Search Documents

By Sandford S. Cole

Manganese compounds occur in many mineral forms widely distributed throughout the crust of the earth. The most important of these commercially are the oxides which are usually found as irregular masses, but in some places (notably U.S.S.R.) occur as extensive beds of varying thickness and purity. The principal sources of ore have been U.S.S.R., Ghana (the Gold Coast of Africa), India, Union of South Africa, Belgian Congo, French Morocco, Cuba, Brazil, and Mexico. New developments of ore are being conducted in Brazil, British Guiana, French Equatorial Africa, and Northern Rhodesia. The production of the United States normally meets less than 10 pct of domestic manganese consumption. Manganese ore (35 pct or more Mn) is used principally by the ferrous metallurgy industry for production of manganese metal, ferromanganese, and other manganese alloys for use in production of steel ingots and castings. Some manganese is used in the nonferrous industry as an alloying element and cleanser in aluminum alloys, aluminum bronze, constantan, manganese bronze, Monel, Everdur, nickel-chromium resistance alloys, and nickel-silver. The metallurgical uses consume about 97 pct of the total manganese ore requirements of the United States. The balance goes principally for the manufacture of dry cells and for chemicals, with limited amounts for ceramic products, plastics, welding rods and varnish. The Materials Survey on Manganese, compiled in 1952 for Materials Office National Security Resources Board by the Bureau of Mines and Geological Survey, provides an excellent review of resources, reserves, specifications, uses, mining, beneficiation, metallurgical processes and deposits, and is worth referring to for greater details. Mineralogy and Geology The more common manganese minerals with typical characteristics are listed in Table 1 in order of importance. [ ]

Jan 1, 1960

By Thomas O. Breitling

The Mill Design Session at the Annual Meeting in New York next February will have a total of four papers. All of these papers will be concerned with the subject of in-plant dust in the hard-rock mining industry. The emphasis on efficient dust collection is timely, because dust is a problem not yet adequately covered in AIME papers. In general, dust collection should be the step following dust suppression. Dust collection and its return to the ore recovery circuit, or its waste to tailing are sources of added operating cost. If possible, dust should be kept in the main stream of ore flow by suppression.

Jan 1, 1970

By J. L. Christie, W. R. Webster, R. S. Pratt

Since the delivery of our paper on Some Comparative Properties of Tough-pitch and Phosphorized Copper,1 a new brand known as "oxygen-free high-conductivity copper" (brand OFHC) has become available to consumers. It was thought desirable to make a comparison between the properties of this material and those of the materials covered by our original paper and its discussion. Preliminary tests had indicated some notable differences. A billet of oxygen-free high-conductivity copper was taken from regular production. A chemical analysis of the particular billet was not made, but the producer of the material has given as typical the analysis shown in Table 1. The

Jan 1, 1933

New York Meets first Wednesday after first Tuesday of each month. DAVID H. BROWNE, Chairman. PERCY E. BARBOUR, Vice-Chairman. A. D. BEERS, Secretary, 55 Wall St., Now York, N. Y. C. A. BOHN, Treasurer. Boston Meets first Monday of each winter month. W. E. C. EUSTIS. Chairman. R. L. AGASSIZ, Vice-Chairman. E. E. BUGBEE, Secretary-Treasurer, Mass. Inst. of Technology, Boston, Mass. ALBERT SAUVEUR, H. L. SMYTH. Columbia Holds four sessions during year. Annualmeeting in September or October. STANLY A. EASTON,- Chairman FREDERIC KEFFER,-Vice-Chairman: LYNDON K. ARMSTRONG, Secretary-Treasurer, P.O. Drawer 2154, Spokane, Wash. D. C. LIVINGSTON, FRANK A. ROSS.

