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By H. Soltanzadeh

This paper summarizes semi-analytical and closed-form solutions that can be used to assess the poroelastic stress changes induced within a porous formation (reservoir) during a pore pressure change. Further, solutions are presented for the stress discontinuities at the interfaces between reservoirs and the rocks that surround them. When used in combination with rock failure criteria, these solutions enable relatively simple analyses of the potential for induced fracturing or fault reactivation within a reservoir or the rock immediately adjacent to it. The latter, in particular, is useful for assessing if the hydraulic integrity of the surrounding rock (i.e., the bounding seal) will be affected by a pore pressure change. The use of the approach presented in this paper is illustrated with an analysis of a pinnacle reef with dimensions and properties representative of reefs in the Zama oil field, northwestern Alberta, Canada. Scenarios of pore pressure decrease (during historical production operations) and pore pressure increase (during several years of acid gas injection operations) are analyzed, for three different idealizations of reservoir properties and geometry (two plane strain and one axisymmetric). These results suggest that that the potential for induced fracturing is not significant at any point within the reservoir or the surrounding rock for both the production and injection scenarios that were simulated. Similarly, fault reactivation was not predicted for the reservoir or any of the points that were analyzed in the surrounding rock. However, fault orientations having the greatest potential for reactivating during historical production operations were identified; thus, illustrating a means of using geomechanical models to focus geological characterization efforts on the features that are most critical to acid gas containment.

May 1, 2009

By Frank Mucciardi, Louca Gourtsoyannis

"Low and inconsistent recoveries of aluminum in the production of aluminum-killed steels triggered an extensive research program on the aluminum dissolution kinetics at McGill University. This research program led to the understanding of the melting kinetics and the hydrodynamics of making additions to liquid steel. It showed the necessity of gradually releasing liquid aluminum at the bottom of the ladle to increase aluminum recoveries.This knowledge was verified in practice at Sidbec-Dosco, where a prototype aluminum wire injector was developed and installed for the first time in Canada. The industrial application showed the validity of the theoretical and experimental results and provided further data for the mathematical modelling of the process.The development of the theoretical understanding, the industrial results, and the interaction between university and industry are presented.IntroductionAluminum is an extremely effective deoxidizer of molten steel; nevertheless, an efficient method of adding it to steel has eluded steelmakers for many years. It is well known that the recovery of aluminum used in the production of aluminum killed steel is both low and eratic, especially when the aluminum is added in the form of bars or lumps from chutes into filling ladles, a practice still common in many of today's steelmaking operations.As the density of aluminum is only about 40010 that of molten steel, it is conceivable that loose bars of aluminum simply ""thrown"" into a filling ladle will resurface before any appreciable dissolution of the aluminum has occurred, particularly if the depth of penetration of the additions is small. Before one can conclude that this is indeed the case, it is necessary to know the melting kinetics of an aluminum addition. Back in 1972, this information was not available; hence an extensive research program which focused on melting kinetics was initiated at McGill University."

Jan 1, 1982

By A. LA. Salama, D. B. Hyma

"The Western Research Centre (WRC) of CANMET located in Devon, Alberta, is a modern research facility offering services ranging from fundamental research to pilot plant investigations. Recently, a 0. 76 metre diameter by 7.9 metre high Flotaire column flotation cell was installed as a demonstration unit for Canadian coal producers. Because the column cell is intended to be used for research, development and demonstration, WRC recognized that additional sensing equipment and improved process control would be required to generate good data for subsequent column scale-up and engineering design.A low cost, personal computer based control system was, therefore, designed and installed. This paper describes the stepwise procedure in developing the control strategies, selection of system software and hardware, and installation and configuration of the system.Preliminary performance data on a western Canadian coal sample are also presented. Future testwork is planned on additional coal samples to expand upon existing database."

