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By K. N. Han, X. Xie

The dissolution behavior of palladium powder in thiourea solutions was investigated. The variables studied were temperature, stirring speed and the concentrations of thiourea, acid and ferric ion. Palladium was found to be soluble in thiourea solutions in the presence of an oxidant such as ferric ion. The dissolution of palladium in thiourea solutions was believed to be chemical-reaction controlled, with an apparent activation energy of about 25.3 kJ/mol.

Jan 1, 1997

By Thomas D. Henderson

Este capítulo presenta- un "caso histórico" de los pasos a dar para estimar IDS castes de capital y operativos para un concentrador típico de cobre porfirico de ± 9;070 toneladas métricas de producción diaria. El concentrador que se describe es hipotético, pero está basado en la experiencia propia y es, en efecto, una composición de varios proyectos reales. Las cifras utilizadas son ilustrativas solamente y no representan los castes reales de ningún lavadero en particular. Estas cifras son, sin embargo, representativas de los castes tipicos de molienda en un punto en el tiempo y son to suficientemente precisas coma para iIustrar los procedimientos de estimación de castes descriIos en este capítulo, No es posible publicar cifras reales y corrientes de los castes del lavadero y, en cualquier caso, las cifras de Ios castes reales pierden rápidamente su significación en Ia actual situación económica con los rápidos incrementos de las diversas partidas que configuran los castes. El trabajo está dividido en tres partes: (1) orden de la magnitud estimada, (2) estimación def estudio de viabilidad, y (3) comparación entre los castes estimados y los castes rea¬les. Con vistas a este trabajo supondremas que una mina tiene una propiedad minera explorada mediante perforación con testigos que refleja un yacimiento, ampliamente definido, como de unas 45,3 millones de toneladas métricas con una ley del d,6°/ de sulfuro de cobre, Esta compañia desea obtener primero una estimación del orden de magnitud de los costes (canto de los costes operativos como del capital) para determinar si la pertenencia garantiza más perforación y desmuestre de testigos. Suponiendo que esta evaluación económica obtenida utiIizando Ia orden de Ia magnitud de Ios costes sea favorable, sera a continuación requerido un estudio de viabilidad más preciso de los castes de capital y operativos. Seguidamente of recemas una descripción de los diferentes pasos dadospara desarrollar ]as costes del orden de primera magnitud y a continuación para los castes del estudio de viabilidad.

Jan 1, 1982

By S. K. Kawatra, R. A. Seitz

Nonpolar hydrocarbon oils are commonly used in the flotation of minerals to fulfill a number of roles. These roles include reducing overall reagent costs by replacing part of the collector addition, improving coarse particle recovery without reducing selectivity, as well as several others. This paper will cover the types of oils which are available, their physical and chemical characteristics, and the effect of these characteristics on the function of hydrocarbon oils in flotation. In addition, techniques for improving the behavior of oils will be discussed.

Jan 1, 1986

By Hazal Melis Aytac, Lana Alagha, Fardis Nakhaei

Gallium (Ga) and Germanium (Ge) are essential strategic elements that are extensively used as semiconductors in many technological fields. Owing to their essential uses and supply disruption, Ga and Ge are deemed critical by the U.S. They are typically found as substitutions or inclusions in zinc minerals. However, their distributions within zinc minerals are not well understood. To address this, trace element and mineralogy analyses of representative samples obtained from an old high-zinc-grade tailing were performed using various qualitative and quantitative techniques. These techniques included Inductively Coupled Plasma Mass Spectrometry (ICP-MS), Tescan Integrated Mineralogical Analysis (TIMA) with Scanning Electron Microscopy (SEM) and X-ray Diffraction (XRD). Moreover, bench-scale froth flotation tests were conducted to enrich zinc minerals, the major hosts of Ga and Ge, using PAX as a collector, Na2S as a sulfidizer, Pb(NO3)2 as an activator, and MIBC as a frother. Comprehensive characterization analyses of the flotation products showed significant enrichment of Zn, Ga and Ge in the flotation concentrates.