Jan 10, 1916

By S. E. Bretherton

Discussion of the paper of S. E. BRETHERTON, presented at. the San Francisco meeting, September, 1915, and printed in Bulletin No. 104, August, 1915, pp. 1595 to1599. ANTON EILERS, Brooklyn, N. Y. (communication to the Secretary*). While the advantages in the use of high-line siliceous slags in lead smelting which Mr. Bretherton discusses in this paper are obvious under certain economical conditions, he gives me credit for the introduction of such slags when it does not belong to me. It is true I did considerable experimental work, off and on, for the purpose of finding such slags, while at the Germania in 1877 and 1878, but I did not have occasion to introduce any such slags for regular work, because I had no ores which fitted the economical conditions for using high silica and high lime, except in isolated cases for very brief periods. On the contrary, the ores I had to treat were mostly very ferruginous and very low in silica, so that, economically, I was compelled to run nearly always on slags, which allowed me to use the abundant flux I had without cost. It was August Raht who first had occasion to establish and use for long periods a slag high in silica and line, and low in iron. This was when he was confronted with the task of smelting the. Horn-Silver ores at the smelting works at Franklin, Utah, with as little expenditure for fluxing material as possible. I was at that time in Leadville, Col., where, in the new works I had built, the Billings and Eilers smelters, I had occasion to use profitably many slags, but never anything as high in the earthy bases and in silica as Mr. Raht had to use.

Jan 12, 1915

Alfred E. Hunt, Pittsburgh, Pa. (communication to the Secretary): Mr. Blue's statement (page 576) that, " owing to the presence of iron and other impurities, makers of aluminum. assert that native corundum is unsuited for the production of that metal," is somewhat incorrect, at least so far as it may refer to any objection made by the officials of the Pittsburgh Reduction Co. to the Canadian corundums. We recognize corundum as among the richest and purest of the ores of aluminum, and the material furnished from Canada would offer for us the advantage of a supply near to our works for the manufacture of aluminum at Niagara Falls. The real difficulty which we find in the use of corundum for this manufacture is the cost of the raw material as compared with that of native bauxites. In this item we include not only, the price of the corundum as it has been offered to us, but also the expense of grinding it to an impalpable powder, which must be done before it can be used directly in the manufacture of aluminum, and the cost of preliminary chemical treatment for purification—which latter operation, however, is also required for bauxite. I agree with Mr. Blue that the introduction of new and irnproved processes has greatly reduced, during the past ten years, the cost of manufacturing aluminum; but I am inclined to believe that any further improvements, facilitating the use of corundum for this purpose, would apply, in equal or greater degree, to the common clays (silicates of aluminum) which exist in all parts of the world, are more easily mined and handled, and are likely to be always cheaper per unit of aluminum than any corundum.

Jan 1, 1899

By A. E. H. Bergmann

INTRODUCTION The Sachtleben Chemie GmbH in Duisburg, a subsidiary of the Metallgesellschaft AG, operates a new sulfuric acid plant that employs fluid bed roasting of pyrite concentrates. The plant produces about 300,000 tons per year of pyrite cinders from the fluid bed roasting unit. The cinder product consists of 58 percent iron and is about 80 percent by weight smaller than 50 microns. This cinder product was found to be a competitive source material for the cement industry as the iron-containing additive. However, the extreme fineness of the cinder and its dusting tendency were undesirable and an agglomerating technique became necessary. In order to keep the price of agglomerated pyrite-cinders at a competitive level, the agglomerating method must be chosen such a way the capital and operating costs are low. Initial experiments were carried out on a laboratory scale to make an appropriate choice of the agglomerating method. Major goals of agglomerating the cinders were to improve the transportation, storage, and proportioning and metering properties. Minimum specifications are put on the size, size distribution and shape of the product. Criterion for handling is that a minimum of minus one mm. fines are produced after several handlings, while for storage, it is also desirable for the agglomerated product to survive several months in open air. Thermal agglomeration processes such as sintering one known to produce excellent products, but are by far too expensive for our application. For the same reason, granulation, balling, and pelletizing tests with addition of organic binding agents, such as tylose, starch, sulfite wash, molasses, etc. were not continued. The costs for the binding agent was considerable, which is probably due to the high pore volume of our cinders (35 %). Furthermore, the pellets or granules

