. The resulting cavities are surveyed and backfilled with concrete. The ore slurry will be processed underground and pumped to surface. This paper discusses the jet boring mining method in general terms and includes highlights of the Cigar Lake test mine program completed in 2000.

Apr 1, 2005

By J. Oliveira, A. R. Barnes, R. Pandher

Sub-stoichiometric roasting of arsenic-bearing copper ores is a well established practice. However, ores containing calcium commonly prove challenging where very low arsenic levels are desired, but the reasons for this phenomenon have largely been speculative. In the course of treating arsenicbearing copper ores by partial roasting in fluid bed reactors, XPS encountered one of these Ca-bearing ores which proved a challenge to roast to acceptably low levels of arsenic. Mineralogical examination of the calcines using a combination of XRD (X-ray diffraction), QEMSCAN (Quantitative Evaluation of Materials by Scanning Electron Microscope) and EPMA (Electron Probe Micro-Analysis) helped to identify the arsenic bearing species and assisted in developing a workable theory on the sequence of reactions occurring during the roast. With the assistance of thermo-chemical modelling, this allowed adjustment of the roasting conditions to minimise the amount of arsenic retention in the calcine in spite of the presence of calcium in the ore and advance the roasting program to a commercially acceptable solution.

Jan 1, 2014

By Zygmunt Wegrzyk

Poland is rich in hard and brown coal reserves, which have become the most important, and steadily developing, primary source of energy. With 192.6 mill. t of hard coal production and 40 mill. t of exports in 1978, Poland is fourth and second in the world respectively. The paper discusses the various mining methods adopted in the country's history of mining. Particular emphasis is placed on longwails, their mechanization and equipment assembled in the form of fully mechanized face complexes suited for varied geological conditions. Measures to improve the recovery ratio of coal resources are dealt with. investment efforts undertaken in the coal industry are outlined. An account is given of the ever improving techno-economic results of coal mining. The country also exports a wide range of mining equipment and transfers its well-founded technical know-how to others. There are strong cooperative links with many foreign partners.

Jan 1, 1979

By Michael Davies

Mined Material Management Meeting or Missing the Mark? o you agree that we have the technology to consistently design robust M3 facilities? ?YES your experience do these M3 facilities perform as expected during operations? ?USUALLY hat can be done to improve performance, e.g. better communications between project and operating teams, discontinuity between design and operational input by designers, others? ?UNDERSTANDINGWHY THINGS GO WRONG an we identify the key characteristics of ?good M3 facilities?, i.e. ones that are performing well? Can we identify ?good M3 facilities?, i.e. ones that perform well and can be held up as examples? ?WITHOUT QUESTION?? your opinion, for what reason do they not perform as expected? ?NO SINGLE REASON??..

May 1, 2010

By D. M. Ward

"The uranium deposits upon which the Rabbit Lake project story is based are located at the eastern margin of the Athabasca Basin just west of Wollaston Lake in northern Saskatchewan. This paper provides a general review of the exploration history for the major deposits and the influence of an expanding geological data base, which served to guide the continuing exploration programs.A brief description of each of the deposits is provided in order of their discovery and with emphasis upon their relative geological and mineralogical characteristics.The Rabbit Lake and Eagle Point orebodies are monometallic uranium deposits localized by thrust faults within the Aphebian Wollaston Group. The Cof/ins Bay A-zone, B-zone, and D-zone are polymetaflic U, Ni, As, Co (Au , Ag) deposits located within the Helikian Athabasca Group at its unconformable contact with the underlying Wollaston Group. INTRODUCTIONThis paper demonstrates the importance of applying the accumulated geological knowledge, gained through the exploration, mining, and development process, to the ongoing success of exploration programs. To emphasize this point, the basic geology of each of the major Rabbit Lake area deposits will be presented in chronological order of their discovery and subsequent development. These depos its include Rabbit Lake, Collins Bay A-zone, B-zone, D-zone and Eagle Point. The geological descriptions are based primarily upon the detailed observations of many current and former geologist s employed by both Gulf Minerals Canada Limited and Eldorado Resources Limited. Much of the early historical data was obtained from Dr. E.E.N. Smith, formerly with Eldorado Resources Limited. Regional GeologyThe Rabbit Lake area which includes the Rabbit Lake, Collins Bay A-zone, B-zone, D-zone and Eagle Point deposit s, is located on the eastern edge of the Athabasca Basin close to the western shores of Wollaston Lake (Fig. I). The area is in the Churchill Province of the Canadian Shield within the Wollaston lithostructural domain, at the eastern edge of the Athabasca Group. The uranium deposits occur within both the Wollaston Group metasedimentary assemblage of probable early Aphebian age, and the diagenetic ally altered quartz sandstones and conglomerates of the Athabasca Group of Paleohelikian age. Both units unconformably overlie granitoid gneisses interlayered with metasediments and a graphitic iron formation all believed to be of Archean age. All uranium depo sits in the Rabbit Lake area occur in close proximity to the Paleohelikian - Aphebian or Paleohelikian - Archean unconformity."