Feb 1, 2025

By G. Raspa

This article describes a procedure for calculating the recoverable reserves of stratified orebodies characterised by a thin and irregular layers. An application on the phosphate deposits in the N'Zeto region of the Popular Republic of Angola is also described. The procedure consists in building a block model of the deposit through the conditioned multivarial geostatistical simulation of small areal units. The recoverable reserves are then calculated and defined by applying to the model a selection processes based on measured geological/economic parameters taken from the drillholes: thickness of overburden and mineralised layers, economic grain-size fraction, grade. The procedure also takes account both of the geometrical constraints of the mining method and dilution. For reasons of confidentiality, a multiplier has been applied to the values adopted for the sampling data.

Jan 1, 1992

By S. K. Mishra, S. B. Kanungo

Because conventional (physical) methods of ore dressing are not suitable for reducing the phosphorus contents of high-phosphorous manganese ores from Andhra Pradesh (AP) and the adjoining area in southern Orissa, India, the adoption of chemical methods becomes imperative. An attempt was therefore made to reduce the phosphorus content of partially beneficiated manganese ores from AP by roasting with sodium carbonate and then leaching with hot water. However, due to the higher phosphorus contents of the manganese ores from Nishikhal mines in southern Orissa, and because of their apparent resistance to dephosphorization by roasting with Na2CO3 alone, a mixture of Na2CO3 and NaCl was found to be necessary to reduce the phosphorus content to below 0.15%. Free-energy calculations at 700°C and above indicated that Na2CO3 (or Na2O as the active component) is a more active reagent than NaCl. Various process parameters, such as the temperature and time of roasting, the amount of sodium carbonate and the temperature and time of leaching, were studied to arrive at the optimum conditions for dephosphorization.

Jan 1, 2000

By J. Hanna, R. Kalathur

Over the years, Alabama's coal industry has generated, during mining and cleaning operations, about 150 million st of fine waste coal, with this total increasing at a rate of 2 million stpy. Reclamation of the fine-size wastes (containing 20% - 60% clean coal by weight) provides, free of charge, mined and crushed feed stocks for coal recovery. Also, the removal or recovery of pyrite from the tailings should eliminate a major source of acid-water pollution. Tests were made on the impounded wastes and current plant discharges to recover the coal fraction by sizing, gravity and flotation techniques. Gravity separation of the +100-mesh material produced commercial-grade coal averaging 7.6% ash, 0.8% sulfur and 13,471 Btu/lb. However, the coal yield, at about 31 % - 56%, was relatively low. Froth flotation, using mechanical and froth column methods, gave similar coal products at much higher coal recovery rates of 87% - 93%. This coal analyzed 10% ash and 1.1% sulfur.

Jan 1, 1993

By Clyde L. Smith

Since the early 1950's exploration in the Yukon Territory, Canada, has been confined largely to Selwyn basin where at least five large stratiform or massive sulfide Pb-Zn deposits have been discovered. The five ore bodies total nearly 100 million tons of 10-16% combined Pb-Zn with 1-3 oz./ton Ag. The only deposit currently in production is the Anvil Mine operating at 8,000 tons per day. Beginning in 1972, exploration in the Mackenzie Mountains, east of Selwyn basin and west of Mackenzie arch, resulted in finds of Mississippi Valley type Zn-Pb mineralization in a belt of Proterozoic and Lower Paleozoic carbonate rocks (Figure 1). Four districts have been located and intensive exploration by numerous Canadian and Arnerican mining companies is currently in progress over a length of 400 miles in the carbonate belt. The consensus is that a major new Zn-Pb province may be taking shape.

Jan 1, 1974

By Tanya Arsh, Thomas P. Kwiatkowski, Heather Marsh, Barry Doyle

The Big Walnut Sanitary Trunk Sewer Extension Project consists of two segments, the first a 10' excavated diameter tunnel in rock through the gas producing Ohio Shale formation and the second will be microtunneled through unconsolidated water-bearing deposits. Relatively large quantities of methane gas have been encountered in the Ohio Shale. In the softground segment, the sands and gravels contain large water storage capacity and contain shallow residential wells. This paper will present an evaluation of potential gas inflows in the rock tunnel, design considerations for contract documents preparation to inform bidders as to the volumes of gases which may been countered and design options for construction of an impermeable shaft excavation support system to insure residential wells remain in service.