Jan 1, 1977

By D. Perry, G. W. Binkley, G. K. Dumbauld, F. A. Brooks

A new cementing technique has been developed which is particularly applicable to permanent-type well completion operations. The technique makes use of the accelerating effect of calcium chloride on setting time and strength development of cement cake deposited in squeeze cementing. An unique feature is that the accelerator is applied after the unaccelera-ted cement slurry has been squeezed and the excess has been reversed from the well. Laboratory data on the accelerating effect of calcium chloride applied to the fi1ter cakes of three low-water-loss cementing compositions demorzstrate that the procedure results in relatively rapid development of strength and impermeability of the cement cake. Simulated squeeze-ceinenting tests made in the laboratory likewise corroborated the practicality of the procedure. The laboratory tests showed that a newly developed oil-emulsion cemerzting composition is more susceptible to acceleration of set than are modified cements containing high percentages of bentonite. The acceleration procedure has been used successfully in field operations. INTRODUCTION Nature of Problem In squeeze-cementing operations, a substantial amount of time is consumed in waiting on the cement to develop strength after it has been squeezed into the well. Frequently, an interval of 18 to 24 hours or longer is required for the development of strength sufficient to prevent failure of the cement during subsequent operations in the well. Reduction of this waiting-on-cement time offers appreciable savings both in time and in money. A particular type of squeeze-cementing operation to which an increasing amount of attention has been given is encountered in permanent-type well completion operations wherein perforations are to be squeezed off1. In this procedure, it is customary to pump the cement slurry down the tubing and out into the perforated section through a retractable extension pipe. Squeeze pressure is then applied, which forces the cement slurry into the perforations and causes the build up of a compact filter cake of cement within the perforations. The excess slurry remaining in the hole is then removed by reverse circulation. The extension pipe is then retracted, and, if a new interval is to be perforated, a perforating gun is run through the tubing. The newly perforated interval may then be tested by swabbing. In such operations, it has been customary to allow approximately 20 hours or so for hardening of the cement squeezed into the perforations. This time interval is usually measured from the time that the cement is reversed out of the hole to the time that subsequent swabbing is started. If the cement has not developed strength at the commencement of swabbing, the pressure differential caused by swabbing results in failure of the squeeze job. At the time that the work described in this report was initiated, particular consideration was given to the reduction of waiting-on-cement time in squeeze cementing by the permanent-type completion technique. Consequently, much of the experimental work was directed to this specific objective, though the process which was developed for acceleration of strength development has possible application in other than permanent-type completion operations. Method of Attack Although quick-setting cements

Jan 1, 1957

By H. C. Gatos, Ahmed Azzam

A UTORADIOGRAPHY would appear to be sim-A pler and less time-consuming for diffusion studies than any of the radioactive tracer techniques commonly employed, namely, the sectioning, surface increase, and surface decrease techniques.' Accord- ingly, it was felt worthwhile to investigate the applicability of autoradiography to self-diffusion measurements, and gold was chosen for this purpose. The radioactive isotope Au'!'' was used, as obtained from the Brookhaven National Laboratory. Its radiation consists of p (0.97 mev) and y (0.41 mev) rays, and it has a half-life of 2.69 days. No-Screen X-ray film was found suitable for these experiments: the film has the desired high speed for recording P rays and yet is practically insensitive to y rays. On the other hand, due to the high atomic weight of gold, this metal is a strong absorber for p rays. The

