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By Barton G. Stone

The mining and exploration industries have been using Geostatistics (Matheron, 1963) for the past forty years. It has been extensively incorporated into three dimensional block modeling software whose usage has reflected the growth in the use of personal computers since 1980. Because of the utility of geostatistical models in mining and production planning, much of the modern reserve and resource modeling is done by mining engineers, geostatisticians and geological engineers. Explorationists are initially less concerned with three dimensional models until such time as a deposit has been roughly delineated. However, the concept of regionalized variables in ore deposits deals with the effect of spatial correlations between data points in a three dimensional sample space and should be useful for optimizing the spacing of drill holes to allow maximum bang-for-the-buck in drilling programs. This paper examines three common deposit types (porphyry copper, VMS and intrusive gold) to examine whether geostatistical methods have been used to minimize drilling costs because of better understanding of spatial correlations. The three model types were chosen from publicly available corporate websites of Canadian based Junior Mining Companies. They include the Wolverine polymetallic zinc deposit of Yukon Zinc in Yukon, Canada; the El Morro Deposit in Chile (30 percent ownership by New Gold Mining Company, and the Fort Knox Gold deposit in Alaska and 50 percent ownership by Nova Gold Resources). Typically, individual mining corporations post their technical reports as CNI 43-101 reports on their corporate website as indications of the favorability or progress on their more exciting properties. Data considered for this paper was not collected or generated by the author, but the information was extracted from these publicly available sites and had a variety of authorship.

Oct 1, 2009

By Morris J. Viljoen, David R. Young

"The zone of economic interest at H.J. Joel Gold Mine is the VS5/Beatrix Composite Reef, a quartz-pebble conglomerate of Archean age. The reef occurs at the base of the Eldorado Formation, Central Rand Group, of the Witwatersrand Supergroup. At least three stratigraphically distinct conglomerates form this economic zone. In order of deposition these are the Footwall, Beatrix, and the VS5/Beatrix reefs. The Footwall and Beatrix reefs are equated with the Aandenk Formation with transport directions toward the northwest, whereas the VS5lBeatrix Reef is of Eldorado age, with transport directions toward the south. The change in the drainage direction was caused by a major basin-wide tectonic event that occurred prior to the deposition of the Eldorado Formation. The Beatrix Reef was formed in a proximal, braided, fluvial environment by a process of aggrading gravel bars between channelways. The VS5/Beatrix Reef was formed by the desegregation of pre-existing Beatrix Reef with the introduction of new material containing much shale detritus and is seen to have been deposited in a more -distal, braided, fluvial environment, similar to the Beatrix Reef.The average gold concentrations are different for each conglomerate; the Beatrix at 32.1 ppm Au, the Footwall at 24.4 ppm Au, and the VS5/Beatrix at only 12.4 ppm Au. A sedimentary gold concentrating process related to higher energy braid channels was primarily responsible for these high gold grades. Not only the basal unconformity surface, but also, internal degredation surfaces, were prime sites for concentration. An understanding of the spatial distribution of these differing conglomerates and their braid channels forming the economic reef zone is necessary in predicting ore grades for future mining."

Jan 1, 1994

By Mark Sherman

"One of the main functions of a process technology and engineering services provider is to select grinding equipment that will meet the client’s throughput rate target. Prudent risk mitigation strategies would suggest that throughput rate estimates be cross-checked using a variety of techniques.Whilst some comminution circuit designers have estimated specific energy requirements via the manipulation of the Bond specific power equation e.g. Barratt’s Grindpower and OMC’s FSAG approach, other designers have opined that the Bond Indices have no role to play in the calculation of SAG mill specific power. As a result, they have developed their own specific energy estimating methodologies, e.g. SMCC’s Drop Weight based power methodology, SPI, SAGDesign, etc. Each method has its supporters and its critics.The challenge facing the engineering provider is how to nominate an SAG mill based circuit throughput rate estimate when faced with significantly disparate specific energies calculated by the different methodologies. This challenge is exacerbated via the continuing evolution of contemporary circuit configurations such as two stage pebble crushing some of which incorporate HPGR technology as the second stage of pebble crushing.The methodology presented in this paper shows that the Bond Indices are an excellent tool for estimating the specific energy requirements for SAG mills in SAB, SABC and SSS circuits. The method accommodates primary crushed feeds, partial and or fully secondary crushed SAG mill feeds, and emulates the impact of pebble crushing on SAG specific energy. As a result, the new Bond Index based method has provided an additional tool for increasing Fluor’s confidence when predicting SAG mill based circuit throughput rates. Based on this outcome, the author proposes that the decades old conundrum of using Bond Indices to calculate SAG specific energies for SAG mill based circuits has been solved."