Jan 1, 2001

By Joseph L. Condon

The U.S. Department of the Interior, Bureau of Mines, is doing research on methods to obtain premining information on problems such as detection of old mine workings, abandoned oil wells, channel sands, faults, and other geologic features that are undesirable from a production or safety aspect. Techniques being developed to acquire the necessary information include seismic and electromagnetic. The seismic methods include high-resolution seismic and acoustic methods applied from the surface and inseam channel waves applied under- ground. The electromagnetic, or radar, methods are applied from the surface, from boreholes, and from the working face underground. All of these methods are useful under certain site-specific conditions, but none of these methods is universally applicable for all mining conditions.

Jan 1, 1980

By Arthur C. Pincomb, Alan R. Shapiro

A public awareness of and commitment to abate pollution of water, air, and soil continues to stimulate demand for industrial minerals and rocks capable of neutralizing strong and weak acids. The role of acid neutralizing agents is 1) to treat acidified water and soil until the desired pH is attained and 2) to remove acid-forming compounds from industrial processes to mitigate the formation of acidic discharges. Environmental applications for these agents include: acid rain mitigation, neutralization and prevention of acidic industrial process discharges, and treatment of acid mine drainage and coal refuse. Desulfurization of industrial flue gases involves removal of sulfate compounds capable of combining with hydrogen to form acids. Details of flue gas desulfurization are covered in the previous chapter on Flue Gas Desulfurization. Ideally, the neutralization of acids results in an upward adjustment of effluent pH 7, or neutrality. The final pH value for many acid treated wastes, especially industrial discharge streams, is commonly over neutralized to pH 8.5 to 9.5. The Clean Water Act sets the upper discharge limit at pH 9. ACID NEUTRALIZATION REAGENTS Acid neutralization is accomplished by adding alkali metal and alkaline earth metal compounds to acidic water or soil until the desired pH is attained. The commonly used alkali ions are calcium (Ca), magnesium (Mg), sodium (Na), and potassium (K). Sodium hydroxide, high calcium and dolomitic hydrate, high calcium and dolomitic lime (quicklime), high calcium and dolomitic limestone, soda ash, and magnesium oxide are the compounds most commonly applied to raise the pH of acidic waters or soils. Limestone and dolomitic limestone, which are calcium and magnesium carbonates, and their equivalent oxides and hydrates formed by calcination, are the industrial materials most commonly used in the manufacture of reagents for acid neutralization. Approximately 327 kt of high calcium and dolomitic lime were consumed for acid neutralization purposes in 1988. Magnesite and brucite are industrial minerals that compete with dolomitic limestone for the magnesium-oxide market. Production of caustic calcined magnesia for neutralization purposes exceeded 6 kt in 1990. Soda ash is an industrial mineral gaining increased acceptance in the neutralization of acid waste discharges. Approximately 182 kt of soda ash were consumed in 1990 for acid waste treatment or acid prevention by flue gas desulfurization. Other mineral products either consumed in minor quantities or receiving attention as future neutralizing agents include zeolite and hectorite. In some cases, waste products have been found to be suitable and cost effective for neutralization of acids. Common wastes gaining acceptance include basic slag, phosphate mining refuse, cement kiln dust, fly ash, and mine tailings.

Jan 1, 1994

By H. Zhu

Qualitative and interpretative information as obtained from geological and/or geophysical studies, in addition to precise measurement, is incorporated into the estimation process through an indicator variable. The indicator conditioned estimator is formulated as a cokriging and its expression is data value dependent as opposed to that of the traditional kriging estimators. The solution of the dual cokriging system pro-vides simultaneously an estimate of the unknown and an estimate of the conditional probability that the unknown belongs to a specific population or class. Being an unbiased and minimum-error-variance estimator by construction, the indicator conditioned estimator is better in the least square sense than the ordinary kriging estimator because it uses additional information carried by the indicator data.