Jan 1, 1953

By Colin Fink

THE important developments within the past few years in electrochemistry, in particular in the electric furnace art, in electrometallurgy and in the methods of combatting corrosion are to be the subjects of my discussion. Fig.1 shows the rise of the electric steel furnace industry in this country and Canada. Many prophesied that the electric furnace was largely a war baby and that the sudden rise in the industry, due to the outbreak of the great war, would be fol-lowed by an equally sudden drop after the armistice. However, the curve shows that this, prophecy was not correct; the number of furnaces in operation in this country and Canada has continued to increase steadily, so that at the end of 1925 there were over 525 electric steel furnaces in successful operation. What does this mean? It has a big significance, namely that the en-tire steel industry has been revolutionized, to a certain extent, that we have been able to introduce certain alloys and steel products that we were unable to pro-duce before. On the table is. a sample of metallic chro-mium, analyzing more than 98 per cent chromium, made in the electric furnace. Before the war, the only commercial method of producing chromium was that by the Goldschmidt process. If chromium oxide is mixed with granulated aluminum, a violent reaction occurs, resulting in the production of metallic chro-mium. However, the price of chromium so made will always be above that of the raw material, which at the present time is about 27 cents a pound.. Furthermore, the chromium metal could only be turned out in small quantities, whereas in the electric furnace, large quan-tities, ton masses, can be produced today. The advent of chromium produced in the electric furnace has brought about an entire new phase in the alloy indus-try. The fuel-fired furnaces can turn out a low-carbon chromium steel that runs about 3 per cent chromium, whereas in the electric furnace, 60 per cent ferro-chromium is daily produced in large masses with almost entire elimination of carbon. It is difficult indeed to turn out ferrochrome very low in carbon. New steels are being produced today, for example the steel with which everyone has become familiar within the 'last few years, "stainless steel,". and which would have been impossible without the low-carbon ferrochrome. The elimination of most of the carbon made it possible to roll the chromium steels into thin sheets and manu-facture them into knife blades.

Jan 2, 1927

By R. G. Grieves, G. Thodos

A method is presented for the accurate calculation of the cricondentherm and cricondenbar pressures of multicomponent hydrocarbon mixtures of known composition. The mixtures may contain six and quite possibly any number of components including paraffins, isoparaffins, olefins, acetylenes, naphthenes and aromatics. The approach is similur to that used for calculating critical pressures and cricondentherm and cricondenbar temperatures. The critical pressure, the normal boiling point and the approximate vapor pressure behavior of each component are all that art required. A stepwise culculation procedure is necessary for mixtures containing more than two components. From an analysis of 22 binary systems and 118 mixtures, the average deviation of calculated cricondentherm pressures from reported values is 2.4 per cent. For nine multicomponent mixtures the average deviation is 1 per cent. Considering 19 binary systems and 108 mixtures, the average deviation of calculated cricondenbar pressures from reported values is 1.7 per cent. For 15 multi-component mixtures, the average deviation is 2.2 per cent. INTRODUCTION A knowledge of the phase behavior in the critical region of multicomponent hydrocarbon mixtures is of value both in industrial processing operations and for the optimum operation of gas condensate reservoirs. Accurate methods of calculating the critical temperatures and critical pressures4,6,7,8,9,23 and cricondentherm and cricondenbar temperatures6p10 of multicomponent hydrocarbon mixtures are available in the literature. If the cricondentherm and cricondenbar pressures could be calculated with equal accuracy, the entire phase diagram of a multicomponent hydrocarbon mixture could be well approximated. The work of Etter and Kay6 is limited to systems containing the normal paraffins and has not been tested on systems containing a heavier component than heptane. In addition, the development of their multicomponent equations is based upon a limited number of mixtures containing from three to six components. Silverman and Thodos have considered systems containing both paraffinic and non-paraffinic hydrocarbons, but their correlation is limited to binary systems and is highly inaccurate for methane systems. Eilerts has done extensive work on the cricondenbar pressure; he has produced an excellent correlation for binary systems. However, his procedure for multicomponent mixtures is chiefly useful for highly complex mixtures requiring a knowledge of the vapor-liquid equilibrium behavior of the mixtures; he has not considered the cricondentherm pressure. The objective of this study was the development of an accurate and rapid method for the calculation of the cricondentherm and cricondenbar pressures of multicomponent mixtures containing all types of hydrocarbons and having a wide volatility range. The approach that was adopted is similar to that used by Grieves and Thodos for cricondentherm and cricondenbar temperaturesl0 and for critical pressures.9 However, methane systems had to be considered separately and a modified stepwise calculation procedure was utilized for the cricondertherm pressure. The correlations were developed in a manner similar to those for critical pressures and cricondentherm and cricondenbar temperatures. Based upon binary data reported in the literature it was observed that the ratios of cricondentherm and cricondenbar pressure to the pseudocritical pressure (molar average), pt/ppc and pp/ppc, respectively, in two-component systems depended upon the mole fraction of the low-boiling component and upon the diversity in properties of the two components. A dimensionless boiling-point parameter Tb,/Tb was chosen to represent the diversity in properties of the components. For a binary system, Ti,'is the molar average of the normal boiling points of the two components involved. For a multicomponent system it is either the molar average of the normal boiling points of all of the components involved or the molar average of the normal boiling point of the pure low-boiling component and of the atmospheric boiling point of the low-boiling-free mixture of