Jan 1, 2012

By Robin N. Adair

The Halfmile Lake stratiform volcanogenic massive-sulfide deposit consists of pyrrhotiterich breccia-matrix sulfides and pyrite-pyrrhotite-rich layered sulfides that form a laterally continuous sheet stratigraphically underlain by an extensive pyrrhotite-chalcopyrite-quartz stringer zone. Mineralization is hosted by a sequence of felsic pyroclastics and volcanic-derived, fine-grained metasediments. The proportion of volcanic to sedimentary rocks indicates increasing vent proximity from southwest to northeast across the deposit area. Fine- to medium-grained felsic pyroclastics and roughly equal amounts of fine-grained metasediments comprise the stratigraphic footwall to the mineralization. Quartz-feldspar porphyritic bodies cut this sequence and may have provided the heat source for exhalite activity. Felsic tuffs, locally crystal-rich, and lesser amounts of metasedimentary rocks make up the immediate stratigraphic hanging wall. This sequence is stratigraphically overlain and locally interfmgered with mafic volcanics that contain substantial proportions of felsic fragments. Deposition of sulfides post-dated the beginning of felsic volcanism, which places the deposit in the middle of the Lower Tetagouche Group. Compositions of the volcanic rocks range from basalt to rhyolite and exhibit sub-alkaline affinities. Strongly overprinted whole-rock, trace-element, and REE geochemical signatures resulting from mineralizing hydrothermal activity confirm the genetic relationship between the stringer zone and the mineralized sheet. Large-scale D1 folding has overturned the entire sequence. D1 thrust faults and related sheath-like folds have profoundly affected sulfide distribution. D2 is manifested by a penetrative S2 foliation, and D3 is represented by large-scale open folds.

Jan 1, 1992

By A. A. Lavrinenko, N. I. Gluhova, L. M. Sarkisova, D. V. Makarov

"The investigated sulfide Cu-Ni ores are characterized by low PGE contents and emulgated impregnations of pentlandite and palladium minerals in the main ore-forming mineral pyrrhotite, which hinders their selective separation, requiring a collective flotation of sulfides to concentrate, and hydrometallurgical processing. As revealed by studies of floatability of Pt-Cu-Ni ore in a mixture of butyl xanthate and chelating phosphorus containing reagents, the most effective additive is Aerophine 3416 (a phosphinates mixture) manufactured by Cytec. Using collective flotation with a butyl xanthate – Aerophine 3416 composite in the ratio of 1:3 has afforded to enhance the Pt, Pd, and Ni recovery by 13.6 %, 9.2 %, and 9.4 %, respectively. The optimal ratios of Aerophine 3416 to butyl collector for the collective flotation are the following: 1:1 for Pt and Pd and 3:1 for Ni. The effect of these reagents on the electrode potential and surface hydrophobicity of pyrrhotite, pentlandite, and platinum black has been investigated. The extraction UV spectrophotometry experiments demonstrate that DIBDTPI exists on the pyrrhotite surface mainly in the form of disulfide in weak acid medium and in the form of compounds with Fe on the mineral surface in minute amounts. There appears some disulfide and few amount of (DIBDTPI)2Ni on the surface after interaction of DIBDTPI and pentlanditeINTRODUCTIONXanthates are widely used in flotation of copper-nickel ores containing platinum group metals (PGM) as sulfides collectors which can concentrate the most part of PGM connected with the sulfides. Though xanthates are hardly efficient for flotation of free PGM, the latter are floated more slowly compared to the sulfides of base metals. The reasons for poor floatation of free (mineral) forms of PGM are under-researched, however the key accepted reasons are: fine disseminations of free PGM, insufficient interaction with xanthate and negative influence of blue copperas and sulfur-containing ions which are sulfides oxidation products (Penberthy et al. 1999; Shackleton et al., 2007). That’s why an additional collector, normally dialkyldithiophosphates, is used during flotation of PGM-containing copper-nickel ores. A reagent DP-4 is used for recovery of PGM at Norilsk mining and metallurgical plant. The reagent represents a slightly-soluble organic calcium sulfonate which is given to flotation pulp in the form of water emulsion of 5% - solution in automotive diesel oil."