Jan 1, 1989

By J. C. Botham, T. D. Brown

"Coke is the most costly item in steelmaking via blast furnaces . Recent innovations in cokemaking have been directed toward reducing this cost while simultaneously improving coke quality and expanding the range of coals used in the process. It is also important to meet increasingly stringent environmental legislation.Improvements in coke quality have been achieved by novel blend selection procedures, by charge density control using both selective pulverization and partial briquetting, and by the use of modifying additives.The Canadian Carbonization Research Association provides a focus for Canadian cokemakin g research which has demonstrated these technologies in a series of pilot-scale experiments."

Jan 1, 1980

By M. Lytle

"The Corbin area of southeastern British Columbia has been a coal mining area since 1908. Byron Creek Collieries Ltd. Has operated its Coal Mountain Mine in this area from 1974 until the present. In February 1981, this company was purchased by Esso Resources Canada Ltd.Coal Mountain is structurally complex and standard computer algorithms are not applicable to model the overturned synclinal structures and faulted bedding surfaces. This paper discusses two approaches used by Esso Resources staff to model the geology of Coal Mountain.The first approach projects digitized cross-section data along trend to develop a large data base which correctly approximates the shape of the structure. The spatial orientation of the structure is corrected by merging the generated data set with drill-hole data. The second approach uses digitized cross-section and bench-plan geology to generate a block model of the coal reserve.HistoryThe Coal Mountain Mine, also known as the Corbin Mine of Byron Creek Collieries Ltd. is located 24 kilometres south of Highway 3 in southeastern B.C.In 1905, two American businessmen recognized the coal potential of the area during a horseback tour. The two businessmen, D.C. Corbin and E.J. Roberts, formed the Corbin Coal and Coke Co. to mine and market coal from their newly acquired 6075 hectares of coal licenses. By 1908, the town of Corbin was under construction, a 22.4-km rail spur was constructed from the mine to the main CPR line and the first underground mine began to produce coal. An open-pit operation was also developed at the 1828-metre elevation using a steam shovel loading into rail cars. The company operated continuously until 1935, when a lengthy strike forced suspension of operations.In 1943, the Consolidated Mining and Smelting Company Ltd. (now known as Cominco Ltd.) operated two surface mines to produce coal for its smelters at Kimberley and Trail, B.C. This operation ceased in 1948."

Jan 1, 1982

By L. A. Homeniuk, R. Bonnar

"The Athabasca Basin has been the scene of an intense exploration effort since the late 1960s, resulting in the establishment of this area as one of the major uranium districts in the world.The A thabasca Group is of Helikian age and unconformably overlies metamorphic rocks of Aphebian and Archean age. Most of the known uranium deposits have a close spatial relationship with the unconformity, graphitic meta-sediments, major northeast-trending structures and the basin edge. It should be noted that, in regard to the latter, some of the Cluff Lake deposits are exceptions.The pre-Helikian rocks underlying the Athabasca Group have been divided into six Iithostructural domains. The known uranium deposits are concentrated in the Wollaston and Mudjatik domains in the southeastern portion of the basin.The orebodies typically have a narrow high-grade portion below the unconformity and a broader, lower-grade disseminated zone in the overlying sandstone. Over-all grades average over 1% U3O8 and our estimate of known reserves totals more than 400 million pounds of contained U3O8. Some of the deposits have high concentrations of other metals, including nickel, arsenic, cobalt and gold. Ubiquitous chlorite and clay alteration is characteristic of the orebodies.Other Proterozoic basins in Canada of similar ages and having analogous geological settings to the Athabasca have received far less attention. Although little of the known uranium mineralization in these basins is related to the Helikian unconformity, there may be an exploration potential for deposits similar to those of the Athabasca basin.IntroductionThe Athabasca sedimentary basin is located within the Churchill Structural Province of the Canadian Shield in Northern Saskatchewan. The basin is elliptically shaped and is approximately 800,000 square kilometres in area.The objective of this paper is to summarize the various elements in the genesis of the unconformity-type uranium deposits of the Athabasca Basin and to evaluate the comparative potential of other Proterozoic basins to host similar unconformity-type deposits."

Jan 1, 1982

By T. Alan O'Hara

"The decision to invest capital in developing a mine and constructing a mineral processing plant and services is usually made after a feasibility study shows 'that the estimated future cash flow from mine operations will yield an adequate return on the estimated capital expenditures.The actual return on investment may differ substantially from that estimated in the feasibility study, because of the probabilities of errors in estimating capital costs, ore reserves, operating costs, mineral revenue and operating productivity. This paper outlines the R.S.S. (root sum of squares) risk analysis procedure of computing the overall probability of the actual project D.C.F. (rate of discounted cash flow), differing from that estimated in the feasibility study.Variation in Project D.C.F.It is assumed that a feasibility study of the project has been completed which has defined the estimated values for all the project parameters, such as ore reserve tons and grade, capital cost, concentrate recovery, metal revenue, daily milling capacity and operating costs.The financial analysis of the mining project will have determined that the cumulative cash flow will yield an expected D.C.F. on the capital cost if all project parameters attain the estimated values. If, however, the actual value of any parameter varies from that estimated, the actual project D.C.F. will vary from the estimated D.C.F. Risk analysis methods attempt to determine the overall effect of probable variations in the estimated values of all project parameters on the D.C.F. of the mining project. This overall effect is expressed as a probability profile, which shows the likelihood of actual D.C.F. values greater or less than that estimated.Thus, a completed risk analysis of a mine project, with an expected D.C.F. of 15.51%, would display the characteristics shown in the preceding diagram."