Jan 1, 1965

The American Gas Association, 420 Lexington Ave., New York, N. Y. The Proceedings and Reports of the American Gas Association are concerned with the technology and utilization of gas, and research along those lines. A list of publications will be sent upon request. Publications are classified under the general headings: Accident Prevention; Accounting; Commercial; General; Rates; Industrial; Publicity and Advertising; Technical; and Testing Laboratory. As' illustrations of the type of paper presented, the following are cited from the Technical classification: Evaluation of gas oils (1930), 40 cents; Agglutinating value of American coals (1927), free; Composition of coal in relation to spontaneous combustion (1927), free; Physical and chemical

Jan 1, 1933

Magazine, Advertising $ 32,823 60 Sale of Magazines 3,93329 Total Magazine $ 36,756 89 Dues, 'Arrears 5,866 97 Dues Current 100,223 80 Dues of New Members 6,143 29 Dues in advance 1,586 32 Initiation fees 6,820 00 Sale of Transactions 5,464 99 Sale of Binding 5,618 90 Sale of Pyrometry Volume 336 30 Sale of Indexes and Emmons 106 10 Sale of Pamphlets 575 32 Miscellaneous Receipts 105 60 Interest on Bank Balances 1,217 67 Interest on Life Membership Investment 512 18 Interest on James Douglas Library Fund 5,678 67 Total Receipts $177,013 00

Jan 1, 1923

[Year of Election to Honorary Membership 1876. PROF. RICHARD AKERMAN Stockholm, Sweden. 1913. DR. FRANK DAWSON ADAMS Montreal, Canada. 1920. HENRY STURGIS DRINKER Bethlehem, Pa. 1888. PROF. HATON DE LA GOUPILLIERE Paris, France. 1906. SIR ROBERT A. HADFIELD London, England. 1917. HERBERT HOOVER Stanford University, Cal. 1919. ROBERT W. HUNT Chicago, 111. 1915. JAMES FURMAN KEMP New York, N. Y. 1905. PROF. HENRI Louis LE CHATELIER Paris, France. 1913. EZEQUIEL ORDOENEZ Mexico City, Mexico. 1909. ALEXANDRE POURCEL Paris, France. 1911. ROBERT H. RICHARDS Boston, Mass. 1906. JOHN E. STEAD Middlesbrough, England. 1902. PROF. DIMITRY CONSTANTIN TSCHERNOFF Petrograd, Russia. 1907. CHARLES D. WALCOTT Washington, D. C.] [ ]

Jan 1, 1925

[Year or HONORARY MEMBERS Election 1876. PROF. RICHARD AKERMAN Stockholm, Sweden. 1913. DR. FRANK DAWSON ADAMS Montreal,. Canada. 1888. PROF. HATON DE LA GOUPILLIERE Paris, France. 1906. SIR ROBERT A. HADFIELD London, England. 1896. HERBERT HOOVER Stanford University, Cal. 1874. ROBERT W. HUNT Chicago, Ill. 1915. JAMES FURMAN KEMP New York, N. Y. 1905. PROF. HENRI Louis LE CHATELIER Paris, France. 1918. EZEQUIEL OBDONEZ Mexico City, Mexico. 1909. ALEXANDRE POUBCEL Paris, France. 1911.. PROF. ROBERT H. RICHARDS Boston, Mass. . 1906. JOHN E. STEAD Middlesbrough, England. 1902. PROF. DIMITRY CONSTANTIN TSCHERNOFF Petrograd, Russia. 1910. PROF. TSUNASHIRO WADA Tokyo, Japan. 1907. CHARLES D. WALCOTT Washington, D. C.] [ ]