Jan 1, 2016

By L. Long

Stirred milling of nickel laterites offers possibilities for improving liberation and selective size reduction of soft nickel-bearing minerals in laterites. Batch grinding tests were performed in a Netzsch LME4 stirred mill on siliceous goethitic (SG), goethitic (G), and saprolitic (SAP) nickel laterite samples (- 2000 ?m particle size) to evaluate the effect of stirrer speed, solid content, water salinity and grinding time. A fine mineral product (-38 µm) was used to evaluate the effect of selective grinding and Ni upgrade. The optimum grinding time for the highest Ni upgrade was 0.25 min, 0.1 min and 0.1 min for the SG, G, and SAP nickel laterite, respectively. A new feed (38-2000 µm) for each nickel laterite sample was prepared for batch grinding tests under the optimum grinding conditions. Upon grinding the 38-2000 µm feed, the - 38 µm product confirmed the effect of selective grinding and nickel upgrade. Size classification followed by stirred milling is a suggested process for Ni upgrade. The best Ni upgrade result was achieved on the SG nickel laterite among the three samples. The Ni grade increased from 0.85% to 1.37%, with 27.8% Ni recovery. Bottle roll leach tests showed that for SG and SAP samples selective grinding had no dramatic effect on Ni extraction due to the slow leach rate of hard mineral particles. Stirred milling of G sample increased the surface area of goethite, resulting in higher Ni extraction. Gravity concentration through a Knelson Concentrator was not effective in the further treatment of the stirred milling products either due to the poor operating conditions or due to the mineralogy characteristics of the feed samples. The energy requirement in the stirred milling was investigated. The first pass of the signature plots study is critical for the purpose of selective grinding, because the best result on selective grinding is achieved in the early stage of the grinding process.

Aug 1, 2013

By David G. Dixon, Ahmad Ghahremaninezhad, Edouard Asselin

"Atmospheric leaching of chalcopyrite in sulfuric acid solutions is a slow process due to the mineral’s passivation. We have investigated the nature of the passive film in this work. Electrochemical reduction and oxidation of chalcopyrite over the potential range of -0.5 to 1.2 VSHE were investigated in 0.5 M sulfuric acid solution (pH 0.3) at 25 ºC by multicyclic voltammetry and open circuit potential measurement. The influence of scan limits on the evolution of current peaks was studied with both stationary and rotating electrodes. It was observed that the anodic oxidation of chalcopyrite begins at potentials above 0.6 VSHE, most likely by preferential dissolution of iron atoms over copper atoms. The selective electro-dissolution process results in formation of a metal-deficient sulfide passive film (i.e. Cu1- xFe1-yS2, y > x). The passive film dissolves at 0.9 VSHE. Elemental sulfur is one of the products of chalcopyrite dissolution above 1.0 VSHE. Cathodic reactions within the potential region of 0.1 to 0.6 VSHE and anodic reactions at potentials lower that 0.5 VSHE are associated with at least one soluble species from solution. The soluble species involved in the cathodic reactions are likely ferric and cupric, while the soluble species involved in the anodic reactions is likely H2Saq."