Jan 1, 1989

By Laurindo De Salles Leal Filho, Arthur Pinto Chaves

The Serrana Process was developed in the 60's to concentrate an igneous low grade phosphate/carbonate ore using tall oil as a collector and corn starch as a modifier in alkaline medium. Nowadays, although tall oil has already been substituted by a new amphoteric synthetic collector, starch hasn't been substituted yet. This study is an attempt towards understanding the role played by corn starch in this specific system. By means of bench scale flotation test, it was observed that corn starch was capable of promoting the flotation of apatite, phlogopite and dolomite. No effect over calcite was observed. The best efficiency of separation apatite/gangue minerals was yielded at the concentration ranges of 17 to 20 mg/l of starch and 13 to 17 mg/l of tall oil. The starch concentration showed a strong influence over the characteristics of the froth produced by the flotation tests, mainly over the volume of the froth and its mineralization.

Jan 1, 1993

By Jerry Grott

Southwest Salt Company is solution mining the Luke Salt Body of probable late Miocene age. The discovery hole, from which the first core was recovered, was drilled in 1968. The deposit was encountered at a depth of 880 feet, and the bit was still in salt at the bottom-hole depth of 4,500 feet. The solar ponds, developed on land formerly dedicated to agriculture, have an annual capacity of about 90,000 tons. Because land values are very high, mining rates and procedures are governed by the need for near-saturated brine to minimize land requirements. Because of the frequency of dust storms, the salt operation uses a unique wet-harvesting method. Most inventory is kept in the ponds under brine and harvested only a few days before shipment. Studies of the nature of crystal growth and the distribution of windblown and brine impurities led to the development of procedures for processing salt of high chemical purity and low insolubles content. Chemical purity exceeds that of most salt produced in fuel-fired evaporators. Salt is shipped from Phoenix as tar east as west Texas and as far west as central California. Occasional shipments have been made to Hawaii and Alaska.

Jan 1, 1987

By Huayang Luo, Hui Li, Wei Zhou, Gang Chen, Scott Huang

Abundant beach and offshore resources of gold deposits are demonstrated along the coast of Alaska, and Nome is one of the richest places. Considerable amounts of mineral resources data were collected and stored in geodatabase of ArcGIS. In searching for the best model for the interpretation of the Nome offshore gold placer deposit and accurate estimation of the reserve, the data were processed and visualized using ArcGIS. The gold concentration data collected from the Nome offshore deposit are of characteristics such that: (1) near lognormal distribution of data, (2) high positive skewed distribution, (3) a small number of extreme values dominating the reserve estimation, and (4) apparent anisotropy of the variogram. These characteristics make the development of an interpolation model for the gold deposit a challenging task. In this study, it is determined that five geostatistical methods provided by ArcGIS with visualization capability, i.e., Inverse Distance Weighted (IDW), Ordinary Kriging (OK), Ordinary Kriging with lognormal transformation (OK-log), Simple Kriging (SK) and Indicator Kriging (IK) are suitable candidates for the development of an interpolation model. The five algorithms are evaluated and compared with each other in the study. Cross-validation technique is employed to examine the accuracy of the five approaches. It is determined that the OK and SK algorithms are not suitable for this dataset because of the difficulty of fitting the semivariogram model despite their lower RMSE (Root-mean-square error) and the higher RMSS (Root-mean-square Standardized). The OK-log algorithm does not provide satisfactory prediction either, because it places too much weight on the role of extreme values resulting in overestimation and extremely high RMSE. Reserve estimation of each blocks is conducted using each of the interpolation methods and compared with the reserve calculated using the conventional polygon method. The IWD and IK algorithm seem to provide estimations more agreeable with the conventional polygon method.