Jan 1, 1993

By B. Misra, B. S: Sastry, Kollu S. Rao

"This paper reports the results of a finite element study of the geothermal heatflow into dry mine airways. For isotropic and unsteady state conditions the heatflow into mine airways is studied for a range of surface heat transfer coefficients between rock and air, and age of the airway. Dimensionless temperature gradient values are presented in tables for different values of Boit and Fourier numbers and the results are compared with Starfield tables and Gibson algorithm. It is found that Starfield tables have consistently over-predicted the G values with errors ranging from 2% to 10%. The differences between results obtained from the finite element study and the G values calculated from Gibson's approximation method are mapped. The small error values over a large range of Fourier and Biot numbers confirm the suitability of Gibson's algorithm to rapidly calculate G values for estimating the heat transfer from surrounding rock to mine air.IntroductionIn many underground mines heat is a major problem, and the provision of acceptable working conditions requires considerable expenditure on ventilation systems. The rational design and operation of these systems depend upon an understanding of the various sources of heat in the mine. The natural source, i.e. geothermal heat, contributes up to 80% of total heat added to mine air and it is difficult to analyze and predict the heat owing to a number of influencing variables. The problem of geothermal heat flow has been studied by many investigators (Goch, 1940; Starfield, 1966; Hemp, 1987; Amano et al., 1982; McPherson, 1986).The primary concern of this paper is to develop a better ready reference dimensionless transient temperature table for estimating heatflow at any stage of mine airway life."

Jan 1, 1994

By A. Iizuka

This study was aimed at separating and recovering arsenic, antimony, and tin from refining byproducts generated in a nonferrous smelter. The target byproduct was a silicate slag containing the above elements. The silicate structure of the slag was destroyed by alkali roasting, which then enabled leaching of arsenic, antimony and tin in solution effectively. Arsenic was selectively leached out by hot water after alkali roasting of the slag, while remained antimony and tin in the residue were leached out by a hot hydrochloric acid solution. However, when the solid-liquid ratio in the leaching solution was increased, hydrous gelatinous silica (gel-like silica) was formed during the hydrochloric acid treatment and filtration became difficult. Therefore, high temperature and high pressure leaching was attempted to improve the filterability of the silica leaching residue. In the high temperature and high pressure treatment, the hydrous gel-like silica was transformed into easily filterable aggregated silica, and thus, filtration became easy. By investigating the neutralization and sulfurization treatment for the obtained hydrochloric acid leachate (second leachate), it was possible to separate antimony and tin. INTRODUCTION This study aims to separate arsenic and recover valuable metals such as antimony and tin from refining byproducts generated in a nonferrous smelter. The target smelting byproduct is antimony-containing slag in this study. In many cases, alkali roasting was adopted as pretreatment for extraction and recovering valuable metals from smelting residues and wastes (Rao, 2006). For antimony-containing slag in this study, one effective method for separating arsenic is to convert arsenic to sodium arsenate (Na3AsO4) by roasting with a sodium compound and then to remove arsenic by hot water leaching. In addition, by alkali roasting, the silicate structure of the slag is destroyed, and effectively alkalizing tin and antimony is accomplished. Then, precipitating and recovering tin and antimony leached into the acid solution are considered possible by sulfurization and neutralization treatments. In this research, we conducted basic studies on the following. 1) Destruction of silicate structure in slag by alkali roasting and leachability of arsenic. 2) Conversion of hydrous gelatinous silica to aggregated silica by hydrochloric acid treatment of residues after arsenic leaching under high temperature and high pressure, as well as leachability of antimony and tin. 3) Separation and recovery of antimony and tin by sulfurization and neutralization treatments of hydrochloric acid leachate. These topics of investigation can support to consider the separation and recovery process of arsenic, antimony, and tin from antimony containing slag.