Jan 1, 2014

By Th. Hassel

The application of magnesium as an absorbable biomaterial demanded the consideration of the alloy composition, the mechanical properties and the corrosion a special adapted material development in terms of the human biological system. Magnesium for technical applications mostly comprised alloying elements up to 10 wt%. Thereby often metals (e.g. rare earth and aluminum) with high toxic potentials are used to optimize the mechanical properties. To minimize toxic reactions during the degradation of a absorbable magnesium alloy, the Mg-Ca system is being selected and investigated because both elements belong to the mineral nutrients. Rods and small tubes are produced by extrusion of gravity die casting billets (Ca-content 0.4 to 4.0wt%). The positive grain fining influence of calcium and its improvement of the corrosion behavior are additional advantages. The microstructure, the mechanical properties and the corrosion attitude are investigated. The results show that an optimal composition of micro alloyed Mg-Ca and ideally processing parameters lead to 16% strain and a tensile strength up to 185MPa. Electrochemical investigations and measurements of the hydrogen production demonstrate the influence of the Ca-content to the corrosion behavior of the investigated alloys.

Jan 1, 2006

By C. V. Corless

THE origin of various types and groups of ore deposits was some years ago a subject of much controversy. To this statement the copper-nickel deposits near Sudbury afforded no exception. Not since the Report of the Ontario Nickel Commission, in 1917, has there been any serious discussion of the origin of this very important group. This may be because, from the opening-up of Murray mine by the British America Nickel Corporation until the recent work at Frood mine, no new ore-body of importance has been developed in the district. The controversy fifteen or twenty years ago between those who favoured the theory of magmatic segregation, among whom Dr. A. P. Coleman was the leading exponent, and those who considered that most, if not all of the Sudbury deposits could more satisfactorily be accounted for by the theory of replacement, will be remembered by many members of the Institute. Perhaps, as too often happens in controversial discussion, each side tended to overemphasize the importance of those geological phenomena which seemed to be most easily accounted for by the theory it favoured. A more balanced view would perhaps admit that replacement was probably predominant in the formation of most of the offset deposits, and magmatic segregation in that of most of the marginal deposits . But there is danger in generalization. Each body of ore should be studied by itself, and no general conclusion of this kind should be allowed to warp the judgment in making such a study.

Jan 1, 1929

By B. Szpunar

Structural and mechanical changes of urania are investigated when oxidized to U3O8. The CASTEP ab-initio quantum mechanical program, employing density functional theory is used. The total energy technique is implemented to investigate changes in the lattice constants. The ab-initio calculations predict a 36% increase in the volume per uranium atom when transforming from UO2 to U3O8, which agrees very well with experimental data. The implication of this prediction on the linear expansion and fuel fragmentation is discussed. The calculated elastic constants of urania are in good agreement with experiment. The predicted mechanical properties of UO2 and U3O8 are compared.

Aug 1, 2010

By V. C. Pandolfelli, S. F. Santos, L. A. Rodrigues

Under conditions of stable crack propagation at room temperature, the elastic energy stored in ceramic materials is converted mainly to surface energy. However, at high temperatures, creep may also occur in such materials, in which case it will present a ductile behavior. This paper discusses the brittle-ductile transition of a refractory material. Stable crack propagation and creep tests were carried out under a three-point bending device. A commercial ceramic containing 63 wt-% of SiO2 and 31 wt-% of Al2O3 was used as testing material. The results revealed that the change in behavior from brittle to ductile was caused by softening of a vitreous phase present in the material's microstructure.

Jan 1, 2004

By Y. Turen, Y. Karakas, E. Candan, C. Sahinturk

In this study, wettability between sprayable tundish lining (MgO) and molten steel was investigated by using sessile drop method. Content of glass fiber (SiO2) in the MgO varied between 0 to 8 wt% whereas mean particle sizes of the MgO were 25, 75, 150 and 300µm. Experimental results revealed that contact angle (0) of sessile drop on the MgO was not altered by the addition of glass fiber up to 1 wt.% whereas above 2 wt.% addition decreased the 0 considerably. Contact angle, 0, increased considerably with increasing MgO particle size. SEM analysis showed deposition of glass phase was present at the interface as the finer MgO particles were used.

Jan 1, 2004

By Louis Tellier

SIDBEC commenced detailed planning of major capital expenditures to install integrated steelmaking facilities in 1969. Today, less than IO years later, SIDBEC and its subsidiaries have completed major mining, concentrating, pelletizing, direct reduction ? electric furnace steelmaking and continuous casting plants. The total cost of these projects was almost 1 billion dollars. The philosophy behind the project planning and the evolution of management control are explained. These extensive projects were undertaken during a period of exceptional inflation and a disturbed labour climate, but were nevertheless completed with only modest overruns, with good control of timetables and with exceptionally good start-up performance. Project planning, relations with consulting engineers, introduction of new technology, purchasing and field management and cost control are discussed.