Jan 1, 2005

By Donald C. Rotherham

The Endako, British Columbia, deposit was initially discovered in 1927 by two local men, Charles H. Foote and Alf Lagdon, who were at that time on a hunting expedition. Four mineral claims were located to cover an area of quartz-molybdenite float that was centered on two small ridges. They subsequently uncovered a 0.5-m (1.6-ft) wide vein on which an inclined shaft was sunk to a depth of 8.3 m (27.2 ft) in 1934. Additionally, a short adit was driven to intersect another vein. Numerous trenches and small pits were also dug. Small test shipments of vein material from this early work were sent to G.S. Eldridge and Co. in Vancouver for metallurgical testing. A concentrate assaying 89.2% MoS, was produced with a recovery reported as 93.3%. The concentrate was essentially free of copper, arsenic, and phosphate. The property was examined by many geologists and engineers during 1934 to 1952, but the only work done was undertaken by the owners in order to maintain their claims in good standing. In 1952, Kennco Explorations (Canada) Ltd. carried out a limited program of bulldozer trenching, sampling, and geological mapping before relin- quishing their option. In 1956, American Standard Mines Ltd. acquired an option on the property, but no assessment work was apparently recorded and the property was allowed to lapse. The key claims were restaked in 1959 by C. Riley and H.T. James of Vancouver. The property was optioned from the new owners by Andrew Robertson in July 1961, and a small amount of trenching was conducted. Robertson, on behalf of his own company, R & P Metals Corp., reoptioned the property in January 1962. The initial results of this work were favorable and justified further exploration. The additional finances required to continue the program resulted in the formation of Endako Mines Ltd. (N.P.L.) on June 21, 1962. Field work by R & P Metals and the first Endako Mines exploration was directed by Bob Couts.

Jan 1, 1991

By Carl R. Christiansen

Excellent underground industrial sites and warehouse facilities have been constructed in Europe and at several locations in the United States. Many quarry and mine operators are considering, or should consider, the possibilities of the development of their mineral properties in such a manner as to make underground space that is suitable for a secondary industrial use. Before proceeding with mine or quarry development, the operator should answer the following questions: 1) Is there a need for underground industrial space in your geographical area? 2) Is your deposit suitable for development of space for industrial usage? 3) If the deposit is suitable, what methods of development can be used? 4) What are the comparative economics of the different methods of space development? An honest analysis of the first two questions may eliminate the need for proceeding to the third. Affirmative answers to questions 1 and 2 should be followed by the engineering and economic studies required in response to questions 3 and 4.

Jan 1, 1975

By Gary P. Thomason

We have all heard a great deal about how various projects were financed or certain companies were successful in obtaining a bank loan. There are many more projects and companies who fail to get the money they need. At least a portion of these failures, and a large percentage of the frustrations connected with even the successful financings, are a result of not understanding the process of obtaining money. Recent years have seen a proliferation of sources available to finance minerals operations, but let me assure you that these represent only a minor portion of the minerals financing market. The fundamental source of borrowed money to almost all minerals related companies remains the banks. Therefore, understanding the "Loan Approval Process" can easily mean the difference between getting the money or not. In the following pages I hope to provide some insight into what I define as the loan approval process. Having pre-offered my definition, I intend to delineate the various stages of the process and the planning and information I believe should be contained in each. My ultimate goal is to help you think like a banker and, in so doing, stay on top of the process so that you can successfully obtain the funding necessary for your projects.

Jan 1, 1983

By L. A. Feldkamp, L. I. Davis, F. Yuan, G. V. Puskorius

Emerging technologies such as neural networks and fuzzy logic have many potential industrial applications in diagnostics, modeling, and control. In the automotive industry, applications can be divided into those that impact manufacturing processes and those that relate directly to the product. Though discussion often centers on neural networks deployed in hardware, their potential in the development of problem solutions (however deployed) could easily be of greater importance. Here we concentrate on the use of neural networks for modeling and control, using a simulation of vehicle active suspension as a concrete example.

Jan 1, 1993

By Steven A. Whittle, Robert E. Cook

Years ago, personal computers (PC) were pricey devices destined for who knows where in the process industry. Now their use runs the gamut from low end data acquisition systems to high performance windows into the process area. Their applications range from CAD, CAM, CIM, and CAE to factory floor scheduling, process planning QC, facility management, cell control, and publishing. This discussion traces the evolution of a zinc plant's control automation program beginning with a PC as an operator interface and migrating to higher level work stations. Included in this paper will be a discussion of an Open Industrial System and the role PCs have played in this facility.

Jan 1, 1993