Jan 1, 2019

By G. Gabra

"A process of leaching niobium oxide from pyrochlore concentrate using hydrofluoric acid is described. Variables such as acid concentration, temperature, reaction time, solid/acid ratio, agitation speed and particle size are correlated to the recovery of niobium oxide.The relatively low activation energy (1,86 Kcal/mole) and the dependence of reaction rate on agitation suggest that the process is diffusion controlled. The optimum conditions for extracting niobium oxide from the leach solution, using either methyl isobutyl ketone or tributyl phosphate have been determined.IntroductionMost of the commercial production of niobium and tantalum has been derived from the treatment of columbite - tantalite minerals.In recent years (1960) , pyrochlore mineral has been found to be an alternate source of niobium . This mineral varies widely in composition and contains in addition to the main elements of calcium , sodium and niobium, some tantalum, fluorine, rare earth elements, titanium, alkali an d alkaline earth elements.It is well known that the province of Quebec possesses several pyrochlore niobium deposits totalling approximately 151 million ton s at an average 0.45% niobium oxide(1). One of the deposits, the St-Honor carbonatite, was brought into production by Niobec Inc. in 1976. Flotation o f this material produces a concentrate of about 60% Nb205(2).In view of an expanding niobium market in recent years and the presence of large niobium deposits in the province, a research and development program was initiated at the Centre de Recherches Miner ales to evaluate known processes for the separation of niobium and tantalum from each other as well as their purification . Some work has also been undertaken at the CRM to develop an improved extraction process. T his work will be the subject of further communication s."

Jan 1, 1985

By T. J. Bruce, G. E. Agar, R. Stratton-Crawley

"A technique by which the design of a flotation circuit may be optimized is described and examples of the application of this methodology are given.Three interrelated criteria are defined and the application of these criteria to the selection of the optimum residence time for each stage of a flotation circuit is demonstrated. The criteria are:(1) Add no material to the concentrate that is lower in grade than the feed to that separation stage.(2) Maximize the difference in recovery between the desired mineral and the gangue.(3) Maximize the separation efficiency.Three independent systems were examined experimentally and it was shown that application of any of the criteria yielded similar results.It was demonstrated how the application of rate measurements (Criterion #2) could lead to the selection of a set of optimized times for several stages in a flotation circuit and that these could in turn be used to simulate the results of a locked cycle test. The predictions were checked against the experimental results from a locked cycle test and there was substantial agreement between the predicted and observed results."

Jan 1, 1980

By J. Currie, J. McManus, R. Chenier

"Cominco Copper Division's Valley Mine is located in the Highland Valley of British Columbia, approximately 275 km by air northeast of Vancouver. The nearest towns are Logan Lake, located IS km to the east and Ashcroft, located about 50 km to the northwest.Preproduction stripping of rock and overburden at the Valley Mine's Lake Zone Pit began in mid-1982 following a decision to discontinue mining in the adjacent Jersey Pit. Equipment and mining methods were carried over from the Bethlehem Copper operations which, with Valley Copper Mines, were merged into Cominco in December 1982.Blasting practices, as carried over from the Bethlehem pits, were designed to provide the fine fragmentation required to meet production requirements using the Bethlehem crusher. However, after mining the first few benches of the Lake Zone Pit, it became apparent that overblasting at the pit limits was causing a number of bench failures, as well as contributing to an over-all reduction of the material strength of the rock mass forming the southwest wall of the pit.With present ultimate pit plans calling for the southwest wall to be as high as 300 m, Valley staff realized that potential slope stability problems should be dealt with as early as possible. This philosophy would enable experimentation on phase pit walls in order to attain the optimum slope angle on the ultimate pit wall.As part of an over-a ll slope stability program, a controlled blasting program was initiated at the Lake Zone Pit in March 1983. In this program, Valley engineering and production staff worked together with Golder Associates in establishing design criteria and evaluating the results. This program resulted in a marked improvement in the soundness of pit walls while maintaining the required degree of fragmentation."

Jan 1, 1985

By R. S. Boorman, L. J. Surges

"Ore reserves at Brunswick Mining and Smelting totalled 101(106) tonnes grading 97 grams tonne-1 silver at the end of 1981. Silver is recovered as a byproduct in the copper, lead and bulk concentrates and is lost to the zinc concentrate and plant tailings. Recovery of silver for the year 1981 was 58,5%. The loss of potential revenue is in excess of Cdn $50(106) year-1 at current silver prices and milling rates.Silver is known to occur in solid solution in galena and as tetrshedrite. Evidence indicating the identity and significance of a third silverbearing mineral assemblage is reviewed and the distribution of silver losses is detailed. Characteristics of each the carrier which may be responsible for observed distribution, including size, surface quality, liberation and composition are considered, and the third carrier is shown to have possible implications for improved silver recovery by other Canadian producers as well as by Brunswick Mining.Silver tetrahedrite tailings distributed tailings and losses occur as coarse, free and as very fine unliberated galena in losses of the third carrier are between the zinc concentrate and are concentrated in the finest size fractions. Process alternatives for enhanced silver recovery by physical and chemical means are reviewed."