Jan 1, 1925

A PROSPECTOR stood atop a Venezuelan mountain called El Florero just 25 years ago, and shouted to the world that he had found a large, rich new source of iron ore. But his words were lost in the big green South American jungles and besides, the world had more iron ore than it could handle. There were no crises in 1926, no major wars on the horizon, no worries about mineral supplies. In the U. S., the populace was "keeping cool with Coolidge," and the solid foundation of the economy-the steel industry-rested on a still firmer basis, the Lake Superior iron ores.

Jan 5, 1951

NEW MEMBERS. The following list comprises the names of those persons who became members during the month of October, 1913: Members. BARNES, KENNETT F., Secty Granby Min. & Smelting Co., St. Louis, Mo. BILLINGSLEY, PAUL, Geol 526 Hennessy Bldg., Butte, Mont. BLANCHORD, RALPH C., Geol 3 Lombard St., London, England. BOYLE, ALBERT C., Jr., Prof. of Min. and Met., University of Wyoming, Laramie, Wyo. BRADFORD, JULIUS S., Min. Engr Chiksan Mining Co., Chiksan, Korea: CLEMES, ALFRED W., Min. Engr P. 0. Box 6,88, Moronic, Ariz. COPELAND, DURWARD, Met Cia. Estamifera de Llallagua, Bolivia, So. America. CRAWFORD, JOHN, JR., Mgr Noble Elec. Steel Co., Heroult, Shasta Co., Cal.

Jan 11, 1913

By D. L. Wood

INTERNAL oxidation of alloys has been investigated by Rhinesl,2 and by Meijering and Druy-vesteyn. Rhines showed that dilute Cu-A1 alloys can be internally oxidized without forming an external scale by annealing in an oxygen partial pressure equal to the decomposition pressure of Cu2O. The oxygen is supplied at the outside surface at a rate sufficient to maintain saturation of the surface with respect to oxygen. Oxygen diffuses inward and, at the interface between the subscale and the alloy, oxygen meets the solute and reacts to precipitate its

Jan 1, 1957

US 4,194,902 - Pig iron or other molten lion is effectlvely desulfurized by treatment with a mixture preferably about 60% by weight commercial grade calcium carbide, 30% dried limestone diamide, and the remainder bituminous coal. Equivalent desulfurization is obtained using a significantly lesser amount of desulfurizer than in previous mixture of calcium carbide and limestone diamide W Gmohling, assigned to SKW Trostberg AG. Mar 25, 1980. 3 pp. (75-55) Filed: 9-12-78 (941,659) Priority. West Germany, 9-15-77 (2,741,588). Same. British 2,008,153, dated May 31, 1979.

Jan 1, 1982

By William E. Ford, Edward Salisbury Dana

The Nitrates being largely soluble in water play but an unimportant r81e i~ Mineralogy. SODA NITER. Rhombohedral. Axis c = 0.8276; rr" 1071 A 7101 = 73' 30'. Homeo- morphous with calcite. Usually massive form, as an incrustation or in beds. Cleavage: r (1011) perfect. Fracture conchoidal, seldom observable. Rather sectile. H. = 1.5-2. G. = 2'262.29. Luster vitreous. Color white; also reddish brown, gray and lemon-yellow. Transparent. Taste cooling. Optically -. w = 1'5874, e = 1'3361. Camp. - Sodium nitrate, NaN03 = Nitrogen pentoxide 63'5, soda 36'5 = 100.

Jan 1, 1922