Jan 1, 1979

By P. Cielo

"Nondestructive inspection is an important quality control tool in the material processing industry. Being nondestructive, such a control may be applied to the whole production, as long as the available techniques are fast and easily automated. Ideally, nondestructive testing (NDT) methods should operate in a noncontact configuration in order to be deployable on-line with minimum perturbation of the production process.After a short introduction to the most common NDT techniques, with particular emphasis on ultrasonic, radiographic and electromagnetic methods, a few new approaches which are under development at the Industrial Materials Research Institute, (Boucherville, Quebec), are reviewed. Noncontact techniques such as laser ultrasound, thermoelastic and thermographic methodologies will be described, and their applications to materials of industrial interest will be discussed."

Jan 1, 1989

By G. J. Simandl, H. -L. Jacob, S. Paradis, G. Valiquette

"Nos travaux de terrain dans le Grenville, effectués dans le cadre d'un projet d'inventaire des gîtes de wollastonite, ont démontré qu'il existe un secteur exceptionnellement favorable à l’exploration pour la wollastonite. Ce secteur s'étend de la municipalité de Grenville jusqu'au pare du Mont-Tremblant (nord de St-Jovite). D'autres secteurs favorables a 'exploration pour la wollastonite ont été délimités dans les regions du Lac-Saint-Jean, de Shawinigan et de la Gatineau. Neuf categories litho-structurales de gites de wollastonite furent identifiées. L'importance d'un système ou vert pour la formation des gîtes de hautes teneurs fut établie. Un guide de prospection pour la wollastonite propre à la province tectonique de Grenville fut développé. Plusieurs des indices sont prometteurs et mériteraient des travaux de raise en valeur afin de determiner s'ils représentent une source de wollastonite exploitable à profit. Lac-Saint-Jean, Shawinigan and Gatineau areas. Deposits may be classified into nine categories depending on their relationship to intrusive rocks, discordant or concordant contacts with the host rocks, morphology, and major structural controls. Deposits consist mainly of wollastonite, calcite and clinopyroxene. They may contain one or several of the following minerals: feldspar, scapolite, quartz, titanite sulphides, zoisite, clinozoisite, garnet, idocrase and prehnite. Wollastonite content may reach over 70%. Some deposits are associated with graphite veins. Better understanding of the geology, combined with the proposed classification provides new exploration guide for wollastonite. Several deposits have grades of economic interest. Further work is needed to determine if any of these deposits can be exploited for profit."

Jan 1, 1990

By D. L. Babbitt, Sniezek

"This paper deals with the varions methods for the rapid Joading of unit trains which are being: used by ore procossors to move their product to dock-s1de storage facilities or their ultimate customer. Some of the techniques that have been used include (1) volumetrie loading, both in motion and static, (2) batch weighing into moving cars and (3) batch weighing into cars that have been stopped. Particular emphasis shall be placed on the two systems now in use at the Adams Mine facility of Jones and Laughlin Steel Corporation and at Cliffs of Canada's Sherman Mine. Typical ""turnaround"" times, loading rates, types of cars, weighing accuracies, material handling concepts and maintenance considerations shall be discussed."