Jan 1, 1983

By Shahram Tafazoli

ABSTRACT: This article presents a novel technology for sensing the size of rocks after blasting in hard rock mines. Blast engineers require rock size statistics to carefully adjust the blasting parameters. The rock fragmentation requirements vary depending on the ore type and crusher specifications. The most popular statistical parameters in the industry are the so-called P numbers (e.g., P80 and P100). A machine vision based system is introduced here for automatic image collection and fragmentation analysis of the material right inside the bucket or dipper of mining shovels. A heavy-duty camera provides the required imaging data to an embedded computer mounted inside the cab. A custom machine vision software continuously analyzes the captured bucket images and stores the suitable ones in local storage which are then fed to a Desktop software for automatic fragmentation analysis. This technology has been developed by Motion Metrics International and is commercially available as FragMetrics?.

Oct 1, 2009

By Shahram Tafazoli

This article presents a novel technology for sensing the size of rocks after blasting in hard rock mines. Blast engineers require rock size statistics to carefully adjust the blasting parameters. The rock fragmentation requirements vary depending on the ore type and crusher specifications. The most popular statistical parameters in the industry are the so-called P numbers (e.g., P80 and P100). A machine vision based system is introduced here for automatic image collection and fragmentation analysis of the material right inside the bucket or dipper of mining shovels. A heavy-duty camera provides the required imaging data to an embedded computer mounted inside the cab. A custom machine vision software continuously analyzes the captured bucket images and stores the suitable ones in local storage which are then fed to a Desktop software for automatic fragmentation analysis. This technology has been developed by Motion Metrics International and is commercially available as FragMetrics?.

Oct 1, 2009

By Shahram Tafazoli

This article presents a novel technology for sensing the size of rocks after blasting in hard rock mines. Blast engineers require rock size statistics to carefully adjust the blasting parameters. The rock fragmentation requirements vary depending on the ore type and crusher specifications. The most popular statistical parameters in the industry are the so-called P numbers (e.g., P80 and P100). A machine vision based system is introduced here for automatic image collection and fragmentation analysis of the material right inside the bucket or dipper of mining shovels. A heavy-duty camera provides the required imaging data to an embedded computer mounted inside the cab. A custom machine vision software continuously analyzes the captured bucket images and stores the suitable ones in local storage which are then fed to a Desktop software for automatic fragmentation analysis. This technology has been developed by Motion Metrics International and is commercially available as FragMetrics?.

Oct 1, 2009

By E. Ghali, J. F. Dorion

This paper presents the results of on-going investigations on the influence of corrosion on the performance of support systems in selected underground gold mines. Rock support is exposed to various conditions that can be aggressive. Samples of corroded support were analysed using SEM and photomicrography to determine the main corrosion forms. Tests are on-going in controlled corrosion chambers to qualify and quantify the impact of rock and minerals particles on steel corrosion. As more data become available these relationships can lead to useful information on the choice of support systems and reliable estimates of their longevity.

Jan 1, 2011

By Akiyoshi Horiuchi, Manabu Kanno, Shigeki Sato, Taro Aichi

"AKITA ZINC Co., Ltd. (Iijima Zinc Refinery), jointly owned by DOWA METALS & MINING Co., Ltd.(DMM), has used the company’s own hematite process for iron control since the beginning of operations in 1971. The hematite process consists of reductive leaching with SO2 gas and iron removal in autoclaves by high temperature hydrolysis. This process enhances not only zinc recovery but also the recovery of gold, silver, copper, lead and rare metals, which is carried out at another DOWA metallurgical plant. All by-products produced in the hematite process are marketed and sold. This paper presents an overview of the hematite process and the recent process improvements made.INTRODUCTION DMM carries out mining and smelting activities for precious metals, PGMs, rare metals and base metals such as copper, lead and zinc. It owns KOSAKA SMELTING & REFINING, producing copper and lead, and the AKITA ZINC Co., Ltd. (AZC) in Akita Prefecture. DOWA is a specialized smelting company which has established a metallurgical complex for copper, lead and zinc, including a recycling business. AZC was established in 1971 at a production capacity of 72,000 t/y zinc; it is jointly owned by DMM and five other non-ferrous metal companies. AZC has increased its capacity continuously and now produces 210,000 t/y of zinc. Figure 1 shows the changes in zinc production and capacity at AZC."