Jan 1, 1982

By T. Lamb, T. Aston

"The Gays River Mine is located within a complex hydrological regime and underground mining environment. Early in the mine history, the operation was' affected by an inability to control mine water inflows. More recently, the reopened mine operation had been unable to maintain consistent drainage of groundwater to the mine workings and sustain low groundwater levels.In 1992, a series of investigations were completed, which in part Were funded under the Canada-Nova Scotia Mineral Development Agreement. The studies undertaken included: hydrochemical and drainhole well screen assessments, an air photo study of sinkhole features, numerical modelling studies and a major piezometer installation and overburden soil study. The results indicate that the water draining to the underground workings is comprised of two distinct components: precipitation over the drawdown cone catchment area and seepage from the nearby Gays River. In addition, a third ""balance"" component was' also found, which represents uncertainties in the areal extent of the drawdown cone and river seepage components.After outlining the history of the groundwater problems experienced at the Gays River Mine, this paper examines the various studies undertaken during 1991-1992 and concludes that control of groundwater levels in the mine area is achievable. A number of recommendations are also proposed for future study ."

Jan 1, 1993

By Tim J. Carew, Dennis C. Martin

"One approach to stabilization of rock slopes is to place a buttress at the toe of the slope to provide additional resisting forces and increase the length and strength properties along the failure surface. This paper describes the rock mechanics and mine planning aspects of incorporating a buttress of intact rock in the lower part of the slope as part of the slope design for the south wall of the final pit at Cassiar Mine. Stability analysis techniques and results are described. Analyses results have indicated that, in order to maintain steep over-all slopes in the final pit, a buttress of intact rock shoud be incorporated into the lower section of the slope until late in mine life. The effect of the buttress is to flatten the slope and reduce the slope height thereby improving slope stability. The mining plans would be such that the buttress would be mined out during the last four months of mining when the consequences of instability would be least severe.IntroductionThe concept of using a buttress to stabilize slopes has been used in mining and civil engineering construction in may locations (Richards and Stimpson, 1977). Most buttresses involve placement of coarse rock fill timber cribs or other material as a load at the toe of an already unstable slope to provide forces which resist failure by counteracting driving forces and increasing the length and strength of the failure path.This paper describes the geotechnical and mine planning aspects of incorporating a buttress of intact rock in the design of the south wall of Cassiar Mine. The effect of an intact rock buttress is to flatten the slope and reduce the slope height, thereby improving slope stability. No actual construction is required other than normal excavation of the slope. The ""mine plans would be such that the buttress would be mined out at the end of mine life when the impact of instability would be less severe and additional ore might possibly be recovered from the slopes. Mining of the buttress could induce instability at the very end of mine life at a time when maximum ore extraction has been achieved."

Jan 1, 1986

By I. G. L. Sinclair

"ABSTRACTTill geochemistry was the principal exploration tool employed by Selco in the investigation of a zinc prospect in Lanark Township, Ontario. The geochemical studies were undertaken after the discovery at surface of marble boulders containing bands of sphalerite and lesser amounts of galena.The source of these mineralized boulders was sought by means of B-horizon soil geochemistry, followed, where appropriate, by back-hoe trenching and till sampling. The thickness of the tiff in this part of Ontario seldom exceeds 3 m or 4 m and it was generally possible to sample complete profiles of the till and thus to obtain detailed information concerning the dispersion of zinc. Drilling and trenching at the up-ice extremity of the zinc dispersion trains showed the source of the float to be sub-economic bands of sphalerite in the Grenville marble. IntroductionTill geochemistry was used extensively by Selco during the period 1975 through 1980. It was the principal exploration technique employed in a program seeking carbonate-hosted lead-zinc deposits of the Balmat-Edwards type in the Grenville rocks of southeastern Ontario. This paper describes the use of the method to locate the bedrock source of a group of sphalerite boulders found at the surface near the village of Hopetown in Lanark Township (Fig. I) . Geochemical investigations at this locality were the subject of a previous publication by the author (Sinclair, 1979).All of the analytical work related to this project was done by Bondar-Clegg & Co. Ltd. in their Ottawa laboratory. In all cases the -80 mesh fraction of the till was analyzed. The total zinc content was determined by atomic ab sorption spectrometry after hot aqua regia digestion; readily extractable zinc was determined by atomic absorption after samples had been cold-leached for 18 hours in an ammonium citrate hydroxylamine hydrochloride solution, the pH of which was adjusted to 8.5"

Jan 1, 1986