Jan 1, 1969

By W. P. Nash, T. E. Mccandless

"Abstract - Detrital minerals of upper mantle origin occur in Holocene conglomerates, pediments and antmounds, and in Oligocene conglomerates in the Green River Basin of southwestern Wyoming. The minerals are derived from disaggregated eclogite and peridotite, and are similar to minerals found in mantle- derived igneous rocks such as kimberlite and lamproite, the primary host rocks for diamond. The Green River Basin bisects the lamproite fields of the Leucite Hills (Wyoming) and Kamas (Utah) and overlies the Archean Wyoming craton, which makes the region favorable for diamond occurrence. Lamproite is the favored host for the indicator minerals because unusual high-Fe salitic diopside macrocrysts from the antmounds and from the ~1 Ma old Leucite Hills lamproites to the northeast are compositionally identical. The salitic diopside is uncommon in other igneous rocks and could be a new indicator mineral for use in lamproite exploration. The Green River Basin indicator minerals are eroded from the ~29 Ma old Bishop Conglomerate, whose source area is the Uinta Mountains to the south. No continuous mineral train exists between the Uinta occurrences and those in the Green River Basin. Assessment of the minerals using established and new geochemical criteria indicate that they formed in an oxidizing upper mantle and were transported to the surface by either kimberlite or lamproite. The existence of cogenetic diamond is unlikely based on the mineral chemistry, but selective removal of diamond indicator minerals through weathering and fluvial transport cannot be excluded. Diamonds and mantle garnets are present in the northeastern Uinta Mountains, but they originated as part of the Diamond Hoax of 1872. A representative mineral assemblage from the true igneous host of the indicator minerals is required to fully establish their economic potential. Post-Oligocene erosion and Pleistocene glaciation have hindered efforts to locate a bona fide igneous source for the indicator minerals. Résumé - Des minéraux détritiques provenant du manteau supérieur ont été trouvés dans des conglomérats, des pédiments et des monticules de fourmis de l’Holocéne, et dans des conglomérats de l’Oligocène du Green River Basin, au sud-ouest du Wyoming. Ces minéraux sont issus du démantellement d’éclogites et de péridotites, et sont semblables aux minéraux trouvés dans des roches ignées provenant du manteau, comme les kimberlites et les lamproïtes. Ces dernières sont les roches hôtes du diamant. Le Green River Basin recoupe les champs à lamproïte de Leucite Hills, au Wyoming et de Kamas en Utah, et il surmonte le craton archéen du Wyoming, connu pour la présence de ses diamants. La lamproïte est l’encaissant privilégié pour les minéraux «indicateurs» parce que des macrocristaux exceptionnels de diopsides salitiques riches en Fer, provenant des monticules de fourmis et des lamproïtes de Leucite Hill (~1 Ma), au nord-est, ont des compositions identiques. Le diopside salitique est rare dans les autres roches ignées et peut être un nouvel indicateur dans la recherche de lamproïte. Les minéraux «indicateurs» du Green River Basin proviennent de l’érosion du Conglomérat de Bishop, daté de ~29 Ma, dont la zone source est représentée par les Uinta Mountains, au sud. Aucune continuité des gisements minéraux n’existe entre les affleurements de Uinta et ceux du Green River Basin. La détermination des minéraux, utilisant des critères géochimiques anciens et récents, indique qu’ils se sont formés dans un manteau supérieur oxydant et qu’ils ont été remontés à la surface soit dans des kimberlites, soit dans des lamproïtes. La genèse du diamant n’est que peu liée à la chimie minérale, mais le lessivage d’indicateurs minéraux du diamant par altération météorique et par transport fluviatile ne peut être exclu. Des diamants et des grenats mantelliques sont présents dans le nord-est des Uinta Mountains, mais sont associés avec le Diamant Hoax de 1872. Un assemblage minéral représentati"

Jan 1, 1996

By B. R. Rakishev

Balanced development of mining works at all the benches of a working zone by use of the excavator-automobile complex is achieved by transition to the technology of the bench excavating with cross panels by the two-sub-bench scheme with the changing levels of the working platforms (is patented in Kazakhstan). In deep quarries realization of this technology will allow to reduce the current volumes of the stripping ore excavation by 10?15 % and more, to increase the opened reserves of minerals by 20?50 % to decrease volume of mining-capital works for construction of stripping excavations by 2?4 times and to provide efficient use of powerful excavator-automobile complexes.