Jan 1, 2016

By Li. L.

Backfilling has become a popular solution in underground mines around the world. It reduces environmental impact of mining industry and improves ground stability. In most cases, backfill has a high water content so that it can be delivered by pipes from a backfill plant on ground surface to underground stopes. Upon deposition in the stope, the backfill tends to consolidate under its own weight, leading to a generation of excess pore-water pressure. To avoid excessive pressure and protect the backfill barricade installed at the base of the stope, the backfilling of the stopes is usually divided into two stages: plug pour and backfill body pour. The interruption of backfilling operation is undesirable as it slowdowns the mining productivity, and sometimes causes pipe clogging, leading to unexpected increase in manpower cost and further reduction in mining productivity. The backfilling interruption time may be reduced, even eliminated if the drainage of backfilled stopes is sufficiently improved. This paper presents an application of wick drains, a material commonly used in civil engineering, to mine backfilled stopes to help accelerating the drainage. A protocol is proposed for installing the wick drains in a mine stope to be backfilled. Numerical simulations were made, showing that the drainage of the backfill can significantly be improved by the introduction of wick drains. The application of wick drains in mine backfill can thus be considered as a promising technique and merits deeper and more detailed investigation.

Aug 1, 2013

Real time analysis of ore quality between the mine and mill provides major benefits to copper mining and processing operations. Prompt gamma neutron activation analysis (PGNAA) is a proven technique that has been successfully applied for real time conveyed flow multi-elemental measurement. The advantage of PGNAA is that it measures through the full conveyed cross section continuously and provides representative element measurement without the need to constantly sample coarse (primary crushed) conveyed flows. High specification PGNAA analyzers enable accurate measurement over time increments as short as thirty seconds. Elements such as copper can be measured to a precision of 0.02% copper which is sufficient for high confidence in decisions for bulk flow diversion. Increments of eight tonnes are being diverted through a bulk ore sorting application to remove batches of waste from mill feed as well as divert material to different stockpiles based on ore quality. Longer measurement increments of two to five minutes are suitable for blending control of ores to reduce feed quality variability and to control average ore quality within a target range. Feed blends can be adjusted as frequently as required but typically multiple measurement increments are composited to produce a rolling average ore quality. The paper details two case studies where analyzers have been successfully used to measure conveyed flows for blending and bulk diversion applications. The real time measurements of ore composition are also used for ore reconciliation, in metal accounting and providing process operators with advance warning of ore quality changes that may affect grinding performance and cause process upsets. Real time ore quality measurement has proven beneficial in improving copper processing performance through better utilising plant capacity in a leaching operation, optimising ore feed quality, and reducing unnecessary processing of waste. INTRODUCTION Representative real time elemental analysis of conveyed ore quality using fully penetrative technologies has been available to the minerals industry since the 1990s. The Prompt Gamma Neutron Activation Analysis (PGNAA) technique was developed into a conveyed material analyser and soon adopted by the cement and coal industries which recognised the benefits in real time quality management. These commodities were ideally suited to this measurement technique as operations generally involved conveying bulk material prior to processing. Measured quality was used to divert material to different destinations or used to control blending for improved quality consistency. Uptake in the minerals industry, however, has been slow until the last ten years, and particularly until the mid-2010s.

Jan 1, 2019

"A 3-dimensional finite element model for stress/stability analysis of rock excavations in underground mines is presented. Developed for use on personal computer under OS/2 operating system, the model employs the 8-node isoparametric brick element and accounts for such loading conditions as in situ stresses and gravity loading of the rock mass. In addition, modelling of backfill in mine stopes as in situ stress-free material is incorporated. Material failure is assessed by Mohr-Coulomb or Hoek-Brown failure criterion. A mine design example is presented to illustrate the potential use of the model as a tool for stope design.IntroductionNumerical modelling of mine structures has become a vital tool for mine design in recent years. The need to maximize ore extraction ratio and to reach deeper mineral deposits underground has led the mining industry to employ numerical methods of analysis to undertake complex ground control studies in order to better understand the ground response to mining excavations and to evaluate the ground support requirements. Thanks to the rapid developments in computer technology, it is now possible to perform very comprehensive analyses including, but not limited to, 3-dimensional, elasto-plastic, or large deformation or time dependent nonlinear analyses on personal computer.During the past ten years or so, many researchers undertook 3-D finite element analyses of rock mechanics problems in mining engineering. The following is only a sample review. For example, Chan'!' used three-dimensional finite elements to study the mechanical response of jointed granite during shaft sinking at the Canadian Underground Research Laboratory. Wang et al.(2) performed 2-D and 3-D finite element analyses of room-and-pillar mining system with flat and rolling coal seams. Thatejatu used three-dimensional finite element method to examine the problem of branching tunnels. Dolezalovaw used three-dimensional finite elements for the analysis of tunnel-face advance with partial excavation as well as full-face excavation in combination with rein for cement of the face by long anchors. Peili (5) used three-dimensional finite elements for the simulation of rock-liner interaction near the tunnel face."

Jan 1, 1992

By Robert A. Gault, T. Scott Ercit, Mehmet F. Taner

"Abstract -Vanadium mineralization occurs in oxide-rich horizons within the layered gabbro zones of the upper parts of the Bell River Complex, Matagami, Québec and the Lac Doré Complex, Chibougamau, Québec. The vanadium-rich horizons are well defined on the ground and in aeromagnetic surveys by their high magnetic susceptibility; consequently, magnetic susceptibility can be an indicator of vanadium mineralization. The main oxide minerals are ilmenite and titanian magnetite, containing 20% to 70% of volume and the ratio of titanian magnetite to ilmenite is relatively constant, ranging from about 1:1 to 2:1. Their sizes are less than 5 µm to greater than 1 mm to 2 mm, occurring as coarse- to medium-grained subhedral crystals intergrown with cumulate silicate minerals (plagioclase, pyroxene, etc.). Electron microprobe analyses indicate that the ilmenite grains are mineralogically and compositionally homogeneous and have low V contents (average 0.18% equivalent V2O5). In contrast, the titanian magnetite grains are inhomogeneous, consisting of trellisworks of ilmenite lamellae in Ti-poor, V-rich magnetite [less than 2 wt% TiO2, and 1.41% equiv. V2O5 (1.16% V2O3) for 20 analyses]. Thus, the magnetite is the principal ore mineral of vanadium; it hosts vanadium in the form of V3+, not V5+, as is commonly and erroneously reported. We have also devised a flowchart for the beneficiation of vanadium-titanium ores. Sommaire - La minéralisation de vanadium se trouve dans des horizons riches en minéraux oxydés de la partie supérieure des zones de gabbros lités des Complexes de la Rivière Bell, Matagami, Québec et du Lac Doré, Chibougamau, Québec. Des horizons riches en vanadium ont été bien définis sur le terrain et dans les levés aéromagnétiques par leur susceptibilité magnétique élevée; conséquemment, la susceptibilité magnétique est l’indicateur directe du contenu en vanadium. Les principaux minéraux oxydés sont l’ilménite et la magnétite titanifère, contenant 20% à 70% du volume et le rapport de magnétite titanifère à ilménite est relativement constant, allant d’environ 1:1 à 2:1. Leur dimension varie de 5 µm à plus grande que 1 mm à 2 mm, apparaissant sous forme de cristaux subidiomorphes, de grains grossiers à médiums, intercroissant avec la gangue silicatée (plagioclase, pyroxène, etc.) de la texture de cumulat. Les analyses à la microsonde électronique montrent que les grains d’ilménite sont minéralogiquement et chimiquement homogènes avec un faible contenu en V (moyenne 0.18% équiv. V2O5 ). Contrairement, les grains de magnétite titanifère sont hétérogènes, contenant des lamelles d’ilménite en "trellisworks"; ces grains sont pauvres en Ti et riches en V pour la portion magnétite de la magnétite titanifère [surtout contenant moins de 2 wt. % TiO2, et en moyenne 1.41% équiv. (1.16% V2O3) pour 20 analyses]. Ainsi, la magnétite est le principal minerai de vanadium; elle renferme du vanadium sous forme de V3+ et non de V5+, tel qu’il a été communément et à tort rapporté. Nous avons aussi défini un "flowchart" pour la bénéficiation des minerais de vanadium-titanium."