Aug 1, 2013

By Lassi Klemettinen, Ari Jokilaakso, Dmitry Sukhomlinov, Pekka Taskinen

The solubilities and distributions of molybdenum and iridium in iron silicate slag and copper-iron mattes were studied using an equilibration-quenching technique and subsequent direct phase composition analyses by EPMA (Electron Probe X-ray Microanalysis) and LA-ICP-MS (Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry). The equilibrations were carried out on a wide matte grade interval, ranging from 55 wt-% Cu to 75 wt-% Cu, in pSO2 = 0.1 atm at 1300°C. The results in equilibrium with a solid iridium-molybdenum alloy indicated an iridium solubility of 150–500 ppmw in the sulphide matte, depending on the matte grade, and a molybdenum solubility of 100–600 ppmw. Iridium was distributing predominantly in the sulphide matte with the distribution coefficient of 10+3 - +4 but molybdenum deported predominantly in the slag with Lm/s(Mo) = 0.02–0.1. The effects of alumina and lime additions in the smelting slag were also examined. INTRODUCTION Iridium is a highly siderophile element (HSE), which means that it is incompatible with the sulphide forming elements and possesses a small solubility in mattes, such as copper- and nickel-iron sulphide melts. Molybdenum behaves only modestly in that way (Walker & Li, 2008; Righter et al., 2017). They both are known to be trace elements accompanying copper and nickel sulphide ores. No solubility data, however, are available for them in copper-rich sulphide mattes. Geochemical data on the behaviour of Ir and Mo deal mostly with low-iron silicate systems, e.g. basaltic melts, and high-sulphur sulphide solutions and mattes (Ertel et al., 2008; Fonseca et al., 2007). They also indicate that Ir and Mo dissolve in silicate melts primarily as oxides and not as electrically neutral metal species. Most geological data of iridium focus on high-sulphur systems of the monosulphide composition and typically Fe-Ni mattes where copper is a trace element (Fleet et al., 1996; Sattari et al., 2002). Direct solubility measurements for mattes and iron-lean silicates have also been made using pure Ir or an Ir alloy as the saturation phase (Borisov & Palme, 2000; O’Neill & Eggins, 2002; Makovicky & Karup-Møller, 1999; Ertel et al., 2008; Mungall & Brenan, 2014). A recent summary about the solubilities of HSE’s in iron- and sulphur free silicates is available in Laurenz (2012). The thermodynamics of molybdenum partitioning between oxides and Fe-S-O melts was studied by Mengason et al. (2011). Their results indicate strong accumulation in the iron-rich sulphide in reducing conditions (pO2 = 10-9.6 atm in Ni-NiO equilibrium at 1050°C). Molybdenum dissolves in iron-lean silicate melts as MoO3 species in oxygen pressures above the Fe-FeO equilibrium and as MoO2 in more reducing conditions (Farges et al., 2006; Righter et al., 2017).

Jan 1, 2019

By A. Ockewitz, A. Trondl, D. -Z. Sun

"Numerical simulation of extrusion processes offers an efficient method for tool design and optimization of geometries and properties of extruded parts. However, until now there are few systematic investigations about influences of material model and different parameters e.g. for friction and thermal processes on calculated local and global responses. Since extrusion processes are essentially influenced by friction between billet and extrusion tools, new friction tests were performed in this work to develop a reliable friction model. Compression and torsion tests were performed at different temperatures and velocities to calibrate the material model for extrusion simulations. Extrusion processes for circular rods and U-profiles were conducted at TU Berlin with backward and forward extrusion for different extrusion ratios, billet temperatures, product velocities and cooling conditions. This work focuses on numerical simulations of the extrusion tests with the FE code HyperXtrude. Based on the calculated distributions of local strain, strain rate and temperature the recrystallized volume fraction and grain sizes were calculated with empirical models and compared with the experimental results from optical micrographs and EBSD scans. The calculated total and friction forces and temperatures were compared with the experimental results and the deviations between experiment and simulation were analyzed.INTRODUCTION Extruded aluminum components are widely used in vehicle constructions due to light weight and manufacturing consideration. Local mechanical properties in the components are inhomogeneous as a consequence of the spatial distribution of microstructure which is influenced by numerous factors like material composition, temperature, tool design, friction, extrusion ratio and speed during the extrusion process. For the optimization of the extrusion process with regard to all these factors numerical simulation can be an essential tool. Based on results of finite element simulations of the extrusion process the microstructure in the extruded components can be predicted and then the resulting mechanical properties can be numerically determined instead of by costly trial and error methods. The aim of the work presented in this paper is the development of a numerical method for the simulation of extrusion processes with modeling of microstructure."

Jan 1, 2018