Jan 1, 1998

By Marc C. Bétournay

Replacing diesel power in underground metal mining vehicles with available clean energy (e.g. hydrogen, lithium-ion batteries) is now a priority due to worker health issues, the increasing price of diesel, ventilation costs and air quality. Hydrogen fuel cells are a known and broadly applied power technology. They have been the focus of a dedicated research program to carry our proof of concept projects as well as regulatory developments for mining application. However, hydrogen remains a demanding energy vector to use in confined, underground applications. Standardization and safety considerations are being addressed in the industrial consortium Hydrogen Mine Introduction Initiative (HMII). Research projects are being carried out to resolve the gaps for regulated use. This article focuses on HMII objectives and Project results. The first has reviewed the relevant codes and standards and mine regulations, indicating that hydrogen and fuel cells could be allowed underground and that current codes, especially the Canadian Hydrogen Installation Code would be sufficient for hydrogen use. The second project established the standard hydrogen storage and distribution architecture along with related risks and safety requirements for its use in the third project, using an underground test chamber to delineate the behaviour of hydrogen leaks in confined conditions with various ventilation regimes and ignition studies. This project will end in 2013. It will be followed by the last project, which will establish best practices in support of regulations development, and develop the ISO standard for mine hydrogen infrastructure and underground application.

Aug 1, 2013

By M. Sommerfeld, U. Schwarz-Schampera, B. Friedrich, D. Friedmann

The steadily growing demand for metals and their price increase at metal exchanges make the mining and utilization of marine mineral resources like polymetallic nodules, manganese crusts or sulfide deposits in the near future a viable option to potentially increase the supply of base and precious metals. For a country with low potential to mine land-based resources like Germany, the industrial recovery of metals from marine mineral resources could lead to a decreased dependency on imports. In this study, seafloor massive sulfides from the German license area in the Indian Ocean (Kairei field, Southern Central Indian Ridge) are treated to recover copper and precious metals. The aim of the project is to demonstrate the transferability of existing metallurgical techniques to the raw material of deep-sea massive sulfides. As a starting point to process this unconventional resource, samples from the Indian Ocean are chemically analyzed and mineralogical characterized. A comparison is carried out between the samples and land-based copper resources, to highlight the potential which lies in mining the deep-sea floor. This paper will show the general possibility of applying a two-stage pyrometallurgical process, based on a concentrate smelting operation, followed by a converting operation in lab-scale to the provided samples of massive sulfides. Generated slag from the concentrate smelting and the converting operation are investigated by X-ray diffraction to determine the mineralogical composition. The two-stage pyrometallurgical process is investigated by the thermochemical modelling tool FactSageTM 7.2 to evaluate the phase distribution of relevant elements between the metal, matte, slag and gas phase. The thermochemical boundaries of the pyrometallurgical process are therefore set and the results of the thermochemical study can be used as an indicator for the efficiency of an up-scaled process and the generated amount of side-streams, which need to be further treated or circulated back into the process. INTRODUCTION Seafloor massive sulfides (SMS) are the third kind of discovered deep-sea minerals besides ferromanganese nodules and cobalt-rich ferromanganese crusts (Sharma, 2017). They occur in water depths around 250–4,000 m (Koschinsky et al., 2018). SMS are characterized by a high base metal and sulfide content. They were created by fluid circulation and hydrothermal convection over time (Han et al., 2018). Commonly, areas rich in SMS are associated with hydrothermal vent fields on the seafloor (Keith et al., 2018).

Jan 1, 2019